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At least 109 records · Page 6

The parental magma for some rocks from the Norite 1 subzone of the Stillwater Complex - A lunar analog study

Single samples from three successive homogeneous but contrasting layers (anorthosite, anorthositic norite, and norite) in the Stillwater Complex Norite 1 subzone were subjected to detailed petrographic and major and trace element chemical analyses. The petrography and the element chemistry of the three layers are found to be generally consistent with formation from a common magma, although a simple model of liquidus phases and trapped magma is not quite consistent with petrography and chemistry. Changes of oxidation level from layer to layer are indicated by both iron in plagioclase and by the distribution coefficient for Eu required for compatibility with a common parent. Such oxidation changes can explain qualitatively the Mg/Fe variation otherwise attributed to trapped liquid. The data demonstrate that for individual lunar highlands igneous rocks, a general picture of the parent magma can be derived, but detailed petrochemical comparisons using a simple trapped liquid model might deny a common parentage for two samples when such in fact existed.

Ryder, G.↗

Along-strike magma mixing beneath mid-ocean ridges - Effects on isotopic ratios

The effects of mixing processes on the isotopic variability of midocean ridge basalts are studied. The processes considered are porous flow dispersion and convective mixing in magma chambers. Porous flow dispersion is capable of mixing magmas over distances of only a few tens of meters. Convective mixing, on the other hand, is found to produce continuous magma chambers, where mixing is limited by convective processes, and for discontinuous chambers, where mixing is limited by chamber size. Preliminary comparison of the calculations with observations along the midocean ridges shows that the calculations are consistent with the existence of a correlation between bathymetry and isotopic ratio at long, but not at short, wavelengths. They are also capable of explaining a decrease in isotopic variability with increasing spreading rate.

Kenyon, P. M.↗

Rheology melts and magmatic suspensions. I - Design and calibration of concentric cylinder viscometer with application to rhyolitic magma

The design and calibration of concentric cylinder viscometer for rhyolitic magma applications are described together with the methods of data reduction and error analysis. Experimental data are presented on two rhyolitic magmas (melt plus a small fraction of vapor) under conditions of varying temperature (1100-1350 C) and shear rate (0.05-13.0/sec) at 100 kPa total pressure. Data obtained include a first reported measurement of a normal stress coefficient for magma.

Spera, Frank J.↗

Evaluation of crustal recycling during the evolution of Archean-age Matachewan basaltic magmas

The simplest model for the Matachewan-Hearst Dike (MHD) magmas is assimilation-fractional crystallization (AFC), presumably occurring at the base of the crust during underplating. Subduction zone enriched mantle sources are not required. Trace elements suggest that the mantle sources for the MHD were depleted, but possessed a degree of heterogeneity. Rates of assimilation were approximately 0.5 (= Ma/Mc); the contaminant mass was less than 20 percent. The contaminant was dominated by tonalites-randodiorites, similar to xenoliths and rocks in the Kapuskasing Structural Zone (KSZ). Assimilation of partial melts of light-rare earth and garnet-bearing basaltic precursors may have produced some the MHD magmas. Apparently, previous underplating-AFC processes had already produced a thick crust. The silicic granitoid assimilant for the MHD magmas was probably produced by earlier processing of underplated mafic crust (4, 5, 10, 21 and 30). Calculations suggest that the derived silicic rocks possess negative Ta and Ti anomalies even though they were not the product of subduction.

Nelson, Dennis O.↗

The parent magmas of the SNC meteorites

Mineral compositions, partition coefficients, and computer-graphic representations of liquidus phase boundaries are used here to calculate parent magma compositions for Nakhla, Chassigny, and the xenocryst assemblage in EETA79001B, ALHA77005, and the EETA79001A groundmass. The calculated SNC parent magma compositions have low concentrations of Al2O3 and widely varying wollastonitite (CaO) component. In this regard they resemble basaltic komatiites, but their range of Wo is more extensive than that of basaltic komatiites and trace element characteristics are different. The calculated Nakhla parent magma has an unusually high Wo content and does not resemble any other known magmatic composition. A model of SNC petrogenesis is proposed.

