DOE OSTI2018
Since more than 30 years now, a number of countries have selected and operated vitrification as the best industrial practice for safely and durably immobilizing the most active liquid waste. This now significant worldwide experience covers a wide range of waste compositions, from concentrated alkaline defense waste sludges with a variety of salts and chemicals (Na, Fe, Al, Cr, sulphate,... ) to relatively clear acidic HLLW from commercial, low salt, PUREX-type processes, waste that include dissolved cladding material (Al, Mg, stainless steel), waste that include high levels of noble metals and fines... The activity levels vary from 40- year old defense waste to relatively young waste from high burn-up commercial fuel. The current throughputs vary from about 5 kg/h of glass to about 90 kg/h of glass per melter. Even higher throughputs are currently being considered for Hanford facility for instance. In order to cope with the range of waste compositions, glass compositions have also evolved from low melting temperature borosilicate or phosphate glass to glass or glass ceramics with higher melting temperatures. More complex matrices are currently under study in a number of countries, to immobilize more complex waste and / or increase waste loadings. Each challenge is unique and, for each challenge, it is necessary to select the best combination of waste form and technology. For instance for very active solutions with high levels of noble metal particles that could settle, increase apparent glass viscosity, and impact electrical conductivity, one would select borosilicate glass in the mechanically-stirred hot wall induction melter with bottom pouring that has proven its efficiency in industrial conditions at La Hague. For high glass throughputs with low solids in a borosilicate melt (typically Defense waste), ceramic melters have proven their reliability and efficiency. For matrices that need higher temperatures, or with very high corrosiveness, Cold-Crucible Induction Melters are now considered, with one first industrial implementation at La Hague to produce borosilicate glass and a glass-ceramic. All these technologies have been improved over the years to increase throughput, waste loading, melting temperature, reliability... Other types of waste are now being studied worldwide, and for each, it is necessary to carefully select the adapted waste form and technology. The technologies studied will range from traditional technologies (such as hot-wall induction melter technology and liquid-fed ceramic melter technologies) to the more recent advanced technologies (such as Cold Crucible Induction Melter or Advanced Ceramic melters). In addition, the field of vitrification is extending to other types of waste; the current advances in this field will also be described. (authors)
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