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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Multiwavelength pyrometry for nongray surfaces in the presence of interfering radiation

A NASA developed multiwavelength pyrometry technique for nongray surfaces was extended to also measure surface temperature in the presence of interfering radiation. This radiation is produced by heat lamps used to raise the temperature of the surface. The necessary instruments are a spectral radiometer, an auxiliary radiation source, and a computer. Four radiation spectra are recorded: (1) the unobstructed spectrum characterizing an auxiliary radiation source; (2) the unobstructed spectrum characterizing the interfering radiation; (3) the radiation spectrum consisting of surface emission plus the interfering radiation; and (4) a spectrum consisting of the radiations of (3) plus the reflected radiation due to the incidence of the auxiliary radiation source on this surface. With these spectra, application of two variable, nonlinear, least squares, curve fitting computer software determines the surface temperature and the spectral emissivity. Use of the method to measure the surface temperature of silicon carbide under a simulated interference condition is shown at a low temperature just above ambient. The instrumentation necessary to extend the method to elevated temperatures is discussed.

Ng, Daniel↗
NASA NTRS1992

Ground-based infrared measurements of carbonyl sulfide total column abundances - Long-term trends and variability

Attention is given to total vertical column abundances of carbonyl sulfide (OCS) derived from time series of high-resolution IR solar absorption spectra recorded near Tucson, Arizona, and in the Swiss Alps. The analysis of both data sets is based on nonlinear least squares spectral fittings of narrow intervals centered on lines of the intense nu3 band of OCS, the P(37) transition at 2045.5788/cm, and the P(15) transition at 2055.8609/cm, with a consistent set of spectroscopic line parameters. The Arizona measurements, recorded on 20 different days between May 1977 and March 1991, show a 10-percent peak-to-peak seasonal cycle with a summer maximum and a winter minimum and a trend in the total column abundance equal to (0.1 +/-0.2) percent/yr, 2sigma. The Alpine total columns exhibit a more complex seasonal variation than noted in the Arizona data. The results from the two sites indicate that there has been no significant change in the OCS total column abundance at northern midlatitudes over the last decade.

Rinsland, C. P.↗
NASA NTRS1992

A convected kappa distribution model for hot ions in the Jovian magnetodisc

Hot ion angular anisotropies measured by the Low Energy Charged Particle (LECP) instrument during the Voyager 2 encounter with the Jovian dayside outer magnetosphere (60-30 RJ) have been fitted to a 2 species convected kappa distribution function using a nonlinear least squares technique. The resulting parameters are well constrained by the data. The heavy ion species was assumed to be either sulfur or oxygen of unknown charge. The light species was assumed to be protons. The bulk flow speeds deduced from the model were found, contrary to some theories, to increase with increasing radial distance from Jupiter within the radial region addressed, remaining a substantial fraction (0.6) of the rigid corotation speed. Agreement with the averaged Voyager Plasma Science results was obtained near 30 RJ. The core Maxwellian temperature of the heavy ion distribution functions (30-100 keV) increased with increasing radial distance, following the trend anticipated from the corotation pickup of heavy ions. The proton temperature (20 keV) remained nearly constant.

Kane, M.↗
NASA NTRS1992

An evaluation of corrosion protection by two epoxy primers on 2219-T87 and 7075-T73 aluminum

A comparison of the corrosion protection provided by two amine epoxy primers was made using salt fog, alternate immersion, and total immersion as exposure media. The study is the result of a request to use an unqualified low volatile organic carbon (VOC) primer (AKZO 463-6-78) in place of the current primer (AKZO 463-6-3) because environmental regulations have eliminated use of the current primer in many states. Primed, scribed samples of 2219-T87 and 7075-T73 aluminum were exposed to 5-percent NaCl salt fog and 3.5-percent NaCl alternate immersion for a period of 90 days. In addition, electrode samples immersed in 3.5-percent NaCl were tested using electrochemical impedance spectroscopy (EIS). The EG&G model 368 ac impedance measurement system was used to monitor changing properties of AKZO 463-6-78 and AKZO 463-6-3 primed 2219-T87 aluminum for a period of 30 days. The response of the corroding system of a frequency scan can be modeled in terms of an equivalent circuit consisting of resistors and capacitors in a specific arrangement. Each resistor/capacitor combination represents physical processes taking place within the electrolyte, at the electrolyte/primer surface, within the coating, and at the coating/substrate surface. Values for the resistors and capacitors are assigned following a nonlinear least squares fit of the data to the equivalent circuit. Changes in the values of equivalent circuit parameters during the 30-day exposure allow assessment of the time to and mechanism of coating breakdown.

