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At least 109 records · Page 6

Using Spectral Measurements to Characterize Solar Reference Cells on a Two-Axis Tracker

A study is commencing relating the spectral responsivity of reference cells in the field to changing spectral distribution during the day. Initial results indicate that measurements of the incident spectral distribution can be used to match results of reference cell measurements on a two-axis tracker with a standard deviation of ±0.25% under clear-sky conditions. Initial results are provided. As more data are obtained covering a variety of field conditions and locations, the robustness of these results will be tested. The website https://midcdmz.nrel.gov/apps/sitehome.pl?site=PVRES contains the data generated by this project.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Improved Primary Reference Cell Calibrations for Higher Accuracy Photovoltaic Cell and Module Performance Measurements

The adoption of photovoltaic (PV) modules for clean electricity relies on accurate measurements of their performance, which are essential for estimating their energy production potential. Herein, the calibration chain of PV cells and modules, with particular emphasis on primary reference cell calibrations, is discussed. Also, herein, the direct sunlight method the group has developed for these calibrations is presented and critical improvements and upgrades that lead to calibration uncertainty as low as 0.45% are discussed. The ultimate motivation behind this work is to provide low‐uncertainty performance measurements of PV modules, and lowering the calibration uncertainty of primary reference cells is a key first step toward achieving this goal. As the use of solar electricity continues to grow, the demand for primary reference cell calibrations inevitably increases beyond what the small handful of primary calibration laboratories can provide today. Therefore, this work can serve as a useful guide for implementing primary PV reference cell calibrations using the outdoor method, as well as outlining the critical elements required to make these calibrations highly accurate.

Osterwald, Carl R.↗

An Interaction-Free Quantum Measurement-Driven Engine

Recently highly-efficient quantum engines were devised by exploiting the stochastic energy changes induced by quantum measurement. Here we show that such an engine can be based on an interaction-free measurement, in which the meter seemingly does not interact with the measured object. We use a modified version of the Elitzur–Vaidman bomb tester, an interferometric setup able to detect the presence of a bomb triggered by a single photon without exploding it. In our case, a quantum bomb subject to a gravitational force is initially in a superposition of being inside and outside one of the interferometer arms. We show that the bomb can be lifted without blowing up. This occurs when a photon traversing the interferometer is detected at a port that is always dark when the bomb is located outside the arm. The required potential energy is provided by the photon (which plays the role of the meter) even though it was not absorbed by the bomb. A natural interpretation is that the photon traveled through the arm which does not contain the bomb—otherwise the bomb would have exploded—but it implies the surprising conclusion that the energy exchange occurred at a distance despite a local interaction Hamiltonian. We use the weak value formalism to support this interpretation and find evidence of contextuality. Regardless of interpretation, this interaction-free quantum measurement engine is able to lift the most sensitive bomb without setting it off.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Measure this, not that: Optimizing the cost and model-based information content of measurements

Model-based design of experiments (MBDoE) is a powerful framework for selecting and calibrating science-based mathematical models from data. Here, this work extends popular MBDoE workflows by proposing a convex mixed integer (non)linear programming (MINLP) to optimize the selection of measurements. The solver MindtPy is modified to support calculating the D-optimality objective and its gradient via an external package, scipy, using the grey-box module in Pyomo. The new approach is demonstrated in two case studies: estimating highly correlated kinetics from a batch reactor and estimating transport parameters in a large-scale rotary packed bed for CO 2 capture. Both case studies show how examining the Pareto optimal trade-offs between information content measured by A- and D-optimality versus measurement budget offers practical guidance for selecting measurements for scientific experiments.

