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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Embedded High-Temperature Sensors: Enhancing Thermoelectrical Performance with Refractory Composites Gradient Layers

To monitor the stability of various energy and manufacturing systems, sensors capable of operating at temperatures exceeding 1000 °C in diverse environments for extended durations are essential. However, under harsh conditions, degradation of sensing materials is a concern that can be controlled by embedding the sensors into refractory oxides. Doped-LaCrO3 based composites are excellent candidates for high-temperature sensing applications due to their good thermoelectrical properties. However, chemical reactivity between the conductive phase and the refractory oxides can decrease the performance of the sensors. In this work, it was devised gradient-type protective layers safeguarding conductive phases within embedded thermocouples, which were fabricated and characterized by X-Ray Diffraction for phase development analysis, Scanning Electron Microscopy and Energy-dispersive X-ray spectroscopy for microstructure and cationic interdiffusion kinetics, long-term thermoelectric testing was completed up to 1400 °C. The enhanced performance of these novel sensors addresses a critical limitation, rendering them viable for long-term high-temperature applications.

20 FOSSIL-FUELED POWER PLANTS↗

Self-Sustainable IoT-Based Remote Sensing Powered by Energy Harvesting Using Stacked Piezoelectric Transducer and Thermoelectric Generator

We propose a self-powered remote multi-sensing system for traffic sensing which is powered by the collective energy harvested from the mechanical vibration of the road caused by the passing vehicles and from the temperature gradient between the asphalt of the road and the soil underneath. A stacked piezoelectric transducer converts mechanical vibrations into electrical energy and a thermoelectric generator harvests the thermal energy from the thermal gradient. Electrical energy signals from the stacked piezoelectric transducer and the thermoelectric generators are converted into usable DC power to recharge the battery using AC-DC and DC-DC converters working simultaneously. The multi-sensing system comprises an embedded system with a microcontroller that acquires data from the sensors and sends the sensory data to an IoT transceiver which transmits the data as RF packets to an ethernet gateway. The gateway converts the RF packets into Internet Protocol (IP) packets and sends them to a remote server. Laboratory and road-testing results showed over 98% sensory data accuracy with the system functioning solely powered by the energy harvested from the alternative energy sources. The successful maximum transmission distance obtained between the IoT, and the gateway was approximately 1 mile, which is a considerable transmission distance achieved in an urban environment. Successful operation of the self-powered multi-sensing system under both laboratory and road conditions contributes considerably to the fields of energy harvesting and self-powered remote sensing systems. The energy flow chart and efficiency for the steps in the system were found to be mechanical power from vehicles to the energy harvester of 0.25%, stacked PZT transducer efficiency was found to be 37%, and for the TEGs the efficiency is 11%. AC-to-DC and DC-to-DC converters’ efficiencies were found to be 90% and 11%. The wireless communication RF transceiver efficiency was found to be 62.5%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Assessment of surface turbulent fluxes using geostationary satellite surface skin temperatures and a mixed layer planetary boundary layer scheme

A method is presented for evaluating the fluxes of sensible and latent heating at the land surface, using satellite-measured surface temperature changes in a composite surface layer-mixed layer representation of the planetary boundary layer. The basic prognostic model is tested by comparison with synoptic station information at sites where surface evaporation climatology is well known. The remote sensing version of the model, using satellite-measured surface temperature changes, is then used to quantify the sharp spatial gradient in surface heating/evaporation across the central United States. An error analysis indicates that perhaps five levels of evaporation are recognizable by these methods and that the chief cause of error is the interaction of errors in the measurement of surface temperature change with errors in the assigment of surface roughness character. Finally, two new potential methods for remote sensing of the land-surface energy balance are suggested which will relay on space-borne instrumentation planned for the 1990s.

