SEARCH · Engineering Papers

Results for “coagulation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

All sources NASA NTRS DOE OSTI

NASA NTRS1978

The development of structure in the expanding universe

A model for clustering in an expanding universe is developed based on an application of the coagulation equation to the collision and aggregation of bound condensations. While the growth rate of clustering is determined by the rate at which density fluctuations reach the nonlinear regime and therefore depends on the initial fluctuation spectrum, the mass spectrum rapidly approaches a self-similar limiting form. This form is determined by the tidal processes which lead to the merging of condensations, and is not dependent on initial conditions.

Silk, J.↗

NASA NTRS1978

A steady-state stratospheric aerosol model

This paper deals with the development of a one-dimensional steady-state stratospheric aerosol model and the subsequent perturbations caused by including the expected Space Shuttle particulate effluents in the model. Two approaches to the basic modeling effort have been made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other, very few simplifications were made and a computer technique was used to solve the equations. The most complete form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. The results indicate that the model is capable of describing many aspects of the stratospheric aerosol layer, such as size distribution and the vertical profile of particles greater than 0.3 micron diameter.

Rosen, J. M.↗

NASA NTRS1977

A stratospheric aerosol model with perturbations induced by the space shuttle particulate effluents

A one dimensional steady state stratospheric aerosol model is developed that considers the subsequent perturbations caused by including the expected space shuttle particulate effluents. Two approaches to the basic modeling effort were made: in one, enough simplifying assumptions were introduced so that a more or less exact solution to the descriptive equations could be obtained; in the other approach very few simplifications were made and a computer technique was used to solve the equations. The most complex form of the model contains the effects of sedimentation, diffusion, particle growth and coagulation. Results of the perturbation calculations show that there will probably be an immeasurably small increase in the stratospheric aerosol concentration for particles larger than about 0.15 micrometer radius.

Rosen, J. M.↗

NASA NTRS1979

The NASA-Ames Research Center stratospheric aerosol model. 2. Sensitivity studies and comparison with observatories

Sensitivity tests were performed on a one-dimensional, physical-chemical model of the unperturbed stratospheric aerosols, and model calculations were compared with observations. The tests and comparisons suggest that coagulation controls the particle number mixing ratio, although the number of condensation nuclei at the tropopause and the diffusion coefficient at high altitudes are also important. The sulfur gas source strength and the aerosol residence time are much more important than the supply of condensation nuclei in establishing mass and large particle concentrations. The particle size is also controlled mainly by gas supply and residence time. In situ observations of the aerosols and laboratory measurements of aerosols, parameters that can provide further information about the physics and chemistry of the stratosphere and the aerosols found there are provided.

Toon, O. B.↗

NASA NTRS1979

Development of a model and computer code to describe solar grade silicon production processes

Mathematical models, and computer codes based on these models were developed which allow prediction of the product distribution in chemical reactors in which gaseous silicon compounds are converted to condensed phase silicon. The reactors to be modeled are flow reactors in which silane or one of the halogenated silanes is thermally decomposed or reacted with an alkali metal, H2 or H atoms. Because the product of interest is particulate silicon, processes which must be modeled, in addition to mixing and reaction of gas-phase reactants, include the nucleation and growth of condensed Si via coagulation, condensation, and heterogeneous reaction.

Srivastava, R.↗

NASA NTRS1978

Properties of the stratospheric aerosol layer studied with a one-dimensional computer model

Aerosol particle effects are often neglected in theoretical studies of stratospheric phenomena. In reality, the particulate matter normally found above the tropopause may influence the terrestrial radiation balance, catalyze heterogeneous chemical interactions, and serve as a tracer of atmospheric motions. The paper proposes a one-dimensional model of the stratospheric aerosol layer, and it is used to compare aerosol theory with observational data. The model considers gaseous sulfur photochemistry and the physical aerosol processes of nucleation, coagulation, sedimentation, and diffusion. Calculations of the effects on the aerosol layer of stratospheric injections of aluminum oxide particles by Space Shuttle engines and of sulfur dioxide molecules by volcanic activity are performed. The relation between measured aerosol variability and changes in stratospheric air temperatures and vertical transport rates are discussed.

Turco, R. P.↗

NASA NTRS1979

Simulated lidar return from a one-dimensional stratospheric aerosol model

Results are presented for theoretical calculations of lidar backscatter at wavelengths of 0.6943 and 1.06 microns from the stratospheric aerosol. The computations are based on the size distribution, particle number density, and particle composition predicted by a one-dimensional model of the stratospheric aerosol layer that assumes that the primary source of sulfur to the stratosphere is biogenic OCS released at ground level. The aerosol particles are taken to be spherical liquid H2SO4-H2O solution droplets with solid cores, which undergo condensation, evaporation, coagulation, sedimentation, and vertical eddy mixing. The theoretical backscatter profiles are compared with experimental results obtained from actual lidar observations of the stratospheric aerosol layer before and after the eruption of Volcan de Fuego in October 1974. The model predictions are shown to be in good agreement with the average of a number of observations.

