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At least 109 records · Page 6

Importance of Sulfur for Phosphorus Mobility on the Martian Surface

Sulfur and phosphorus were mobile on the martian surface, and we present evidence that sulfate was likely a control on phosphate mobility. Mobility of the two elements on the martian surface is crucial for the habitability of Mars because their availability for biochemical reactions and biological structures is a major constraint on life. In the sedimentary rocks of Gale crater, the rover Curiosity has discovered evidence of mobile S and P with the alpha particle X-ray spectrometer (APXS). Sulfur-rich fluids are evident in ubiquitous Ca-sulfate veins that crosscut the bedrock. Compelling evidence of P mobility is in nodules, veins, crusts, and haloes with P2O5 enrichments (1.5-7.5 wt%) relative to the median bedrock (0.9-1.2 wt%) and average basaltic crust (~0.9 wt%). We have investigated phosphorus mobility in Hawaiian analogues, where the primary P2O5 (0.2-2.1 wt%) is contained in Ca-apatite. Four relevant processes have emerged: (1) In open-system, circumneutral regolith weathering profiles, we found up to 40% of the P was leached over 10s-100s ka. (2) Natural acid-sulfate alteration at the Maunakea summit resulted in the dissolution of apatite and mobilization of phosphate 10s-1000s µm to rock surfaces where it formed Al-phosphates and substituted into crystalline sulfates (alunite and jarosite). (3) Experimental results indicate that basaltic sediment chemisorbs phosphate (pH < 7). (4) In experimental systems containing water, basaltic sediment, and a starting pH = 2-7, phosphate has higher solubility in chloride-rich fluids, but significantly lower solubility in sulfate-rich fluids. For example, in water doped with phosphate (~100-500 mg/L), ~60-80% of the PO43- was removed from the sulfate-rich fluid, whereas ~20% of the PO43- was removed from the Cl-rich and pure water fluids (likely via adsorption). Gypsum precipitated from the sulfate-rich fluids; the fate of phosphate in the solid residue is unconfirmed. The potential for phosphate incorporation in martian sulfates is reflected in the enrichment of P2O5 in Gale Ca-sulfate veins, based on preliminary analyses of APXS data. Models for the mobility of phosphorus in Gale crater should consider these conflicting P characteristics: (1) P solubility may have been inhibited by sulfate and (2) P¬ is enriched in diagenetic features and was therefore mobile.

Jeff A. Berger↗

A proposed architecture for a satellite-based mobile communications network - The lowest three layers

Architecture for a commercial mobile satellite network is proposed. The mobile satellite system (MSS) is composed of a network management center, mobile terminals, base stations, and gateways; the functions of each component are described. The satellite is a 'bent pipe' that performs frequency translations, and it has multiple UHF beams. The development of the MSS design based on the seven-layer open system interconnection model is examined. Consideration is given to the functions of the physical, data link, and network layers and the integrated adaptive mobile access protocol.

Yan, T. Y.↗

Data and Reasoning Fabric (DRF) Phase I & Phase II Report

A Data & Reasoning Fabric (DRF) is envisioned to enable the full potential of advanced air mobility by providing all data and reasoning where they are needed. The DRF marketplace is based on an open foundational ecosystem of data and reasoning exchange between the many systems that must seamlessly interplay to manage the envisioned highly complex and dense airspace operations. DRF activities will identify, test and - as needed - research and develop critical core technologies, and collaboratively test these technologies, open standards and architectures, and the integrated framework with end-users so as to deliver reference designs and development environments that catalyze broad private and public sector buy-in and self-sustaining development of it and associated standards.

UAM↗

A Data & Reasoning Fabric to Enable Advanced Air Mobility

A Data & Reasoning Fabric (DRF) is envisioned to enable the full potential of advanced air mobility by providing all data and reasoning where they are needed. The DRF marketplace is based on an open foundational ecosystem of data and reasoning exchange between the many systems that must seamlessly interplay to manage the envisioned highly complex and dense airspace operations. DRF activities will identify, test and - as needed - research and develop critical core technologies, and collaboratively test these technologies, open standards and architectures, and the integrated framework with end-users so as to deliver reference designs and development environments that catalyze broad private and public sector buy-in and self-sustaining development of it and associated standards.

