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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

An examination of the performance of molecular dynamics force fields: Silicon and silicon dioxide reactive ion etching

Classical molecular dynamics (MD) simulations of plasma-surface interactions were performed of physical sputtering and reactive ion etching (RIE), with predictions based on several force fields. In this paper, we focus mainly on SiO 2 but include some results for Si substrates as well. Here, we compare predictions from these MD simulations to experimental studies of SiO 2 physical sputtering (by Ar + ions), RIE of Si, and RIE of SiO 2 (both using F atoms and Ar + ions). MD results using different published force fields are compared to reported yields from published vacuum beam experiments. The near-surface depth profiles predicted using different force fields are compared. One motivation for the present study is to document the nature and magnitude of differences in the predictions for selected systems and conditions of practical interest.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Binary pseudo-random array (BPRA) for inspection and calibration for cylindrical wavefront interferometry

High-accuracy metrology is vitally important in manufacturing ultra-high-quality free-form mirrors designed to manipulate X-ray light with nanometer-scale wavelengths. However, surface topography measurements are instrument dependent, and without the knowledge of how the instrument performs under the practical usage conditions, the measured data contain some degree of uncertainty. Binary Pseudo Random Array (BPRA) “white noise” artifact are effective and useful for characterizing the Instrument Transfer Function (ITF) of surface topography metrology tools and wavefront measurement instrument. BPRA artifact contains features with all spatial frequencies in the instrument bandpass with equal weight. As a result, power spectral density of the patterns has a deterministic white-noise-like character that allows direct determination of the ITF with uniform sensitivity over the entire spatial frequency range. The application examples include electron microscopes, x-ray microscopes, interferometric microscopes, and large field-of-view Fizeau Interferometers. Furthermore, we will introduce the application of BPRA method to characterizing the ITF of Cylindrical Wavefront Interferometry (CWI), by developing the BPRA artifact which matches the radius of curvature of the cylindrical wavefront. The data acquisition and analysis procedures for different applications of the ITF calibration technique developed are also discussed.

Munechika, K↗

A Numerical Study on the Impact of Cathode Catalyst Layer Loading on the Open Circuit Voltage

The open-circuit voltage (OCV) is the measured potential when no current is drawn from a cell. Additionally, theoretically this potential is given by the equilibrium potential, which is determined from thermodynamics based on the operating conditions. In practice, the actual potential at zero current is measured to be approximately 300 mV lower than the theoretical value.

42 ENGINEERING↗

Integration of a DER Management System in Riverside. Final report

The tasks in this project covered various aspects, including algorithm development, algorithm integration into a commercial Active Network Management (ANM) platform, hardware-in-the-loop (HIL) testing in an industry-standard testing platform, pilot demonstration in Riverside, California, and also cost and benefit analysis. The DERMS platform in this project can host different algorithms developed on different platforms (e.g., MATLAB and Python) and it can interact with different hardware devices (e.g., different PV inverters, battery inverters, and different sensors). The DER control solution are based on an advanced model-free, layered, and clustered DER control paradigm. At the core of the DER control algorithms was the concept of Extremum Seeking (ES), which is a model-free probing-based control technique. The ES-based control algorithms were tested on major real-world inverters; both individually and in a cluster. It was shown that even legacy equipment (or when paired with a few additional advanced equipment) can support such advanced control. The monitoring algorithms utilize a heterogeneous set of legacy and advanced sensor measurements, such as behind-the-meter DER sensors, distribution-level Phase Measurement Units, distribution-substation Supervisory Control and Data Acquisition (SCADA), and line current sensors, with their limited availability; in order to infer practical network conditions. Sensor data are utilized to achieve resource forecasting, phase identification, and distribution system state estimation. The technology that was developed and demonstrated in this project could be transformational to utilities, including the smaller municipal utilities such as in Riverside, which may not have the resources to deploy advanced distribution system and DERMS solutions in order to support high penetration of solar power integration. This project created a real-world prototype to provide utilities with an assessment of smart grid monitoring and control technologies.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Molecular Ionic Composites: A New Class of Polymer Electrolytes to Enable All-Solid-State and High-Voltage Lithium Batteries (Final Project Report for DOE EERE VTO grant EE0008860)

Based on a newly discovered class of solid PE materials, that is, molecular ionic composites (MICs), the major goal of this project is to develop solid-state lithium conductors targeted for use in transportation applications. MICs form a mechanically stiff, electrochemically stable, and thermally stable matrix. Specific objectives include the following: (1) development of robust MIC electrolyte thin films (~ 20 µm) to serve as simultaneous nonflammable separators and dendrite-blocking Li + conductors, (2) electrochemical quantification of key performance metrics including electrolyte stability, interfacial reactions, and suitability/compatibility with a range of electrode materials, and (3) comprehensive investigation of ion transport mechanisms and electrode-electrolyte interfacial reactivity under practical operating conditions using NMR and synchrotron X-ray analyses.