Longhi, J.↗

Parental magmas of Mare Fecunditatis - Evidence from pristine glasses

Results are presented on the petrography and electron microprobe analyses of 14 discrete glass beads from the Luna 16 core sample (21036,15) from Mare Fecunditatis regolith, that were previously characterized as representing pristine glasses. Compared to Apollo pristine glasses analyzed by Delano (1986), the Luna 16 pristine glasses have higher CaO and Al2O3 contents but lower MgO and Ni. On the basis of their contents of MgO, FeO, Al2O3, and CaO, these pristine glasses could be divided into two groups, A and B. It is suggested that at least two parental magmas are needed to explain the chemical variations among these glasses. The Group B glasses appear to represent primitive parental magma that evolved by olivine fractionation to the compositions of the Luna 16 aluminous mare basalts, whereas the Group A volcanic glasses may represent an unusual new basalt magma type that contains a high plagioclase component.

Jin, Y.↗

La/Sm ratios in mare basalts as a consequence of mafic cumulate fractionation from an initial lunar magma

A model is constructed for the La/Sm ratio and the abundance of chrondrite-normalized La in different proportions of partial melts of a mafic cumulate source that might have settled to the bottom of an initial lunar magma ocean prior to any plagioclase separation. It is proposed that La/Sm ratios and chrondrite-normalized La abundances of common mare basalts are found in partial melts only if: the mafic cumulate consists mostly of clinopyroxene, a very low fraction of the cumulate melts, and the cumulate represents a moderate to high proportion of the crystallization of the initial magma ocean. Only if the partitioning of clinopyroxene is forced to mimic plagioclase (DLa is greater than DSm) do the present modeling results become compatible with the scenario for producing appropriate parent melts of mare basalts from mafic cumulates. It is found unlikely that parent melts of mare basalts were produced from mafic cumulates of an initial lunar magma ocean that had not had any plagioclase crystallization.

Shaffer, E. E.↗

Thermal evolution and chemical differentiation of the terrestrial magma ocean

The release of gravitational energy resulted in global melting and formation of a magma ocean during accretion of the Earth. Although it is believed that the formation of the magma ocean resulted in gravitational differentiation of melt and solid, the differentiation might be disturbed by the following processes: (1) convective mixing; (2) cooling and solidification; and (3) growth of the earth, which results in secular increase of pressure, and stirring by planetesimal impacts. The purpose of this study is to investigate the differentiation processes of the terrestrial magma ocean by taking into account various disturbing processes.

Abe, Y.↗

Magma ocean: Mechanisms of formation

The thermal state of the Earth at the time relevant to formation of a magma ocean was dominated by the great impact that created the Moon. As shown in computer experiments, the iron in the impacting bodies quickly sank to the core of the proto-Earth, while a significant fraction of silicates was pushed far enough out beyond the geosynchronous limit to constitute the main material of the Moon. Most of any atmosphere would have been pushed aside, rather than being expelled in the impact. However, the energy remaining in the material not going to the core or expelled was still sufficient to raise its temperature some 1000's of degrees, enough to vaporize silicates and to generate a strong 'planetary wind': a hydrodynamic expansion carrying with it virtually all volatiles plus appreciable silicates. This expansion was violent and uneven in its most energetic stage, but probably the resulting magma ocean was global. The duration, until cooling, was sufficient for silicates to condense to melt and the duration was probably short. Comparison of the Earth and Venus indicates that the great impact was extraordinarily effective in removing volatiles from the proto-Earth; in particular, the enormous differences in primordial inert gases between the planets demand a catastrophic difference in origin circumstances. On the other hand, the comparison limits the amount of silicates lost by the Earth to a rather minor fraction; most of that expelled in the wind must have condensed soon enough for the silicate to fall back to Earth or be swept up by the proto-Moon. So the Earth was left with a magma ocean. The question is whether sufficient water was retained to constitute a steam atmosphere. Probably not, but unknowns affecting this question are the efficiencies of outgassing in great impacts and in subsequent convective churnings deep in the mantle. During the stage when mantle convection is turbulent, an appreciable fraction of volatiles were also retained at depth, perhaps in some mineral phases not yet well-defined. We still have primordial helium being outgassed.