Mendrek, M. J.↗
NASA NTRS1992

Solar O I 1304-A triplet line profiles

Estimates were made of the full-disk line profiles of the solar O I resonant triplet at 1304 A, using data from the SMM and the Orbiting Solar Observatory 8 for the time period 1975-1985. The observed line profiles are parameterized using a nonlinear least squares fit of the data by a simple empirical representation of the general line shape. The derived full-disk line shape parameters may be used, in combination with an appropriate value for the line-integrated full-disk solar flux, in the analysis of planetary or cometary O I 1304-A observations under any solar conditions.

Gladstone, G. R.↗
NASA NTRS1993

Multiple degree of freedom force-state component identification

Force-state mapping is extended to allow the quasistatic characterization of realistic multiple degree of freedom systems whose constitutive relations are nonlinear, dissipative, coupled and depend on memory of past states. A general constitutive force-state model is formulated, which includes dynamic hysteresis phenomena typical of that found in deployable structures. A two step parameter identification approach is developed, which employs a linear extended Kalman filter and a nonlinear least squares fit. A six degree of freedom force-state testing device was constructed, and used to obtain data on one bay of a simple truss and on one bay of the MODE deployable truss.

Masters, Brett P.↗
NASA NTRS1993

The millimeter-wave spectrum of CaH (X 2Sigma(+))

The millimeter-wave spectrum of the CaH and CaD radicals (X 2Sigma(+)) has been observed in the laboratory via direct absorption spectroscopy. The species were generated by the reaction of calcium vapor, produced in a Broida-type oven, with hydrogen atoms created in a microwave discharge. The six hyperfine components of the N = 0 yields 1 rotational transition of CaH near 254 GHz were resolved and their frequencies determined to an accuracy of +/- 100 kHz. The main hyperfine lines originating in the N = 0 yields 1, 1 yields 2, and 2 yields 3 rotational transitions of CaD were also detected. Spectroscopic constants were determined for both radicals from a nonlinear least squares fit to the data, using a 2Sigma Hamiltonian. These measurements constitute the first laboratory observation of CaH at high spectral resolution, and are essential to the detection of this radical in interstellar space.

Barclay, W. L., Jr.↗
NASA NTRS1993

Estimating snow grain size using AVIRIS data

Estimates of snow grain size for the near-surface snow layer were calculated for the Tioga Pass region and Mammoth Mountain in the Sierra Nevada, California, using an inversion technique and data collected by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The Tioga Pass and Mammoth Mountain single-band AVIRIS radiance images were atmospherically corrected to obtain surface reflectance. A discrete-ordinate model was used to calculate directional reflectance as a function of snowpack grain size for a wide range of snow grain radii. The resulting radius vs. reflectance curves were each fit using a nonlinear least squares technique which provided a means of transforming surface reflectance in each AVIRIS image to optically equivalent grain size on a per-pixel basis. The model results and grain size estimates derived from the AVIRIS data show that, for solar incidence angles between 0 and 30, the technique provides good estimates of grain size. This work provides the first quantitative estimates for grain size using data acquired from an airborne remote sensing instrument and is an important step in improving our ability to retrieve snow physical properties independent of field measurements.

Nolin, Anne W.↗
NASA NTRS1993

Chemical kinetic studies of atmospheric reactions using tunable diode laser spectroscopy

IR absorption using tunable diode laser spectroscopy provides a sensitive and quantitative detection method for laboratory kinetic studies of atmospheric trace gases. Improvements in multipass cell design, real time signal processing, and computer controlled data acquisition and analysis have extended the applicability of the technique. We have developed several optical systems using off-axis resonator mirror designs which maximize path length while minimizing both the sample volume and the interference fringes inherent in conventional 'White' cells. Computerized signal processing using rapid scan (300 kHz), sweep integration with 100 percent duty cycle allows substantial noise reduction while retaining the advantages of using direct absorption for absolute absorbance measurements and simultaneous detection of multiple species. Peak heights and areas are determined by curve fitting using nonlinear least square methods. We have applied these techniques to measurements of: (1) heterogeneous uptake chemistry of atmospheric trace gases (HCl, H2O2, and N2O5) on aqueous and sulfuric acid droplets; (2) vapor pressure measurements of nitric acid and water over prototypical stratospheric aerosol (nitric acid trihydrate) surfaces; and (3) discharge flow tube kinetic studies of the HO2 radical using isotopic labeling for product channel and mechanistic analysis. Results from each of these areas demonstrate the versatility of TDL absorption spectroscopy for atmospheric chemistry applications.

