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At least 109 records · Page 6

Numerical investigation of Lower Tuscaloosa Sandstone and Selma Chalk caprock under geological CO 2 sequestration conditions: mineral precipitation and permeability evolution

Abstract A numerical model was developed using CrunchFlow to simulate reactive transport and porosity and permeability changes of sandstone and carbonate rock samples taken from the Lower Tuscaloosa Formation and the Selma Chalk Formation, Jackson County, MS, USA. The model predicted a permeability decrease from 2190 mD to 2038 mD for the Lower Tuscaloosa Sandstone sample in a static batch reactor after 180 days of exposure to CO 2 ‐saturated brine, which is consistent with measured permeability results. The model predicted a negligible permeability change from 2.00 mD to 2.08 mD for the Selma Chalk carbonate sample after 180 days of exposure to CO 2 ‐saturated brine. Based on model prediction, key mineral dissolution and precipitation reactions in the Lower Tuscaloosa Sandstone sample include dissolution of quartz, chlorite, and feldspar, as well as precipitation of amorphous silica and kaolinite. For the Selma Chalk carbonate sample, key predicted reactions include dissolution of calcite, quartz and chlorite, and precipitation of kaolinite and amorphous silica. Initial porosity, initial feldspar content and the exponent n value (related to pore structure and tortuosity) used in permeability calculations were three important factors affecting permeability evolution of sandstone samples under CO 2 sequestration conditions. The small permeability change predicted for both the Lower Tuscaloosa Sandstone and the Selma Chalk caprock after exposure to CO 2 ‐saturated brine suggests that poro‐permeability changes during CO 2 injection into the Lower Tuscaloosa Formation are not likely to significantly affect reservoir and seal quality. © 2017 Society of Chemical Industry and John Wiley & Sons, Ltd.

Zhang, Liwei↗

Apparent permeability prediction of organic shale with generalized lattice Boltzmann model considering surface diffusion effect

Gas flow in shale is associated with both organic matter (OM) and inorganic matter (IOM) which contain nano-pores ranging in size from a few to hundreds of nano-meters. In addition to the non-continuum effect which leads to an apparent permeability of gas higher than the intrinsic permeability, the surface diffusion of adsorbed gas in organic pores also can influence the apparent permeability through its own transport mechanism. In this study, a generalized lattice Boltzmann model (GLBM) is employed for gas flow through the reconstructed shale matrix consisting of OM and IOM. The Expectation–Maximization (EM) algorithm is used to assign the pore size distribution to each component, and the dusty gas model (DGM) and generalized Maxwell–Stefan model (GMS) are adopted to calculate the apparent permeability accounting for multiple transport mechanisms including viscous flow, Knudsen diffusion and surface diffusion. Effects of pore radius and pressure on permeability of both IOM and OM as well as effects of Langmuir parameters on OM are investigated. The effect of total organic content and distribution on the apparent permeability of the reconstructed shale matrix at different surface diffusivity is also studied. It is found that the influence of pore size and pressure on the apparent permeability of organic matter is affected by the surface diffusion of adsorbed gas. Furthermore, surface diffusion plays a significant role in determining apparent permeability and the velocity distribution of shale matrix.

02 PETROLEUM↗

Mineralogical Controls on Frictional Strength, Stability, and Shear Permeability Evolution of Fractures

Massive fluid injection into the subsurface can induce microearthquakes by reactivating preexisting faults or fractures as seismic or aseismic slip. Such seismic or aseismic shear deformationsmay result in different modes of permeability evolution. Previous experimental studies have explored frictional stability-permeability relationships of carbonate-rich and phyllosilicate-rich samples under shear, suggesting that friction-permeability relationship may be primarily controlled by fracture minerals. We examine this relationship and identify the role of mineralogy (i.e., tectosilicate, carbonate, and phyllosilicate content) using direct-shear experiments on smooth saw-cut fractures of natural rocks and sintered fractures with distinct mineralogical compositions. These results indicate that the friction-permeability relationship is controlled by mineralogy. Frictional strength and permeability change upon reactivation decrease with phyllosilicate content but increase with tectosilicate content. In contrast, the reverse trend is observed for frictional stability (a-b). However, the permeability change decreases with carbonate content while both frictional strength and stability increase. The permeability change always decreases with an increase in frictional stability. This relationship implies a new mechanical-hydrochemical coupling loop via a linkage of frictional properties, mineralogy, and permeability.

