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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Demonstrating resonant ultrasound spectroscopy as a viable technique to characterize thermally conditioned high explosive materials

We present results of resonant ultrasound spectroscopy (RUS) measurements applied to granular high explosive materials at different bulk pressing densities and degree of thermal conditioning. The material chosen in this study is a ubiquitously used explosive material known as pentaerythritol tetranitrate (PETN), which is used commercially in civil and defense applications both as a binderized plastic bonded explosive material and an unbinderized neat material. However, changes in granular PETN bulk elastic properties due to thermal conditioning, which could have implications for better understanding environmental aging-related effects, have not been well studied even though it is believed that elasticity may play an important role in explosive material initiation mechanisms. Furthermore, monitoring elastic property changes in granular explosive pressings has not yet been demonstrated using RUS, which is an appealing non-destructive characterization tool that requires only dry point contact with the explosive material. To this end, we report the first study using RUS to quantify the elastic properties of binderized and neat PETN pressings as well as to quantify changes in elastic properties as a function of both thermal conditioning and bulk pressing density. Elastic stiffness coefficients, sometimes more commonly referred to as elastic constants, calculated from the RUS measurements on the different PETN-based materials show a significant increase for the post-conditioned samples compared to the pre-conditioned samples. This trend of increasing elastic properties with thermal conditioning was consistent for different density pressings, different thermal exposure conditions, and even different neat PETN pressings of differing average crystal sizes and/or specific surface areas.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Role of Bifunctional Ru/Acid Catalysts in the Selective Hydrocracking of Polyethylene and Polypropylene Waste to Liquid Hydrocarbons

Hydrogenolysis of C–C bonds over Ru-based catalysts has emerged as a deconstruction strategy to convert single-use polyolefin waste to liquid alkanes at relatively mild conditions, but this approach exhibits limitations, including methane formation resulting from terminal C–C bond scission. In this study, a variety of catalysts were investigated for the reductive deconstruction of polyethylene (PE) and polypropylene (PP) to identify supports that promote nonterminal C–C bond scission. We found that Ru nanoparticles supported on Brønsted-acidic zeolites with the faujasite (FAU) and Beta (BEA) topologies were highly active for the cleavage of C–C bonds in PE and PP, exhibiting improved liquid yields and suppressed methane formation. For the deconstruction of PE, supporting ruthenium nanoparticles (5 wt %) on FAU increased the yields of liquid alkanes to 67% compared to 33% over an inert silica support (5 wt % Ru/SiO 2 ) at 200 °C, 16 h, under 30 bar of H2. A dramatic selectivity enhancement toward liquid hydrocarbons was also observed for PP over Ru/FAU and Ru/BEA compared to Ru/SiO 2 . To understand the origin of this selectivity improvement, a combination of ex situ and operando characterization techniques were used to reveal that both catalyst structure and acidity play key roles in PE and PP conversion. Operando X-ray absorption spectroscopy studies with model polyolefins over Ru-supported catalysts with varying acidity levels revealed that the local chemical environment of Ru [0] during the reaction is consistent across multiple acidic supports, although the onset of reduction during synthesis of the nanoparticles varies across different supports. These results, combined with reactivity data, demonstrate the importance of the acid-noble metal cooperativity in promoting selective C–C bond scission toward liquid alkanes that shifts the mechanism from hydrogenolysis to ideal hydrocracking.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Nitrate-To-Ammonia Electroconversion at Neutral pH on Polycrystalline Vanadium Sulfide Derived from Vanadium Disulfide

The electrochemical nitrate reduction reaction (NO3RR) offers a pathway to produce NH3 for fuel and fertilizer from waste NO3-. In this work, a polycrystalline vanadium sulfide (VSx), which is derived from solvothermally grown and annealed VS2, is shown to exhibit excellent NO3RR activity (2.3 +- 0.6 mg.cm-2 geo..h-1 @ -0.92 VRHE) and Faradaic efficiency to NH4+ (69 +- 6% at -0.69 VRHE) in buffered neutral pH electrolyte containing 0.1 M NO3-. A variety of characterization techniques are leveraged to support the VSx assignment, including X-ray photoelectron spectroscopy, near-edge X-ray absorption fine structure spectroscopy, selected area electron diffraction, and X-ray diffraction measurements. The VS2 annealing step reduces the oxide character and generates VSx, which, based on the improved NO3RR activity, results in the creation of active sites for NO3- binding. To help shed light on NO3RR on VSx, VS2 is used as a model system, and a grand-canonical density functional theory (GC-DFT) investigation of VS2 shows strong evidence that S vacancies are active sites for NO3RR, where NO3- outcompetes H+ for adsorption at the S-vacancy sites. Moreover, GC-DFT results highlight a thermodynamically favorable reaction to generate NH4+ in an aqueous electrolyte at relevant cathodic potentials. As an annealed material, VSx may contain undersaturated V sites, which show an electronic structure similar to the theoretically calculated S-vacancy site of VS2, and these sites may contribute to the observed increase in NO3RR activity and selectivity for NH4+ on VSx versus unannealed VS2. Finally, kinetic isotope effect measurements suggest that the kinetic rate-limiting step of the NO3RR on VSx is not proton-coupled, indicating it may be the first electron transfer to adsorbed NO3*.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Techniques to characterize dynamics in biomaterials microenvironments: XPCS and microrheology of alginate/PEO–PPO–PEO hydrogels