Worsnop, Douglas R.↗
NASA NTRS1992

A linear spectral matching technique for retrieving equivalent water thickness and biochemical constituents of green vegetation

Over the last decade, technological advances in airborne imaging spectrometers, having spectral resolution comparable with laboratory spectrometers, have made it possible to estimate biochemical constituents of vegetation canopies. Wessman estimated lignin concentration from data acquired with NASA's Airborne Imaging Spectrometer (AIS) over Blackhawk Island in Wisconsin. A stepwise linear regression technique was used to determine the single spectral channel or channels in the AIS data that best correlated with measured lignin contents using chemical methods. The regression technique does not take advantage of the spectral shape of the lignin reflectance feature as a diagnostic tool nor the increased discrimination among other leaf components with overlapping spectral features. A nonlinear least squares spectral matching technique was recently reported for deriving both the equivalent water thicknesses of surface vegetation and the amounts of water vapor in the atmosphere from contiguous spectra measured with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The same technique was applied to a laboratory reflectance spectrum of fresh, green leaves. The result demonstrates that the fresh leaf spectrum in the 1.0-2.5 microns region consists of spectral components of dry leaves and the spectral component of liquid water. A linear least squares spectral matching technique for retrieving equivalent water thickness and biochemical components of green vegetation is described.

Gao, Bo-Cai↗
NASA NTRS1992

The European Southern Observatory-MIDAS table file system

The new and substantially upgraded version of the Table File System in MIDAS is presented as a scientific database system. MIDAS applications for performing database operations on tables are discussed, for instance, the exchange of the data to and from the TFS, the selection of objects, the uncertainty joins across tables, and the graphical representation of data. This upgraded version of the TFS is a full implementation of the binary table extension of the FITS format; in addition, it also supports arrays of strings. Different storage strategies for optimal access of very large data sets are implemented and are addressed in detail. As a simple relational database, the TFS may be used for the management of personal data files. This opens the way to intelligent pipeline processing of large amounts of data. One of the key features of the Table File System is to provide also an extensive set of tools for the analysis of the final results of a reduction process. Column operations using standard and special mathematical functions as well as statistical distributions can be carried out; commands for linear regression and model fitting using nonlinear least square methods and user-defined functions are available. Finally, statistical tests of hypothesis and multivariate methods can also operate on tables.

Peron, M.↗
NASA NTRS1993

Are existing magnetospheric models excessively stretched?

The distribution of the average north-south magnetic field component Bz in the vicinity of the neutral sheet has been investigated. This component is crucial for mappings between the nightside polar ionosphere and the equatorial magnetosphere. Data sets consisting of about 0.5 R(E) averages of magnetic field observations by the IMP/HEOS and ISEE spacecraft have been compared to the field predicted by the Tsyganenko (1987, 1989) models T87 and T89. It was found that both T87 and T89 underestimate Bz in the near tail region by as much as a factor of 2. Modified versions of the T87 model, incorporating plasma sheet warping, were obtained by fitting the model parameters via nonlinear least squares to the ISEE data set and yielded Bz values in agreement with the ISEE data. The study reveals an enormous scatter among the observed baseline values of Bz (on a time scale of 10-20 min), as well as intrinsic biases imposed by the mathematical structure of tail models, and these two factors (especially the first one) greatly limit the accuracy of model predictions of tail Bz.

Peredo, Mauricio↗
NASA NTRS1994

Statistic analysis of annual total ozone extremes for the period 1964-1988

Annual extremes of total column amount of ozone (in the period 1964-1988) from a network of 29 Dobson stations have been examined using the extreme value analysis. The extremes have been calculated as the highest deviation of daily mean total ozone from its long-term monthly mean, normalized by the monthly standard deviations. The extremes have been selected from the direct-Sun total ozone observations only. The extremes resulting from abrupt changes in ozone (day to day changes greater than 20 percent) have not been considered. The ordered extremes (maxima in ascending way, minima in descending way) have been fitted to one of three forms of the Fisher-Tippet extreme value distribution by the nonlinear least square method (Levenberg-Marguard method). We have found that the ordered extremes from a majority of Dobson stations lie close to Fisher-Tippet type III. The extreme value analysis of the composite annual extremes (combined from averages of the annual extremes selected at individual stations) has shown that the composite maxima are fitted by the Fisher-Tippet type III and the composite minima by the Fisher-Tippet type I. The difference between the Fisher-Tippet types of the composite extremes seems to be related to the ozone downward trend. Extreme value prognoses for the period 1964-2014 (derived from the data taken at: all analyzed stations, the North American, and the European stations) have revealed that the prognostic extremes are close to the largest annual extremes in the period 1964-1988 and there are only small regional differences in the prognoses.

