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At least 109 records · Page 6

Preparation and characterization of methacrylate hydrogels for zeta potential control

A technique based on the measurement of streaming potentials has been developed to evaluate the effects of hydrophilic coatings on electroosmotic flow. The apparatus and procedure are described as well as some results concerning the electrokinetic potential of glass capillaries as a function of ionic strength, pH, and temperature. The effect that turbulence and entrance flow conditions have on accurate streaming potential measurements is discussed. Various silane adhesion promoters exhibited only a slight decrease in streaming potential. A coating utilizing a glycidoxy silane base upon which methylcellulose is applied affords a six-fold decrease over uncoated tubes. Hydrophilic methacrylate gels show similar streaming potential behavior, independent of the water content of the gel. By introduction of positive or negative groups into the hydrophilic methacrylate gels, a range of streaming potential values are obtained having absolute positive or negative signs.

Gregonis, D. E.↗

Prediction of large negative shaded-side spacecraft potentials

A calculation by Knott, for the floating potential of a spherically symmetric synchronous-altitude satellite in eclipse, was adapted to provide simple calculations of upper bounds on negative potentials which may be achieved by electrically isolated shaded surfaces on spacecraft in sunlight. Large (approximately 60 percent) increases in predicted negative shaded-side potentials are obtained. To investigate effective potential barrier or angular momentum selection effects due to the presence of less negative sunlit-side or adjacent surface potentials, these expressions were replaced by the ion random current, which is a lower bound for convex surfaces when such effects become very severe. Further large increases in predicted negative potentials were obtained, amounting to a doubling in some cases.

Prokopenko, S. M. L.↗

Photoelectron spectrometer with means for stabilizing sample surface potential

An improved X-ray photoelectron spectrometer is disclosed, which includes circuit means to determine the surface potential of a sample, e.g., an insulator. The circuit means comprise an electron gun, whose potential is modulated at a preselected frequency above and below a selected potential with respect to the spectrometer common potential, e.g., ground. The beam of electrons is directed to the sample surface. The sample's surface potential is offset by an offset power supply with respect to the spectrometer common potential until the ac current which flows through the sample reaches a peak amplitude. A lock-in amplifier is included to measure the ac current in phase with the modulating frequency.

Grunthaner, F. J.↗

ATS-5 and ATS-6 potentials during eclipse

The ATS 5 and ATS 6 data for spacecraft charging during eclipse conditions is analyzed. The ATS 5 and ATS 6 charged to voltages greater than 100 volts for about 55 percent of the eclipse periods examined. The mean spacecraft potential during eclipse was 2 keV for ATS 5, and the highest potential measured was 10 kilovolts. For ATS 6, the mean potential during eclipse was 4 keV, the highest potential measured 20 keV. The average measured spacecraft potentials for both ATS 5 and 6 depend approximately linearly upon Kp. This relationship is due mainly to the dependence of electron current density on Kp near midnight. Spacecraft potentials at geosynchronous orbit may, to a rough approximation, thus be inferred from ground-based measurements of Kp, the planetary 3-hour index.

Rubin, A. G.↗

The alkaline zinc electrode as a mixed potential system

Cathodic and anodic processes for the alkaline zinc electrode in 0.01 molar zincate electrolyte (9 molar hydroxide) were investigated. Cyclic voltammograms and current-voltage curves were obtained by supplying pulses through a potentiostat to a zinc rotating disk electrode. The data are interpreted by treating the system as one with a mixed potential; the processes are termed The zincate and corrosion reactions. The relative proportions of the two processes vary with the supplied potential. For the cathodic region, the cathodic corrosion process predominates at higher potentials while both processes occur simultaneously at a lower potential (i.e., 50 mV). For the anodic region, the anodic zincate process predominates at higher potentials while the anodic corrosion process is dominant at lower potential (i.e., 50 mV) if H2 is present.

Fielder, W. L.↗

A potential enstrophy and energy conserving scheme for the shallow water equations

To improve the simulation of nonlinear aspects of the flow over steep topography, a potential enstrophy and energy conserving scheme for the shallow water equations is derived. It is pointed out that a family of schemes can conserve total energy for general flow and potential enstrophy for flow with no mass flux divergence. The newly derived scheme is a unique member of this family, that conserves both potential enstrophy and energy for general flow. Comparison by means of numerical experiment with a scheme that conserves (potential) enstrophy for purely horizontal nondivergent flow demonstrated the considerable superiority of the newly derived potential enstrophy and energy conserving scheme, not only in suppressing a spurious energy cascade but also in determining the overall flow regime. The potential enstrophy and energy conserving scheme for a spherical grid is also presented.

Arakawa, A.↗

Dependence of polar cap potential drop on interplanetary parameters

The convection potential drop across the polar cap is computed from data obtained on high-inclination low-altitude satellites. Potential measurements are correlated with various combinations of parameters measured simultaneously in the upstream solar wind. Most of the potential drop is successfully predicted by merging theory, although a significant background potential drop of 35 kV does not depend on IMF parameters and is attributed to a process other than merging. Results indicate that small values of the IMF are amplified by a factor of 5-10 at the dayside magnetopause, which, when taken into account, improves correlations between IMF parameters and polar cap potential drop. Potential drop is better correlated with IMF parameters than with geomagnetic indices, due to nonlinear response of the magnetosphere affecting geomagnetic activity indices.

