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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

REBOUND: Reverse Engineering Bidirectional Outflow Under Non-Equilibrium Diffusion

Rare-earth elements (REEs) are essential for electronics, renewable energy, and defense technologies. However, the current supply of REEs relies on mining concentrated in a few countries and energy-intensive separations. DOE’s Basic Energy Sciences (BES) program has launched a grand challenge which aims to ensure a sustainable supply of critical REEs by developing innovative and environmentally friendly separation methods. As an alternative to costly and harmful traditional methods, the Non-Equilibrium Transport Driven Separations (NETS) initiative has created a microfluidic Y-channel co-flow method that applies external fields to exploit magneto- and electrohydrodynamic effects for separating dilute REE ions from complex feedstocks. Computational fluid dynamics (CFD) studies have identified a few operating conditions with promising ion selectivity and separation efficiency. However, challenges remain regarding Y-channel versatility across feedstocks and accurate incorporation of physical phenomena into CFD models. In this work, we develop a multi-fidelity modelling approach which integrates experimental results with CFD simulation to build a surrogate model for the dependence of separation efficiency to variation of design parameters. The surrogate model enables a reinforcement learning (RL) method to adaptively launch CFD and experimental runs, improving model fidelity around optimal Y-channel parameters.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Improving bioenergy recovery from municipal wastewater with a novel cloth-filter anaerobic membrane bioreactor

Anaerobic membrane bioreactors (AnMBR) have been used for treating high-strength industrial wastewater at full-scale and the potential to use them for mainstream municipal wastewater treatment presents an important opportunity to turn energy-intensive plants into net-energy producers. However, several limitations of the AnMBR technology have prevented their adoption in the municipal wastewater industry, namely, high membrane cleaning energy demand and low membrane flux. This study demonstrated a novel AnMBR configuration that uses a commercially available cloth filter technology to address the key limitations of cleaning energy and membrane flux. The cloth filter anaerobic membrane bioreactor (CFAnMBR) is comprised of an anaerobic fixed-film bioreactor coupled with a cloth filter membrane with nominal pore size of 5 µm. The pilot CFAnMBR was operated for 150 days through the winter at a municipal wastewater plant in central Illinois (minimum/average influent temperature 5/13°C). The CFAnMBR increased membrane flux by more than 2 orders of magnitude (3,649 ± 1,246 L per meter squared per hour) and reduced cleaning energy demand by 78%—92% (0.0085 kWh/m 3 ) relative to previously reported AnMBR configurations. With the CFAnMBR, average chemical oxygen demand and total suspended solids removal were 66% and 91%, respectively, and were shown to be increased up to 88% and 96% by in-line coagulant dosing with ferric chloride. Average headspace methane yield was 154 mL CH 4 /g COD removed by the end of the study period with influent temperatures of 11°C± 4°C. The CFAnMBR resolves major limitations of AnMBR technology by employing a commercially-available technology already used for other municipal wastewater treatment applications.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

MEASUR Up: Identifying opportunities in a facility

The commercial and industrial sectors account for nearly half of the total U.S. energy consumption. To help these sectors reduce their energy intensity, the U.S. Department of Energy (DOE) designed the Better Buildings, Better Plants Initiative. Through this initiative, more than 900 industrial, commercial, public and residential organizations commit to long-term sustainability goals and share their proven energy efficiency strategies, which inspire others to tap into the continued potential for energy efficiency. Collectively, these organizations have saved 2.5 quadrillion BTUs of energy, equivalent to US$15.3 billion, and 155 million metric tons of carbon dioxide. Within the initiative, the Better Plants side of the program focuses specifically on the industrial sector. More than 270 industrial partners have taken advantage of the unique selection of resources offered including workforce development programs, information sharing, peer-to-peer networking, diagnostic tool loans and software tools. One of the most powerful tools off ered is a revitalization of the legacy DOE software tools used by industry for decades. These have been transformed into a new, free, opensource software tool suite: MEASUR (Manufacturing Energy Assessment Software for Utility Reduction)

Armstrong, Kristina↗
NASA NTRS2020

Modeling the Transport Processes of a Pair of Solar Energetic Particle Events Observed by Parker Solar Probe near Perihelion

