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At least 109 records · Page 6

Ultrasonic Fiber Waveguides for Measuring Spatially Distributed Environmental and Material Properties

We report using carbon fibers (<100 μm in diameter) as ultrasonic waveguides to measure spatial changes in the environment and material properties. We connected carbon fibers of different lengths to an ultrasonic transducer and measured changes in the times of flight in a pulse-echo mode in response to elevated temperatures. By simultaneously interrogating multiple fibers of different lengths and collectively analyzing the time of flight in each fiber, we demonstrated dynamic measurements of the temperature distribution along the fiber bundle during their heating.

Walton, Kenneth↗

Ultrasonic Measurements of Temperature Profile and Heat Fluxes in Coal-Fired Power Plants (Final Report)

Many industrial processes are inaccessible or inhospitable to characterization by traditional temperature measurement methods, such as thermocouples, especially over prolonged exposure to harsh environments. Ultrasound is an established characterization technology with diverse applications ranging from medical imaging to therapies to flaw detection to nondestructive evaluation. Ultrasound may characterize solid materials and components noninvasively as a nondestructive evaluation modality and obtain internal measurements of material properties. For example, the speed of ultrasound propagation changes with Young’s modulus and Poisson’s ratio, which can be found from its measurements. Traditional ultrasonic characterization assumes all material properties remain constant with the position. When this assumption holds, a property of interest may be measured by relating it to the speed of ultrasound propagation (or a speed of sound, SOS) and measuring the SOS by timing the ultrasound propagation through a known distance. However, when a property of interest is spatially distributed, the propagation time depends on the SOS changing with the position along the ultrasound propagation path. The multiple temperature distributions may lead to an identical time of flight (TOF). Temperature is one property that impacts the speed of ultrasound and often cannot be assumed to remain constant with the position. Previously, in the context of temperature, we addressed the challenge of ultrasonic characterization of spatially distributed properties by developing a method for measuring segmental temperature distributions (MSTD). This method divides the ultrasonic propagation into segments bound by echogenic features. These features provide ultrasonic interfaces where some energy is reflected toward the receiving transducer, and the rest continues through the medium. The time-of-flight between the echoes reflected from echogenic features characterizes the spatial distribution in the properties of interest in the corresponding segment of the ultrasonic propagation path. This project demonstrated the application of the MSTD method in industrial conditions of the coal-fired power plant. We implemented the MSTD using metals and alloys waveguides, which may be the existing structure for which the temperature distribution is characterized or purposefully designed waveguides added to the structure by welding or other means specifically to quantify thermal properties using the MSTD method. Previous iterations of the MSTD method used ceramic and cementitious waveguides, which significantly attenuate ultrasound. On the other hand, low attenuation in metallic waveguides creates interactions between echogenic features which compilates the signal analysis in the segmental TOF measurements. We have established the WG design principles that minimize the interferences between trailing and primary echoes and, in some cases, eliminate them. The waveguides in which echoes do not interfere improve the timing accuracy and the robustness of ultrasonic measurements of the spatial distributions in material properties. Our emphasis remained on the estimation of the temperature distributions. We have developed general recommendations for designing ultrasonically segmented waveguides with the reduced influence of trailing echoes. Two of our waveguide designs were tested in the industry. The first waveguide was designed for insertion into a combustion zone of the utility-scale coal-fired power plant boiler. The second design allows the characterization of temperature distribution in the direction normal to the boiler’s water wall, a large heat exchanger converting the chemical energy released during combustion to the steam driving the electrical power generation turbines. These waveguides were designed to operate within a restrictive space of thermally insulated water wall and incorporate densely located echogenic features while combatting the influence of trailing echoes. The project has successfully demonstrated the feasibility of using the developed method for accurate, continuous, and robust temperature measurements in extreme environments of power generation and other industrial processes. It, therefore, has achieved its overarching goal of advancing the technology readiness level of the novel Ultrasound Measurements of Segmental Temperature Distribution (US-MSTD) method for real-time measurements of the temperature distribution and heat fluxes closer to commercial availability, developing a prototype multipoint measurement system, and validating its performance on coal-fired utility boilers. The success of this project was achieved in collaboration with the power generator, Rocky Mountain Power, and set the stage for the transfer of this technology from the laboratory to the industry.

