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At least 109 records · Page 6

New Fiber Reinforced Waterless Concrete for Extraterrestrial Structural Applications

Commercial use of sulfur concrete on Earth is well established, particularly in corrosive, e.g., acid and salt, environments. Having found troilite (FeS) on the Moon raises the question of using extracted sulfur as a lunar construction mate: iii an attractive alternative to conventional concrete as it does not require water For the purpose of this paper it is assumed that lunar ore is mined, refined, and the raw sulfur processed with appropriate lunar regolith to form, for example, brick and beam elements. Glass fibers produced from regolith were used as a reinforcement to improve the mechanical properties of the sulfur concrete. Glass fibers and glass rebar were produced by melting the lunar regolith simulant. Lunar regolith stimulant was melted in a 25 cc Pt-Rh crucible in a Sybron Thermoline 46100 high temperature MoSi2 furnace at melting temperatures of 1450 to 1600G. The glass melt wets the ceramic rod and long continuous glass fibers were easily hand drawn. The glass fibers were immediately coated with a protective polymer to maintain the mechanical strength. The viability of sulfur concrete as a construction material for extraterrestrial application is presented. The mechanical properties of the glass fiber reinforced sulfur concrete were investigated.

Toutanji, H.↗

Properties of the Guin ungrouped iron meteorite - The origin of Guin and of group-IIE irons

The composition and structure of the Guin ungrouped iron meteorite inclusions have been investigated experimentally. The structural characteristics of polished and etched slabs of the meteorite were studied microscopically in reflected light. Modal abundances of troilite nodules and silicate inclusions were determined by weighing paper traces. The bulk composition of the silicate inclusions was calculated by combining modal phase abundances and mineral compositions. It is found that the largest silicate inclusion (2 x 4 cm) consists mostly of a shock-melted plagioclase-rich matrix surrounding large, partly melted augite grains. The oxygen isotopic composition of the inclusion is near that of LL chondrites. The inclusion is found to be similar in composition to selected melt pocket glasses in ordinary chondrites produced in situ by preferential melting of plagioclase rock due to shock compression. It is suggested that the Guin assemblage was formed by impact melting on a chondritic parent body. Silicate inclusions in IIE irons share many of the compositional and petrological characteristics of the Guin inclusions, indicating that IIE irons also formed by impact-melting of chondritic materials. Black and white photomicrographs of the silicate inclusions are provided.

Rubin, A. E.↗

Mutual interactions of redox couples via electron exchange in silicate melts - Models for geochemical melt systems

The mutual interactions via electron exchange of redox couples in glass-forming melts were investigated both theoretically and experimentally. A thermodynamic approach for considering the mutual interactions leads to conclusion that the degree of mutual interaction in the melt should be proportional in part to the difference in relative reduction potentials of the interacting redox couples. Experimental studies verify this conclusion for numerous redox couples in several composition/temperature/oxygen fugacity regimes. Geochemical systems simultaneously possess many potentially multivalent elements; the stabilized redox states in the resulting magmas can be explained in part by mutual interactions and by redox buffering through the central Fe(III)- Fe(II) couples in the melts. The significance of these results for basaltic magmas of the earth, moon, and meteorites is addressed.