25 ENERGY STORAGE↗

Decarbonizing Cooking Appliances With Hydrogen

A novel hydrogen compatible heterogeneous burner prototype was engineered, fabricated, and evaluated for applications in cooking appliances. The key features targeted and accomplished under this effort included fuel flexibility, tolerance to high hydrogen concentrations (up to 85% in atmospheric design and 100% in premixed design), wide range of thermal power ratings, thermal cycling, reliability, and most importantly safety. The burner was operated in the range of 3000 – 12,000 Btu/h under all practical operating conditions (cold start, hot restart, fuel concentration variance). The heterogeneous oxidation burner technology was evaluated for overall performance targeting safety, reliability, emissions, fuel flexibility, and energy efficiency in a commercial RV and residential cooking range appliance prototypes. The burner demonstrated safe and reliable performance generating infrared heating energy without the consumption of any parasitic energy while using low-cost materials. Performance evaluation testing of the novel IR burner demonstrated fuel flexibility with hydrogen blended natural gas while significantly eliminating air pollutants like NOx and methane and increasing the energy efficiency by up to 20%.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Developing Stable Critical Materials and Microstructure for High-Flux and Efficient Hydrogen Production through Reversible Solid Oxide Cells

Reversible Solid Oxide Cells (RSOCs), which operate as either Solid Oxide Fuel Cells (SOFCs) or Solid Oxide Electrolytic Cells (SOECs), hold great promise for clean, high-efficiency energy conversion and hydrogen production. However, their commercial potential is hindered by stability issues arising from temperature-induced materials degradation. While substantial progress has been made in developing durable, reduced-temperature SOFCs - bringing them closer to commercial deployment, SOECs still exhibit substantially higher degradation rates at both the cell and stack levels under practical operating conditions.

08 HYDROGEN↗

Mass Transport in Membrane Systems: Flow Regime Identification by Fourier Analysis

The numerical calculation of local mass distributions in membrane systems by computational fluid dynamics (CFD) offers indispensable benefits. However, the concept to calculate such distributions in response to separate variations of operation conditions (OCs) makes it difficult to address overall, flow-physics-related questions, which require the consideration of the collective interaction of OCs. It is shown that such understanding-related relationships can be obtained by the analytical solution of the advection–diffusion equation considered. A Fourier series model (FSM) is presented, which provides exact solutions of an advection–diffusion equation for a wide range of OCs. On this basis, a new zeroth-order model is developed, which is very simple and as accurate as the complete FSM for all conditions of practical relevance. Advection-dominated blocked and diffusion-dominated unblocked flow regimes are identified (depending on a Péclet number which compares the flow geometry with a length scale imposed by the flow), which implies relevant requirements for the use of lab results for pilot- and full-scale applications. Analyses reveal the equivalence of variations of OCs, which offers a variety of options to accomplish desired flow regime changes.

Heinz, Stefan (ORCID:0000000248712416)↗

Investigating the relationship between simulation parameters and flow variables in simulating atmospheric gravity waves for wind energy applications