01 COAL, LIGNITE, AND PEAT↗

Discovery of complex oxides via automated experiments and data science

Significance Automation is accelerating the discovery of useful materials, yet testing even a small fraction of the billions of possible materials for a desired property is beyond the reach of workflows involving resource-intensive property measurements. Due to relationships among composition, structure, and properties, identifying a complex material with one interesting property makes it the proverbial needle in a haystack that merits testing for additional properties. We accelerate materials synthesis and optical characterization by employing physics-aware data science to identify materials for further investigation. With this approach, one does not need high-throughput methods for measuring every material property of interest since a single ultra-high–throughput workflow can guide material selection for other properties, which is a new paradigm for accelerated materials discovery.

36 MATERIALS SCIENCE↗

Truncating the distribution of modulus properties in natural populations of wood

This disclosure is directed to methods of separating wood veneer material by property measurements, and thereafter improving the properties of veneer material with property values lower than a target threshold value, until those materials meet or exceed that threshold values. In some aspects of the disclosure, veneer materials are prepared, non-destructively measured, and separated into passing and failing material collections. The failing material collection may then be treated to improve the density and flexural modulus of the material therein. Also disclosed herein are products and materials incorporating the treated veneer materials according to the disclosed methods.

Bradshaw, Allan↗

Measurement of the properties of lossy materials inside a finite conducting cylinder

Broadband, swept frequency measurement techniques were investigated for the evaluation of the electrical performance of thin, high temperature material coatings. Reflections and transmission measurements using an HP8510B Network Analyzer were developed for an existing high temperature test rig at NASA Lewis Research Center. Reflection measurements will be the initial approach used due to fixture simplicity even though surface wave transmission measurements would be more sensitive. The minimum goal is to monitor the electrical change of the material's performance as a function of temperature. If possible, the materials constitutive parameters, epsilon and muon will be found.

Dominek, A.↗

Development of seal ring carbon-graphite materials (tasks 8, 9, and 10)

A screening study was conducted to develop improved carbon-graphite materials for use in self-acting seals at air temperatures to 1300 F (704 C). Property measurements on materials prepared during this study have shown that: (1) The mechanical properties of a carbon-graphite material were significantly improved by using a fine milled artificial graphite filler material and including intensive mixing, warm molding, and pitch impregnation in the processing; and (2) the oxidation resistance of a carbon-graphite material was improved by including fine milled boron carbide as an oxidation-inhibiting additive. These techniques were employed to develop a material that has 10 times more oxidation resistance than that of a widely used commercial grade and mechanical properties that approach those of the commercial grade.

Fechter, N. J.↗

Characterization of Aluminum Metal Powders for Plutonium-238 Program

As part of radioisotope thermoelectric generator (RTG) production for power sources in deep space exploration, Oak Ridge National Laboratory (ORNL) produces plutonium-238 ( 238 Pu). To produce 238 Pu, neptunium-237 ( 237 Np) targets are fabricated at ORNL and subsequently irradiated at the High Flux Isotope Reactor (HFIR) at ORNL and the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). Specifically, current flowsheets utilize neptunium dioxide ( 237 NpO 2 ) targets. Aluminum (Al) powder is blended with 237 NpO 2 target material to improve thermal conductivity during irradiation. The current composition of 237 NpO 2 /Al pellets (i.e., cermets, or ceramic–metallics) is 20% 237 NpO 2 , 70% Al, and 10% void space. Al powders utilized by the 238 Pu program are high-fired under vacuum before blending into targets. The primary objective of this work is to measure the physical, chemical, and thermal properties of Al before and after the high-firing process. Properties of interest include the morphology, surface texture, particle size, crystal phase(s), and thermal conductivity of the material. These properties are measured with existing materials characterization equipment at ORNL, including powder x-ray diffraction (pXRD), scanning electron microscopy (SEM) with energy-dispersive spectroscopy (EDS), laser flash analysis (LFA), and thermogravimetric analysis (TGA). A secondary objective of this work is to compare the Al powders before and after the high-firing procedure to determine the effects of high-firing on chemical, physical, and thermal properties and to determine the efficacy of the high-firing process.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Summary of the Effects of Two Years of Hygro-Thermal Cycling on a Carbon/Epoxy Composite Material