58 GEOSCIENCES↗

Cyclic Permeability Evolution During Repose Then Reactivation of Fractures and Faults

Abstract Cyclic growth and decay of permeability in fractures is explored during repeated reactivation and repose of saw‐cut fractures of Green River shale. These slide‐hold‐slide experiments are supported by measurements of fracture normal deformation and optical surface profilometry. Overall, we observe continuous permeability decay during repose (holds) and significant permeability enhancement during slow reactivation (slide). The permeability decay is accompanied by fault compaction. Both hydraulic aperture change (Δ b h ) and measured compaction (Δ b s ) are consistent with time‐dependent power law closure with a power exponent of ~0.2–0.4. These dual compaction magnitudes are positively correlated but Δ b h > Δ b s in late stage holds. Permeability enhancement during reactivation is typically also accompanied by fault dilation. However, we also observe some cases where hydraulic aperture change decouples from the measured deformation, conceivably driven by mobilization of wear products and influenced by the development of flow bottlenecks. Pretest and posttest surface profiles show that the surface topography of the fractures is planed down by shear removal. The shear removal is significant with initial laboratory prepared surface (~10 μm of aperture height) but less significant following consecutive reactivations (~2 μm). The flattened surfaces retain small‐scale, ~10–20 μm wavelength, roughness. Flow simulations, constrained by the surface topography and measured deformation, indicate that small‐scale roughness may control permeability at flow bottlenecks within a dominant flow channel. These results suggest cycles of permeability creation and destruction are an intrinsic component of the natural hydraulic system present in faults and fractures and provide an improved mechanistic understanding of the evolution of permeability during fault repose and reactivation.

Im, Kyungjae↗

Application of a convolutional neural network in permeability prediction: A case study in the Jacksonburg-Stringtown oil field, West Virginia, USA

Permeability is a critical parameter for understanding subsurface fluid flow behavior, managing reservoirs, enhancing hydrocarbon recovery, and sequestering carbon dioxide. In general, permeability is measured in the laboratory based on subsurface core samples, calculated from well logs or estimated from well tests. However, laboratory measurements and well tests are expensive, time-consuming, and usually limited to a few core samples or wells in a hydrocarbon field or carbon storage site. Machine-learning techniques are good options for generating a rapid, robust, and cost-effective permeability prediction model because of their strengths to recognize the potential interrelationships between input and output variables. Convolutional neural networks (CNN), as a good pattern recognition algorithm, are widely used in image processing, natural language processing, and speech recognition, but are rarely used with regression problems and even less often in reservoir characterization. We have developed a CNN regression model to estimate the permeability in the Jacksonburg-Stringtown oil field, West Virginia, which is a potential carbon storage site and enhanced oil recovery operations field. We also evaluate the concept of the geologic feature image, which is converted from geophysical well logs. Five variables, including two commonly available conventional well logs (the gamma rays [GRs] and bulk density) and three well-log-derived variables (the slopes of the GR and bulk density curves, and shale content), are used to generate a geologic feature image. The CNN treats the geologic feature image as the input and the permeability as the desired output. In addition, the permeability predicted using traditional backpropagation artificial neural networks, which are optimized by genetic algorithms and particle swarm optimization, is compared with the permeability estimated using our CNN. Our results indicate that the CNN regression model provides more accurate permeability predictions than the traditional neural network.

Geochemistry & Geophysics↗

Influence of fiber packing structure on permeability

The study on the permeability of an aligned fiber bundle is the key building block in modeling the permeability of advanced woven and braided preforms. Available results on the permeability of fiber bundles in the literature show that a substantial difference exists between numerical and analytical calculations on idealized fiber packing structures, such as square and hexagonal packing, and experimental measurements on practical fiber bundles. The present study focuses on the variation of the permeability of a fiber bundle under practical process conditions. Fiber bundles are considered as containing openings and fiber clusters within the bundle. Numerical simulations on the influence of various openings on the permeability were conducted. Idealized packing structures are used, but with introduced openings distributed in different patterns. Both longitudinal and transverse flow are considered. The results show that openings within the fiber bundle have substantial effect on the permeability. In the longitudinal flow case, the openings become the dominant flow path. In the transverse flow case, the fiber clusters reduce the gap sizes among fibers. Therefore the permeability is greatly influenced by these openings and clusters, respectively. In addition to the porosity or fiber volume fraction, which is commonly used in the permeability expression, another fiber bundle status parameter, the ultimate fiber volume fraction, is introduced to capture the disturbance within a fiber bundle.