Wind farms, particularly offshore clusters, are becoming larger than ever before. Besides influencing the surface wind flow and the inflow for downstream wind farms, large wind farms can trigger atmospheric gravity waves in the inversion layer and the free atmosphere aloft. Wind-farm-induced gravity waves can cause adverse pressure gradients upstream of the wind farm, which contribute to the global blockage effect, and can induce favorable pressure gradients above and downstream of the wind farm that enhance wake recovery. Numerical modeling is a powerful means of studying these wind-farm-induced atmospheric gravity waves, but it comes with the challenge of handling spurious reflections of these waves from domain boundaries. Typically, approaches which employ radiation boundary conditions and forcing zones are used to avoid these reflections. However, the simulation setup of these approaches relies heavily on ad hoc processes. For instance, the widely used Rayleigh damping method requires ad hoc tuning to produce a setup that may only produce satisfactory results for a particular case. To provide more systematic guidance on setting up realistic simulations of atmospheric gravity waves, we conduct a large-eddy simulation (LES) study of flow over a 2D hill and through a wind farm canopy that explores the optimum domain size and damping layer setup depending on the fundamental parameters which determine the flow characteristics. In this work, we only consider linearly stratified conditions (i.e., no inversion layer), thereby focusing on internal gravity waves in the free atmosphere and their reflections from the domain boundaries. This type of flow is governed by a single Froude number, which dictates most of the internal wave properties, such as wavelength, amplitude, and direction. This, in turn, will dictate the optimum domain size and Rayleigh damping layer setup. We find the effective horizontal and vertical wavelengths (the representative wavelengths of the entire wave spectrum) to be the appropriate length scales to size the domain and damping layer thickness, and the optimal Rayleigh damping coefficient scales with the Brunt–Väisälä frequency. Considering Froude numbers seen in wind farm applications, we propose recommendations to limit the reflections to less than 10 % of the total upward-propagating wave energy. Typically, damping is done at the top boundary, but given the non-periodic lateral boundary conditions of practical wind farm simulation domains, we find that damping the inflow–outflow boundaries is of equal importance to damping the top boundary. The Brunt–Väisälä frequency-normalized damping coefficient should be between 1 and 10. The damping layer thickness should be at least one effective vertical wavelength; damping layers exceeding 1.5 times the vertical wavelength are found to be unnecessary. The domain length and height should accommodate at least one effective horizontal and vertical wavelength, respectively. Moreover, Rayleigh damping does not damp the waves completely, and the non-damped energy might accumulate over the simulation time.

17 WIND ENERGY↗

Simulation study to evaluate a constant-groundspeed approach method in moderate and severe wind shears

The use of a constant-groundspeed procedure for flying final approaches in moderate and severe wind shear environments was investigated. Performance was compared to results of simulated constant-airspeed approaches in identical wind profiles. The simulation model was a medium twin-jet transport equipped with an autothrottle for maintaining constant groundspeed or constant airspeed. For both moderate and severe wind shears, the constant-groundspeed approach method was shown to provide a way to more safely negotiate the shears while also providing predictable and acceptable touchdown performance. Results showed airspeeds on final approach to be considerably higher using the constant-groundspeed method, which supplied the additional stall margin needed when tail-wind shears were encountered. Throttle movements were noticeably reduced in all wind profiles when constant-groundspeed approaches were flown. Touchdown conditions were practically identical for both approach methods in moderate wind shear.

Kelley, W. W.↗

Comparisons of subsonic drag estimates derived from Pioneer Venus probes flight data with wind-tunnel results

Subsonic drag coefficients have been obtained from flight data for the Pioneer Venus multiprobes. The technique used to extract the information from the data consisted of utilizing in situ pressure and temperature measurements. Analysis of the major model parameter error sources indicates overall error levels of five percent or less in the flight values of the drag coefficient. Comparisons of the flight coefficients with preflight wind-tunnel test data showed generally good agreement except for the Sounder descent probe configuration. To preclude atmospheric phenomena as a possible explanation of this difference, additional wind-tunnel tests were performed on the Sounder descent probe. Special attempts were made to duplicate the probe geometry for tests in a high Reynolds number environment in order to achieve as realistic model and flight conditions as practical. Preliminary results from this testing in the NASA LaRC Low Turbulence Pressure Tunnel produced a drag coefficient of 0.68 at 0 deg angle of attack which is within the expected accuracy limits of the flight derived drag coefficient value of 0.72 + or - 0.04, thus eliminating atmospheric phenomena as the explanation for the initial difference.

Blanchard, R. C.↗

Effect of elastic end rings on the eigenfrequencies of thin cylinders

The effect of elastic end rings on the eigenfrequencies of thin cylindrical shells is studied by using an exact solution of the linear eigenvalue problem. The out-of-plane and torsional rigidities of the rings are responsible for the overall shell stiffness. Considerable mode interaction exists for modes with low circumferential wave numbers when the mass of the ring is comparable with that of the shell. The hypothetical simply supported and clamped boundary conditions are practically impossible to realize with a finite-mass ring for relatively short and thin shells.