Composite materials are beginning to be used for structures in the fan section of commercial gas turbine engines. This paper explores the type of damage that could occur within one type of composite material after exposure to hygrothermal cycles (temperature/humidity cycles) that are representative of the environment in the fan section of an engine. The effect of this damage on composite material properties is measured. Chemical changes in the matrix material were limited to the exposed surface. Microcrack formation was identified in the composite material. This damage did not cause a significant reduction in tensile strength or impact penetration resistance of the composite material. Additional data is needed to assess the effect of damage on compressive strength.

Kohlman, Lee W.↗

High-toughness graphite/epoxy composite material experiment

This experiment was designed to measure the effect of near space exposure on three mechanical properties of specially toughened 5208/T300 graphite/epoxy composite materials. The properties measured are elastic modulus, strength, and fracture toughness. Six toughness specimens and nine tensile specimens were mounted on an external frame during the time of the Long Duration Exposure Facility (LDEF) mission. Three identical sets of specimens were manufactured at the outset: the flight set, a zero time non-flight set, and a total time non-flight set. To date, two toughness specimens and three strength and modulus specimens have been tested from each of the three groups.

Felbeck, David K.↗

NBS (National Bureau of Standards): Materials measurements

Work directed toward the measurement of materials properties important to the design and interpretation of space processing experiments and determinations of how the space environment may offer a unique opportunity for performing improved measurements and producing materials with improved properties is reported. Surface tensions and their variations with temperature and impurities; convection during undirectional solidification; and measurement of the high temperature thermophysical properties of tungsten group liquids and solids are discussed and results are summarized.

Manning, J. R.↗

Material Property Estimation in Thin Battery Components Using Guided Wave Measurement, Experimental Dispersion Curve Extraction and Finite Element Modeling

At NASA, we are investigating nondestructive evaluation (NDE) and structural health monitoring (SHM) techniques to detect precursors of thermal runaway failure in lithium metal based lithium ion batteries (LIB). The approach is centered on computational simulation models to guide inspection and aid in interpretation of results. Since lithium metal LIBs have combinations of solid and fluid-filled porous materials, obtaining accurate material properties is both challenging and critical for successful simulation of battery inspection. To this end, we investigated a multi-verification approach for material characterization of thin battery components. First, a laser Doppler vibrometer (LDV) was used to measure guided wave fields in thin (microns-thick) battery components subject to broadband excitation. The time-space wavefield data was converted to frequency-wave number data to extract guided wave dispersion curves. A data visualization and post processing graphics user interface (GUI) was developed at NASA to aid the data exploration and analysis. Due to the thinness of the samples, low frequency-thickness-product plate wave approximations allowed for the calculation of closed-form solutions for material elastic property estimation. These approximations were then verified by calculating the Lamb wave solutions using the previously obtained material properties. Finally, the estimated elastic material properties were implemented in a COMSOL simulation model, and dispersion curves were extracted from simulation results. The dispersion curves and derived material properties were then compared to the analysis results from the experimental data. These comparisons informed on the accuracy of the measured material properties and helped demonstrate the accuracy of the finite element analysis (FEA) computational models. This assessment will prove vital when we start simulating more complex multi-layer components and poroelastic media. This paper gives a brief background of the problem space, outlines the workflow for data analysis and verification, shows results from the workflow, and gives an overview of future plans for simulation of lithium metal LIB inspection.

