Liquid pump-enabled hydrogen refueling system for medium and heavy duty fuel cell vehicles: Station design and technoeconomic assessment
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Hydrogen technologies are rapidly spreading, with significant attention to the mobility sector requiring a robust and widespread fueling infrastructure. Hydrogen stations are indeed fundamental to transitioning from pilot projects towards large-scale implementation in many countries. Operating under extreme conditions, the new stations need more informed designs and equipment to meet the growing demand and their more frequent utilization. Via a set of experimental research activities and investigated scenarios carried out at the Cal State LA Hydrogen Research and Fueling Facility, here this paper shares a novel and comprehensive set of data collected over a period of one year on fueling events frequency and refueling process station behaviors. A performance evaluation of the station is presented under different load scenarios in severe conditions during "back-to-back fuelings", with monitoring of fundamental parameters for infrastructure sizing, including dynamic cooling response, pressure levels, thermodynamics, and the state of charge of the vehicle. The presented data analysis could surely contribute as closer-to-reality inputs for a variety of station performance modeling tools.
The regenerative fuel cell, a candidate technology for the Space Station's energy storage system, is described. An advanced development program was initiated to design, manufacture, and integrate a regenerative fuel cell Space Station prototype (RFC SSP). The RFC SSP incorporates long-life fuel cell technology, increased cell area for the fuel cells, and high voltage cell stacks for both units. The RFC SSP's potential for integration with the Space Station's life support and propulsion systems is discussed.
The NASA Space Station will employ alkaline regenerative fuel cells (RFCs) as its sole electrochemical energy storage system, in virtue of demonstrated technology readiness and a high degree of system-level design flexibility. NASA Johnson and NASA Lewis are currently engaged in the development of a 10-kW alkaline engineering model system, for 1987 delivery, which will encompass a fully autonomous 120-V system with 55 percent overall electrical efficiency and a 20,000-hr service life.
A regenerative fuel cell system (RFCS) for energy storage aboard the Modular Space Station (MSS) was selected over the battery technique because of lower cost, lower launch weight, lower required solar array area, and its ability to be integrated into the station's reaction control and environmental control and life support subsystems in addition to the electrical power subsystem. The total MSS energy storage requirement was met by dividing it into four equal modular RFCSs, each made up of a fuel cell subsystem, a water electrolysis subsystem, a gas accumulator subassembly, and a water tank subassembly. The weight of each of the four RFCSs varied from 4000 to 7000 lb with the latter being a more maintainable design. The specific energy ranged between 5.6 to 9.4 watt-hr/lb.
From late 2017 to early 2022, six independent studies with flames of gaseous fuels were conducted on the International Space Station (ISS) in the U.S. combustion research facility. An exploration of flames at the extremes of high sooting and high dilution was conducted with a coaxial coflow burner, where the fuel and oxidizer velocities were typically matched. An investigation of electric-field effects also used the same coflow burner as well as a simple gas-jet burner, with a circular electrode mesh, downstream of the burner, at voltages of either polarity up to 10 kV. A study focused on material flammability in a quiescent atmosphere emulated the burning of condensed-phased fuels using cylindrical burners with a flat perforated outlet instrumented to measure the heat flux to the burner, i.e., emulated fuel. Three studies of soot processes, flame dynamics, and low-temperature combustion used porous spherical burners, yielding a nominally one-dimensional flame structure. The objectives and selected findings of each investigation will be briefly discussed after a short review of the advantages of studying combustion in microgravity, earlier ISS research, and the experimental hardware and its operation.
From late 2017 to early 2022, six independent studies with flames of gaseous fuels were conducted on the International Space Station (ISS) in the U.S. combustion research facility. An exploration of flames at the extremes of high sooting and high dilution was conducted with a coaxial coflow burner, where the fuel and oxidizer velocities were typically matched. An investigation of electric-field effects also used the same coflow burner as well as a simple gas-jet burner, with a circular electrode mesh, downstream of the burner, at voltages of either polarity up to 10 kV. A study focused on material flammability in a quiescent atmosphere emulated the burning of condensed-phased fuels using cylindrical burners with a flat perforated outlet instrumented to measure the heat flux to the burner, i.e., emulated fuel. Three studies of soot processes, flame dynamics, and low-temperature combustion used porous spherical burners, yielding a nominally one-dimensional flame structure. The objectives and selected findings of each investigation will be briefly discussed after a short review of the advantages of studying combustion in microgravity, earlier ISS research, and the experimental hardware and its operation.
