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At least 109 records · Page 6

Miniature Heat Transport System for Spacecraft Thermal Control

Loop heat pipes (LHP) are efficient devices for heat transfer and use the basic principle of a closed evaporation-condensation cycle. The advantage of using a loop heat pipe over other conventional methods is that large quantities of heat can be transported through a small cross-sectional area over a considerable distance with no additional power input to the system. By using LHPs, it seems possible to meet the growing demand for high-power cooling devices. Although they are somewhat similar to conventional heat pipes, LHPs have a whole set of unique properties, such as low pressure drops and flexible lines between condenser and evaporator, that make them rather promising. LHPs are capable of providing a means of transporting heat over long distances with no input power other than the heat being transported because of the specially designed evaporator and the separation of liquid and vapor lines. For LHP design and fabrication, preliminary analysis on the basis of dimensionless criteria is necessary because of certain complicated phenomena that take place in the heat pipe. Modeling the performance of the LHP and miniaturizing its size are tasks and objectives of current research. In the course of h s work, the LHP and its components, including the evaporator (the most critical and complex part of the LHP), were modeled with the corresponding dimensionless groups also being investigated. Next, analysis of heat and mass transfer processes in the LHP, selection of the most weighted criteria from known dimensionless groups (thermal-fluid sciences), heat transfer rate limits, (heat pipe theory), and experimental ratios which are unique to a given heat pipe class are discussed. In the third part of the report, two-phase flow heat and mass transfer performances inside the LHP condenser are analyzed and calculated for Earth-normal gravity and microgravity conditions. On the basis of recent models and experimental databanks, an analysis for condensing two-phase flow regimes, pressure gradients, and local heat transfer coefficients using ammonia, propylene, and R134, are carried out.

Ochterbeck, Jay M.↗

Linearized unsteady jet analysis

The introduction of a time dependency into a jet flow to change the rate at which it mixes with a coflowing stream or ambient condition is investigated. The advantages and disadvantages of the unsteady flow are discussed in terms of steady state mass and momentum transfer. A linear system which is not limited by frequency constraints and evolves through a simplification of the equations of motion is presented for the analysis of the unsteady flow field generated by the time dependent jet.

Viets, H.↗

Non-linear resonance of fluids in a crystal growth cavity

In the microgravity environment, the effect of gravity on fluid motion is much reduced. Hence, secondary effects such as vibrations, jitters, surface tension, capillary effects, and electromagnetic forces become the dominant mechanism of fluid convection. Numerous studies have been conducted to investigate fluid behavior in microgravity with the ultimate goal of developing processes with minimal influence from convection. Industrial applications such as crystal growth from solidification of melt and protein growth for pharmatheutical application are just a few examples of the vast potential benefit that can be reaped from material processing in space. However, a space laboratory is not immune from all undesirable disturbances and it is imperative that such disturbances be well understood, quantifiable, and controlled. Non-uniform and transient accelerations such as vibrations, jitters, and impulsive accelerations exist as a result of crew activities, space vehicle maneuvering, and the operations of on-board equipment. Measurements conducted on-board a U.S. Spacelab showed the existence of vibrations in the frequency range of 1 to 100 Hz with a dominant mode of 17 Hz and harmonics of 54 Hz. The observed vibration is not limited to any coordinate plane but exists in all directions. Similar situation exists on-board the Russian MIR space station. Due to the large structure of its design, the future International Space Station will have its own characteristic vibration spectrum. It is well known that vibration can exert substantial influence on heat and mass transfer processes, thus hindering any attempts to achieve a diffusion-limited process. Experiments on vibration convection for a liquid-filled enclosure under one-g environment showed the existence of different flow regimes as vibration frequency and intensity changes. Results showed the existence of a resonant frequency, near which the enhancement is the strongest, and the existence of a high frequency asymptote. Numerical simulations of vibration convection have been conducted by Yurkov, Fu and Shieh, and by Wang. These analyses considered a two-dimensional air-filled cell under weightlessness condition and showed results similar to those of the experiments. It is not yet known whether resonance convection can be triggered by jitter alone or whether it requires the interaction of jitter with other convective forces in low gravity. An order of magnitude analysis, however, can be used to show the dependence of the resonance frequency on the fluid Prandtl number. Even though the onset of resonance convection may depend on other factors, results indicates that fluids with low Prandtl numbers are more susceptible to resonance than those with high Prandtl numbers. The current study is aimed at gaining additional insights to this problem using germanium as working fluid. Germanium was chosen for this analysis because of its common usage in solidification process and its relatively low Prandtl number (Pr = 0.02).

