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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Life Cycle Assessment and Techno-Economic Assessment of Lithium Recovery from Geothermal Brine

Lithium-ion batteries (LIB) play an essential role in the electrification of the transportation sector, and battery demand for lithium compounds will see a significant increase in the coming decades. This has raised concerns on the supply of lithium, and as a result, technologies are being developed to process unconventional lithium sources. One promising technology is to extract lithium from geothermal brine using lithium-aluminum-layered double hydroxide chloride (LDH) sorbent and forward osmosis. A combined life cycle assessment (LCA) and techno-economic assessment (TEA) is conducted to evaluate the environmental and economic performance of this technology. It is assumed that the lithium extraction unit is an add-on to a 50 MW geothermal power plant located in California. The analysis is based on lab-scale experimental data and stoichiometry while considering the economy of scale for an industrial system. LCA results suggest that, compared with conventional LiOH and Li 2 CO 3 production pathways, the new technology achieves 1–95% reduction in environmental impacts. Even higher reduction can be achieved for LiOH produced via electrolysis. This add-on unit for lithium extraction could achieve a payback period of less than 1 year and reach net present values of $454M and $315M and internal rates of return of 792 and 1130% for LiOH and Li 2 CO 3 production pathways, respectively. The favorable environmental and economic performance suggests that LDH sorption coupled with forward osmosis has great potential to enable the domestic production of battery lithium compounds and that further development should be carried out.

15 GEOTHERMAL ENERGY↗
DOE OSTI2026

Separation of Lithium and Magnesium from Brines Using Zwitterionic Simulated Moving Beds: Cooperative Research and Development (Final Report)

The purpose of this work was to separate lithium and magnesium from lithium-containing brines by applying a zwitterionic simulated moving bed (zSMB) system that NLR developed. This work was needed to validate lithium and magnesium separation for future development at scale. Below is a summary of the tasks outlined in the Statement of Work and the results that were generated.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Chemical Impacts of Potential CO2 and Brine Leakage on Groundwater Quality with Quantitative Risk Assessment: A Case Study of the Farnsworth Unit

Potential leakage of reservoir fluids is considered a key risk factor for geologic CO2 sequestration (GCS), with concerns of their chemical impacts on the quality of overlying underground sources of drinking water (USDWs). Effective risk assessment provides useful information to guide GCS activities for protecting USDWs. In this study, we present a quantified risk assessment case study of an active commercial-scale CO2-enhanced oil recovery (CO2-EOR) and sequestration field, the Farnsworth Unit (FWU). Specific objectives of this study include: (1) to quantify potential risks of CO2 and brine leakage to the overlying USDW quality with response surface methodology (RSM); and (2) to identify water chemistry indicators for early detection criteria. Results suggest that trace metals (e.g., arsenic and selenium) are less likely to become a risk due to their adsorption onto clay minerals; no-impact thresholds based on site monitoring data could be a preferable reference for early groundwater quality evaluation; and pH is suggested as an indicator for early detection of a leakage. This study may provide quantitative insight for monitoring strategies on GCS sites to enhance the safety of long-term CO2 sequestration.

58 GEOSCIENCES↗
DOE OSTI2020

Brine Availability Test in Salt: Thermal-Hydrological-Mechanical-Chemical Simulations of a Heated Borehole in Salt - 20239

The Brine Availability Test in Salt (BATS) is a collaboration between Los Alamos, Sandia, and Lawrence Berkeley National Laboratories that is being conducted to reduce the uncertainties associated with disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW) in a hypothetical bedded salt repository. Bedded salt formations may be an acceptable host rock for disposal of nuclear waste due to salt's high thermal conductivity, extremely low permeability, and self-healing capability. In this paper, we report on the first round of the BATS project, a 'shakedown test' known as Phase 1s, with an emphasis on the supporting numerical modeling. The experiment was conducted at the Waste Isolation Pilot Plant (WIPP) using previously drilled horizontal boreholes. The test included a heater borehole in which temperature, pressure, and moisture was monitored, and two nearby temperature monitoring boreholes. Numerical simulations that reflect the 36-year-long history of activity at the WIPP site are necessary to develop the appropriate initial conditions. Testing with different heater designs reveals that a 750 W radiative heater within a borehole can achieve the 120 deg. C borehole wall temperature goal. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Rapid determination of supercritical CO 2 and brine relative permeability using an unsteady-state flow method

In this study, relative permeability of supercritical CO 2 (scCO 2 ) and brine was determined in reactive and non-reactive rock cores using a combination of unsteady-state methodology and computed tomography. Experiments were conducted using a medical grade CT scanner to determine saturation using a custom Python script. The saturation and differential pressure across the core were then used to derive four empirical constants to calculate relative permeability. This methodology increases temporal efficiency while reducing experimental complexity. Additionally, we show that the method can be used to determine scCO 2 relative permeability in a wide range of lithologies and flow rates, and with the ability to account for matrix dissolution during scCO 2 flooding.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Chemical-Free Lithium Separation from High-Salinity Brines Using Model-Informed and Machine Learning-Optimized Multi-Column Zwitterionic Chromatography