Research for a set of six independent experiments with flames of gaseous fuels has been carried out on the International Space Station (ISS) since 2017 using the Combustion Integrated Rack (CIR) and a set of modular hardware. While ISS testing has been completed for most of the studies in the Advanced Combustion via Microgravity Experiments (ACME) project, it is expected to continue into 2022. The objectives and selected findings for each investigation are briefly discussed after a short review of the advantages of studying combustion in microgravity, previous research conducted in space, and the experimental hardware and its operation.
Research for a set of six independent experiments with flames of gaseous fuels has been carried out on the International Space Station (ISS) since 2017 using the Combustion Integrated Rack (CIR) and a set of modular hardware. While ISS testing has been completed for most of the studies in the Advanced Combustion via Microgravity Experiments (ACME) project, it is expected to continue into 2022. The objectives and selected findings for each investigation are briefly discussed after a short review of the advantages of studying combustion in microgravity, previous research conducted in space, and the experimental hardware and its operation.
The development of a fuel cell energy storage system for the Space Station Extravehicular Mobility Unit (EMU) is discussed. The ion-exchange membrane fuel cell uses hydrogen stored as a metal hydride. Several features of the hydrogen-oxygen fuel cell are examined, including its construction, hydrogen storage, hydride recharge, water heat, water removal, and operational parameters.
Hydrogen-oxygen fuel cells have been shown, in several NASA and contractor studies, to be an enabling technology for providing electrical power for lunar bases, outposts, and vehicles. The fuel cell, in conjunction with similar electrolysis cells, comprises a closed regenerative energy storage system, commonly referred to as a regenerative fuel cell (RFC). For stationary applications, energy densities of 1,000 watt-hours per kilograms an order of magnitude over the best rechargeable batteries, have been projected. In this RFC, the coupled fuel cell and electrolyzer act as an ultra-light battery. Electrical energy from solar arrays 'charges' the system by electrolyzing water into hydrogen and oxygen. When an electrical load is applied, the fuel cell reacts the hydrogen and oxygen to 'discharge' usable power. Several concepts for utilizing RFC's, with varying degrees of integration, have been proposed, including both primary and backup roles. For mobile power needs, such as rovers, an effective configuration may be to have only the fuel cell located on the vehicle, and to use a central electrolysis 'gas station'. Two fuel cell technologies are prime candidates for lunar power system concepts: alkaline electrolyte and proton exchange membrane. Alkaline fuel cells have been developed to a mature production power unit in NASA's Space Shuttle Orbiter. Recent advances in materials offer to significantly improve durability to the level needed for extended lunar operations. Proton exchange membrane fuel cells are receiving considerable support for hydrospace and terrestrial transportation applications. This technology promises durability, simplicity, and flexibility.
Reliable design and safe operation of heavy-duty hydrogen refueling stations are essential for the successful deployment of heavy-duty fuel cell electric vehicles (FCEVs). Fueling heavy-duty FCEVs is different from light-duty vehicles in terms of the dispensed hydrogen quantities and fueling rates, requiring tailored fueling station design for each vehicle class. In particular, the selection and design of the onboard hydrogen storage tank system and the fueling performance requirements influence the safe design of hydrogen fueling stations. A thermodynamic modeling and analysis are performed to evaluate the impact of various fueling parameters and boundary conditions on the fueling performance of heavy-duty FCEVs. Here, we studied the effect of dispenser pressure ramp rate and precooling temperature, initial tank temperature and pressure, ambient temperature, and onboard storage design parameters, such as onboard storage pipe diameter and length, on the fueling rate and final vehicle state-of-charge, while observing prescribed tank pressure and temperature safety limits. An important finding was the sensitivity of the temporal fueling rate profile and the final tank state of charge to the design factors impacting pressure drop between the dispenser and vehicle tank, including onboard storage pipe diameter selection, and flow coefficients of nozzle, valves, and fittings. The fueling rate profile impacts the design and cost of the hydrogen precooling unit upstream of the dispenser.
An offshore wind power system is described that consists of wind driven electrical dc generators mounted on floating towers in offshore waters. The output from the generators supplies underwater electrolyzer stations in which water is converted into hydrogen and oxygen. The hydrogen is piped to shore for conversion to electricity in fuel cell stations. It is estimated that this system can produce 159 x 10 to the ninth power kilowatt-hours per year. It is concluded that solar energy - and that includes wind energy - is the only way out of the US energy dilemma in the not too distant future.