Diak, George R.↗

Precision Formation Delta-V Requirements for Distributed Platforms in Earth Orbit

Distributed spacecraft flying in formation can overcome the resolution limitations of monolithic, Earth-sensing systems. However, formation spacecraft must now expend fuel to counteract disturbances and the gravity gradients between spacecraft. We consider three different formation architectures and determine the (Delta)(nu) required to maintain relative positions at accuracies from 0.1 to 10 m (1(sigma)). The three architectures considered are: (i) Leader/Follower, in which individual spacecraft controllers track with respect to a passive, leader spacecraft, (ii) Center of Formation, in which individual spacecraft controllers track with respect to the geometric center of the formation, and (iii) Iterated Virtual Structure, in which a formation template is fit each timestep and individual spacecraft controllers track with respect to the fitted template.

formation flying↗

Monitoring Delamination of Thermal Barrier Coating During Interrupted High-Heat Flux Laser Testing Using Upconversion Luminescence Imaging

Upconversion luminescence imaging of thermal barrier coatings (TBCs) has been shown to successfully monitor TBC delamination progression during interrupted furnace cycling. However, furnace cycling does not adequately model engine conditions where TBC-coated components are subjected to significant heat fluxes that produce through-thickness temperature gradients that may alter both the rate and path of delamination progression. Therefore, new measurements are presented based on luminescence imaging of TBC-coated specimens subjected to interrupted high-heat-flux laser cycling exposures that much better simulate the thermal gradients present in engine conditions. The TBCs tested were deposited by electron-beam physical vapor deposition (EB-PVD) and were composed of 7wt% yttria-stabilized zirconia (7YSZ) with an integrated delamination sensing layer composed of 7YSZ co-doped with erbium and ytterbium (7YSZ:Er,Yb). The high-heat-flux exposures that produce the desired through-thickness thermal gradients were performed using a high power CO2 laser operating at a wavelength of 10.6 microns. Upconversion luminescence images revealed the debond progression produced by the cyclic high-heat-flux exposures and these results were compared to that observed for furnace cycling.

Eldridge, Jeffrey I.↗

Estimating tropical cyclone outer surface winds from satellite microwave data

Warm temperature anomalies over tropical cyclones are sensed by the 55.45 GHz channel of the Nimbus 6 Scanning Microwave Spectrometer. Radial brightness temperature gradients are related to radial surface pressure gradients through the hydrostatic and radiative transfer equations. Surface wind speeds outside of the radius of maximum wind are calculated from the pressure gradients and compared with observations.

Kidder, S. Q.↗

Thermoelastic Theory for the Response of Materials Functionally Graded in Two Directions with Applications to the Free-Edge Problem

A recently developed micromechanical theory for the thermoelastic response of functionally graded composites with nonuniform fiber spacing in the through-thickness direction is further extended to enable analysis of material architectures characterized by arbitrarily nonuniform fiber spacing in two directions. In contrast to currently employed micromechanical approaches applied to functionally graded materials, which decouple the local and global effects by assuming the existence of a representative volume element at every point within the composite, the new theory explicitly couples the local and global effects. The analytical development is based on volumetric averaging of the various field quantities, together with imposition of boundary and interfacial conditions in an average sense. Results are presented that illustrate the capability of the derived theory to capture local stress gradients at the free edge of a laminated composite plate due to the application of a uniform temperature change. It is further shown that it is possible to reduce the magnitude of these stress concentrations by a proper management of the microstructure of the composite plies near the free edge. Thus by an appropriate tailoring of the microstructure it is possible to reduce or prevent the likelihood of delamination at free edges of standard composite laminates.