We present model calculations of the transport processes of solar energetic particles in the corona and interplanetary medium for two events detected by Parker Solar Probe near its second perihelion on 2019 April 2 and April 4. In the 2019 April 2 event, the <100 keV proton differential intensity measured by the ISOIS EPI-Lo instrument increased by more than a factor of 10 above the pre-event intensity, whereas the ~1 MeV proton differential intensity detected by the EPI-Hi instrument did not show any intensity enhancement. In the 2019 April 4 event, the ~1 MeV proton intensity showed an increase of more than a factor of 100 above the pre-event intensity, but the <100 keV proton intensity enhancement was rather low and gradual. The observational fact that only the 2019 April 4 event displayed a high-energy intensity enhancement indicates that the associated acceleration process in the second event was more energetic than the first event. However, the gradual and low enhancement of the low-energy proton intensity in the second event is at odds with the scenario. In this paper, we investigate the injection and transport processes of protons in the corona and interplanetary magnetic fields with numerical model simulations. Our model calculations suggest that the gradual and low rise of the low-energy protons in the April 4 event was probably due to the different diffusion conditions in these two events and the fact that the spacecraft was moving away from the source region during these two events.

Solar energetic particles↗
NASA NTRS2023

Solar Activity Relations in Energetic Electron Events Measured By the MESSENGER Mission

Aims. We perform a statistical study of the relations between the properties of solar energetic electron (SEE) events measured by the MESSENGER mission from 2010 to 2015 and the parameters of the respective parent solar activity phenomena in order to identify the potential correlations between them. During the time of analysis, the MESSENGER heliocentric distance varied between 0.31 and 0.47 au. Methods. We used a published list of 61 SEE events measured by MESSENGER, which includes information on the near-relativistic electron peak intensities, the peak-intensity energy spectral indices, and the measured X-ray peak intensity of the flares related to the SEE events. Taking advantage of multi-viewpoint remote-sensing observations, we reconstructed, whenever possible, the associated coronal mass ejections (CMEs) and shock waves; and we determined the three-dimensional (3D) properties (location, speed, and width) of the CMEs and the maximum speed of the 3D CME-driven shocks in the corona. We used different methods (Spearman, Pearson, and a Bayesian approach, namely the Kelly method to linear regression) to estimate the correlation coefficients between the flare intensity, maximum speed at the apex of the CME-driven shock, CME speed at the apex, and CME width with the electron peak intensities and with the energy spectral indices. In this statistical study, we considered and addressed the limitations of the particle instrument on board MESSENGER (elevated background intensity level, anti-Sun pointing). Results. There is an asymmetry to the east in the range of connection angles (CAs) for which the SEE events present the highest peak intensities, where the CA is the longitudinal separation between the footpoint of the magnetic field connecting to the spacecraft and the flare location. Based on this asymmetry, we define a subsample of well-connected events as when −65° ≤ CA ≤ +33°. For the well-connected sample, we find moderate to strong correlations between the near-relativistic electron peak intensity and the 3D CME-driven shock maximum speed at the apex (Spearman: cc = 0.53 ± 0.05; Pearson: cc = 0.65 ± 0.04; Kelly: cc = 0.87 ± 0.20), the flare peak intensity (Spearman: cc = 0.63 ± 0.03; Pearson: cc = 0.59 ± 0.03; Kelly: cc = 0.74 ± 0.30), and the 3D CME speed at the apex (Spearman: cc = 0.50 ± 0.04; Pearson: cc = 0.46 ± 0.03; Kelly: cc = 0.60 ± 0.39). When including poorly connected events (full sample), the relations between the peak intensities and the solar-activity phenomena are blurred, showing lower correlation coefficients. Conclusions. Based on the comparison of the correlation coefficients presented in this study using near 0.4 au data, (1) both flare and shock-related processes may contribute to the acceleration of near relativistic electrons in large SEE events, in agreement with previous studies based on near 1 au data; and (2) the maximum speed of the CME-driven shock is a better parameter to investigate particle-acceleration-related mechanisms than the average CME speed, as suggested by the stronger correlation with the SEE peak intensities.