Wang, Francis C.↗

Modeling Of Metabolic Heat Regenerated Temperature Swing Adsorption (MTSA) Subassembly For Prototype Design

This paper describes modeling methods for the three core components of a Metabolic heat regenerated Temperature Swing Adsorption (MTSA) subassembly: a sorbent bed, a sublimation (cooling) heat exchanger (SHX), and a condensing icing (warming) heat exchanger (CIHX). The primary function of the MTSA, removing carbon dioxide from a space suit Portable Life Support System (PLSS) ventilation loop, is performed via the sorbent bed. The CIHX is used to heat the sorbent bed for desorption and to remove moisture from the ventilation loop while the SHX is alternately employed to cool the sorbent bed via sublimation of a spray of water at low pressure to prepare the reconditioned bed for the next cycle. This paper describes subsystem heat a mass transfer modeling methodologies relevant to the description of the MTSA subassembly in Thermal Desktop and SINDA/FLUINT. Several areas of particular modeling interest are discussed. In the sorbent bed, capture of the translating carbon dioxide (CO2) front and associated local energy and mass balance in both adsorbing and desorbing modes is covered. The CIHX poses particular challenges for modeling in SINDA/FLUINT as accounting for solids states in fluid submodels are not a native capability. Methods for capturing phase change and latent heat of ice as well as the transport properties across a layer of low density accreted frost are developed. This extended modeling capacity is applicable to temperatures greater than 258 K. To extend applicability to the minimum device temperature of 235 K, a method for a mapped transformation of temperatures from below the limit temperatures to some value above is given along with descriptions for associated material property transformations and the resulting impacts to total heat and mass transfer. Similar considerations are given for the SHX along with functional relationships for areal sublimation rates as limited by flow mechanics in t1he outlet duct.

Bower, Chad E.↗

Mapping the Limitations of Breakthrough Analysis in Fixed-Bed Adsorption

The separation of gases through adsorption plays an important role in the chemical processing industry, where the separation step is often the costliest part of a chemical process and thus worthy of careful study and optimization. This work developed a number of new, archival aspects on the computer simulations used for the refinement and design of these gas adsorption processes: 1. Presented a new approach to fit the undetermined heat and mass transfer coefficients in the axially dispersed plug flow equation and associated balance equations 2. Examined and described the conditions where non-physical simulation results can arise 3. Presented an approach to determine the limits of the axial dispersion and LDF mass transfer terms above which non-physical simulation results occur.

Knox, James Clinton↗

Analysis of Integrated Spacecraft Performance Using A Rotating Detonation Rocket Engine

For spacecraft with especially stringent mass fraction constraints, the use of a rotating detonation rocket engine (RDRE) may yield potentially significant system mass savings. The pressure gain combustion inherent to RDREs provides higher thrust than traditional rocket engines for a given supply pressure and throat area. This opens multiple avenues for reducing system mass via higher specific impulse, reduced gravity losses, and reduced feed pressures. To highlight the potentially weight-saving characteristics of RDRE systems, the integrated performance of representative spacecraft designs using either a conventional rocket engine or an RDRE was assessed. This paper details the assumptions, methods, and results of this trade study. Two representative spacecraft were assessed. The first is a Liquid Mars Ascent Vehicle (MAV). This spacecraft was designed by NASA in 2011 for the Mars Sample Return Campaign but was not selected for flight due in part to it exceeding the mass requirements by 119 lbm. The second is MIURA-1, a kerolox sounding rocket developed by Payload Aerospace S.L.. The Liquid MAV assessment showed that an RDRE powered design met the mass requirements with a total vehicle mass 46 lbm below the limit. The MIURA-1 assessment showed that wall heat transfer and regenerative cooling are significant challenges for kerolox RDREs, but these challenges may be mitigated by reducing mixture ratio and using both propellants to cool the chamber. The assessment showed that an RDRE powered sounding rocket could achieve 12% more microgravity time than a conventional sounding rocket with the same payload and total vehicle mass. Alternately, if the payload mass and target apogee are held constant, then an RDRE powered sounding rocket can be 8% shorter and 11% lighter than a conventional sounding rocket. These results suggest that the advent of RDREs for in-space propulsion may unlock new missions for which conventional propulsion is not feasible.