Cai, Zhong↗

Permeability and Strength Measurements on Sintered, Porous, Hollow Turbine Blades Made by the American Electro Metal Corporation under Office of Naval Research Contract N-ONR-295 (01)

An experimental investigation was made to determine the permeability and strength characteristics of a number of sintered, porous, hollow turbine rotor blades and to determine the effectiveness of the blade fabrication method on permeability control. The test blades were fabricated by the American Electro Metal Corporation under a contract with the Office of Naval Research, Department of the Navy, and were submitted to the NACA for testing. Of the 22 test blades submitted, ten were sintered but not coined, five were sintered and coined, and seven were sintered and not coined but contained perforated reinforcements integral with the blade shells. Representative samples of each group of blades were tested. Large variations in permeability in both chordwise and spanwise directions were found. Local deviations as large as 155 to -85 percent from prescribed values were found in chordwise permeability. Only one blade, an uncoined one, had a chordwise permeability variations which reasonably approached that specified. Even for this blade, local deviations exceeded 10 percent. Spanwise permeability, specified to be held constant, varied as much as 50 percent from root to tip for both an uncoined and a coined blade. Previous NACA analyses have shown that in order to maintain proper control of blade wall temperatures, permeability variations must not exceed plus or minus 10 percent. Satisfactory control of permeability in either the chordwise or the spanwise direction was not achieved in the blades tested. Spin tests made at room temperature for six blades revealed the highest material rupture strength to be 8926 pounds per square inch. This value is about one third the strength required for rotor blades in present-day turbojet engines. The lowest value of blade strength was 1436 pounds per square inch.

Richards, Hadley T.↗

Prediction of Thermal Protection System Material Permeability and Hydraulic Tortuosity Factor Using Direct Simulation Monte Carlo

Carbon preforms used in Thermal Protection System (TPS) materials are 80 to 90% porous, allowing for boundary layer and pyrolysis gases to flow through the porous regions. The bulk material properties such as permeability and hydraulic tortuosity factor affect the transport of the boundary layer gases. The use of Direct Simulation Monte Carlo along with the Klinkenberg permeability formulation allows us to compute the continuum permeability and Knudsen correction factor for flow in the transition regime. In this work, we have computed the permeability for two types of carbon preforms, namely, Morgan Felt and FiberForm, and assessed the effect of orientation on the permeability. Since both the materials are anisotropic, the permeability was found to depend on orientation, wherein, the materials are more permeable in the in-plane orientation than the through-thickness orientation. The through-thickness orientation was also more tortuous compared to the in-plane material orientation. Compared to Morgan Felt, FiberForm is less permeable, in both, through thickness and in-plane directions.

Jambunathan, Revathi↗

The water retention curve and relative permeability for gas production from hydrate-bearing sediments: pore-network model simulation

Here, the water retention curve and relative permeability are critical to predict gas and water production from hydrate–bearing sediments. However, values for key parameters that characterize gas and water flows during hydrate dissociation have not been identified due to experimental challenges. This study utilizes the combined techniques of micro–focus X–ray computed tomography (CT) and pore–network model simulation to identify proper values for those key parameters, such as gas entry pressure, residual water saturation, and curve fitting values. Hydrates with various saturation and morphology are realized in the pore–network that was extracted from micron–resolution CT images of sediments recovered from the hydrate deposit at the Mallik site, and then the processes of gas invasion, hydrate dissociation, gas expansion, and gas and water permeability are simulated. Results show that greater hydrate saturation in sediments lead to higher gas entry pressure, higher residual water saturation, and steeper water retention curve. An increase in hydrate saturation decreases gas permeability but has marginal effects on water permeability in sediments with uniformly distributed hydrate. Hydrate morphology has more significant impacts than hydrate saturation on relative permeability. Sediments with heterogeneously distributed hydrate tend to result in lower residual water saturation and higher gas and water permeability. In this sense, the Brooks–Corey model that uses two fitting parameters individually for gas and water permeability properly capture the effect of hydrate saturation and morphology on gas and water flows in hydrate–bearing sediments.