Schreiber, Henry D.↗

Mechanisms for the Crystallization of ZBLAN

The objective of this ground based study is to test the hypothesis that shear thinning (the non-Newtonian response of viscosity to shear rate) is a viable mechanism to explain the observation of enhanced glass formation in numerous low-g experiments. In 1-g, fluid motion results from buoyancy forces and surface tension driven convection. This fluid flow will introduce shear in undercooled liquids in 1-g. In low-g it is known that fluid flows are greatly reduced so that the shear rate in fluids can be extremely low. It is believed that some fluids may have weak structure in the absence of flow. Very small shear rates could cause this structure to collapse in response to shear resulting in a lowering of the viscosity of the fluid. The hypothesis of this research is that: Shear thinning in undercooled liquids decreases the viscosity, increasing the rate of nucleation and crystallization of glass forming melts. Shear in the melt can be reduced in low-g, thus enhancing undercooling and glass formation. The viscosity of a model glass (lithium di-silicate, L2S) often used for crystallization studies has been measured at very low shear rates using a dynamic mechanical thermal analyzer. Our results are consistent with increasing viscosity with a lowering of shear rates. The viscosity of L2S may vary as much as an order of magnitude depending on the shear rate in the temperature region of maximum nucleation and crystal growth. Classical equations for nucleation and crystal growth rates, are inversely related to the viscosity and viscosity to the third power respectively. An order of magnitude variation in viscosity (with shear) at a given temperature would have dramatic effects on glass crystallization Crystallization studies with the heavy metal fluoride glass ZBLAN (ZrF2-BaF2-LaF3-AlF3-NaF) to examine the effect of shear on crystallization are being initiated. Samples are to be melted and quenched under quiescent conditions at different shear rates to determine the effect on crystallization. The results from this study are expected to advance the current scientific understanding of glass formation in low-g and glass crystallization under glass molding conditions and will improve the scientific understanding of technological processes such as fiber pulling, bulk amorphous alloys, and glass fabrication processes.

Ethridge, Edwin C.↗

Crystal nucleation in amorphous (Au/100-y/Cu/y/)77Si9Ge14 alloys

Because, unlike most metallic glasses, melt-spun alloys of the series (Au/100-y/Cu/y/)77Si9Ge14 exhibit well separated glass transition and kinetic crystallization temperatures, crystallization can be studied in the fully relaxed amorphous phase. An isothermal calorimetric analysis of the devitrification kinetics of the amorphous alloy indicates sporadic nucleation and a constant growth rate. It is found for the cases of alloys with y values lower than 25 that the classical theory of homogeneous nucleation is consistent with observations, including transient effects. An analysis of the crystallization kinetics shows that slow crystal growth rates play an important role in glass formation in these alloys. Although the reduced glass transition temperature increases with Cu content, glass formation is more difficult at high Cu contents, perhaps because of a difference in nucleus composition.

Thompson, C. V.↗

Making Highly Pure Glass Rods

Proposed quasi-containerless method for making glass rods or fibers minimizes contact between processing equipment and product. Method allows greater range of product sizes and shapes than achieved in experiments on containerless processing. Molten zone established in polycrystalline rod. Furnace sections separated, and glass rod solidifies between them. Clamp supports solid glass as it grows in length. Pulling clamp rapidly away from melt draws glass fiber. Fiber diameter controlled by adjustment of pulling rate.

Naumann, R. J.↗

Superheat in magma oceans

The existence of 'totally molten' planets implies the existence of a superheat (excess of heat) in the magma reservoirs since the heat buffer (i.e., presence of crystals having high latent heat of fusion) does not exist in a large, completely molten reservoir. Any addition of impacting material results in increase of the temperature of the melt and under favorable circumstances heat is stored. The behavior of superheat melts is little understood; therefore, we experimentally examined properties and behavior of excess heat melts at atmospheric pressures and inert gas atmosphere. Highly siliceous melts (70 percent SiO2) were chosen for the experiments because of the possibility of quenching such melts into glasses, the slow rate of reaction in highly siliceous composition, and the fact that such melts are present in terrestrial impact craters and impact-generated glasses. Results from the investigation are presented.

Jakes, Petr↗

Air jet levitation furnace system for observing glass microspheres during heating and melting

A collimated hole structure air jet levitation system has been developed which can be used to levitate hollow glass microspheres used in inertial confinement fusion studies. An ellipsoidal furnace has been added to the system to provide a heating source. A video camera and a 16 mm movie camera connected to a microsphere system provide real time observation as well as permanent documentation of the experiments. Microspheres have been levitated at temperatures over 1400 C for over 10 minutes at a time.