Reiff, P. H.↗

Degree variances of the earth's potential, topography and its isostatic compensation

A spherical harmonic expansion of the earth's gravitational potential and equivalent rock topography to degree and order 180 is described. The potential implied by the topography considered as uncompensated and with isostatic compensation has been computed. Good agreement with the observed potential field is found when the depth of compensation in the Airy theory is assumed to be 50 km. At the higher degrees the correlation coefficient between the potential expansion and the equivalent rock topography is about 0.5. The Lachapelle equations for the topographic isostatic potential were tested using 1 x 1 deg equivalent rock topography. The degree variances agree at the lower degrees but at degree 36 the Lachapelle results using 5 deg data underestimate the potential degree variances by about one-third.

Rapp, R. H.↗

Simulating sunflower canopy temperatures to infer root-zone soil water potential

A soil-plant-atmosphere model for sunflower (Helianthus annuus L.), together with clear sky weather data for several days, is used to study the relationship between canopy temperature and root-zone soil water potential. Considering the empirical dependence of stomatal resistance on insolation, air temperature and leaf water potential, a continuity equation for water flux in the soil-plant-atmosphere system is solved for the leaf water potential. The transpirational flux is calculated using Monteith's combination equation, while the canopy temperature is calculated from the energy balance equation. The simulation shows that, at high soil water potentials, canopy temperature is determined primarily by air and dew point temperatures. These results agree with an empirically derived linear regression equation relating canopy-air temperature differential to air vapor pressure deficit. The model predictions of leaf water potential are also in agreement with observations, indicating that measurements of canopy temperature together with a knowledge of air and dew point temperatures can provide a reliable estimate of the root-zone soil water potential.

Choudhury, B. J.↗

Comment on 'Hy-wire measurements of atmospheric potential' by R. H. Holzworth

It is shown that the Hy-wire fluctuations in atmospheric potential measured by Holzworth (1983) were not changes in the global circuit. The close association between the Hy-wire potential variations and meteorological changes, as well as the lack of correlation between the potential and the Carnegie curve, indicates that the tethered balloon measurements were responding to local meteorological factors. The abnormally high potentials and the reversed curvature of the potential profiles suggest that the Hy-wire apparatus was not measuring atmospheric potentials accurately.

Markson, R.↗

The numerical simulation of steady transonic rotational flow using a dual potential formulation

A finite-difference method is presented that simulates steady transonic rotational flow of an inviscid fluid by representing the velocity field as the sum of scalar and vector potentials. This dual potential velocity decomposition extends the validity of the scalar (full) velocity potential to include vorticity. The inclusion of a vector potential also permits an alternate treatment of lift that does not require a circulation wake cut. This is accomplished by specifying the vector potential as a constant on the airfoil surface in order to satisfy a Kutta condition. The governing equations are solved as iteratively decoupled scalar equations using approximate factorization techniques, and the overall efficiency approaches that of the full potential equation. The governing equations are able to convect entropy and vorticity throughout the flow field and are equivalent to the Euler equations in continuous flow domains, however at shocks the Rankine-Hugoniot entropy jump must be supplied. An entropy correction method is presented and verified with transonic airfoil solutions of the Euler equations.

Chaderjian, N. M.↗

Analysis of LIMS data by potential vorticity inversion

This paper analyzes LIMS data for a minor warming of January 1979 by potential vorticity inversion, to investigate how flows in the middle atmosphere were determined. The inversion problem of calculating the flow from the potential vorticity is solved repeatedly, including and excluding different portions of the potential vorticity, thus revealing which bits of potential vorticity were important in determining the flow at a time and location of interest. The results of the analysis of LIMS data indicate that the middle stratospheric flow is dominated by potential vorticity that is local in height and in latitude, while planetary-scale mesospheric flows are primarily induced by potential vorticity in the stratosphere. A possible explanation for this difference is proposed.

Robinson, Walter A.↗

Electrostatic potential jump across fast-mode collisionless shocks

The electrostatic potential jump across fast-mode collisionless shocks is examined by comparing published observations, hybrid simulations, and a simple model, in order to better characterize its dependence on the various shock parameters. In all three, it is assumed that the electrons can be described by an isotropic power-law equation of state. The observations show that the cross-shock potential jump correlates well with the shock strength but shows very little correlation with other shock parameters. Assuming that the electrons obey an isotropic power law equation of state, the correlation of the potential jump with the shock strength follows naturally from the increased shock compression and an apparent dependence of the power law exponent on the Mach number which the observations indicate. It is found that including a Mach number dependence for the power law exponent in the electron equation of state in the simple model produces a potential jump which better fits the observations. On the basis of the simulation results and theoretical estimates of the cross-shock potential, it is discussed how the cross-shock potential might be expected to depend on the other shock parameters.

