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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Combined micromechanical and fabrication process optimization for metal-matrix composites

A method is presented to minimize the residual matrix stresses in metal matrix composites. Fabrication parameters such as temperature and consolidation pressure are optimized concurrently with the characteristics (i.e., modulus, coefficient of thermal expansion, strength, and interphase thickness) of a fiber-matrix interphase. By including the interphase properties in the fabrication process, lower residual stresses are achievable. Results for an ultra-high modulus graphite (P100)/copper composite show a reduction of 21 percent for the maximum matrix microstress when optimizing the fabrication process alone. Concurrent optimization of the fabrication process and interphase properties show a 41 percent decrease in the maximum microstress. Therefore, this optimization method demonstrates the capability of reducing residual microstresses by altering the temperature and consolidation pressure histories and tailoring the interphase properties for an improved composite material. In addition, the results indicate that the consolidation pressures are the most important fabrication parameters, and the coefficient of thermal expansion is the most critical interphase property.

Morel, M.↗
NASA NTRS2005

Boron Nitride Nanotubes for Engineering Applications

Boron nitride nanotubes (BNNT) are of significant interest to the scientific and technical communities for many of the same reasons that carbon nanotubes (CNT) have attracted wide attention. Both materials have potentially unique and important properties for structural and electronic applications. However of even more consequence than their similarities may be the complementary differences between carbon and boron nitride nanotubes While BNNT possess a very high modulus similar to CNT, they also possess superior chemical and thermal stability. Additionally, BNNT have more uniform electronic properties, with a uniform band gap of 5.5 eV while CNT vary from semi-conductive to highly conductive behavior. Boron nitride nanotubes have been synthesized both in the literature and at NASA Glenn Research Center, by a variety of methods such as chemical vapor deposition, arc discharge and reactive milling. Consistent large scale production of a reliable product has proven difficult. Progress in the reproducible synthesis of 1-2 gram sized batches of boron nitride nanotubes will be discussed as well as potential uses for this unique material.

Hurst, Janet↗
NASA NTRS2003

High performance structural laminate composite material for use to 1000.degree. F. and above, apparatus for and method of manufacturing same, and articles made with same

A novel materials technology has been developed and demonstrated for providing a high modulus composite material for use to 1000.degree. F. and above. This material can be produced at 5-20% of the cost of refractory materials, and has higher structural properties. This technology successfully resolves the problem of thermal shock or ply lift, which limits traditional high temperature laminates (such as graphite/polyimide and graphite/phenolic) to temperatures of 550-650.degree. F. in thicker (0.25 and above) laminates. The technology disclosed herein is an enabling technology for the nose for the External Tank (ET) of the Space Shuttle, and has been shown to be capable of withstanding the severe environments encountered by the nose cone through wind tunnel testing, high temperature subcomponent testing, and full scale structural, dynamic, acoustic, and damage tolerance testing.

Seal, Ellis C.↗
NASA NTRS1992

Compression failure mechanisms of single-ply, unidirectional, carbon-fiber composites

A single-ply composite compression test was used to study compression failure mechanisms as a function of fiber type, matrix type, and interfacial strength. Composites made with low- and intermediate-modulus fibers (Hercules AS4 and IM7) in either an epoxy (Hercules 3501-6) or a thermoplastic (ULTEM and LARC-TPI) matrix failed by kink banding and out-of-plane slip. The failures proceeded by rapid and catastrophic damage propagation across the specimen width. Composites made with high-modulus fibers (Hercules HMS4/3501-6) had a much lower compression strength. Their failures were characterized by kink banding and longitudinal splitting. The damage propagated slowly across the specimen width. Composites made with fibers treated to give low interfacial strength had low compression strength. These composites typically failed near the specimen ends and had long kink bands.