Ethridge, E. C.↗

Preserved Flora and Organics in Impact Melt Breccias

At least seven glass-bearing strata of varying ages occur at different horizons in the Pampean sediments of Argentina dating back to the Miocene. In a strict sense, these impact glasses are melt-matrix breccias composed of partially digested minerals clasts and basement fragments indicative of crater excavation. Ar-40/Ar-39 dating yield ages (+/- 2 sigma) of 6 +/- 2 Ka, 114 +/- 26 Ka, 230 +/- 30 Ka, 445 +/- 21 Ka, 3.27 +/- 0.08 Ma (near Mar del Plata = MdP), 5.28 +/- 0.04 Ma, and 9.21 +/- 0.08 Ma (near Chasico = CH) Where found in place (not reworked), these ages are consistent with the local stratigraphy and faunal assemblages. A striking property of some of these impact glasses is the encapsulation of preserved fragments of floral (and even soft-tissue faunal remains). Here we identify retained organics and describe a likely process of encapsulation and preservation.

Schultz, P. H.↗

Acid-Sulfate-Weathering Activity in Shergottite Sites on Mars Recorded in Grim Glasses

Based on mass spectrometric studies of sulfur species in Shergotty and EET79001, [1] and [2] showed that sulfates and sulfides occur in different proportions in shergottites. Sulfur speciation studies in gas-rich impact-melt (GRIM) glasses in EET79001 by the XANES method [3] showed that S K-XANES spectra in GRIM glasses from Lith A indicate that S is associated with Ca and Al presumably as sulfides/sulfates whereas the XANES spectra of amorphous sulfide globules in GRIM glasses from Lith B indicate that S is associated with Fe as FeS. In these amorphous iron sulfide globules, [4] found no Ni using FE-SEM and suggested that the globules resulting from immiscible sulfide melt may not be related to the igneous iron sulfides having approximately 1-3% Ni. Furthermore, in the amorphous iron sulfides from 507 GRIM glass, [5] determined delta(sup 34)S values ranging from +3.5%o to -3.1%o using Nano-SIMS. These values plot between the delta(sup 34)S value of +5.25%o determined in the sulfate fraction in Shergotty [6] at one extreme and the value of -1.7%o obtained for igneous sulfides in EET79001 and Shergotty [7] at the other. These results suggest that the amorphous Fe-S globules likely originated by shock reduction of secondary iron sulfate phases occurring in the regolith precursor materials during impact [7]. Sulfates in the regolith materials near the basaltic shergottite sites on Mars owe their origin to surficial acid-sulfate interactions. We examine the nature of these reactions by studying the composition of the end products in altered regolith materials. For the parent material composition, we use that of the host shergottite material in which the impact glasses are situated.

Rao, M. N.↗

Fractionation of Iron and Titanium Isotopes By Ilmenite and the Isotopic Compositions of Lunar Magma Ocean Cumulates

Basaltic volcanism on the Moon produced low- and high-Ti mare basalt suites that are also distinct with respect to their iron, titanium, and magnesium iso- topic compositions. Here, the equilibrium fractionation of Fe and Ti isotopes between ilmenite and melt was experimentally investigated in order to evaluate the role of ilmenite in generating the isotopic compositional variability among the lunar mare basalts. Ilmenite crystallization experiments were conducted using two bulk compositions: an ilmenite-saturated basaltic andesite and an ilmenite-saturated Apollo 14 black glass, and the Fe and Ti isotopic compo- sitions of the experimental ilmenites and glass (quenched melt) were analyzed using solution MC-ICPMS after hand-picking. Additionally, Nuclear Resonant Inelastic X-ray Scattering (NRIXS) measurements on synthetic ilmenite were conducted and compared to previous NRIXS measurements on synthetic lunar glasses in order to derive temperature-dependent equilibrium ilmenite-melt Fe isotopic fractionations. Experimentally determined ilmenite-melt fractionations were then incorporated into a lunar magma ocean crystallization model that tracks the major element and isotopic compositional evolution of lunar magma ocean cumulates and residual liquid. There is good agreement between the Fe equilibrium isotopic fractionation measured by NRIXS and the laboratory equili- bration experiments, and we find that the isotopic fractionation is sensitive to il- menite compositional differences (0 vs. 10% Fe3+). Further, the light Ti isotopic composition of ilmenite relative to the melt (∆49Ti ilmenite-melt = −0.09 ± 0.03h at 1100°C) is consistent with the higher coordination of Ti in ilmenite relative to melts and results of previous studies. The modeled Ti isotopic compositions for lunar magma ocean cumulates display Ti isotopic variability sufficient to explain the low- and high-Ti mare basalt sources. However, the difference in Fe isotopic composition between the low- and high-Ti mare basalts cannot be attributed solely to ilmenite fractionation. Instead, Fe isotopic fractionation by additional products of lunar magma ocean crystallization, such as clinopy- roxene, is required to generate the inferred Fe and Mg isotopic variability in the lunar mantle. Alternatively, the Fe and Mg isotopic compositions of the lunar mare basalts may indicate Fe-Mg interdiffusion has occurred in the Ti- rich component of the mare basalt source regions via reaction between ilmenite cumulates and the olivine- and pyroxene-rich lunar mantle.