Rotating Detonation Rocket Engine↗

Analysis of Integrated Spacecraft Performance Using Rotating Detonation Rocket Engine

For spacecraft with especially stringent mass fraction constraints, the use of a rotating detonation rocket engine (RDRE) may yield potentially significant system mass savings. The pressure gain combustion inherent to RDREs provides higher thrust than traditional rocket engines for a given supply pressure and throat area. This opens multiple avenues for reducing system mass via higher specific impulse, reduced gravity losses, and reduced feed pressures. To highlight the potentially weight-saving characteristics of RDRE systems, the integrated performance of representative spacecraft designs using either a conventional rocket engine or an RDRE was assessed. This paper details the assumptions, methods, and results of this trade study. Two representative spacecraft were assessed. The first is a Liquid Mars Ascent Vehicle (MAV). This spacecraft was designed by NASA in 2011 for the Mars Sample Return Campaign but was not selected for flight due in part to it exceeding the mass requirements by 119 lbm. The second is MIURA-1, a kerolox sounding rocket developed by Payload Aerospace S.L.. The Liquid MAV assessment showed that an RDRE powered design met the mass requirements with a total vehicle mass 46 lbm below the limit. The MIURA-1 assessment showed that wall heat transfer and regenerative cooling are significant challenges for kerolox RDREs, but these challenges may be mitigated by reducing mixture ratio and using both propellants to cool the chamber. The assessment showed that an RDRE powered sounding rocket could achieve 12% more microgravity time than a conventional sounding rocket with the same payload and total vehicle mass. Alternately, if the payload mass and target apogee are held constant, then an RDRE powered sounding rocket can be 8% short and 11% lighter than a conventional sounding rocket. These results suggest that the advent of RDREs for in-space propulsion may unlock new missions for which conventional propulsion is not feasible.

Rotating Detonation Rocket Engine↗

Diffusion of Brønsted acidic dopants in conjugated polymers

Many semiconductor devices (e.g., light emitting diodes and photovoltaics) utilize heterojunctions of doped and undoped layers or depend on gradients of electronic doping to control charge transport. Understanding of the formation and stability of gradients in doping requires an understanding of diffusion of dopants and the complex changes in polymer properties that arise during doping. Conjugated polymers can be electrically doped by strong acids, but the details of the reaction mechanism and subsequent stability are not understood. Here, we show a clear kinetic isotope effect in the doping of thin films of poly(3-hexylthiophene) (P3HT) by bis(trifluoromethane)sulfonimide (HTFSI) from solution indicating that this doping process is limited by proton transfer to the polymer. Complementary X-ray photoelectron spectroscopy and dynamic secondary ion mass spectrometry (DSIMS) depth profiling of dopant concentrations show definitive evidence of dopant enrichment at the P3HT surface. These surface-limited concentration profiles suggest that diffusivity of dopants vary inversely with dopant concentration due to doping-induced changes to the structure of the conjugated polymer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Manufacturing Water‐Based Low‐Tortuosity Electrodes for Fast‐Charge through Pattern Integrated Stamping

Achieving high energy density and fast charging of lithium‐ion batteries can accelerate the promotion of electric vehicles. However, the increased mass loading causes poor charge transfer, impedes the electrochemical reaction kinetics, and limits the battery charging rate. Herein, this work demonstrated a novel pattern integrated stamping process for creating channels in the electrode, which benefits ion transport and increases the rate performance of the electrode. Meanwhile, the pressure applied during the stamping process improved the contact between electrode and current collector and also enhanced the mechanical stability of the electrode. Compared to the conventional bar‐coated electrode with the same thickness of 155 μm (delivered a discharge capacity of 16 mAh g −1 at the rate of 3 C), the stamped low‐tortuosity LiFePO 4 electrode delivered 101 mAh g −1 capacity. Additionally, water was employed as a solvent in this study. Owing to its eco‐friendliness, high scalability, and minimal waste generation, this novel stamping technique inspire a new method for the industrial‐level efficient roll to roll fabrication of fast‐charge electrodes.