Aboudi, Jacob↗

Design and Modeling of the Off-Axis Parabolic Deformable (OPD) Mirror Laboratory

Coronagraph-equipped direct imaging missions need an active wavefront control system to cancel out the optical aberrations that degrade the performance of the coronagraphs. A fast steering mirror is used to control Line-of-Sight (LoS) pointing error caused by the telescope jitter. In addition to controlling other low-order aberrations such as astigmatism and coma, high stroke, high actuator density deformable mirrors (DMs) are also used to control the electric field at the required high spatial frequencies. We are designing a testbed to verify a different deformable architecture, where the powered optic in the optical train are controllable and have lower actuator count compared to the existing DMs with flat nominal surfaces. This simplifies the packaging issue for space missions and reduces both cost and risk of having the entire coronagraph instrument's performance depending on one or two high-actuator count DMs. The testbed would also be capable of testing different low-order wavefront sensing algorithms, which focuses in the near-term on a new adaptive Kalman filtering and gradient decent method to estimate the harmonic LoS errors that affect space telescopes. In long run, we would test different machine learning techniques to estimate low-order aberrations and non-linear algorithms for digging the region of high contrast called the dark holes (DH).

Subedi, Hari↗

Design and Modeling of the Off-Axis Parabolic Deformable Mirror Laboratory

Coronagraph-equipped direct imaging missions need an active wavefront control system to cancel out the optical aberrations that degrade the performance of the coronagraphs. A fast steering mirror is used to control Line-of-Sight (LoS) pointing error caused by the telescope jitter. In addition to controlling other low-order aberrations such as astigmatism and coma, high stroke, high actuator density deformable mirrors (DMs) are also used to control the electric field at the required high spatial frequencies. We are designing a testbed to verify a different deformable architecture, where the powered optic in the optical train are controllable and have lower actuator count compared to the existing DMs with flat nominal surfaces. This simplifies the packaging issue for space missions and reduces both cost and risk of having the entire coronagraph instrument's performance depending on one or two high-actuator count DMs. The testbed would also be capable of testing different low-order wavefront sensing algorithms, which focuses in the near-term on a new adaptive Kalman filtering and gradient decent method to estimate the harmonic LoS errors that affect space telescopes. In long run, we would test different machine learning techniques to estimate low-order aberrations and non-linear algorithms for digging the region of high contrast called the dark holes (DH).

Communication↗

CO2 partial pressure and fluxes in the Amazon River Plume using in situ and remote sensing data

Estimations of the global carbon budget include a quantitative understanding of the evolving processes that occur along river-to-ocean gradients. However, high spatiotemporal resolution observations of these processes are limited. Here we present in situ measurements of the partial pressure of CO2 (pCO2) made through the Amazon River plume (ARP) during different discharge seasons, from 2010-2012. We evaluated the spatiotemporal distribution of pCO2 using Soil Moisture and Ocean Salinity (SMOS) satellite observations for each hydrologic period in the ARP. Regression models were used to estimate pCO2 at the ARP for the period of 2010-2014. From these distributions we calculated sea-air gas exchange of CO2 between the plume waters and the atmosphere (F_co2^sea). Intra-annual variability of F_co2^sea was related to discharge at the river mouth and ocean currents as well as trade winds in the plume. Climatic events during the study period had a significant impact on the F_co2^sea. Including the plume area closer to the river mouth makes the ARP a net source of CO2 with an annual net sea-air flux of 8.6 ±7.1 Tg C y-1 from 2011-2014.

Amazon↗

The Uncertainty of Biomass Estimates from LiDAR and SAR Across a Boreal Forest Structure Gradient

In this study, weexamined the uncertainty of aboveground live biomass (AGB) estimates based on light detection and ranging (LiDAR) and synthetic aperture radar (SAR) measurements distributed across a low-biomass vegetation structure gradient fromforest to non-forest in boreal-like ecosystems. The conifer-dominant structure gradient was compiled from ground data amassed from multiple field expeditions in central Maine (USA), Aurskog (Norway), and across central Siberia (Russia). Single variable empirical models were built tomodel AGB fromremote sensingmetrics. Using thesemodels, we calculated a rootmean square error (RMSE) and a 95% confidence interval (CI) of the RMSE fromthe difference between the remote sensing AGB predictions and the ground reference AGB estimates within AGB intervals across a 0-100 Mg ha(exp.−1) boreal forest structure gradient. The results show that the error in AGB predictions (RMSE) and the error uncertainty (the CI) from LiDAR and SAR change across a forest gradient. The errors of airborne LiDAR and SAR metrics and spaceborne LiDAR platforms show a general trend of reduced relative errors as AGBmagnitudes increase, particularly from0 to 60 Mg ha (exp.−1). Empirical models relating spaceborne metrics to AGB and estimates of spaceborne LiDAR error uncertainty demonstrate the difficulty of characterizing differences in AGB at the site-level with current spaceborne sensors, particularly below 80 Mg ha (exp.−1) with less than 50-100% error.