Mandt, M. E.↗

Real-time obstacle avoidance using harmonic potential functions

This paper presents a new formulation of the artificial potential approach to the obstacle avoidance problem for a mobile robot or a manipulator in a known environment. Previous formulations of artificial potentials for obstacle avoidance have exhibited local minima in a cluttered environment. To build an artificial potential field, harmonic functions that completely eliminate local minima even for a cluttered environment are used. The panel method is employed to represent arbitrarily shaped obstacles and to derive the potential over the whole space. Based on this potential function, an elegant control strategy is proposed for the real-time control of a robot. The harmonic potential, the panel method, and the control strategy are tested with a bar-shaped mobile robot and a three-degree-of-freedom planar redundant manipulator.

Kim, Jin-Oh↗

Electromagnetic potential vectors and the Lagrangian of a charged particle

Maxwell's equations can be shown to imply the existence of two independent three-dimensional potential vectors. A comparison between the potential vectors and the electric and magnetic field vectors, using a spatial Fourier transformation, reveals six independent potential components but only four independent electromagnetic field components for each mode. Although the electromagnetic fields determined by Maxwell's equations give a complete description of all possible classical electromagnetic phenomena, potential vectors contains more information and allow for a description of such quantum mechanical phenomena as the Aharonov-Bohm effect. A new result is that a charged particle Lagrangian written in terms of potential vectors automatically contains a 'spontaneous symmetry breaking' potential.

Shebalin, John V.↗

Analytic model of aurorally coupled magnetospheric and ionospheric electrostatic potentials

This paper describes modest but significant improvements on earlier studies of electrostatic potential structure in the auroral region using the adiabatic auroral arc model. This model has crucial nonlinearities (connected, for example. with aurorally produced ionization) which have hampered analysis; earlier work has either been linear, which I will show is a poor approximation or, if nonlinear, either numerical or too specialized to study parametric dependencies. With certain simplifying assumptions I find new analytic nonlinear solutions fully exhibiting the parametric dependence of potentials on magnetospheric (e.g.. cross-tail potential) and ionospheric (e.g., recombination rate) parameters. No purely phenomenological parameters are introduced. The results are in reasonable agreement with observed average auroral potential drops, inverted-V scale sizes, and dissipation rates. The dissipation rate is quite comparable to tail energization and transport rates and should have a major effect on tail and magnetospheric dynamics. This paper gives various relations between the cross-tail potential and auroral parameters (e.g., total parallel currents and potential drops) which can be studied with existing data sets.

Cornwall, J. M.↗

Analytic model of aurorally coupled magnetospheric and ionospheric electrostatic potentials

This paper describes modest but significant improvements on earlier studies of electrostatic potential structure in the auroral region, using the adiabatic auroral arc model. With certain simplifying assumptions, new analytic nonlinear solutions fully exhibiting the parametric dependence of potentials on magnetospheric (e.g., cross-tail potential) and ionospheric (e.g., recombination rate) parameters are found. No purely phenomenological parameters are introduced. The results are in reasonable agreement with observed average auroral potential drops, inverted-V scale sizes, and dissipation rates. The dissipation rate is quite comparable to tail energization and transport rates and should have a major effect on tail and magnetospheric dynamics. Various relations between the cross-tail potential and auroral parameters (e.g., total parallel currents and potential drops) are given which can be studied with existing data sets.

Cornwall, John M.↗

Auroral plasma transport processes in the presence of kV potential structures

We have simulated plasma transport processes in the presence of a quasi-two-dimensional current filament, that generated kV potential structure in the auroral region. The simulation consists of a set of one-dimensional flux tube simulations with different imposed time-dependent, field-aligned currents. The model uses the 16 moment system of equations and simultaneously solves coupled continuity and momentum equations and equations describing the transport along the magnetic field lines of parallel and perpendicular thermal energy and heat flows for each species. The lower end of the simulation is at an altitude of 800 km, in the collisional topside ionosphere, while the upper end is at 10 R(sub E) in the magnetosphere. The plasma consists of hot electrons and protons of magnetospheric origin and low-energy electrons, protons, and oxygen ions of ionospheric origin. The dynamical interaction of the individual current filaments with ionospheric and magnetospheric plasma generates a potential structure in the horizontal direction and kilovolt field-aligned potential drops along the field lines. The side-by-side display exhibits the evolution of the implied potential structure in the horizontial direction. In the presence of this potential structure and parallel electric field ionospheric plasma density is depleted and velocity is reduced, while density enhancement and increased velocity is observed in magnetospheric plasma. The ionospheric and magnetospheric electron temperatures increase below 2 R(sub E) due to magnetic mirror force on converging geomagnetic field lines. The primary cross-field motion produced by the horizontal E field (E x B drift) is perpendicular to both of the significant spatial directions and is thus ignorable in this geometry. The effects of other cross-field drift processes are discussed. The simulation thus provides insight into the dynamical evolution of two-dimensional potential structures driven by an imposed finite width, field-aligned current profile.

Ganguli, Supriya B.↗