El Raheb, M.↗

Effect of oxygen concentration in ZDP containing oils on surface composition and wear

A pin-on-disk wear study was performed with the lubricants dibutyl sebacate (DBS) and mineral oil (MO) with and without 1 weight percent zinc-dialkyl-dithiophospatee (ZDP) as an additive. The pin was annealed pure iron and the disk was M-2 tool steel. The selected load and speed guaranteed boundary lubrication. The ambient atmospheric oxygen concentration in an oxygen-nitrogen mixture was varied from 0 percent to 20 percent in order to examine its relationship to ZDP effectiveness. Auger electron spectroscopy combined with argon ion bombardment (depth profiling) was used to determine surface elemental composition on the pin when tested in DBS with and without ZDP. The ambient atmosphere was found to cause large variations in wear rate and surface composition. With MO, ZDP reduced wear under all conditions, but had little advantage over oxides formed at 20 percent oxygen atmosphere. With DBS, ZDP reduced wear at 0 percent oxygen, but gave varied results at other oxygen concentrations. Depth profiling revealed sulfuide formation at 0 percent oxygen and probably sulfates at 20 percent oxygen. The results are significant because varied oxygen concentrations can occur under actual lubricating conditions in practical machinery.

Brainard, W. A.↗

Modeling and equalization of nonlinear bandlimited satellite channels

The problem of modeling and equalization of a nonlinear satellite channel is considered. The channel is assumed to be bandlimited and exhibits both amplitude and phase nonlinearities. A discrete time satellite link is modeled under both uplink and downlink white Gaussian noise. Under conditions of practical interest, a simple and computationally efficient design technique for the minimum mean square error linear equalizer is presented. The bit error probability and some numerical results for a binary phase shift keyed (BPSK) system demonstrate that the proposed equalization technique outperforms standard linear receiver structures.

Konstantinides, K.↗

Estimating regional evapotranspiration from remotely sensed data by surface energy balance models

Spatial and temporal variations of surface radiative temperatures of the burned and unburned areas of the Konza tallgrass prairie were studied. The role of management practices, topographic conditions and the uncertainties associated with in situ or airborne surface temperature measurements were assessed. Evaluation of diurnal and seasonal spectral characteristics of the burned and unburned areas of the prairie was also made. This was accomplished based on the analysis of measured spectral reflectance of the grass canopies under field conditions, and modelling their spectral behavior using a one dimensional radiative transfer model.

Asrar, Ghassem↗

Modelling and computationally efficient time domain linear equalisation of nonlinear bandlimited QPSK satellite channels

The problem of modeling and equalization of a nonlinear satellite channel is considered. The channel is assumed to be bandlimited and exhibits both amplitude and phase nonlinearities. In traditional models, computations are usually performed in the frequency domain and solutions are based on complex numerical techniques. A discrete time model is used to represent the satellite link with both uplink and downlink white Gaussian noise. Under conditions of practical interest, a simple and computationally efficient time-domain design technique for the minimum mean square error linear equalizer is presented. The efficiency of this technique is enhanced by the use of a fast and simple iterative algorithm for the computation of the autocorrelation coefficients of the output of the nonlinear channel. Numerical results on the evaluations of bit error probability and other relevant parameters needed in the design and analysis of a nonlinear bandlimited QPSK system demonstrate the simplicity and computational efficiency of the proposed approach.

Konstantinides, K.↗

Special Propeller Protractor

A special protractor was designed and built with a view towards supplying a simple, inexpensive, practical, portable instrument for making measurements to detect propeller warpage under practically all conditions, without the use of auxiliary equipment, and without having to remove the propeller from the airplane. A detailed description is given of the protractor. Techniques for measuring are described. Directions are given on how to use the protractor to set detachable blade-type propellers on an airplane.

Heim, A M↗

Factors Influencing the Fatigue Strength of Materials

A number of factors are considered which influence the static and fatigue strength of materials under practical operating conditions as contrasted with the relations obtaining under conditions of the usual testing procedure. Such factors are interruptions in operation, periodically fluctuating stress limits and mean stresses with periodic succession of several groups and stress states, statistical changes and succession of stress limits and mean stresses, frictional corrosion at junctures, and notch effects.

Bollenrath, F↗