25 ENERGY STORAGE↗

A three-dimensional pore-scale model for redox flow battery electrode design analysis

A three-dimensional (3-D) pore-scale model has been developed to construct multiscale fibrous electrodes for redox flow batteries (RFB). New designs, such as biporous electrodes modify electrode structures by creating secondary pores on single carbon fiber to reduce internal battery resistance. Existing pore-scale models only resolve electrodes to the single carbon fiber scale and cannot incorporate recent multiscale electrode designs into numerical models. Our new model aims to bridge this gap and provide a tool to rapidly screen new electrode configurations. Two multiscale electrodes, laser-perforated and biporous electrodes, were investigated at varying operation conditions with the proposed 3-D pore-scale models. The laser-perforated electrode exhibits a reduced pressure drop, but follows the same permeability correlation compared to the corresponding pristine electrode. For the biporous electrode, the added specific surface area and faster reaction kinetics from the secondary pores are the most influential factors leading to improved battery efficiency. However, operating the biporous electrode in limiting current density conditions should be avoided due to the decreased mass transfer efficiency and a more significant voltage loss. Finally, we believe that our 3-D pore-scale model can accelerate the flow battery electrode design process and provide new insights into electrode geometry optimizations.

25 ENERGY STORAGE↗

Ionic Diffusion in Slurry Electrolytes for Redox Flow Batteries

Slurry electrodes have been proposed as a method to decouple the storage and power capacities of hybrid redox flow batteries by allowing the reduced metal to adhere to a flowing dispersion of electrically conductive particles rather than accumulate in the flow cell. In this work, the ionic mass transport through these slurry electrolytes is investigated via voltammetry at a rotating disc electrode and in a parallel channel flow cell. A modified Levich equation, i l = 0.6 2 nFC ω 1 / 2 ν − 1 / 6 ( D + r 2 Φ ω m ) 2 / 3 , is developed to describe limiting currents to a rotating disc electrode when using a particle filled electrolyte. Mass transfer is demonstrated to be enhanced by greater particle loading so long as there are sufficient particles such that their respective flow velocity boundary layers interact. In the flow cell, faradaic current in a carbon black slurry electrolyte was observed to decrease over time. This suggests that the carbon particles adhere and accumulate on the stationary electrode, impeding mass transport by imposing diffusion path tortuosity. This accumulation is undesirable in hybrid redox flow batteries as it encourages metal deposition in the cell, limiting the scalability of the technology.

Electrochemistry↗

System efficiency and power assessment of the all-aqueous copper thermally regenerative ammonia battery

Thermally regenerative ammonia batteries (TRABs) use low-temperature (T < 100 °C) heat to provide stationary energy and power with higher power densities and efficiency relative to other waste heat devices. TRABs are an active area of research in waste heat devices, but currently there is little consensus on what aspect of the system is limiting TRAB performance and what maximum efficiencies are possible. Experiments and numerical models were used here to examine the sensitivity of the battery and distillation column in a TRAB system to key operating variables, thereby establishing practical limits and identifying focus areas for improving performance. Battery power was eight times more sensitive to ohmic losses than kinetic and mass transfer losses, regardless of the operating temperature, and the peak power density was simulated to be 18.8 mW cm –2 at 75 °C. Theoretical energy efficiency limits were defined for a series of ammonia concentrations and operating pressures, ranging from 5 – 12%, which is 2–3 times higher than previous experimental estimations. Atmospheric pressure column operation used a larger amount of waste heat compared to sub-atmospheric pressure. It is estimated that the volume of the battery would take up 9.2m 3 for every 1% of the power output of a natural gas turbine, but with realistic improvements to cell conductivity, the size would reduce to 2.5 m 3 . Finally, the results presented in this work will help streamline future development by focusing on minimizing ohmic losses and provide specific data for full system evaluation of future TRABs.