58 GEOSCIENCES↗

Permeability of Single–Layer–Free–Standing Meshes at Varying Capillary Pressure via a Novel Method

The permeability of mesh wicks is important for various applications, including two–phase heat transfer. However, the understanding of the permeability of single–layer, free–standing mesh wicks, with liquid–gas interfaces on both sides, is limited. A novel and simpler method is presented to determine the permeability of a free–standing wick and apply it to a representative mesh. This method involves modifying the capillary pressure via elevation and simultaneously measuring the permeability to determine the permeability–capillary pressure relationship. When applied to a copper mesh with plain weave having undergone surface cleaning, the permeability is found to decrease as capillary pressure for deionized water increases. A dimensional analysis is presented to generalize this data for other mesh sizes with similar weaves and fluids. The behavior of mesh in application is modeled, based on the integration of Darcy's law with an analytic function fit to measured data, and parametric studies are conducted to investigate the superficial velocity of liquids through the mesh under varying driving pressures, transport lengths, and liquid viscosity, based on the obtained capillary pressure–permeability relationship. This study provides valuable insights into the transport properties of mesh wicks, with potential applications in fields such as electronics cooling, electrochemical devices, and fluid purification technologies.

36 MATERIALS SCIENCE↗

CO 2 storage in the Paluxy formation at the Kemper County CO 2 storage complex: Pore network properties and simulated reactive permeability evolution

The Paluxy formation is being considered as a prospective CO 2 reservoir at the Kemper County CO 2 Storage Complex. Herein, the pore and pore-throat size distributions and connectivity of the Paluxy formation is evaluated through analysis of 3D X-ray Computed Tomography images. In spite of resolution limitations that constrain the pore-throat sizes detectable by imaging, the permeability contributing pore-throats are successfully characterized through 3D imaging analysis. Image-obtained pore and pore-throat size distributions and pore connectivity are then utilized to construct pore network models and simulate permeability. After CO 2 is injected, it will dissolve into formation brine and create conditions favorable for dissolution of primary minerals and precipitation of secondary minerals. These reactions will alter the porosity and permeability of the system to varying degrees depending on the spatial location of reactions. In this research, the possible porosity-permeability evolution is simulated using pore network models considering mineral reactions occurring uniformly and non-uniformly throughout the network. For a given change in porosity, there is a large range of possible permeability outcomes. Depending on the extent and spatial location of mineral reactions, permeability may decrease by more than one order of magnitude as minerals precipitate. During dissolution, simulated permeability increases as much as 500%.

03 NATURAL GAS↗

Side-Chain and Ring-Size Effects on Permeability in Artificial Water Channels

Artificial water channels (AWCs) have emerged as a promising framework for stable water permeation, with water transport rates comparable to aquaporins (3.4–40.3 × 10 8 H 2 O/channel/s). In this study, we probe the influence of ring-size and side-chain length on the water permeability observed within a class of AWCs termed ligand-appended pillar[n]arenes (LAPs) that have an adjustable ring-size (m) and side-chain length (n). Through all-atom molecular dynamics simulations, we calculate the permeability of these channels using the collective diffusion model and find their permeabilities. We characterize the mechanistic influence of pillar[n]arene ring-size and side-chain length on the channel water permeability by analyzing the characteristics of the internal permeating water-wire and the surrounding channel structure. We observe that water permeability decreases as a function of increasing ring-size due to increases in hydrophilic contacts between the permeating water-wire and the oxygen groups on the channel wall. Further, we observe an increase in water permeability as a function of side-chain length due to increased partitioning of the channel terminal groups into the hydrophilic blocks of the surrounding bilayer. For the LAP6 channel, with increase in side-chain length, the distance between terminal groups increases and leads to an increase in pore size, thereby enhancing water permeability. In the case of LAP5, as side-chain length increases, the channel displays a compensatory effect between tilt and bend angle due to the flexible side-chains. Such flexibility leads to higher terminal group partitioning in the hydrophilic blocks of the bilayer and extends the permeating water-wire. Furthermore, this increase in water-wire length and hydrophilic block access overcomes the nonmonotonic pore size trend in pillar[5]arene channels.