97 MATHEMATICS AND COMPUTING↗

Tidal energy resource characterization measurements at Cook Inlet’s East Foreland: Velocity and turbulence

To characterize tidal current and turbulence at a top tidal energy site off the East Foreland in Cook Inlet, Alaska, United States, three moorings were deployed for two months between July and August 2021, and a transect survey was conducted over the course of two tidal cycles at the end of the deployment period. Measurements of velocity and turbulence were then analyzed to better understand the site's hydrodynamics and power potential. Analysis reveals that swift, north-flowing flood currents peak at 4~m/s, while south-flowing ebb currents reach just over 3~m/s. Turbulence intensity ranges from 23\% at the seafloor to 8\% near the surface, and the presence of the foreland creates more intense turbulence near-shore during ebb tide than flood. Power availability at the site could be as high as 720~MW, or 13~kW/m$^2$, though the energy available to a marine energy device will be smaller than this estimate because of water-to-wire efficiency and wake losses. The results from this measurement campaign will inform the validation of a high-resolution tidal hydrodynamic model, as well as early tidal energy projects that are beginning to move beyond the prototyping and demonstration stages to full-scale deployments.

McVey, James R.↗

Interference fringe (IF) technique for droplet contact angle and thickness measurements: Ultralow contact angle and nanoscale thickness measurement

Recently, reflection interference fringe (RIF) and transmission fringe (TIF) techniques have been introduced to investigate the origin of far-field interference fringe (IF) formation and to determine a droplet's contact angle and thickness by measuring the fringe radius. In this study, characteristics of the IF technique are analyzed based on the RIF and TIF by varying the schematics, such as configuration (transmission/reflection), the droplet's side (left-hand side/right-hand side), and the substrate types (flat/prism). The analysis also investigates the refraction effect at the droplet edge and the maximum incidence and contact angles. The schematic variation shows that the widest contact angle range can be measured in a transmission configuration with droplet's right-hand side, and that the fringe radius decreases with incidence angles on a prism substrate, consistent with the recent observation. Refraction at the droplet edge causes the fringe radius to increase or decrease depending on the degree of refraction. Based on the characteristics study, it is revealed that the IF technique can determine nanometer-scale thicknesses below 100 nm on droplets, corresponding to ultra-small contact angles of less than 0.01°, with an extended working distance of 3000 mm and an optimized incidence angle, assuming a spherical profile. This finding is significant, as it demonstrates that the nanoscale thickness can be determined in situ under ambient conditions using a simple optical configuration, without requiring a sophisticated setup, such as a microscope. It is anticipated that the IF technique can be combined with other nanoscale thickness measurement techniques to enhance its measurement reliability.

36 MATERIALS SCIENCE↗

Development and experimental evaluation of new building air leakage measurement methods: measurement of interior air leaks and comparison to conventional methods

Building air leaks (both through exterior and interior surfaces) can have a significant impact on energy consumption, indoor air quality, fire safety, and moisture accumulation affecting structural durability. Blower door testing has been used to measure leaks in buildings, but commonly used testing methods do not directly measure interior leaks. In this paper, new testing methods (guarded interior test and zonal multipoint pressure testing method) are presented that directly measure these interior leaks, utilizing common blower door equipment for both single and multi-point testing. Furthermore, these new methods are compared to conventional methods in terms of the information provided, limitations and time/effort needed. In addition, building leak measurement results are analyzed to reveal a) coupling between power law model values (exponent and coefficient) for an ensemble of buildings, b) the error in using single point testing when estimating low pressure leakage, and c) how building power law models vary from low to high pressure ranges.

99 GENERAL AND MISCELLANEOUS↗

Line Faults Classification Using Machine Learning on Three Phase Voltages Extracted from Large Dataset of PMU Measurements

An end-to-end supervised learning method is developed to classify transmission line faults in a twoyear field-recorded dataset that includes synchronized measurements of three-phase voltages recorded by 38 Phasor Measurement Units (PMU) sparsely located in in the US Western Grid interconnection. Statistical analysis is performed to extract features from this large dataset to train Support Vector Machine (SVM), Random Forest (RF), and eXtreme Gradient Boosting (XGBoost) classifiers initially. The training further leverages a simulated dataset from a synthetic grid with 12 PMUs to increase the number of faults of types infrequently seen in the field-recorded dataset. Training the classification models with the combined dataset resulted in a classification accuracy of 97.7%. This is a significant improvement over 89.7% to 92.5% accuracy obtained by relying on the field-recorded dataset alone.