The James Webb Space Telescope (JWST), a ten billion-dollar infrared telescope with a 6.5m primary mirror to be launched in 2021, is designed to operate in a Halo orbit around the second Sun-Earth Lagrange point (SEL2) for five to ten years. At that point fuel for station keeping and attitude maneuvers will run out. Refueling missions to JWST, as well as to similar space telescope missions proposed for SEL2, could greatly enhance the “science-per-dollar” value and promote a more sustainable use of space assets. In this paper, we present a novel approach to designing fuel optimal trajectories that will allow the refueling spacecraft to arrive at the SEL2 Halo orbit with maximum final mass (i.e. fuel payload). The low thrust optimal control problem is formulated using an indirect optimization method, leading to a two-point boundary value problem with a bang-bang control structure. We make use of a hyperbolic tangent smoothing technique for performing continuation on the thrust magnitude to reduce the sharpness of the control switches in early iterations and, thus, promote convergence. The problem is posed and solved in the circular restricted three-body problem. In this dynamical system, invariant manifolds exist that can be utilized to reduce fuel consumption. The here presented methodology to this challenging and important problem in astrodynamics demonstrates a significant potential for low-cost refueling mission design.
Hydrogen refueling stations (HRSs) that dispense hydrogen to fuel cell vehicles need to ensure the quality of hydrogen to avoid contamination of the vehicle’s expensive fuel cell stacks. Currently, stations verify their fuel quality only periodically to ensure that they meet the strict fuel quality standards specified by either International Organization for Standards (ISO) or Society for Automotive Engineers (SAE). The development of hydrogen contaminant detectors (HCDs) that can provide low cost continuous monitoring at the HRS can be an invaluable asset in protecting fuel cell vehicles from any fuel contamination in-between infrequent expensive analysis of hydrogen fuel quality. An HCD capable of detecting < 200 ppb of CO in hydrogen is presented in this paper. The HCD is based on an electrochemical hydrogen pumping cell whose ultra-low loaded working electrode is poisoned by the contaminant, thus reducing its hydrogen oxidation reaction rate. The hydrogen pumping cell consists of a Nafion® membrane, a sputtered Pt working electrode, a Pt/Ru counter/pseudo-reference electrode and an internal water wicking system that provides humidification to the membrane and electrodes. When this HCD is operated in a pulsed voltammetry mode, it can provide stable CO response for thousands of hours in a HRS.
The Russian Central Institute of Aviation Motors (CIAM) performed a flight test of a CIAM-designed, hydrogen-cooled/fueled dual-mode scramjet engine over a Mach number range of approximately 3.5 to 6.4 on February 12, 1998, at the Sary Shagan test range in Kazakhstan. This rocket-boosted, captive-carry test of the axisymmetric engine reached the highest Mach number of any scramjet engine flight test to date. The flight test and the accompanying ground test program, conducted in a CIAM test facility near Moscow, were performed under a NASA contract administered by the Dryden Flight Research Center with technical assistance from the Langley Research Center. Analysis of the flight and ground data by both CIAM and NASA resulted in the following preliminary conclusions. An unexpected control sensor reading caused non-optimal fueling of the engine, and flowpath modifications added to the engine inlet during manufacture caused markedly reduced inlet performance. Both of these factors appear to have contributed to the dual-mode scramjet engine operating primarily in a subsonic combustion mode. At the maximum Mach number test point, combustion caused transition from supersonic flow at the fuel injector station to primarily subsonic flow in the combustor. Ground test data were obtained at similar conditions to the flight test, allowing for a meaningful comparison between the ground and flight data. The results of this comparison indicate that the differences in engine performance are small.
The Tropical Rainfall Measuring Mission (TRMM) will have completed nine years in orbit in November 2006. This successful research mission, a joint U.S./Japan effort, has become a key element in the routine monitoring of global precipitation. The package of rain measuring instrumentation, including the first meteorological radar in space, continues to function perfectly, and with the increase in orbital altitude (from 350 km to 400 km) in August 2001 and the mission extension approval in 2005, the satellite has sufficient station-keeping fuel to potentially last until 2012, or perhaps longer. The status of TRMM algorithms and products will be summarized, including the impact of the altitude boost in 2001, and the plans for the upcoming Version 7 of the products will be outlined. The role of TRMM as part of the constellation of rain-measuring satellites preceding GPM will be discussed, as well as its role in climate analysis using its unique radar/radiometer combination.
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