Ha, Jong-Bae↗
NASA NTRS1996

Improved Damage Resistant Composite Materials Incorporating Shape Memory Alloys

Metallic shape memory alloys (SMA) such as nitinol have unique shape recovery behavior and mechanical properties associated with a material phase change that have been used in a variety of sensing and actuation applications. Recent studies have shown that integrating nitinol-SMA actuators into composite materials increases the composite material's functionality. Hybrid composites of conventional graphite/epoxy or glass/epoxy and nitinol-SMA elements can perform functions in applications where monolithic composites perform inadequately. One such application is the use of hybrid composites to function both in load bearing and armor capacities. While monolithic composites with high strength-to-weight ratios function efficiently as loadbearing structures, because of their brittle nature, impact loading can cause significant catastrophic damage. Initial composite failure modes such as delamination and matrix cracking dissipate some impact energy, but when stress exceeds the composite's ultimate strength, fiber fracture and material perforation become dominant. One of the few methods that has been developed to reduce material perforation is hybridizing polymer matrix composites with tough kevlar or high modulus polyethynylene plies. The tough fibers increase the impact resistance and the stiffer and stronger graphite fibers carry the majority of the load. Similarly, by adding nitinol-SMA elements that absorb impact energy through the stress-induced martensitic phase transformation, the composites' impact perforation resistance can be greatly enhanced. The results of drop-weight and high velocity gas-gun impact testing of various composite materials will be presented. The results demonstrate that hybridizing composites with nitinol-SMA elements significantly increases perforation resistance compared to other traditional toughening elements. Inspection of the composite specimens at various stages of perforation by optical microscope illustrates the mechanisms by which perforation is initiated. Results suggest that the out-of-plane transverse shear properties of the composite and nitinol elements have a significant effect on the perforation resistance. Applications that can utilize the hybrid composites effectively will also be presented with the experimental studies.

Paine, Jeffrey S. N.↗
NASA NTRS2001

Long-Term Durability of a Matrix for High-Temperature Composites Predicted

Polymer matrix composites (PMC's) are being increasingly used in applications where they are exposed for long durations to harsh environments such as elevated temperatures, moisture, oils and solvents, and thermal cycling. The exposure to these environments leads to the degradation of structures made from these materials. This also affects the useful lifetimes of these structures. Some of the more prominent aerospace applications of polymer matrix composites include engine supports and cowlings, reusable launch vehicle parts, radomes, thrust-vectoring flaps, and the thermal insulation of rocket motors. This demand has led to efforts to develop lightweight, high-strength, high-modulus materials that have upper-use temperatures over 316 C. A cooperative program involving two grants to the Massachusetts Institute of Technology and in-house work at the NASA Glenn Research Center was conducted to identify the mechanisms and the measurement of mechanical and physical properties that are necessary to formulate a mechanism-based model for predicting the lifetime of high-temperature polymer matrix composites. The polymer that was studied was PMR-15 polyimide, a leading matrix resin for use in high-temperature-resistant aerospace composite structures such as propulsion systems. The temperature range that was studied was from 125 to 316 C. The diffusion behavior of PMR-15 neat resin was characterized and modeled. Thermogravimetric analysis (TGA) was also conducted in nitrogen, oxygen, and air to provide quantitative information on thermal and oxidative degradation reactions. A new low-cost technique was developed to collect chemical degradation data for isothermal tests lasting up to 4000 hr in duration. In the temperature range studied, results indicate complex behavior that was not observed by previous TGA tests, including the presence of weight-gain reactions. These were found to be significant in the initial periods of aging from 125 to 225 C. Two types of weight loss reactions dominated at aging temperatures above 225 C. One was concentrated at the surface of the polymer and was very active at temperatures above 225 C. The second was observed to dominate in the latter stages of aging at temperatures below 260 C. This three-reaction model satisfactorily explains past findings that the degradation mechanism of PMR-15 appears to change around 316 C. It also indicates that the second weight gain mechanism is a significant factor at temperatures below 204 C. On the basis of these results, a predictive model was developed for the thermal degradation of PMR-15 at 316 C. A comparison of data generated by this model with actual experimental data is shown in the following figure.

Bowles, Kenneth J.↗
NASA NTRS1986

Effects of graphitization on the environmental stability of brominated pitch-based fibers

The residual bromine graphite intercalation compounds of high modulus pitch-based fibers (Amoco P-55, P-75, P-100, and P-120) were formed and their resistances were monitored under a variety of environmental conditions. A threshold graphitization was observed below which the bromination reaction does not occur to an appreciable extent. The graphitization of the P-55 fibers falls below that threshold, precluding an extensive reaction. The P-75, P-100, and P-120 fibers all form bromination compounds which are stable at ambient conditions, under vacuum, and under high humidity (100 percent humidity at 60 C). The thermal stability of the resistivity increased with decreasing graphitization, with the stable temperature for P-120 being 100 C; for P-100, 200 C; and for P-75, 250 C. When cost is a consideration, bromination of pitch-based fibers is an economical way to achieve low resistivities.