36 MATERIALS SCIENCE↗

Permeability Evolution and Frictional Stability of Fabricated Fractures With Specified Roughness

Roughness is widely observed on natural fractures, and its impact on the potential for induced seismicity and associated fluid migration in the subsurface remains unclear. Here we perform fracture shearing and fluid flow experiments on artificially fabricated fractures with specified roughness to investigate the role of fracture roughness on frictional properties and permeability evolution. Given the experimental conditions, we observe that rough fractures show high roughness ratio S q /L w and return higher frictional strength due to the presence of cohesive interlocking asperities. Rough fracture surfaces show velocity strengthening behavior in the initial shearing stage, which may evolve to velocity neutral and velocity weakening at greater displacements—suggesting a dynamic weakening that rough fractures become less stable with shearing. The surface roughness exerts a dominant control on permeability evolution over the entire shearing history. Permeability declines monotonically by about 2 orders of magnitude for smooth fractures. For high roughness fractures, the permeabilities evolve episodically due to cycled compaction and dilation during shearing. With a slip distance of 6 to 8 mm, permeability of the rough surface may enhance up to an order of magnitude, but significant permeability reduction may also occur for rough samples when asperities are highly worn with gouge clogging flow paths. However, there is no obvious correlation between permeability evolution and frictional behavior for rough fracture samples when fractures are subject to sudden sliding velocity changes.

58 GEOSCIENCES↗

IFN-γ, IL-17A, or zonulin rapidly increase the permeability of the blood-brain and small intestinal epithelial barriers: Relevance for neuro-inflammatory diseases

Highlights: • Zonulin rapidly (within 60 min) increases the permeability of the IEB and BBB in vitro. • Both IL-17A and IFN-γ enhance the permeability of the BBB and IEB within 1 h. • All three pro-inflammatory mediators rapidly modify IEB TJs, by causing mislocalization of ZO-1, claudin-5, and occludin. • Rapid TJ disassembly by all mediators was accompanied by dramatic depolymerization of the peri-junctional actin cytoskeleton. Breakdown of the blood-brain barrier (BBB) precedes lesion formation in the brains of multiple sclerosis (MS) patients. Since recent data implicate disruption of the small intestinal epithelial barrier (IEB) in the pathogenesis of MS, we hypothesized that the increased permeability of the BBB and IEB are mechanistically linked. Zonulin, a protein produced by small intestine epithelium, can rapidly increase small intestinal permeability. Zonulin blood levels are elevated in MS, but it is unknown whether zonulin can also disrupt the BBB. Increased production of IL-17A and IFN-γ has been implicated in the pathogenesis of MS, epilepsy, and stroke, and these cytokines impact BBB integrity after 24 h. We here report that primary human brain microvascular endothelial cells expressed the EGFR and PAR2 receptors necessary to respond to zonulin, and that zonulin increased BBB permeability to a 40 kDa dextran tracer within 1 h. Moreover, both IL-17A and IFN-γ also rapidly increased BBB and IEB permeability. By using confocal microscopy, we found that exposure of the IEB to zonulin, IFN-γ, or IL-17A in vitro rapidly modified the localization of the TJ proteins, ZO-1, claudin-5, and occludin. TJ disassembly was accompanied by marked depolymerization of the peri-junctional F-actin cytoskeleton. Our data indicate that IFN-γ, IL-17A, or zonulin can increase the permeability of the IEB and BBB rapidly in vitro, by modifying TJs and the underlying actin cytoskeleton. These observations may help clarify how the gut-brain axis mediates the pathogenesis of neuro-inflammatory diseases.

60 APPLIED LIFE SCIENCES↗

A new apparatus for the concurrent measurement of friction and permeability evolution in fault gouge

Here we introduce a new miniature double direct shear (mini-DDS) apparatus, housed within a standard-triaxial (TEMCO) pressure vessel, capable of concurrently measuring the evolution of frictional strength, stability, healing and along-fault permeability under in situ conditions of stress and temperature. The apparatus accommodates gouge samples (25 mm × 32 mm) and intact rock samples with confining and shear stresses and pore pressures up to ~26 MPa. Permeability may be measured with applied flow rates ranging from 1.67 × 10 -11 to 3.6 × 10 -6 m 3 /s to a flow accuracy of 0.5% representing a lower bound of permeability >2.2 × 10 -18 m 2 . Sliding velocities are in the range 0.1 μm/s to 0.67 cm/s with a frame stiffness of 0.067 kN/μm. We describe protocols and procedures for calibration and experiments and note the potential of the apparatus for both rapid and extended-duration measurements of friction-permeability evolution and healing. The apparatus returns measurements of friction and stability of reference materials of F110 quartz consistent with the literature while additionally allowing the concurrent measurement of permeability. Permeability of F110 quartz evolves in slide-hold-slide (SHS) experiments with increases during holds and decreases during subsequent slides. These observations are consistent with grain crushing and resultant wear products that reduce that permeability by clogging during slides with unclogging of the major fluid channels occurring during shearing.