Taiga↗

Ground-Based Passive Microwave Remote Sensing Observations of Soil Moisture at S and L Band with Insight into Measurement Accuracy

Accurate estimates of spatially heterogeneous algorithm variables and parameters are required in determining the spatial distribution of soil moisture using radiometer data from aircraft and satellites. A ground-based experiment in passive microwave remote sensing of soil moisture was conducted in Huntsville, Alabama from July 1-14, 1996 to study retrieval algorithms and their sensitivity to variable and parameter specification. With high temporal frequency observations at S and L band, we were able to observe large scale moisture changes following irrigation and rainfall events, as well as diurnal behavior of surface moisture among three plots, one bare, one covered with short grass and another covered with alfalfa. The L band emitting depth was determined to be on the order of 0-3 or 0-5 cm below 0.30 cubic centimeter/cubic centimeter with an indication of a shallower emitting depth at higher moisture values. Surface moisture behavior was less apparent on the vegetated plots than it was on the bare plot because there was less moisture gradient and because of difficulty in determining vegetation water content and estimating the vegetation b parameter. Discrepancies between remotely sensed and gravimetric, soil moisture estimates on the vegetated plots point to an incomplete understanding of the requirements needed to correct for the effects of vegetation attenuation. Quantifying the uncertainty in moisture estimates is vital if applications are to utilize remotely-sensed soil moisture data. Computations based only on the real part of the complex dielectric constant and/or an alternative dielectric mixing model contribute a relatively insignificant amount of uncertainty to estimates of soil moisture. Rather, the retrieval algorithm is much more sensitive to soil properties, surface roughness and biomass.

Laymon, Charles A.↗

Confronting the water potential information gap

Water potential directly controls the function of leaves, roots and microbes, and gradients in water potential drive water flows throughout the soil–plant–atmosphere continuum. Notwithstanding its clear relevance for many ecosystem processes, soil water potential is rarely measured in situ, and plant water potential observations are generally discrete, sparse, and not yet aggregated into accessible databases. These gaps limit our conceptual understanding of biophysical responses to moisture stress and inject large uncertainty into hydrologic and land-surface models. Here, we outline the conceptual and predictive gains that could be made with more continuous and discoverable observations of water potential in soils and plants. We discuss improvements to sensor technologies that facilitate in situ characterization of water potential, as well as strategies for building new networks that aggregate water potential data across sites. Here, we end by highlighting novel opportunities for linking more representative site-level observations of water potential to remotely sensed proxies. Together, these considerations offer a road map for clearer links between ecohydrological processes and the water potential gradients that have the ‘potential’ to substantially reduce conceptual and modelling uncertainties.

58 GEOSCIENCES↗

Diagnosis of the role of vertical deformation in a two-dimensional primitive equation model of upper-level frontogenesis

In the present equations for the temporal rates of change of the magnitudes of potential temperature and absolute momentum vector gradients that are projected onto vertical planes transverse to straight frontal zones, the terms involving the transverse ageostrophic circulation are of the same mathematical form, and in a kinematic sense are also analogous to, the divergence and deformation terms that involve the horizontal wind field in Pettersen's (1936) classic equation for frontogenesis in the potential temperature field. The proposed frontogenesis equation form for the magnitude of the potential temperature gradient in the transverse plane is illustrated with the results of two simulations from an idealized, two-dimensional primitive equation model in which upper level frontogenesis proceeds by very different mechanisms.