Many recent studies have highlighted the timescale for stress relaxation of biomaterials on the microscale as an important factor in regulating a number of cell-material interactions, including cell spreading, proliferation, and differentiation. Relevant timescales on the order of 0.1–100 s have been suggested by several studies. While such timescales are accessible through conventional mechanical rheology, several biomaterials have heterogeneous structures, and stress relaxation mechanisms of the bulk material may not correspond to that experienced in the cellular microenvironment. Here we employ X-ray photon correlation spectroscopy (XPCS) to explore the temperature-dependent dynamics, relaxation time, and microrheology of multicomponent hydrogels comprising of commercial poly(ethylene oxide)–poly(propylene oxide)–poly(ethylene oxide) (PEO–PPO–PEO) triblock copolymer F127 and alginate. Previous studies on this system have shown thermoreversible behavior in the bulk oscillatory shear rheology. At physiological temperatures, bulk rheology of these samples shows behavior characteristic of a soft solid, with G' > G" and no crossover between G' and G" over the measurable frequency range, indicating a relaxation time >125 s. By contrast, XPCS-based microrheology shows viscoelastic behavior at low frequencies, and XPCS-derived correlation functions show relaxation times ranging from 10–45 s on smaller length scales. Finally, we are able to use XPCS to effectively probe the viscoelasticity and relaxation behavior within the material microenvironments.

36 MATERIALS SCIENCE↗
NASA NTRS1973

Evaluation of satellite remote sensing and automatic data techniques for characterization of wetlands and marshlands

The author has identified the following significant results. Using the 12S Digicol color additive viewer and eight color classification map has been produced of a portion of the study area. Channel 3 of the MSS produced the best map. Enlargements of the MSS data have been accomplished by using the Data Analysis Station. The attached film recorder has three color guns which are capable of placing 2400 square elements across a 9 inch film. It has been found that by repeating ERTS element 9 times and each scan line 13 times that a map of a scale approximately 1:62,000 can be produced as a color negative film strip. This can be contact printed to produce a color map of the scale. As yet this procedure does not correct for image skew caused by rotation which is believed to be the major source of distortion and blockiness in the image. However, the final product which has not undergone any photographic enlargement is superior to photographically enlarged maps of the same scale.

Cartmill, R. H.↗
NASA NTRS1974

Evaluation of satellite remote sensing and automatic data techniques for characterization of wetlands and coastal marshlands

The author has identified the following significant results. ERTS digital data has been used to detect and measure accretion in the large estuarial system of the Atchafalaya River in southern Louisiana. Comparisons of aerial photography taken in October 1970 with a computer printout of ERTS digital data collected on October 1, 1972, show that in a delineated area of 1400 hectares (3460 acres) an accretion of land area in the amount of 112 hectares (277 acres) had occurred. Analysis of band 3 of the ERTS MSS was used to make a land-water map of the area. The accretion test area was marked on this map and the percentage of elements indicated as land was calculated. This percentage was then multiplied by the total test area to obtain the area of land on the date of the ERTS observation for comparison with the aerial photography. Significant improvement in classification accuracy of ERTS MSS data has been achieved by use of a priori probabilities of occurrence in pattern recognition programs. Two classifications were made with accuracies of 76.0% and 81.5%, respectively.

Cartmill, R. H.↗
NASA NTRS1974

Evaluation of satellite remote sensing and automatic data techniques for characterization of wetlands and coastal marshlands

The author has identified the following significant results. The evaluation was conducted in a humid swamp and marsh area of southern Louisiana. ERTS digital multispectral scanner data was compared with similar data gathered by intermediate altitude aircraft. Automatic data processing was applied to several data sets to produce simulated color infrared images, analysis of single bands, thematic maps, and surface classifications. These products were used to determine the effectiveness of satellites to monitor accretion of land, locate aquatic plants, determine water characteristics, and identify marsh and forest species. The results show that to some extent all of these can be done with satellite data. It is most effective for monitoring accretion and least effective in locating aquatic plants. The data sets used show that the ERTS data is superior in mapping quality and accuracy to the aircraft data. However, in some applications requiring high resolution or maximum use of intermittent clear weather conditions, data gathering by aircraft is preferable. Data processing costs for equivalent areas are about three times greater for aircraft data than ERTS data. This is primarily because of the larger volume of data generated by the high resolution aircraft system.