Kaula, W. M.↗

Imperfect fractional crystallization of the lunar magma ocean and formation of the lunar mantle: A realistic chemical approach

It is generally considered that lunar mare basalts were generated by the melting of a cumulate mantle formed in an early Moon-wide magma ocean or magmasphere. However, the nature and chemistry of this cumulate mantle and the logistics of its origin have remained elusive. Extensive studies of terrestrial layered mafic intrusions over the past sixty years have emphasized the imperfection of fractional crystallization and attendant crystal-crystal and crystal-liquid separation in a convecting magma chamber. These separations were similarly inefficient during evolution of the lunar magmasphere, allowing for the trapping of interstitial melt and entrainment of a small proportion of less-dense plagioclase into the more-dense mafic cumulate mush. Indeed, petrography of lunar highlands samples demonstrates this well for anorthosites (with 1-10 percent olivine). Therefore, we propose a 'realistic' model for the evolution of the lunar mantle, which takes these observations into consideration, by the imperfect fractional crystallization of an early lunar magma ocean.

Snyder, Gregory A.↗

Lunar magma transport phenomena

An outline of magma transport theory relevant to the evolution of a possible Lunar Magma Ocean and the origin and transport history of the later phase of mare basaltic volcanism is presented. A simple model is proposed to evaluate the extent of fractionation as magma traverses the cold lunar lithosphere. If Apollo green glasses are primitive and have not undergone significant fractionation en route to the surface, then mean ascent rates of 10 m/s and cracks of widths greater than 40 m are indicated. Lunar tephra and vesiculated basalts suggest that a volatile component plays a role in eruption dynamics. The predominant vapor species appear to be CO CO2, and COS. Near the lunar surface, the vapor fraction expands enormously and vapor internal energy is converted to mixture kinetic energy with the concomitant high-speed ejection of vapor and pyroclasts to form lunary fire fountain deposits such as the Apollo 17 orange and black glasses and Apollo 15 green glass.

Spera, Frank J.↗

The parent magma of the nakhlite meteorites - Clues from melt inclusions

Several forms of trapped liquid found within nakhlite meteorites have been examined, including interstitial melt and magmatic inclusions within the cores of large olivine grains. Differences in the mineralogy and texture between two types of trapped melt inclusions, and between these inclusions and the mesostasis, indicate that vitrophyric inclusions are most appropriate for estimating the composition of a nakhlite parental magma in equilibrium with early-forming olivine and augite. Parent liquids were calculated from the mineralogy of large inclusions in Nakhla and Governador Valadares, using a system of mass-balance equations solved by linear regression methods. The chosen parental liquids were cosaturated in olivine and augite and had Mg/Fe values consistent with measured augite/liquid Kds. These parental magma compositions are similar to other published compositions for Nakhla, Chassigny, and Shergotty parental melts, and may correspond to a significant magma type on Mars.

Harvey, Ralph P.↗

Mechanisms for the generation of compositional heterogeneities in magma chambers

The two main hypotheses concerning the origin of compositional heterogeneities in magma chambers are discussed: (1) models in which the development of compositional zonation is simultaneous with the birth and growth of the magma body and (2) models in which zonation develops within an initially homogeneous batch of magma. The paper presents an overview of the geological possibilities and evaluates them on the basis of current research. Calculations are presented for boundary-layer flow in isothermal ternary component systems, and it is demonstrated that multicomponent diffusion effects may be very significant, as was earlier suggested by Trial and Spera (1988).

Trial, Alain F.↗

The magma ocean as an impediment to lunar plate tectonics

The primary impediment to plate tectonics on the moon was probably the great thickness of its crust and particularly its high crust/lithosphere thickness ratio. This in turn can be attributed to the preponderance of low-density feldspar over all other Al-compatible phases in the lunar interior. During the magma ocean epoch, the moon's crust/lithosphere thickness ratio was at the maximum theoretical value, approximately 1, and it remained high for a long time afterwards. A few large regions of thin crust were produced by basin-scale cratering approximately contemporaneous with the demise of the magma ocean. However, these regions probably also tend to have uncommonly thin lithosphere, since they were directly heated and indirectly enriched in K, Th, and U by the same cratering process. Thus, plate tectonics on the moon in the form of systematic lithosphere subduction was impeded by the magma ocean.