Kelsey Prissel↗

Acid-Sulfate Weathering Environment at Shergottite Provenance on Mars

In some impact melt (IM) glasses in the shergottites such as EET79001, Shergotty and Tissint, recently showed that secondary mineral assemblages having large sulfur excesses cannot be produced in-situ by impact shock melting of the host rock constituents. Instead, these putative secondary minerals inferred to be present in IM glasses were produced somewhere else in the shergottite source region and were subsequently mobilized into the host rock voids (by lava erosion or aolian activity) prior to impact ejection. In this abstract, we examine the aqueous conditions (pH and water/rock ratios) under which the acid sulfate solutions could have interacted with the primary minerals in the basaltic rocks and precipitated the secondary minerals such as Fe-sulfates in some cases and Ca- and Al-sulfates in other cases under favorable conditions at the shergottite provenance on Mars.

Rao, M. N.↗

Isotopic Evidence for a Martian Regolith Component in Martian Meteorites

Noble gas measurements in gas-rich impact-melt (GRIM) glasses in EET79001 shergottite showed that their elemental and isotopic composition is similar to that of the Martian atmosphere [1-3]. The GRIM glasses contain large amounts of Martian atmospheric gases. Those measurements further suggested that the Kr isotopic composition of Martian atmosphere is approximately similar to that of solar Kr. The (80)Kr(sub n) - (80)Kr(sub M) mixing ratio in the Martian atmosphere reported here is approximately 3%. These neutron-capture reactions presumably occurred in the glass-precursor regolith materials containing Sm- and Br- bearing mineral phases near the EET79001/ Shergotty sites on Mars. The irradiated materials were mobilized into host rock voids either during shock-melting or possibly by earlier aeolian / fluvial activity.

Rao, M. N.↗

Fiber glass pulling

Experiments were conducted to determine the viability of performing containerless glass fiber pulling in space. The optical transmission properties and glass-forming capabilities of the heavy metal fluorides are reviewed and the acoustic characteristics required for a molten glass levitation system are examined. The design limitations of, and necessary modifications to the acoustic levitation furnace used in the experiments are discussed in detail. Acoustic levitator force measurements were performed and a thermal map of the furnace was generated from thermocouple data. It was determined that the thermal capability of the furnace was inadequate to melt a glass sample in the center. The substitution of a 10 KW carbon monoxide laser for the original furnace heating elements resulted in improved melt heating.

Workman, Gary L.↗

Containerless processing of fluoride glass

Ground-based experiments on glass formation, crystallization, surface tension, vaporization, and chemical durability of a zirconium-barium-lanthanum (ZBL) fluoride glass are summarized. In a container large, columnar grains grew out from the container-glass interface during cooling. The main crystalline phase was alpha BaZrF6. A ZBL glass sphere was levitated acoustically during Shuttle flight STS-11. The glass was melted and then cooled while being levitated (containerless). Crystallization in the recovered sample was very fine and mainly beta BaZr2F10, showing the influence of the container on the nucleation and microstructure of crystallization in the glass. Glass formation should be easier for a containerless glass than in a container.