Sun↗
DOE OSTI2025

Optimizing semi-hydrogenation of unsaturated hydrocarbons by electrolyte engineering approach

Electrochemical hydrogenation of unsaturated hydrocarbons, when powered by renewables, represents a unique opportunity to substitute current energy-intensive synthetic routes. Modulation of adsorption energies of the organic substrate and key intermediates of the reaction is critical for fine tuning of the yield, selectivity and kinetics of the reaction. Interestingly, mounting evidence exists regarding the role of electrolyte composition in the outcome of semi-hydrogenation reactions. Nevertheless, electrolyte optimization is a complex task, owing to its hybrid nature. Indeed, it is composed of water serving as a proton source, an organic solvent necessary to dissolve the organic substrate and a conducting salt. Herein, we demonstrate that varying conducting salt and organic solvent has a dramatic impact on the outcomes of semi-hydrogenation of alkynes. By varying salt and water concentrations, we demonstrate that water does not serve as a proton source, and instead addition of an acid is necessary. While increasing the acid concentration increases the yield of the reaction, at too large concentrations the hydrogen evolution reaction becomes predominant. Furthermore, by combining electrochemical measurements with spectroscopic techniques including Fourier transform infrared (FTIR) spectroscopy and small angle X-ray spectroscopy (SAXS), we demonstrate that the electrolyte solvation structure dramatically impacts the yield of the reaction. Organic solvents weakly interacting with water, including acetonitrile, form aqueous nanoheterogeneities that prevent the organic substrate from accessing the catalyst interface and thus lead to limited yields. Instead, solvents such as dimethylformamide form homogeneous mixtures with which all reactants can access the interface, leading to yields greater than 80% for optimized compositions.

Zhang, Rongyu↗
DOE OSTI2020

Molybdenum Carbide Electrocatalysts for Electrochemical Synthesis of Ammonia from Nitrogen: Activity and Stability

Ammonia production has increased from few thousand tons in 1908 to above 200 million tons per year today, revolutionizing the fertilizer industry thanks to the Haber-Bosch (HB) process. However, the HB process is highly energy intensive consuming about 1.4% of fossil energy generated worldwide and releasing 1.87 tons of CO 2 per ton of ammonia produced. This further reduces ammonia’s scope as a carrier fuel for the hydrogen economy. Hence, finding alternative energy efficient ways to synthesize ammonia is important from more than one perspective. Ammonia synthesis from its constituent nitrogen and hydrogen gases is mainly hampered by the nitrogen reduction reaction (NRR) due to the strong N≡N bond (945 kJ mol −1 ). Electrochemical synthesis (ES) routes in this regard offer a milder approach. However, ES of ammonia under different temperatures, utilizing different electrolytes and catalysts has not yet reliably produced ammonia at viable rates and efficiencies. We report an origami-like Mo 2 C cathode catalyst for NRR that achieved a maximum synthesis rate of 2.16 × 10 −11 mol cm −2 s −1 and a faradaic efficiency of 1.8% at 30 °C using Nafion-212 as electrolyte. Origami-like morphology containing numerous kinks appears to improve electrocatalytic activity and show a promising route for fabricating NRR catalysts with higher catalytic activity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Advances in MINLP to Identify Energy-Efficient Distillation Configurations

Separation of mixtures of chemicals, ubiquitous in chemical and petrochemical industries, by distillation is energy intensive. Nearly 3% of the overall energy is used for distillation in the United States. Improving the distillation process is crucial for making chemical industries more sustainable. However, designing distillation sequences is challenging because the choice set is vast, and the equations governing the physical process are highly nonconvex. Traditional design practices rely on heuristics and often result in suboptimal solutions. Tumbalam Gooty et al. present the first approach that reliably identifies the distillation sequence that requires the least energy for a given separation. By embedding convex hulls of substructures and adapting the reformulation-linearization technique to fractions of polynomials, they demonstrated that their approach outperforms the state-of-the-art. Their work will help the chemical industry reduce greenhouse gas emissions associated with distillation.