Warren, Paul H.↗

Styles of zoning in central Andean ignimbrites - Insights into magma chamber processes

Data are presented showing that calc-alkaline high-K ignimbrites from the Altiplano-Puna Volcanic Complex of the Central Volcanic Zone of the Andes, showing a variety of compositional zonations. The characteristics of the juvenile material from the zoned and heterogenous ignimbrites suggest that crystallization of the observed phenocrysts occurred in prezoned magma chambers consisting of two or more layers. It is suggested that the width/height ratio of a magma chamber plays a critical role in the control of the style of zonation that may develop in a closed magma chamber.

De Silva, S. L.↗

Experimental Study of Lunar and SNC Magmas

The research described in this progress report involved the study of petrological, geochemical and volcanic processes that occur on the Moon and the SNC parent body, generally accepted to be Mars. The link between these studies is that they focus on two terrestrial-type parent bodies somewhat smaller than earth, and the fact that they focus on the role of volatiles in magmatic processes and on processes of magma evolution on these planets. The work on the lunar volcanic glasses has resulted in some exciting new discoveries over the years of this grant. We discovered small metal blebs initially in the Al5 green glass, and determined the significant importance of this metal in fixing the oxidation state of the parent magma (Fogel and Rutherford, 1995). More recently, we discovered a variety of metal blebs in the Al7 orange glass. Some of these Fe-Ni metal blebs were in the glass; others were in olivine phenocrysts. The importance of these metal spheres is that they fix the oxidation state of the parent magma during the eruption, and also indicate changes during the eruption (Weitz et al., 1997) They also yield important information about the composition of the gas phase present, the gas which drove the lunar fire-fountaining. One of the more exciting and controversial findings in our research over the past year has been the possible fractionation of H from D during shock (experimental) of hornblende bearing samples (Minitti et al., 1997). This research is directed at explaining some of the low H2O and high D/H observed in hydrous phases in the SNC meteorites.

Rutherford, Malcolm J.↗

Iron Redox Systematics of Shergottites and Martian Magmas

Martian meteorites record a range of oxygen fugacities from near the IW buffer to above FMQ buffer [1]. In terrestrial magmas, Fe(3+)/ SigmaFe for this fO2 range are between 0 and 0.25 [2]. Such variation will affect the stability of oxides, pyroxenes, and how the melt equilibrates with volatile species. An understanding of the variation of Fe(3+)/SigmaFe for martian magmas is lacking, and previous work has been on FeO-poor and Al2O3-rich terrestrial basalts. We have initiated a study of the iron redox systematics of martian magmas to better understand FeO and Fe2O3 stability, the stability of magnetite, and the low Ca/high Ca pyroxene [3] ratios observed at the surface.

Righter, Kevin↗

Chemical Zoning of Feldspars in Lunar Granitoids: Implications for the Origins of Lunar Silicic Magmas

Fine-scale chemical and textural measurements of alkali and plagioclase feldspars in the Apollo granitoids (ex. Fig. 1) can be used to address their petrologic origin(s). Recent findings suggest that these granitoids may hold clues of global importance, rather than of only local significance for small-scale fractionation. Observations of morphological features that resemble silicic domes on the unsampled portion of the Moon suggest that local, sizable net-works of high-silica melt (>65 wt % SiO2) were present during crust-formation. Remote sensing data from these regions suggest high concentrations of Si and heat-producing elements (K, U, and Th). To help under-stand the role of high-silica melts in the chemical differentiation of the Moon, three questions must be answered: (1) when were these magmas generated?, (2) what was the source material?, and (3) were these magmas produced from internal differentiation. or impact melting and crystallization? Here we focus on #3. It is difficult to produce high-silica melts solely by fractional crystallization. Partial melting of preexisting crust may therefore also have been important and pos-sibly the primary mechanism that produced the silicic magmas on the Moon. Experimental studies demonstrate that partial melting of gabbroic rock under mildly hydrated conditions can produce high-silica compositions and it has been suggested by that partial melting by basaltic underplating is the mechanism by which high-silica melts were produced on the Moon. TEM and SIMS analyses, coordinated with isotopic dating and tracer studies, can help test whether the minerals in the Apollo granitoids formed in a plutonic setting or were the result of impact-induced partial melting. We analyzed granitoid clasts from 3 Apollo samples: polymict breccia 12013,141, crystalline-matrix breccia 14303,353, and breccia 15405,78

Mills, R. D↗