25 ENERGY STORAGE↗

Synchronous orbit power technology needs

An attempt is made to define the needs for future geosynchronous spacecraft power subsystem components, including power generation, energy storage, and power processing. Three projected models (a mission model, an orbit transfer vehicle model, and a mass model) for power subsystem components are used to define power requirements and mass limitations for future spacecraft. Based upon these models, the power subsystems for a 10-kW, 10-year-life, dedicated spacecraft and for a 20-kW, 20-year-life multimission platform are analyzed to establish power density requirements for orbit transfer vehicles. Comparison of these requirements to state-of-the-art (Intelsat 5) design values shows that major improvements, by a factor of 2 or more, are needed to accomplish the near term missions.

Slifer, L. W., Jr.↗

Optimum rocket propulsion for energy-limited transfer

In order to effect large-scale return of extraterrestrial resources to Earth orbit, it is desirable to optimize the propulsion system to maximize the mass of payload returned per unit energy expended. This optimization problem is different from the conventional rocket propulsion optimization. A rocket propulsion system consists of an energy source plus reaction mass. In a conventional chemical rocket, the energy source and the reaction mass are the same. For the transportation system required, however, the best system performance is achieved if the reaction mass used is from a locally available source. In general, the energy source and the reaction mass will be separate. One such rocket system is the nuclear thermal rocket, in which the energy source is a reactor and the reaction mass a fluid which is heated by the reactor and exhausted. Another energy-limited rocket system is the hydrogen/oxygen rocket where H2/O2 fuel is produced by electrolysis of water using a solar array or a nuclear reactor. The problem is to choose the optimum specific impulse (or equivalently exhaust velocity) to minimize the amount of energy required to produce a given mission delta-v in the payload. The somewhat surprising result is that the optimum specific impulse is not the maximum possible value, but is proportional to the mission delta-v. In general terms, at the beginning of the mission it is optimum to use a very low specific impulse and expend a lot of reaction mass, since this is the most energy efficient way to transfer momentum. However, as the mission progresses, it becomes important to minimize the amount of reaction mass expelled, since energy is wasted moving the reaction mass. Thus, the optimum specific impulse will increase with the mission delta-v. Optimum I(sub sp) is derived for maximum payload return per energy expended for both the case of fixed and variable I(sub sp) engines. Sample missions analyzed include return of water payloads from the moons of Mars and of Saturn.

Zuppero, Anthony↗

Space cryogenics components based on the thermomechanical (TM) effect

He II vapor-liquid phase separation (VLPS) is discussed, with emphasis on fluid-related transport phenomena. The VLPS system has been studied for both linear and nonlinear regimes, demonstrating that well-defined convection patterns exist in porous plug phase separators. In the second part, other components based on the thermomechanical effect are discussed in the limit of ideal conditions. Examples considered include the heat pipe transfer of zero net mass flow, liquid transfer pumps based on the fountain effect, mechanocaloric devices for cooling purposes, and He II vortex refrigerators.

Yuan, S. W. K.↗

Interaction between Convection and Heat Transfer in Crystal Growth

Crystals are integral components in some of our most sophisticated and rapidly developing industries. Single crystals are solids with the most uniform structures that can be obtained on an atomic scale. Because of their structural uniformity, crystals can transmit acoustic and electromagnetic waves and charged particles with essentially no scattering or interferences. This transparency, which can be selectively modified by controlled additions of impurities known as dopants, is the foundation of modern electronic industry. It has brought about widespread application of crystals in transistors, lasers, microwave devices, infrared detectors, magnetic memory devices, and many other magnets and electro-optic components. The performance of a crystal depends strongly on its compositional homogeneity. For instance, in modern microcircuitry, compositional variations of a few percent (down to a submicron length scale) can seriously jeopardize predicted yields. Since crystals are grown by carefully controlled phase transformations, the compositional adjustment in the solid is often made during growth from the nutrient. Hence, a detailed understanding of mass transfer in the nutrient is essential. Moreover, since mass transfer is often the slowest process during growth, it is usually the rate limiting mechanism. Crystal growth processes are usually classified according to the nature of the parent phase. Nevertheless, whether the growth occurs by solidification from a melt (melt growth), nucleation from a solution (solution growth), condensation from a vapor (physical vapor transport) or chemical reaction of gases (chemical vapor deposition), the parent phase is a fluid. As is with most non-equilibrium processes involving fluids, liquid or vapor, fluid motion plays an important role, affecting both the concentration and temperature gradients at the soli-liquid interface.