Cartmill, R. H.↗
NASA NTRS1977

A laser technique for characterizing the geometry of plant canopies

The interception of solar power by the canopy is investigated as a function of solar zenith angle (time), component of the canopy, and depth into the canopy. The projected foliage area, cumulative leaf area, and view factors within the canopy are examined as a function of the same parameters. Two systems are proposed that are capable of describing the geometrical aspects of a vegetative canopy and of operation in an automatic mode. Either system would provide sufficient data to yield a numerical map of the foliage area in the canopy. Both systems would involve the collection of large data sets in a short time period using minimal manpower.

Vanderbilt, V. C.↗
NASA NTRS1984

Coaxial carbon plasma gun deposition of amorphous carbon films

A unique plasma gun employing coaxial carbon electrodes was used in an attempt to deposit thin films of amorphous diamond-like carbon. A number of different structural, compositional, and electrical characterization techniques were used to characterize these films. These included scanning electron microscopy, scanning transmission electron microscopy, X ray diffraction and absorption, spectrographic analysis, energy dispersive spectroscopy, and selected area electron diffraction. Optical absorption and electrical resistivity measurements were also performed. The films were determined to be primarily amorphous, with poor adhesion to fused silica substrates. Many inclusions of particulates were found to be present as well. Analysis of these particulates revealed the presence of trace impurities, such as Fe and Cu, which were also found in the graphite electrode material. The electrodes were the source of these impurities. No evidence of diamond-like crystallite structure was found in any of the film samples. Details of the apparatus, experimental procedure, and film characteristics are presented.

Sater, D. M.↗
NASA NTRS1987

Flaw imaging and ultrasonic techniques for characterizing sintered silicon carbide

The capabilities were investigated of projection microfocus x-radiography, ultrasonic velocity and attenuation, and reflection scanning acoustic microscopy for characterizing silicon carbide specimens. Silicon carbide batches covered a range of densities and different microstructural characteristics. Room temperature, four point flexural strength tests were conducted. Fractography was used to identify types, sizes, and locations of fracture origins. Fracture toughness values were calculated from fracture strength and flaw characterization data. Detection capabilities of radiography and acoustic microscopy for fracture-causing flaws were evaluated. Applicability of ultrasonics for verifying material strength and toughness was examined.

Baaklini, George Y.↗
NASA NTRS1991

Use of photostress techniques to characterize the mechanical behavior of weldments

Photoelastic coatings are useful to view strains in a large field and to examine strain gradients in the field. Contrary to strain gages which average strains along their length, photoelastic coatings provide measurements of strain over a gage length of essentially zero (at a point). When testing is done using specimens having welds between parent material, there are, in general, four zones in which strains may be significantly different. These zones are: (1) the weld material; (2) the fusion boundary; (3) the heat affected zone; and (4) the parent material. To date, most all strain measurement on welded specimens has been done using strain gages to measure in the various zones, thereby averaging across the strain gradient and across zone boundaries in some cases. In an effort to eliminate strain averaging, photoelastic coatings were used to characterize the mechanical behavior of weldments when tested in uniaxial tension. Data were taken at various points along the specimen and were used to construct stress-strain curves.

Gambrell, Samuel C., Jr.↗
NASA NTRS2002

A novel technique for characterizing the thickness of first-year sea ice with the GPS reflected signal

We have examined the characteristics of the GPS signal reflected off the sea ice surface and collected by an airborne or spaceborne receiver, forming a bistatic radar. The constellation of existing transmitters allows gathering bistatic reflections off the sea ice surface at different incidence angles over the course of a day, in contrast to a traditional radar that measures backscattering. We expect to see a strong coherent signal which is much higher than the incoherent one because of forward reflections from very smooth (particularly at L-band) and highly saline first year ice.

GPS ice thickness rough surface scattering↗
NASA NTRS2022

Development and Application of Advanced Measurement Techniques for Characterizing and Controlling Flow Instabilities in Axial Turbomachines

This report summarizes the recent progress in a project aimed at characterizing the flow structure, instabilities, and turbulence in axial compressors, and also on the utilization of casing grooves for delaying the onset of stall without performance degradation at high flow rates. Progress had been hindered by the COVID-19 laboratory closures and restrictions on the number of people that could be present in the laboratory during Fiscal Year 2020. Once the restrictions were lifted, the tasks described in this report were completed.

compressor↗