47 OTHER INSTRUMENTATION↗

Atmospheric ice nuclei concentration measurements over a high altitude-station in the Western Ghats, India

Mixed-phase and ice clouds play a significant role in modulating the Indian summer monsoon rainfall, and modeling studies suggest that inaccurate representation of ice nucleating particles (INP) is one of the factors, which have resulted in a deficiency in the prediction of cloud properties and hydrological cycle. We do not understand the ice nucleation mechanisms to represent the ice formation in the model, and therefore more INP measurements at various supercooled temperatures are needed. This study reports for the first time real-time INP concentration at a high altitude station in the Western Ghats region of India, and these results will be used to constrain the ice nucleation parameterizations in the model. The variation of INP for any particular cloud condition can have strong microphysical responses of mixed-phase precipitation formation processes. Also, to improve the representation of heterogeneous ice nucleation, INP measurements of various types of aerosols commonly observed over the Indian region are needed. This study presents, the INP concentrations and daily concentration of non-refractory chemical composition (organics, sulfate, nitrate, ammonium, and chloride), cloud condensation nuclei (CCN), and aerosol size distribution. Spectrometer for Ice Nuclei (SPIN) was operated to measure INP concentration at the mountain site from August to December 2018. INP measurements were performed at three different temperatures (-25, -30, and - 34 °C) in the immersion freezing mode relevant for mixed-phase cloud conditions. The average INP concentrations approximately varied from 0.18 to 12.4 L-1, 0.39 to 24 L-1, 1.1 to 40.2 L-1 at -25, -30, and - 34 °C, respectively. These concentrations are within the concentrations reported in the literature from different regions across the globe. The air mass back trajectory analysis showed that continental air mass contains more INP compared to maritime air mass. The information on INP concentration and chemical characteristics of aerosol will help to improve heterogeneous ice nucleation parameterization in numerical models.

Kumar, Anil V.↗

Vapor and Liquid ( p –ρ– T–x ) Measurements of Binary Refrigerant Blends Containing R-32, R-152a, R-227ea, R-1234yf, and R-1234ze(E)

In this article, The pressure–density–temperature–composition (p–ρ–T–x) data of binary refrigerant mixtures containing R-32 (difluoromethane), R-152a (1,1,-difluoroethane), R-227ea (1,1,1,2,3,3,3-heptafluoropropane), R-1234yf (2,3,3,3-tetrafluoropropene), and R-1234ze(E) (trans-1,3,3,3-tetrafluoropropene) were measured in both the vapor and liquid phases using a two-sinker, magnetic suspension densimeter. The specific samples in this study comprised two compositions of approximately (0.3/0.7) and (0.7/0.3) mole fraction for each of the following four binary refrigerant blends: R-32 + R-1234yf, R-32 + R-1234ze(E), R-1234yf + R-152a, and R-1234ze(E) + R-227ea. Single-phase vapor densities were measured over a temperature range of approximately 253 to 293 K and pressures from 0.05 to 0.98 MPa. Single-phase liquid and supercritical densities were measured over a temperature range of approximately 230 to 400 K and pressures up to 22 MPa; for refrigerant blends containing R-1234yf, the maximum pressure was limited to 14 MPa. Overall relative combined, expanded (k = 2) uncertainties in density ranged from 0.025 to 0.191%, with an average uncertainty of approximately 0.05%. Here, we present measurement results, along with comparisons to available literature data and to default equations of state and mixture models included in REFPROP.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Broad Applicability of Electrochemical Impedance Spectroscopy to the Measurement of Oxygen Nonstoichiometry in Mixed Ion and Electron Conductors