Keyser, D.↗

Core–Shell Gold Nanoparticle-Star Copolymer Composites with Gradient Transfer and Transport Properties: Toward Electro-Optical Sensors and Catalysis

A series of hybrid core–shell nanomaterials was prepared by solvent phase transfer methods with gold (Au) nanoparticles (NPs) as a core and star copolymers (h-PEI-b-PCL-Cbz) as a shell—consisting of hyperbranched polyethyleneimine (h-PEI) with different poly(ε-caprolactone) (PCL) chain lengths and a carbazole-contained terminating agent (Cbz). By varying the PCL chain length, these core–shell nanomaterials exhibited gradient energy transfer properties, surface hydrophobicity, electropolymerizability, and ionic probe transport and diffusion properties. The systematic copolymer formation was verified with quadruple-detector size exclusion chromatography (SEC) and 1H nuclear magnetic resonance (NMR). High-resolution atomic force microscopy-infrared spectroscopy (AFM-IR) chemical mapping verified nanoparticle-substrate adhesion and film formation. The design of these hybrid NPs and elucidation of gradient properties will be useful for future applications of the core–shell systems in electro-optical sensing and catalysis.

36 MATERIALS SCIENCE↗

The Electron Drift Technique for Measuring Electric and Magnetic Fields

The electron drift technique is based on sensing the drift of a weak beam of test electrons that is caused by electric fields and/or gradients in the magnetic field. These quantities can, by use of different electron energies, in principle be determined separately. Depending on the ratio of drift speed to magnetic field strength, the drift velocity can be determined either from the two emission directions that cause the electrons to gyrate back to detectors placed some distance from the emitting guns, or from measurements of the time of flight of the electrons. As a by-product of the time-of-flight measurements, the magnetic field strength is also determined. The paper describes strengths and weaknesses of the method as well as technical constraints.

Paschmann, G.↗

The Ozone Water-Land Environmental Transition Study: An Innovative Strategy for Understanding Chesapeake Bay Pollution Events

Coastal regions have historically represented a significant challenge for air quality investigations because of water-land boundary transition characteristics and a paucity of measurements available over water. Prior studies have identified the formation of high levels of ozone over water bodies, such as the Chesapeake Bay, that can potentially recirculate back over land to significantly impact populated areas. Earth-observing satellites and forecast models face challenges in capturing the coastal transition zone where small-scale meteorological dynamics are complex and large changes in pollutants can occur on very short spatial and temporal scales. An observation strategy is presented to synchronously measure pollutants “over land” and “over water” to provide a more complete picture of chemical gradients across coastal boundaries for both the needs of state and local environmental management and new remote sensing platforms. Intensive vertical profile information from ozone lidar systems and ozonesondes, obtained at two main sites, one over land and the other over water, are complemented by remote sensing and in situ observations of air quality from ground-based, airborne (both personned and unpersonned), and shipborne platforms. These observations, coupled with reliable chemical transport simulations, such as the National Oceanic and Atmospheric Administration (NOAA) National Air Quality Forecast Capability (NAQFC), are expected to lead to a more fully characterized and complete land–water interaction observing system that can be used to assess future geostationary air quality instruments, such as the National Aeronautics and Space Administration (NASA) Tropospheric Emissions: Monitoring of Pollution (TEMPO), and current low-Earth-orbiting satellites, such as the European Space Agency’s Sentinel-5 Precursor (S5-P) with its Tropospheric Monitoring Instrument (TROPOMI).

Forecast Models↗

High Sensitivity Stress Sensor Based on Hybrid Materials

A sensing device is used to detect the spatial distributions of stresses applied by physical contact with the surface of the sensor or induced by pressure, temperature gradients, and surface absorption. The sensor comprises a hybrid active layer that includes luminophores doped in a polymeric or organic host, altogether embedded in a matrix. Under an electrical bias, the sensor simultaneously converts stresses into electrical and optical signals. Among many applications, the device may be used for tactile sensing and biometric imaging.

Cao, Xian-An↗