Source record↗

NASA Advanced Explorations Systems: Concepts for Logistics to Living

The NASA Advanced Exploration Systems (AES) Logistics Reduction and Repurposing (LRR) project strives to enable a largely mission-independent cradle-to-grave-to-cradle approach to minimize logistics contributions to total mission architecture mass. The goals are to engineer logistics materials, common crew consumables, and container configurations to meet the following five basic goals: 1. Minimize intrinsic logistics mass and improve ground logistics flexibility. 2. Allow logistics components to be directly repurposed for on-orbit non-logistics functions (e.g., crew cabin outfitting) thereby indirectly reducing mass/volume. 3. Compact and process logistics that have not been directly repurposed to generate useful on-orbit components and/or compounds (e.g., radiation shielding, propellant, other usable chemical constituents). 4. Enable long-term stable storage and disposal of logistics end products that cannot be reused or repurposed (e.g., compaction for volume reduction, odor control, and maintenance of crew cabin hygienic conditions). 5. Allow vehicles in different mission phases to share logistics resources. This paper addresses the work being done to meet the second goal, the direct repurposing of logistics components to meet other on-orbit needs, through a strategy termed Logistics to Living (L2L). L2L has several areas but can be defined as repurposing or converting logistical items (bags, containers, foam, components, etc.) into useful crew items or life support augmentation on-orbit after they have provided their primary logistics function. The intent is that by repurposing items, dedicated crew items do not have to be launched and overall launch mass is decreased. For non-LEO missions, the vehicle interior volume will be relatively fixed so L2L will enable this volume to be used more effectively through reuse and rearrangement of logistical components. Past work in the area of L2L has already conceptually developed several potential technologies [Howe, Howard 2010]. Several of the L2L concepts that have shown the most potential in the past are based on NASA cargo transfer bags (CTBs) or their equivalents which are currently used to transfer cargo to and from the ISS. A high percentage of all logistics supplies are packaging mass and for a 6-month mission a crew of four might need over 100 CTBs. These CTBs are used for on-orbit transfer and storage but eventually becomes waste after use since down mass is very limited. The work being done in L2L also considering innovative interior habitat construction that integrate the CTBs into the walls of future habitats. The direct integration could provide multiple functions: launch packaging, stowage, radiation protection, water processing, life support augmentation, as well as structure. Reuse of these CTBs would reduce the amount of waste generated and also significantly reduce future up mass requirements for exploration missions. Also discussed here is the L2L water wall , an innovative reuse of an unfolded CTB as a passive water treatment system utilizing forward osmosis. The bags have been modified to have an inner membrane liner that allows them to purify wastewater. They may also provide a structural water-wall element that can be used to provide radiation protection and as a structural divider. Integration of the components into vehicle/habitat architecture and consideration of operations concepts and human factors will be discussed. In the future these bags could be designed to treat wastewater, concentrated brines, and solid wastes, and to dewater solid wastes and produce a bio-stabilized construction element. This paper will describe the follow-on work done in design, fabrication and demonstrations of various L2L concepts, including advanced CTBs for reuse/repurposing, internal outfitting studies and the CTB-based forward osmosis water wall.

Shull, Sarah A.↗

Synchronous orbit power technology needs

The needs are defined for future geosynchronous orbit spacecraft power subsystem components, including power generation, energy storage, and power processing. A review of the rapid expansion of the satellite communications field provides a basis for projection into the future. Three projected models, a mission model, an orbit transfer vehicle model, and a mass model for power subsystem components are used to define power requirements and mass limitations for future spacecraft. Based upon these three models, the power subsystems for a 10 kw, 10 year life, dedicated spacecraft and for a 20 kw, 20 year life, multi-mission platform are analyzed in further detail to establish power density requirements for the generation, storage and processing components of power subsystems as related to orbit transfer vehicle capabilities. Comparison of these requirements to state of the art design values shows that major improvements, by a factor of 2 or more, are needed to accomplish the near term missions. However, with the advent of large transfer vehicles, these requirements are significantly reduced, leaving the long lifetime requirement, associated with reliability and/or refurbishment, as the primary development need. A few technology advances, currently under development, are noted with regard to their impacts on future capability.

Slifer, L. W., Jr.↗