Hamill, P.↗

NASA NTRS1978

Collisional evolution of mass-distribution spectrum of planetesimals

The early growth of planetesimals by mutual direct collisions is numerically simulated with a Monte Carlo technique to show how planetesimals with specific mass and velocity distributions evolve into a full-size planet. Four types of collisions are taken into account: rebound, erosion, catastrophic break-up, and coagulation. It is shown that evolution of mass-distribution spectrum is expressed by an inverse power relation. It is also suggested that whether or not a planetesimal can survive catastrophic collision is primarily dependent on mean relative velocity and mechanical properties of planetesimals. It is necessary for the early growth of rocky (basaltic) materials that mean relative velocity be much smaller than 0.1 km/s. Otherwise it is necessary to introduce something like nucleating agents (such as iron bodies which have plastic properties at temperatures higher than 200 K) for the formation of terrestrial planets.

Matsui, T.↗

NASA NTRS1980

Atherosclerotic changes of vessels caused by restriction of movement

The effect of restriction of movement on the development of atheroscelerosis was studied in rabbits. Drastic restriction of movement for 20 and 30 days causes atherosclerotic alterations of the aorta and shifts in ECG which are characteristic of coronary atherosclerosis. At the same time, shortening of the duration of blood coagulation and an increase in the content of catecholamines and beta-lipoproteids occur.

Gvishiani, G. S.↗

NASA NTRS1979

A search for experiments to exploit the space shuttle environment, volume 1

A search for worthwhile experiments in pure and applied physics and chemistry which might take advantage of conditions achievable aboard the space shuttle is documented. Of particular interest were the very large pumping speeds at high or ultra high vacuum, the highly nonequilibrium composition of the ambient atmosphere, and the relative absence of gravitational effects. Ideas and suggestions were solicated in the course of visits to 31 research establishments in Western Europe, India, and Japan; conversations with over 90 scientists; and presentations at 3 international meetings. Intriguing possibilities emerged in the following arenas: (1) spectroscopy of the transition state in chemical reactions; (2) flame structure and analysis; (3) solid propellant combustion; (4) analysis of atmospheric composition; (5) turbulence effects on aerosol coagulation.

Fenn, J. B.↗

NASA NTRS1980

Origin of large interstellar grains toward Rho Ophiuchi

The paper considers why the interstellar grains toward Rho Oph are unusually large. Because the visual opacity per gram is lower than average toward Rho Oph, it is concluded that the simplest interpretation of the observations is that grain coagulation has occurred. This result may be important for understanding the evolution of interstellar clouds and may provide insight into the initial stages of the formation of large solid bodies such as planets.

Jura, M.↗

NASA NTRS1979

Collisional evolution of the mass-distribution spectrum of planetesimals. II

An investigation of conditions for the early growth of planetesimals through their mutual collisions using Monte Carlo technique is presented. Rebound, erosion, catastrophic breakup, and coagulation are considered, mean random velocity is assumed to vary with time, and growth of km-sized planetesimals is shown to occur only when they have the mechanical properties similar to iron meteorites. The formation time of several hundred-km sized planetesimals is much longer than previously reported by Greenberg (1978), and an expression was derived for the temporal variation of the mean mass.

Matsui, T.↗

NASA NTRS1980

Stratospheric aerosol modification by supersonic transport and space shuttle operations - Climate implications

The potential effects on stratospheric aerosols of supersonic transport emissions of sulfur dioxide gas and submicron soot granules, and space shuttle rocket emissions of aluminum oxide particulates are estimated. An interactive particle-gas model of the stratospheric aerosol layer is used to calculate changes due to exhaust emissions, and an accurate radiation transport model is employed to compute the effect of aerosol changes on the earth's average surface temperature. It is concluded that the release of large numbers of small particles (soot or aluminum oxide) into the stratosphere should not lead to a corresponding significant increase in the concentration of large, optically active aerosols, but that the increase in large particles is severely limited by the total mass of sulfate available to make large particles in situ, and by the rapid loss of small seed particles via coagulation. We find that a fleet of several hundred advanced supersonic aircraft operating daily at 20 km, or the launch of one space shuttle rocket per week, could produce roughly a 20% increase in the large-particle concentration of the stratosphere. We find, in addition, that aerosol increases of this magnitude would reduce the global surface temperature by less than 0.01 K.