Urban Air Mobility↗

Dynamical Ion Correlations in Polymer and Membrane Electrolytes: Recent Advances and Open Questions

Ion transport in polymer and membrane electrolytes is often described using uncorrelated models like the Nernst–Einstein (NE) approximation, which link conductivity, transference number, and salt diffusivity to individual ion mobilities. However, growing evidence shows that dynamical ion correlations─arising from ion pairing, polymer-mediated coupling, confinement, and electrostatic interactions─can substantially alter macroscopic transport properties. The Onsager transport formalism offers a rigorous framework to quantify these effects via cross-correlated ionic displacements. This Perspective highlights how such correlations manifest across dry and hydrated systems, including salt-doped polymers, block copolymers, hydrogels, and ion-exchange membranes. Here, we examine key physical origins, the influence of salt chemistry and polymer structure, and open questions in measuring and controlling correlated motion. Embracing correlation-aware design enables new pathways to optimize conductivity, transference number, and selectivity─shifting the focus from individual ion mobility to engineered collective dynamics for next-generation electrolytes in energy storage and separations.

Charge transport↗

Investigating the interconnectedness of active transportation and public transit usage as a primer for Mobility-as-a-Service adoption and deployment

With the advent of Mobility-as-a-Service packages to reduce car usage and (by extension) greenhouse gas emissions, it is crucial that researchers and practitioners consider mutual determinants and outcomes that link the adoption of multiple alternative modes. This study therefore investigates the joint usage of active travel (walking, cycling, bike-sharing) and public transit (bus, rail) modes with respect to personal and situational contexts. Online survey data (n = 826) were collected across six Midwestern U.S. states using Amazon MTurk. Respondents indicated their average weekly usage of eight travel modes across three trip purposes so that multimodality could be assessed. Several psychological constructs were extracted via (a) the stages of change framework, used to indicate willingness to adopt new behavior, and (b) confirmatory factor analysis conducted on Likert scales rooted in theories of community, identity, norms, personality, and well-being. A multiple-indicators multiple-causes structural equation model is then employed to investigate the process of adopting a modality style that incorporates active and transit modes. The model confirms that compatible physical and social contexts, as well as navigational skills and openness to learning, are key primers of multimodalism. However, a path juncture stemming from neighborhood support for mobility innovation illustrates a potential polarity in outcomes between individuals and communities. In addition, the stage of active mobility adoption is linked to identity and norm activation, offering further guidance on what influences readiness for change. The seamless integration of mobility services is critical to matching the convenience and comfort of the private vehicle; understanding potential pathways to sustainable mobility, though, requires analyses and interventions that are driven by well-being outcomes and grounded in rigorous psychological frameworks. Here, the research findings offer practical guidance for identifying intervention opportunities to be linked with MaaS enrollment while demonstrating the need to illuminate how mobility might relate to social cohesion, identity expression, and various sources of satisfaction.

42 ENGINEERING↗

Iron crystals in lunar breccias

Many of the vugs in the highly recrystallized breccias from Apollos 14, 15, and 16 contain euhedral iron crystals. Three populations have been recognized based on crystal habit. In the first group the trapezohedron predominates and the cube faces are smaller. The second group is characterized by the cube as the dominant form; trapezohedron and tetrahexahedron faces are smaller and about equally developed. The dominant habit of the third group is the octahedron with smaller but equally developed cube and dodecahedron faces. Iron has been mobilized and redistributed in a vapor phase. The euhedral crystals, the abundant growth steps, and the open network of substrate crystals clearly support the concept of growth from a vapor-phase.

Clanton, U. S.↗

Thermal metamorphism of primitive meteorites. XI - The enstatite meteorites: Origin and evolution of a parent body

The neutron activation data for Ag, As, Bi, Cd, Co, Cs, Cu, Ga, In, Rb, Se, Te, Tl, and Zn were obtained in samples of Abee heated to 1000-1400 C at low pressures. In addition, these elements were reported in nine enstatite achondrites and in the silicate part of the Mt. Egerton stony-iron. The data show trace element losses above 1000 C by diffusion-controlled processes with apparent activation energies of 8 to 55 kcal/mol; these data together with abundances of aubrites, Mt. Egerton, and E4-6 chondrites, and isotopic results link all enstatite meteorites to a common parent body. The data also indicate that aubrites and the Mt. Egerton material reflect fractional crystallization of a magma produced from enstatite chondrite-like parent material (E6) and the late introduction of chalcophiles and mobile elements transported by an FeS-Fe eutectic from an E4-6 region undergoing open-system metamorphism.