Gaier, J. R.↗
NASA NTRS1998

Comparison of Graphite Fabric Reinforced PMR-15 and Avimid N Composites After Long Term Isothermal Aging at Various Temperatures

Extensive effort is currently being expended to demonstrate the feasibility of using high-performance, polymer-matrix composites as engine structural materials over the expected operating lifetime of the aircraft, which can extend from 18,000 to 30,000 hr. The goal is to develop light-weight, high-strength, and high-modulus materials for use in higher temperature sections of advanced 21 st century aircraft propulsion systems. To accomplish this goal, it is necessary to pursue the development of thermal and mechanical durability models for graphite-fiber-reinforced, polymer-matrix composites. Numerous investigations have been reported regarding the thermo-oxidative stability (TOS) of the polyimide PMR-15 (1-5). A significant amount of this work has been directed at edge and geometry effects, reinforcement fiber influences, and empirical modeling of high-temperature weight loss behavior. It is yet to be determined if the information obtained from the PMR-15 composite tests is applicable to other polyimide-matrix composites. The condensation-curing polymer Avimid N is another advanced composite material often considered for structural applications at high temperatures. Avimid N has better thermo-oxidative stability than PMR-15 (6), but the latter is more easily processed. The most comprehensive study of the thermo-oxidative stability of Avimid N neat resin and composites at 371 (infinity)C is found in Salin and Seferis (7). The purposes of the work described herein were to compare the thermal aging behavior of these two matrix polymers and to determine the reasons for and the consequences of the difference in thermal durability. These results might be of some use in improving future polymer development through the incorporation of the desirable characteristics of both polyimides.

Bowles, Kenneth J.↗
NASA NTRS1988

A test for interfacial effects and stress transfer in ceramic matrix composites

A test specimen was devised for measuring stress transfer between a high modulus fiber and a ceramic matrix. Single filaments of SiC were embedded in chemically vapor deposited SiC on a thin plate of molybdenum. The CVD overcoating which encapsulated the fiber was continuous with a coating of SiC on the molybdenum. When placed in a microtensile test device and loaded in the fiber direction, the fiber fracture characteristics provide information on the fiber/matrix adhesion and stress transfer. Problems were encountered due to the formation of a weak boundary between the SiC and the molybdenum which obviated any meaningful tensile tests. Also, the high CVD temperature used in fabricating these specimens restrict the fiber, matrix (and substrate) to materials having similar thermal coefficients of expansion in order to minimize thermal stresses.

Source record↗
NASA NTRS1989

Microscopic deformation in a heated unidirectional graphite-epoxy composite

Both in-plane and out-of-plane displacements were determined in patches of the toughened 1962-ERLX epoxy bounded by three closely packed high-modulus P75S graphite fibers. The P75S/1962-ERLX composite was unidirectional, with an average fiber volume of 60 percent. On heating to 44 C from room temperature, the epoxy confined between clusters of three fibers sank in a trough beneath the plane of the fiber ends by 50-120 nm. When the maximum temperature achieved in the prior thermal cycles exceeded 100 C the depth of the trough increased. However, when cycles exceeding 100 C were followed by thermal cycles of decreasing amplitude, chosen to reduce interfacial stress relaxation, the depth of the trough decreased. The results illustrate the feasibility of deducing quantitative data on local deformation from high-resolution strain measurements on cut surfaces.

Morris, W. L.↗
NASA NTRS2004

Issues on Fabrication and Evaluation of SiC/SiC Tubes With Various Fiber Architectures

SiC/SiC engine components, high-modulus Sylramic-iBN SiC fiber tows were used to form nine different tubular architectural preforms with 13 mm (0.5 in.) inner diameter and lengths of approx. 75 and 230 mm (approx. 3 and approx, 9 in.). The thin-walled preforms were then coated with a BN interphase and densified with a hybrid SiC matrix using nearly the same process steps previously established for slurry-cast melt-infiltrated Sylramic-iBN/BN/SiC flat panels. The as-fabricated CMC tubes were microstructurally evaluated and tested for tensile hoop and flexural behavior, and some of the tubes were also tested in a low-pressure burner rig test with a high thru-thickness thermal gradient. To date, four general tube scale-up issues have been identified: greater CVI deposits on outer wall than inner wall; increased ply thickness and reduced fiber fraction; poor test standards for accurately determining the hoop strength of a small-diameter tube; and poor hoop strength for architectures with seams or ply ends. The underlying mechanisms and possible methods for their minimization are discussed.