Business & Economics↗
DOE OSTI2022

Predicting Catalyst Surface Stability Under Reaction Conditions Using Deep Reinforcement Learning and Machine Learning Potentials

Catalysts are critical for most large-scale energy intensive chemical transformation processes, such as energy storage, liquid fuel production, and the formation of chemical building blocks. The catalyst composition, structure, and morphology impact the performance under reaction conditions and influences properties like activity and selectivity. Many industrial catalysts offer imperfect activity/selectivity, or contain expensive metals. Further, catalysts can deactivate over time as the morphology changes or harsh reactive environments alter the surface structure. Methods to automatically model and predict the kinetics of how catalyst surfaces will restructure would enable engineers to design around these challenges, improve performance, increase longevity. This project investigated a specific type of machine learning model, deep reinforcement learning, machine learning models to act as surrogates for the physical system, and compared the results of these approaches with a specialized high-throughput experimental synthesis and measurement platform.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1979

On the inference of properties of Saturn's Ring E from energetic charged particle observations

The paper demonstrates that information about Saturn's Ring E particle size is potentially obtainable from observations of Saturnian trapped radiation. It is shown that observations of the radial dependence of the intensities, energy spectra, electron-to-proton intensity ratio, and pitch angle distributions of energetic charged particles trapped outside of Ring A can potentially provide information (1) on the existence of Ring E, (2) on the effective size of the particulate matter therein, and (3) on the magnitude of the radial diffusion coefficient for energetic particles. A parametric study of these possibilities is specialized to the characteristics of the University of Iowa detectors on Pioneer 11 which was scheduled to make a close encounter with Saturn in 1979.

Thomsen, M. F.↗
DOE OSTI2026

Technology pathways for energy- and water-efficient controlled environment agriculture: A review of technologies, implementation pathways, and regional use cases

Controlled Environment Agriculture (CEA) offers high-yield, climate-resilient food production, but high energy and resource demands challenge its sustainability. This paper synthesizes technologies that can improve outcomes across six categories—energy, CO 2 utilization, building envelope, hardware, water, and process—plus colocation strategies. We evaluate 80 technologies and define ten implementation pathways bundling complementary technologies to reduce energy use, optimize water consumption, and minimize emissions. Regional application is demonstrated through five U.S. case studies spanning different climates. A logic framework guides pathway selection for case studies based on climate, infrastructure, and regulatory context, informing context-sensitive technology deployment. Results show energy intensity reductions of 3–55 %, ranging from energy management programs to comprehensive lighting retrofits; water savings of 20–40 % through closed-loop recirculation; and emissions reductions of 3–100 %, with strategic energy management achieving 3–5 % and renewable electricity paired with electrified heating achieving up to 100 %. Text mining revealed that energy, hardware, and process technologies account for 91 % of literature coverage. Water, building envelope, and CO 2 utilization remain underexplored, indicating priorities for future research. This integrative approach to technology assessment supports growers, developers, and policymakers in aligning CEA system design with local conditions, improving resource efficiency and addressing gaps in cross-domain technology coverage.

Controlled environment agriculture↗
DOE OSTI2022

Materials research and development needs to enable efficient and electrified buildings

Because of the complexity of modern buildings—with many interconnected materials, components, and systems—fully electrifying buildings will require targeted R&D and efficient coordination across those material, component, and system levels. Because buildings that consume the smallest amount of energy are easier to electrify, energy efficiency is a crucial step toward fully electrified buildings. Materials advances will play an important role in both reducing the energy intensity of buildings and electrifying their remaining energy use. Materials are currently being explored, discovered, synthesized, evaluated, optimized, and implemented across many building components, including solid-state lighting; dynamic windows and opaque envelopes; cold climate heat pumps; thermal energy storage; heating, ventilating, and air conditioning (HVAC); refrigeration; non-vapor compression HVAC; and more. In this article, we review the current state-of-the-art of materials for various buildings end uses and discuss R&D challenges and opportunities for both efficiency and electrification.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS1975

Conservation and the industry sector

The following six highly energy intensive industries were studied as targets of energy conservation opportunity: food and kindred products, paper and allied products, chemicals and allied products, petroleum and coal products, stone, glass and clay products, and primary manufacturing. After studying conservation actions within each industry the actions were grouped under three broad categories: increased combustion efficiency, process improvement, and good housekeeping. Some of the results were: (1) approximately 2.18 quads could be saved in 1980 and 2.57 quads in 1985 by installing cogenerative facilities in 50% of the industries, (2) regenerative air-preheaters could result in a 10-15% increase in furnace efficiency representing a 15-25% fuel savings (2.3 to 3.9 quads in 1980 and 2.7 to 4.5 quads in 1985), (3) several major industries have potential for energy savings by recycling-aluminum (0.2 quads), steel (1 quad), glass (0.006 quads), paper and cement (0.08 quads).