Biswas, S.↗

Shifting temporal dynamics of human mobility in the United States

In this paper we analyze the average hourly temporal dynamics of human mobility in the United States from 2019 to 2020. We discuss how large decreases in human mobility nonuniformly effect the daily temporal dynamics of aggregate human behavior. The data used are weekly activity patterns for POIs from 2019 to 2020 in the United States, provided by SafeGraph and made openly available to academic and research institutions. We use clustering methods to create metrics describing how human activity changes throughout the day/week at the county and national levels. In response to significant mobility reductions starting March 2020, daily temporal patterns of human activity changed nonuniformly. Morning activity started later, and evening activity started earlier in 2020 compared to 2019, and temporal behavioral patterns on weekdays began to look more similar to weekends. The changes in daily temporal behavior persisted throughout the year even as total mobility levels recovered. The results provide insights on the changes in human behavior in response covid-19 policies and illustrate influences on social systems, health, and transportation networks.

99 GENERAL AND MISCELLANEOUS↗

Understanding Mobility Behavior Using OpenPATH

In this presentation, we present the motivation behind the creation of NRELOpenPATH, what data the tool can collect, how the app works, and how interested parties can set up a deployment for their own project. OpenPATH is unique in it's ability to engage users in longitudinal travel diary collection with a smartphone app. The app allows projects to examine the modes of users travel, as well as the purpose of that travel. Many deployments have examined the way users travel by e-bike, and the app supports data collection across all modes to gain a holistic view of mobility behavior. The app is configurable for each deployment, and we will describe the way in which NREL hosts project deployments of our open-source project. As this presentation is a part of a panel, time for questions will be included.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

The effect of minority carrier mobility variations on the performance of high voltage silicon solar cells

A multistep diffusion processing schedule is described which allows the attainment of high open circuit voltages in 0.1 ohm/cm silicon cells. The schedule consists of a deep primary diffusion, followed by an acid etch of emmitter surface which is then followed by a shallow secondary diffusion. A correlation is made between the observed voltage increases and the time of primary diffusion. Results indicate that as the primary diffusion time increases, the voltage rises monotonically.

Weizer, V. G.↗

Rapid Assessment of Contrast Sensitivity with Mobile Touch-screens

The availability of low-cost high-quality touch-screen displays in modern mobile devices has created opportunities for new approaches to routine visual measurements. Here we describe a novel method in which subjects use a finger swipe to indicate the transition from visible to invisible on a grating which is swept in both contrast and frequency. Because a single image can be swiped in about a second, it is practical to use a series of images to zoom in on particular ranges of contrast or frequency, both to increase the accuracy of the measurements and to obtain an estimate of the reliability of the subject. Sensitivities to chromatic and spatio-temporal modulations are easily measured using the same method. We will demonstrate a prototype for Apple Computer's iPad-iPod-iPhone family of devices, implemented using an open-source scripting environment known as QuIP (QUick Image Processing,

mobile devices↗

Nanorovers and Subsurface Explorers for Mars

Recent advances in microtechnology and mobile robotics have made it feasible to create extremely small automated or remote-controlled vehicles which open new application frontiers. One of these possible applications is the use of nanorovers (robotic vehicles with a mass of order one kilogram or less) in planetary exploration. NASA and Japan's Institute of Space and Astronautical Science (ISAS) are cooperating on the first mission to collect samples from the surface of an asteroid and return them to Earth for in-depth study. The ISAS MUSES-C mission will be launched on a Japanese launch vehicle in July 2002 from Japan toward a rendez-vous with the asteroid 1989ML in September 2003. A NASA-provided nanorover will conduct in-situ measurements on the surface. With a mass of about one kilogram, the rover experiment will be a direct descendant of the technology used to build the Sojourner rover. The rover will carry three science instruments: (1) a visible imaging camera, (2) a near-infrared point spectrometer, and (3) an alpha X ray spectrometer. The solar-powered rover will move around the surface of 1989ML collecting imagery data, which are complimentary to the spacecraft investigation. The imaging system will be capable of making surface texture, composition, and morphology measurements at resolutions better than one millimeter. The rover will transmit this data to the spacecraft for relay back to Earth. Due to the microgravity environment on 1989ML, the rover has been designed to right itself in case it flips over. Solar panels on four sides of the rover will ensure that enough power will always be available to the rover to activate the motors needed to turn over. Posable struts will allow the rover to position its chassis such that the camera can be pointed straight down at the surface or straight up at the sky.