Oxygen non-stoichiometry is a fundamental feature of mixed ion and electron conductors (MIECs). In this work a general electrochemical method for determining non-stoichiometry in thin film MIECs, via measurement of the chemical capacitance, is demonstrated using ceria and ceria-zirconia (Ce 0.8 Zr 0.2 O 2-δ ) as representative materials. A.C. impedance data are collected from both materials at high temperature (750-900 °C) under reducing conditions with oxygen partial pressure (pO 2 ) in the range 10-13 to 10-20 atm. Additional measurements of ceria-zirconia films are made under relatively oxidizing conditions with pO 2 in the range 0.2 to 10 -4 atm and temperatures of 800-900 °C. Under reducing conditions, the impedance spectra are described by a simple circuit in which a resistor is in series with a resistor and capacitor in parallel, and thickness dependent measurements are used to resolve the capacitance into interfacial and chemical terms. Under more oxidizing conditions, the impedance spectra (of Ce 0.8 Zr 0.2 O 2-δ ) reveal an additional diffusional feature, which enables determination of the ionic resistance of the film in addition to the capacitance, and hence the transport properties. A generalized mathematical formalism is presented for recovering the non-stoichiometry from the chemical capacitance, without recourse to defect chemical models. The ceria non-stoichiometry values are in good agreement with literature values determined by thermogravimetric measurements but display considerably less scatter and are collected on considerably shorter timescales. Here, the thermodynamic analysis of Ce 0.8 Zr 0.2 O 2-δ corroborates earlier findings that introduction of Zr into ceria enhances its reducibility.

08 HYDROGEN↗

Long-term variability of root production in bioenergy crops from ingrowth core measurements

Long-term determination of root biomass production upon land-use conversion to biofuel crops is rare. To assess land-use legacy influences on belowground biomass accumulation, we converted 22-year-old Conservation Reserve Program (CRP) grasslands and 50+-year-old agricultural (AGR) lands to corn (C), switchgrass (Sw) and restored prairie (Pr) biofuel crops. We maintained one CRP grassland as a reference (Ref). We hypothesized that land-use history and crop type have significant effects on root density, with perennial crops on CRP grasslands having a higher root biomass productivity, while corn grown on former agricultural lands produce the lowest root biomass. Methods The ingrowth core method was used to determine in situ ingrowth root biomass, alongside measurements of aboveground net primary productivity (ANPP). Ancillary measurements, including air temperature, growing season length and precipitation were used to examine their influences on root biomass production. Important Findings Root biomass productivity was the highest in unconverted CRP grassland (1716 g m-2 yr-1) and lowest in corn fields (526 g m-2 yr-1). All perennial sites converted from CRP and AGR lands had lower root biomass and ANPP in the first year of planting but peaked in 2011 for switchgrass and a year later for restored prairies. Ecosystem stability was higher in restored prairies (AGR-Pr: 4.3 ± 0.11; CRP-Pr: 4.1 ± 0.10), with all monocultures exhibiting a lower stability. Root biomass production was positively related to ANPP (R2 = 0.40). Overall, attention should be given to root biomass accumulation in large-scale biofuel production as it is a major source of carbon sequestration.

Environmental Sciences & Ecology↗

Assessment of Clonal Expansion Using CarcSeq Measurement of Lung Cancer Driver Mutations and Correlation With Mouse Strain- and Sex-Related Incidence of Spontaneous Lung Neoplasia