58 GEOSCIENCES↗

Viscous Dissipation and Apparent Permeability of Gas Flow in Nanoporous Media

The nanopore confinement effect can increase the mobility for gas flow in shale rocks, and the apparent permeability is usually adopted to account for this effect. However, most of the apparent permeability calculation models are derived based on straight channels (capillaries) and neglect the influence of end effect. The end effect is caused by the bending of streamlines which yields more viscous dissipation and additional flow resistance for gas flow in nanoporous media. Here, for the first time the viscous dissipation for gas flow in nanoporous media is analyzed. In addition, an improved apparent permeability calculation model is proposed based on the Beskok-Karniadakis (B-K) model by introducing the influence of end effect, which is characterized by the ratio of the length to the width of a short channel (L/H). The accuracy of this model is validated by lattice Boltzmann simulations of gas flow in three different geometries: an infinite-length straight channel, a finite-length straight channel, and nanoporous media. For the infinite-length straight channel, there is no end effect therefore both the B-K model and the improved model can well predict the apparent permeability. However, for the finite-length straight channel and nanoporous media, the original B-K model overestimates the gas apparent permeability as it neglects the influence of end effect, while the improved model can still well predict the gas apparent permeability. In summary, the improved apparent permeability calculation model is more reasonable in predicting gas mobility in nanoporous media.

58 GEOSCIENCES↗

Co‐Evolution of Specific Stiffness and Permeability of Rock Fractures Offset in Shear

Abstract Fractures and faults represent planes of weakness and compliance in rock masses that serve as focal points for both microearthquakes and fluid transport, with seismicity and permeability evolution closely linked. Contact stiffness is highly stress‐sensitive and directly influences permeability. We explore the co‐evolution of specific stiffness and permeability of rough fractures under normal stress and shear offset using numerical simulations. Individual rough fractures are represented by variable amplitude (Root mean square) and wavelength ( λ ) using a granular mechanics model. Contacting rough surfaces are mated, offset in shear, and then compacted in displacement mode. The compacting fractures generate stress‐dependent changes in contact porosity, which govern both permeability and stiffness evolution. We establish a universal dimensionless relationship linking specific stiffness and permeability that inherently incorporates the effects of surface roughness, shear offset, and microcracking. The observed cracking effect—where local stress redistribution and pressure‐driven microcrack propagation dynamically alter the aperture field—introduces a nonlinear permeability response at high stress. Increased roughness amplitude and larger shear offsets reduce stiffness while dampening permeability sensitivity to stress, demonstrating a strong interplay between surface texture and hydro‐mechanical behavior. While the model captures this behavior effectively, deviations emerge at very low porosities due to extreme aperture sensitivity in this limit.

He, Xinxin [Energy and Mineral Engineering Pennsyl↗

Distributed Acoustic Sensing to Estimate the Permeability

Optical fiber in a borehole can be interrogated with distributed acoustic sensors (DAS) to capture fracture displacements with the potential to map surrounding fracture networks. We designed a laboratory experiment to test the capability of DAS to determine borehole flow characteristics, and we show that for the first time DAS can be used to remotely estimate permeability. Optical fiber was wrapped around a bead filled pipe and the pressure drop and flow velocity were measured to directly calculate permeability. A machine learning model using statistical features from continuous DAS estimated the bulk permeability. Fluid interactions with the permeable material demonstrate insufficient resolution using DAS amplitude-based measurements for estimating pressure drop to infer permeability. Variations in the spectral domain relate DAS measurements to the pressure drop and provide consistent permeability estimates. Resolution with DAS is sufficient to estimate permeability and provides a reliable method to monitor at depth in borehole conditions.

58 GEOSCIENCES↗