Doremus, Robert H.↗

Formation of Nanophase Iron in Lunar Soil Simulant for Use in ISRU Studies

For the prospective return of humans to the Moon and the extensive amount of premonitory studies necessary, large quantities of lunar soil simulants are required, for a myriad of purposes from construction/engineering purposes all the way to medical testing of its effects from ingestion by humans. And there is only a limited and precious quantity of lunar soil available on Earth (i.e., Apollo soils) - therefore, the immediate need for lunar soil simulants. Since the Apollo era, there have been several simulants; of these JSC-1 (Johnson Space Center) and MLS-1 (Minnesota Lunar Simulant) have been the most widely used. JSC-1 was produced from glassy volcanic tuff in order to approximate lunar soil geotechnical properties; whereas, MLS-1 approximates the chemistry of Apollo 11 high-Ti soil, 10084. Stocks of both simulants are depleted, but JSC-1 has recently gone back into production. The lunar soil simulant workshop, held at Marshall Space Flight Center in January 2005, identified the need to make new simulants for the special properties of lunar soil, such as nanophase iron (np-Fe(sup 0). Hill et al. (2005, this volume) showed the important role of microscale Fe(sup 0) in microwave processing of the lunar soil simulants JSC-1 and MLS-1. Lunar soil is formed by space weathering of lunar rocks (e.g., micrometeorite impact, cosmic particle bombardment). Glass generated during micrometeorite impact cements rock and mineral fragments together to form aggregates called agglutinates, and also produces vapor that is deposited and coats soil grains. Taylor et al. (2001) showed that the relative amount of impact glass in lunar soil increases with decreasing grain size and is the most abundant component in lunar dust (less than 20 micrometer fraction). Notably, the magnetic susceptibility of lunar soil also increases with the decreasing grain size, as a function of the amount of nanophase-sized Fe(sup 0) in impact-melt generated glass. Keller et al. (1997, 1999) also discovered the presence of abundant np-Fe(sup 0) particles in the glass patinas coating most soil particles. Therefore, the correlation of glass content and magnetic susceptibility can be explained by the presence of the np-Feo particles in glass: small particles contain relatively more np-Fe(sup 0) as glass coatings because the surface area versus mass ratio of the grain size is so increased. The magnetic properties of lunar soil are important in dust mitigation on the Moon (Taylor et al. 2005). Thus material simulating this property is important for testing mitigation methods using electromagnetic field. This np- Fe(sup 0) also produces a unique energy coupling to normal microwaves, such as present in kitchen microwave ovens. Effectively, a portion of lunar soil placed in a normal 2.45 GHz oven will melt at greater than 1200 C before your tea will boil at 100 C, a startling and new discovery reported by Taylor and Meek (2004, 2005). Several methods have been investigated in attempts to make nanophase-sized Feo dispersed within silicate glass; like in the lunar glass. We have been successful in synthesizing such a product and continue to improve on our recipe. We have performed extensive experimentation on this subject to date. Ultimately it will probably be necessary to add this np-Fe(sup 0) bearing silicate glass to lunar soil stimulant, like JSC-1, to actually produce the desired magnetic and microwave coupling properties for use in appropriate ISRU experimentation.

Liu, Yang↗

Water in Pyroxene and Olivine from Martian Meteorites

Water in the interior of terrestrial planets can be dissolved in fluids or melts and hydrous phases, but can also be locked as protons attached to structural oxygen in lattice defects in nominally anhydrous minerals (NAM) like olivine, pyroxene, or feldspar [1-3]. Although these minerals contain only tens to hundreds of ppm H2O, this water can amount to at least one ocean in mass when added at planetary scales because of the modal dominance of NAM in the mantle and crust [4]. Moreover these trace amounts of water can have drastic effects on melting temperature, rheology, electrical and heat conductivity, and seismic wave attenuation [5]. There is presently a debate on how much water is present in the martian mantle. Secondary ionization mass spectrometry (SIMS) studies of NAM [6], amphiboles and glass in melt inclusions [7-10], and apatites [11, 12] from Martian meteorites report finding as much water as in the same phases from Earth's igneous rocks. Most martian hydrous minerals, however, generally have the relevant sites filled with Cl and F instead of H [13, 14], and experiments using Cl [15] in parent melts can reproduce Martian basalt compositions as well as those with water [16]. We are in the process of analyzing Martian meteorite minerals by Fourier transform infrared spectrometry (FTIR) in order to constrain the role of water in this planet s formation and magmatic evolution

Peslier, A. H.↗