Quantification of variation in levels of spontaneously occurring cancer driver mutations (CDMs) was developed to assess clonal expansion and predict future risk of neoplasm development. Specifically, an error-corrected next-generation sequencing method, CarcSeq, and a mouse CarcSeq panel (analogous to human and rat panels) were developed and used to quantify low-frequency mutations in a panel of amplicons enriched in hotspot CDMs. Mutations in a subset of panel amplicons, Braf, Egfr, Kras, Stk11, and Tp53, were related to incidence of lung neoplasms at 2 years. This was achieved by correlating median absolute deviation (MAD) from the overall median mutant fraction (MF) measured in the lung DNA of 16-week-old male and female, B6C3F1 and CD-1 mice (10 mice/sex/strain) with percentages of spontaneous alveolar/bronchioloalveolar adenomas and carcinomas reported in bioassay control groups. A total of 1586 mouse lung mutants with MFs > x 10-4 were recovered. The ratio of nonsynonymous to synonymous mutations was used to assess the proportion of recovered mutations conferring a positive selective advantage. The greatest ratio was observed in what is considered the most lung tumor-sensitive model examined, male B6C3F1 mice. Of the recurrent, nonsynonymous mouse mutations recovered, 55.5% have been reported in human tumors, with many located in or around the mouse equivalent of human cancer hotspot codons. MAD for the same subset of amplicons measured in normal human lung DNA samples showed a correlation of moderate strength and borderline significance with age (a cancer risk factor), as well as age-related cumulative lung cancer risk, suggesting MAD may inform species extrapolation.

Toxicology↗

Measurement of the transverse energy density in Measurement of the transverse energy density in Au + Au collisions at $\sqrt{𝑠_{𝑁⁢𝑁}}$ = 200 GeV with the sPHENIX detector

Here, this paper reports measurements of the transverse energy per unit pseudorapidity (𝑑⁢𝐸 𝑇 /𝑑⁢𝜂) produced in Au + Au collisions at $\sqrt{𝑠_{𝑁⁢𝑁}}$ = 200 GeV, performed with the sPHENIX detector at the Relativistic Heavy Ion Collider (RHIC). The results cover the pseudorapidity range |𝜂| < 1.1 and constitute the first such measurement performed using a hadronic calorimeter at RHIC. Measurements of 𝑑⁢𝐸 𝑇 /𝑑⁢𝜂 are presented for a range of centrality intervals and the average 𝑑⁢𝐸 𝑇 /𝑑⁢𝜂 as a function of the number of participating nucleons, 𝑁 part , is compared to a variety of Monte Carlo heavy-ion event generators. The results are in agreement with previous measurements at RHIC, and feature an improved granularity in 𝜂 and improved precision in low-𝑁 part events.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Measurements of the E-mode polarization and temperature-E-mode correlation of the CMB from SPT-3G 2018 data

We present measurements of the E -mode ( E E ) polarization power spectrum and temperature- E -mode ( T E ) cross-power spectrum of the cosmic microwave background using data collected by SPT-3G, the latest instrument installed on the South Pole Telescope. This analysis uses observations of a 1500 deg 2 region at 95, 150, and 220 GHz taken over a four-month period in 2018. We report binned values of the E E and T E power spectra over the angular multipole range 300 ≤ ℓ < 3000 , using the multifrequency data to construct six semi-independent estimates of each power spectrum and their minimum-variance combination. These measurements improve upon the previous results of SPTpol across the multipole ranges 300 ≤ ℓ ≤ 1400 for E E and 300 ≤ ℓ ≤ 1700 for T E , resulting in constraints on cosmological parameters comparable to those from other current leading ground-based experiments. We find that the SPT-3G data set is well fit by a Λ CDM cosmological model with parameter constraints consistent with those from Planck and SPTpol data. From SPT-3G data alone, we find H 0 = 68.8 ± 1.5 km s - 1 Mpc - 1 and σ 8 = 0.789 ± 0.016 , with a gravitational lensing amplitude consistent with the Λ CDM prediction ( A L = 0.98 ± 0.12 ). We combine the SPT-3G and the Planck data sets and obtain joint constraints on the Λ CDM model. The volume of the 68% confidence region in six-dimensional Λ CDM parameter space is reduced by a factor of 1.5 compared to Planck-only constraints, with no significant shifts in central values. We note that the results presented here are obtained from data collected during just half of a typical observing season with only part of the focal plane operable, and that the active detector count has since nearly doubled for observations made with SPT-3G after 2018.

79 ASTRONOMY AND ASTROPHYSICS↗