Peter Juarez↗

The Center for Integrated Nanotechnologies (CINT)

The Center for Integrated Nanotechnologies (CINT) offers world-leading scientific expertise and specialized capabilities to create, characterize, and integrate nanostructured materials at a range of length scales, from nano- to meso-scale. CINT helps scientists perform cutting-edge research in the areas of nanoscience and nanotechnology, providing FREE ACCESS for nonproprietary research. CINT facilities are open to the international research community, including government, academic, and industry researchers. One of CINT's core research areas is in-situ S/TEM experiments. Early capabilities focused on electrical and electrochemical property measurements of materials during high-resolution imaging. More recently, the staff has expanded the available techniques to include gaseous environments (ETEM), liquid-cell, mechanics, ion irradiation, laser ablation, cryogenic, heating, and air-free transfer. In-situ investigations have focused on coupled structure-property measurements on real materials, with the CINT user community expanding many of the in-situ method developments.

36 MATERIALS SCIENCE↗

Lanthanum sulfides as high temperature thermoelectric materials

Thermoelectric property measurements have been made for the nonstoichiometric lanthanum sulfides, LaS(R) with R in the range 1.33-1.50. The Seebeck coefficients and electrical resistivities increase with temperature from 200 to 1100 C. Power factors (defined as Seebeck coefficient squared divided by electrical resistivity) generally increase both as the temperature is increased and as the compound composition is varied from LaS(1.48) to LaS(1.35). The power factor values combined with estimates of thermal conductivities for LaS(1.38) and LaS(1.4) yield figures of merit greater than 0.0005 at 1000 C.

Danielson, L. R.↗

High-toughness graphite/epoxy composite material experiment

This experiment was designed to measure the effect of near-earth space exposure on three mechanical properties of specially toughened 5208/T300 graphite/epoxy composite materials. The properties measured are elastic modulus, strength, and fracture toughness. Six toughness specimens and nine tensile specimens were mounted on an external frame during the 5.8-year orbit of the Long Duration Exposure Facility (LDEF). Three identical sets of specimens were manufactured at the outset: the flight set, a zero-time non-flight set, and a total-time non-flight set.

Felbeck, David K.↗

NBS: Materials measurements

Measurement of materials properties and thermophysical properties is described. The topics discussed are: surface tensions and their variations with temperature and impurities; convection during unidirectional solidification: measurement of high temperature thermophysical properties of tungsten liquid and solid; thermodynamic properties of refractory materials at high temperatures; and experimental and theoretical studies in wetting and multilayer adsorption.

Manning, J. R.↗

Strain-tunable microwave-resonance technique for quantum materials

By integrating a dielectric microwave resonator with a piezoelectric-based strain device, we develop an in situ strain-tunable microwave spectroscopy technique that enables contactless measurements of material properties under strain. To demonstrate the capability of this device, we measure the strain-dependent microwave surface impedance of the representative iron-based superconductor Ba⁢Fe 2 (As 1−𝑥 ⁢P 𝑥 ) 2 at the slightly overdoped composition. We successfully control and observe the suppression of superconductivity under both compressive and tensile anisotropic lattice distortions along the tetragonal [110] T direction, as manifested by changes in the quality factor and resonance frequency shifts of microwave resonance. Furthermore, strain-induced changes in microwave surface resistivity, an extension of conventional DC-limit transport elastoresistivity to the microwave regime, provide information on electronic anisotropy equivalent to that of DC elastoresistivity, while offering a contactless alternative. Furthermore, our strain-tunable cavity therefore serves as a powerful, contactless probe of fundamental material properties under strain and may also potentially facilitate the design of hybrid quantum systems with strain-engineered quantum degrees of freedom.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Measurement of the properties of lossy materials inside a finite conducting cylinder

A computer code was developed to automatically perform swept frequency reflection and transmission measurements using a HP5510B Network Analyzer and computer. This software is used in conjunction with a modified high temperature test rig to obtain reflection measurements from a flat material sample. The software allows data processing to eliminate measurement errors and to obtain a reflection coefficient in the frequency or time domain. A description of the program is presented.

Caldecott, R.↗