Turco, R. P.↗

NASA NTRS1980

Smoke and dust particles of meteoric origin in the mesosphere and stratosphere

A height profile of ablated mass from meteors is calculated, assuming an incoming mass of 10 to the -16th g/sq cm/s (44 metric tons per day) and the velocity distribution of Southworth and Sekanina, which has a mean of 14.5 km/s. The profile peaks at 84 km. The fluxes of micrometeorites and residual meteoroids are also calculated. The coagulation of the evaporated silicates into 'smoke' particles is then followed by means of a model adapted from a previous study of the stratospheric sulfate layer. Numerous sensitivity tests are made. Features of the results are a sharp cutoff of the particle distribution above 90 km, and a surface area close to 10 to the -9th sq cm/cu cm all the way from 30 to 85 km. Some confirmation is obtained from balloon studies of condensation nuclei, although the various measurements differ greatly. The optical scattering and extinction are shown to be undetectable. Several potential applications are suggested: nucleation of sulfate particles and noctilucent clouds, scavenging of metallic ions and atoms, and perhaps other aeronomical effects. The latter are limited to processes that can be influenced by a collision time of the order of a day.

Hunten, D. M.↗

NASA NTRS1980

Investigation of multiple scattering effects in aerosols

The results are presented of investigations on the various aspects of multiple scattering effects on visible and infrared laser beams transversing dense fog oil aerosols contained in a chamber (4' x 4' x 9'). The report briefly describes: (1) the experimental details and measurements; (2) analytical representation of the aerosol size distribution data by two analytical models (the regularized power law distribution and the inverse modified gamma distribution); (3) retrieval of aerosol size distributions from multispectral optical depth measurements by two methods (the two and three parameter fast table search methods and the nonlinear least squares method); (4) modeling of the effects of aerosol microphysical (coagulation and evaporation) and dynamical processes (gravitational settling) on the temporal behavior of aerosol size distribution, and hence on the extinction of four laser beams with wavelengths 0.44, 0.6328, 1.15, and 3.39 micrometers; and (5) the exact and approximate formulations for four methods for computing the effects of multiple scattering on the transmittance of laser beams in dense aerosols, all of which are based on the solution of the radiative transfer equation under the small angle approximation.

Deepak, A.↗

NASA NTRS1981

Particles above the tropopause - Measurements and models of stratospheric aerosols, meteoric debris, nacreous clouds, and noctilucent clouds

An outline is presented of the present status of knowledge of stratospheric aerosols, meteoric debris, nacreous clouds, and noctilucent clouds. Considerable progress has been made in studies of these particles during the previous decade and it is appropriate to synthesize the information to provide a background for studies planned for the 1980s. Numerical models of the formation, growth, and evolution are considered and a description is given of the physical processes involved, taking into account aspects of nucleation, coagulation, condensational growth, sedimentation, and questions of dynamical transport. A schematic outline of the physical and chemical processes included in a model of stratospheric aerosols is provided.

Toon, O. B.↗

NASA NTRS1982

Stratospheric aerosols - Observation and theory

Important chemical and physical roles of aerosols are discussed, and properties of stratospheric aerosols as revealed by experimental data are described. In situ measurements obtained by mechanical collection and scattered-light detection yield the overall size distribution of the aerosols, and analyses of preserved aerosol precursor gases by wet chemical, cryogenic and spectroscopic techniques indicate the photochemical sources of particle mass. Aerosol chemical reactions including those of gaseous precursors, those in aqueous solution, and those on particle surfaces are discussed, in addition to aerosol microphysical processes such as nucleation, condensation/evaporation, coagulation and sedimentation. Models of aerosols incorporating such chemical and physical processes are presented, and simulations are shown to agree with measurements. Estimates are presented for the potential aerosol changes due to emission of particles and gases by aerospace operations and industrial consumption of fossil fuels, and it is demonstrated that although the climatic effects of existing levels of stratospheric aerosol pollution are negligible, potential increases in those levels might pose a future threat.

Turco, R. P.↗

NASA NTRS1981

Relatively low-temperature pyrolysis of silane in free space

The continuous flow pyrolyzer is a free space reactor that is used to study the effects of concentration, flow rate and temperature in making solar-grade silicon by pyrolysis of silane gas. Work with the continuous flow pyrolyzer is within the DOE-sponsored Low-Cost Solar Array Project. The work has led to a new theoretical treatment of silane pyrolysis in free space at relatively low temperatures (550 C to 750 C). It involves a sequential, three-step mechanism of particle growth: first, silicon atom generation by homogeneous reaction; second, coagulation to a 0.1 micron particle due to Brownian motion and van der Waals forces; and finally, chemical vapor deposition by heterogeneous reaction to final particle size.

Levin, H.↗