Krzyscin, Janusz W.↗
NASA NTRS1994

Radiative transfer code based estimation of atmospheric parameters for inversion of imaging spectrometer measured radiance to apparent surface reflectance

Surface reflectance is required to quantitatively investigate molecular absorption and particle scattering properties of materials on the Earth's surface. Atmospheric aerosol optical depth, surface pressure and water vapor are required to constrain a radiative transfer code for the inversion of measured spectral radiance to apparent surface reflectance. A suite of algorithms using nonlinear least squares fitting techniques are described that directly estimate these atmospheric parameters from spectral radiance measured by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The derived atmospheric parameters are used to constrain a radiative transfer code for the inversion of the imaging spectrometer radiance to apparent reflectance. The derived apparent reflectance is validated with respect to in situ measurement on the same target.

Green, Robert O.↗
NASA NTRS1995

Modeling of aircraft unsteady aerodynamic characteristics. Part 2: Parameters estimated from wind tunnel data

Aerodynamic equations with unsteady effects were formulated for an aircraft in one-degree-of-freedom, small-amplitude, harmonic motion. These equations were used as a model for aerodynamic parameter estimation from wind tunnel oscillatory data. The estimation algorithm was based on nonlinear least squares and was applied in three examples to the oscillatory data in pitch and roll of 70 deg triangular wing and an X-31 model, and in-sideslip oscillatory data of the High Incidence Research Model 2 (HIRM 2). All three examples indicated that a model using a simple indicial function can explain unsteady effects observed in measured data. The accuracy of the estimated parameters and model verification were strongly influenced by the number of data points with respect to the number of unknown parameters.

Klein, Vladislav↗
NASA NTRS1995

Laboratory detection and millimeter spectrum of the MgCCH radical

The pure rotational spectrum of the magnesium monoacetylide radical, MgCCH, has been recorded in the laboratory using millimeter/sub-mm direct absorption spectroscopy. These measurements constitute the first time this molecule has been observed in the laboratory by any spectroscopic method. Seventeen rotational transitions were observed in the frequency range 210-370 GHz for MgCCH, which appears to be a linear molecule with a (sup 2)Sigma ground electronic state. Rotational and fine structure constants were determined for this radical from a nonlinear least squares fit to the data. The rotational rest frequencies measured here will enable astronomical observations to be carried out for MgCCH towards IRC +10216, where the magnesium compounds MgCN and MgNC, as well as many acetylide species, are present.

Anderson, M. A.↗
NASA NTRS1995

Spectroscopic study of the seasonal variation of carbon monoxide vertical distribution above Kitt Peak

A method to retrieve elements of the carbon monoxide (CO) vertical distribution from ground-based high-resolution infrared solar spectra has been developed. The method is based on the fact that the total column amount retrieved by nonlinear least squares spectral fitting techniques depends on the shape of the assumed a priori profile and this dependence is a function of the absorption line intensity and the lower state energy of the transition. Four CO lines between 2057 and 2159/cm have been selected and the method has been tested on synthetic spectra. The CO total column content and average concentrations in two atmospheric layers (surface to 400 mbar and 400 mbar to the top of the atmosphere) can be retrieved with precisions of about 1% and less than 10%, respectively. Solar spectra recorded at Kitt Peak from 1982 to 1993 have been analyzed. The CO total column and the average concentration in the two layers show an asymmetrical seasonal cycle with extreme values of (1.1-2.1) x 10(exp 18) molecules cm(exp -2), (50-80) parts per billion by volume (ppbv) in the top layer and (80-160) ppbv in the bottom layer, and precisions of 1, 3, and 6%, respectively; a spring maximum and late summer minimum are observed.

Pougatchev, N. S.↗
NASA NTRS1995

Neptune inbound bow shock

Voyager 2 crossed the inbound or upstream Neptunian bow shock at 1430 spacecraft event time on August 24 in 1989 (Belcher et al., 1989). The plasma and magnetic field measurements allow us to study the solar wind interaction with the outermost gas giant. To fully utilize all of the spacecraft observations, an improved nonlinear least squares, 'Rankine-Hugoniot' magnetohydrodynamic shock-fitting technique has been developed (Szabo, 1994). This technique is applied to the Neptunian data set. We find that the upstream bow shock normal points nearly exactly toward the Sun consistent with any reasonable large-scale model of the bow shock for a near subsolar crossing. The shock was moving outward with a speed of 14 +/- 12 km/s. The shock can be characterized as a low beta, high Mach number, strong quasi-perpendicular shock. Finally, the shock microstructure features are resolved and found to scale well with theoretical expectations.

Szabo, Adam↗