Wilcox, Brian H.↗

A~1 Kilogram Asteroid Exploration Rover

Recent advances in microtechnology and mobile robotics have made it feasible to create extremely small automated or remote-controlled vehicles which open new application frontiers.

kilogram asteroid exploration rover↗

Nanorover Technology and the MUSES-CN Mission

The National Aeronautics and Space Administration has been sponsoring efforts to develop very small planetary rovers for Mars and other planetary bodies. Recent advances in microtechnology and mobile robotics have made it feasible to create extremely small automated or remote-controlled vehicles which open new application frontiers.

nanorover MUSES-C asteriod Nereus.↗

Highly Efficient Ternary Solar Cells with Efficient Förster Resonance Energy Transfer for Simultaneously Enhanced Photovoltaic Parameters

Introducing a third component into organic bulk heterojunction solar cells has become an effective strategy to improve photovoltaic performance. Meanwhile, the rapid development of non-fullerene acceptors (NFAs) has pushed the power conversion efficiency (PCE) of organic solar cells (OSCs) to a higher standard. In this study, a series of fullerene-free ternary solar cells are fabricated based on a wide bandgap acceptor, IDTT-M, together with a wide bandgap donor polymer PM6 and a narrow bandgap NFA Y6. Insights from the morphological and electronic characterizations reveal that IDTT-M has been incorporated into Y6 domains without disrupting its molecular packing and sacrificing its electron mobility and work synergistically with Y6 to regulate the packing pattern of PM6, leading to enhanced hole mobility and suppressed recombination. IDTT-M further functions as an energy-level mediator that increases open-circuit voltage ( V OC ) in ternary devices. In addition, efficient Förster resonance energy transfer (FRET) between IDTT-M and Y6 provides a non-radiative pathway for facilitating exciton dissociation and charge collection. As a result, the optimized ternary device features a significantly improved PCE up to 16.63% with simultaneously enhanced short-circuit current ( J SC ), V OC , and fill factor (FF).

36 MATERIALS SCIENCE↗

Integrating Mercury Concentrations in American Alligators ( Alligator mississippiensis ) with Hunter Consumption Surveys to Estimate Exposure Risk

Mercury is a naturally occurring element but is also considered a widespread contaminant due to global anthropogenic activity. Even in moderate amounts, mercury (Hg) is an established neurotoxin and is associated with a range of adverse outcomes both in humans and wildlife. Humans in the United States are most commonly exposed to Hg through contaminated food or drinking water, and the consumption of game species, particularly those occupying higher trophic levels, has the potential to expose hunters to high concentrations of Hg. In the present study, we determined Hg concentrations in tail muscle and blood from American alligators (Alligator mississippiensis) inhabiting a region (Savannah River Site, SC, USA) with known Hg contamination. We then integrated these data with alligator harvest records and previously published surveys of alligator meat consumption patterns to estimate potential exposure risk. We found that the average Hg concentrations in tail muscle (1.34 mg/kg, wet wt) from sampled alligators exceeded the recommended threshold for Hg exposure based on the World Health Organization's guidelines (0.5mg/kg, wet wt). In addition, based on regional consumption patterns reported for both adults and children, we estimated Hg exposures (x¯ Adult = 0.419 μg/kg/day, x¯ Child = 2.24 μg/kg/day) occurring well above the US Environmental Protection Agency methylmercury reference dose of 0.1 μg/kg/day. Although the two reservoirs sampled in the present study are not currently open to alligator hunting, they are connected to waters that are publicly accessible, and the extent of alligator mobility across these sites is not known. Together, the findings reported in the present study further demonstrate the need for active monitoring of Hg concentrations in game species, which can convey substantial exposure risks to the public.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