Yun, H. M.↗
NASA NTRS2004

Inflatable Space Structures Technology Development for Large Radar Antennas

There has been recent interest in inflatable space-structures technology for possible applications on U.S. Department of Defense (DOD) missions because of the technology's potential for high mechanical-packaging efficiency, variable stowed geometry, and deployment reliability. In recent years, the DOD sponsored Large Radar Antenna (LRA) Program applied this new technology to a baseline concept: a rigidizable/inflatable (RI) perimeter-truss structure supporting a mesh/net parabolic reflector antenna. The program addressed: (a) truss concept development, (b) regidizable materials concepts assessment, (c) mesh/net concept selection and integration, and (d) developed potential mechanical-system performance estimates. Critical and enabling technologies were validated, most notably the orbital radiation durable regidized materials and the high modulus, inflatable-deployable truss members. These results in conjunction with conclusions from previous mechanical-packaging studies by the U.S. Defense Advanced Research Projects Agency (DARPA) Special Program Office (SPO) were the impetus for the initiation of the DARPA/SPO Innovative Space-based Antenna Technology (ISAT) Program. The sponsor's baseline concept consisted of an inflatable-deployable truss structure for support of a large number of rigid, active radar panels. The program's goal was to determine the risk associated with the application of these new RI structures to the latest in radar technologies. The approach used to define the technology maturity level of critical structural elements was to: (a) develop truss concept baseline configurations (s), (b) assess specific inflatable-rigidizable materials technologies, and (c) estimate potential mechanical performance. The results of the structures portion of the program indicated there was high risk without the essential materials technology flight experiments, but only moderate risk if the appropriate on-orbit demonstrations were performed. This paper covers both programs (LRA and ISAT) in two sections, Parts 1 and 2 respectively. Please note that the terms strut, tube, and column are all used interchangeably and refer to the basic strut element of a truss. Also, the paper contains a mix of English and metric dimensional descriptions that reflect prevailing technical discipline conventions and common usage.

Freeland, R. E.↗
NASA NTRS1971

Theoretical buckling loads of boron/aluminum and graphite/resin fiber composite anisotropic plates

Theoretical results are presented for the buckling of anisotropic plates. The plates are subjected to simple and combined in-plane loading. The plates are made from fiber composite material of boron/aluminum or high-modulus graphite/resin. The results are presented in nondimensional form as buckling load against fiber orientation angle for various plate aspect ratios. The results indicate that buckling loads of boron/aluminum plates are independent of fiber direction if the plate aspect ratios are greater than about 1, and moderately dependent when this ratio is less than about 1. In addition, the results indicate that the buckling loads are independent of aspect ratio for plates with aspect ratios greater than about 2. Boron/ aluminum composite plates can resist buckling loads more efficiently than graphite/resin composites on a specific buckling stress basis. The numerical algorithm and a listing of the computer code used to obtain the results are included.

Chamis, C. C.↗
NASA NTRS1972

Automated testing data reduction computer program

The capability of a computer program which can be part of a larger computer program for a fully automated multiaxial testing facility is described. The program was designed to process test data from tubular or flat specimens made from isotropic or anistropic materials, including high modulus fiber composites. Data from a large number of strain gages and combinations of applied loads can be used. Options are provided for single element, 90-degree, rectangular or Delta rosettes, or any combinations of these types of strain gages. Options are provided for strain gage transverse sensitivities. The program outputs include: structural axes strains and stresses, initial and strain-dependent elastic constants, shift of principal strain direction with load, and local curvatures from back-to-back strain gages, and either Calcomp or microfilm plots. The computer program is described with respect to its flow chart, input/output, embedding or linking with other programs.

Chamis, C. C.↗
NASA NTRS1971

Buckling of boron/aluminum and graphite/resin fiber composite anisotropic panels.

Theoretical results are presented for the buckling of anisotropic plates. The plates are subjected to simple and combined inplane loading. The plates are made from fiber composite material of boron/aluminum or high modulus graphite/resin. The results are presented in nondimensional form as buckling load vs fiber orientation angle for various plate aspect ratios.

Chamis, C. C.↗
NASA NTRS1972

Automated testing data reduction computer program.

The capability of a computer program which can be part of a larger computer program for a fully automated multiaxial testing facility is described. This computer program is designed to process test data from tubular or flat specimens made from isotropic or anisotropic materials including high modulus fiber composites. The program can receive data from a large number of strain gages and combinations of applied loads. Options are provided for single element, 90-degree, rectangular or Delta rosettes, or any combinations of these types of strain gages. Options are provided for strain gage transverse sensitivities. The program outputs include: structural axes strains and stresses, initial and strain dependent elastic constants, shift of principal strain direction with load, and local curvatures from back-to-back strain gages, and either calcomp or microfilm plots. The computer program is described with respect to its flow chart, input/output, embedment or linking with other programs and its possible utility in a fully automated testing system.

Chamis, C. C.↗
NASA NTRS1972

A comparative study of tensile fracture mechanisms.

Identification of the failure mechanism characteristic for the more widely used carbon fibers in epoxy matrices under tensile loads as an aid toward improvements and more reliable predictions of the performance of these composites. The presented results pertain to high-strength, high-modulus, and low-modulus fibers in unmodified and modified epoxy novolac matrices.

Mullin, J. V.↗