Source record↗
NASA NTRS1977

Observations of energetic electrons /E no less than about 200 keV/ in the earth's magnetotail - Plasma sheet and fireball observations

An earlier paper by the authors (1976) has reported on energetic electron anisotropies observed in conjunction with the acceleration regions identified by Frank et al., (1976). The present paper gives more detailed analyses of observations in the distant plasma sheet, including specific features of intensities, energy spectra, and pitch angle distributions of the very energetic electrons associated with intense plasma particle events, with energies ranging between 50 eV and 45 keV, detected with an electron/isotope spectrometer aboard the earth-orbiting spacecraft Imp 8. Two domains are considered: the plasma sheet and the regions near and within the localized magnetotail acceleration regions known as the fireball regions. The instrumentation used offered a number of observational advantages over many previous studies, including inherently low background, large geometric factors, excellent species identification, good angular distribution measurement capability, and availability of high resolution of differential intensities.

Baker, D. N.↗
DOE OSTI2023

Cross-flow separation characteristics and piloting of graphene oxide nanofiltration membrane sheets and tubes for kraft black liquor concentration

Dewatering of weak black liquor (WBL) in the kraft cycle by evaporation is highly energy intensive. Membranes are an attractive alternative for energy-efficient dewatering, but existing commercial polymeric or ceramic membranes are either degraded in BL or have high capital costs. Our recent works have demonstrated the engineering of graphene oxide (GO) nanofiltration membranes, their stability and promising performance in BL conditions, and preliminary scale-up into sheets and tubes. Here, we describe in detail the separation characteristics of GO membrane sheets and tubes under real BL conditions and crossflow operation. Recycle-mode piloting of a GO tubular membrane showed average “production flux” of 16 L/m2/h (LMH) and high rejections of lignin (98.3%), total solids (66%), and total organic carbon (83%), with no signs of irreversible fouling identified. A corresponding GO sheet membrane produced an average flux of ~25 LMH and maintained high lignin rejection of ~97% during a slipstream pilot at a kraft mill site using WBL with ~16 wt% total solids (TS). Finally, we piloted a Dow/DuPont XUS1808 polyamide composite reverse osmosis (RO) membrane for last-mile processing of the GO nanofiltration membrane permeate. The RO membrane showed a steady state flux of 19 LMH at 65 bar and produced ~0.02 wt% TS water product, which is highly suitable for reuse in pulp washing operations in the kraft process. The results have strong positive implications for the industrial application of GO membranes in BL concentration and other related applications.

Materials Science↗
NASA NTRS2002

Evaluation of two fiber optic-based solar collection and distribution systems for advanced space life support

Growing plants in an enclosed controlled environment is crucial in developing bioregenerative life-support systems (BLSS) for space applications. The major challenge currently facing a BLSS is the extensive use of highly energy-intensive electric light sources, which leads to substantial energy wastes through heat dissipations by these lamps. An alternative lighting strategy is the use of a solar irradiance collection, transmission, and distribution system (SICTDS). Two types of fiber optic-based SICTDS, a Fresnel-lens Himawari and a parabolic-mirror optical waveguide (OW) lighting system, were evaluated. The overall efficiency for the OW SICTDS of 40.5% exceeded by 75% that for the Himawari of 23.2%. The spectral distributions of the light delivered by the Himawari and the OW SICTDS were almost identical and had practically no difference from that of terrestrial solar radiation. The ratios of photosynthetically active radiation (PAR) to total emitted radiation (k) of 0.39 +/- 0.02 for the Himawari and 0.41 +/- 0.04 for the OW SICTDS were statistically indistinguishable, were not significantly different from that of 0.042 +/- 0.01 for terrestrial solar radiation, and were comparable to that of 0.35 for a high-pressure sodium (HPS) lamp. The coefficients of variation (CV) of 0.34 and 0.39 for PPF distributions, both at 50 mm X 50 mm square grid arrays, corresponding to the Himawari and the OW SICTDS, respectively, were comparable with each other but were both significantly greater than the CV of 0.08 corresponding to the HPS lamp. The average fresh weight or dry weight of lettuce grown in the solar chamber with either the Himawari or the OW SICTDS showed no statistical difference from the average fresh weight or dry weight of lettuce grown in the reference chamber with the HPS lamp. The results of this study suggest that an SICTDS could help reduce the electric power demand in a BLSS.

NASA Discipline Life Support Systems↗