Direct Lithium Extraction (DLE) technologies often struggle to produce high-purity lithium salts from high-salinity brines, as current approaches require chemical-based elution, regeneration, and precipitation steps, resulting in significant environmental footprints. A novel salt fractionation approach using carboxybetaine resin, known as zwitterionic chromatography (ZIC), has demonstrated that lithium ions can be separated from divalent cations under high-salinity conditions using only water as eluent, with no regeneration required. To enable continuous and scalable deployment of this approach, we developed a chemical-free Multi-column Zwitterionic Chromatography (MZC) process and its theoretical and process models. To predict and optimize this nontraditional separation system, we introduced a novel anti-Langmuir isotherm, and the isotherm parameters were estimated through a machine learning-driven optimization based on artificial neural network ensembles with numerical feasibility assessment. Using machine learning-driven optimization, the MZC process achieved 98.0% lithium recovery, 99.5 % Li/(Li + Mg + Ca) purity, a 31.3% productivity increase, and a 33% reduction in water use compared to batch operation. The proposed MZC process enables lithium separation at $0.6-1.2 kg-1 Li, with costs dominated by resin manufacturing, while offering lower separation costs and carbon footprint compared with conventional carbonation. Overall, these findings position the MZC process as an effective polishing step within scalable and sustainable lithium production pipelines.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Efficient Low-Temperature Direct Lithium Extraction from Chloride Brines Enabled by High-Capacity Sorbent

The demand for lithium, a key component in rechargeable batteries for electric vehicles and renewable energy storage systems, has surged in recent years. Meeting this demand requires efficient extraction methods that are both environmentally friendly and economically viable. This study investigates the utilization of the high-capacity sorbent amorphous aluminum hydroxide for enabling efficient direct lithium extraction at low temperatures. Traditional extraction methods often involve acid-leaching and energy-intensive processes that are not only expensive but also environmentally taxing. In contrast, our approach leverages the exceptional sorption properties of amorphous aluminum hydroxide to facilitate lithium extraction directly from brine, achieving extraction efficiencies of 94.4% in case 1 and 96.2% in case 2 at low temperatures. Kinetic modeling using the Avrami–Erofe’ev framework reveals a nucleation-growth mechanism ( n = 0.71, k = 0.131 h –1 ), providing quantitative insights into the solid-state phase transformation process. This method significantly reduces energy consumption and minimizes the environmental footprint. Through systematic experimentation and optimization, we demonstrate the effectiveness and scalability of our approach, highlighting its potential to revolutionize lithium extraction processes. Our findings highlight the potential of high-capacity sorbents, particularly amorphous aluminum hydroxide toward sustainable lithium production, contributing to the advancement of clean-energy technologies.

anions↗
DOE OSTI2020

Impacts of Mixed-Wettability on Brine Drainage and Supercritical CO 2 Storage Efficiency in a 2.5-D Heterogeneous Micromodel

Geological carbon storage (GCS) involves unstable drainage processes, the formation of patterns in a morphologically unstable interface between two fluids in a porous medium during drainage. The unstable drainage processes affect CO 2 storage efficiency and plume distribution and can be greatly complicated by the mixed-wet nature of rock surfaces common in hydrocarbon reservoirs where supercritical CO 2 (scCO 2 ) is used in enhanced oil recovery. Here, we performed scCO 2 injection (brine drainage) experiments at 8.5 MPa and 45°C in heterogeneous micromodels, two mixed-wet with varying water- and intermediate-wet patches, and one water-wet. The flow regime changes from capillary fingering through crossover to viscous fingering in the micromodels of the same pore geometry but different wetting surfaces at displacement rates with logCa (capillary number) increasing from –8.1 to –4.4. While the mixed-wet micromodel with uniformly distributed intermediate-wet patches yields ~0.15 scCO 2 saturation increase at both capillary fingering and crossover flow regimes (–8.1 ≤ logCa ≤ –6.1), the one heterogeneous wetting to scCO 2 results in ~0.09 saturation increase only at the crossover flow regime (–7.1 ≤ logCa ≤ –6.1). The interconnected flow paths in the former are quantified and compared to the channelized scCO 2 flow through intermediate-wet patches in the latter by topological analysis. At logCa > –6.1 (near well), the effects of wettability and pore geometry are suppressed by strong viscous force. Both scCO 2 saturation and distribution suggest the importance of wettability on CO 2 storage efficiency and plume shape in reservoirs and capillary leakage through caprock at GCS conditions.

58 GEOSCIENCES↗
DOE OSTI2020

Viral Ecogenomics of Arctic Cryopeg Brine and Sea Ice

This study explores viral community structure and function in remote and extreme Arctic environments, including subzero brines within marine layers of permafrost and sea ice, using a modern viral ecogenomics toolkit for the first time. In addition to providing foundational data sets for these climate-threatened habitats, we found evidence that the viruses had habitat specificity, infected dominant microbial hosts, encoded host-derived metabolic genes, and mediated horizontal gene transfer among hosts. These results advance our understanding of the virosphere and how viruses influence extreme ecosystems. More broadly, the evidence that virally mediated gene transfers may be limited by host range in these extreme habitats contributes to a mechanistic understanding of genetic exchange among microbes under stressful conditions in other systems.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Bipolar Membrane Capacitive Deionization for the Selective Capture of Lithium Ions from Brines and Conversion to Lithium Hydroxide

Meeting the increasing demand for lithium in vehicle electrification and renewable energy storage requires innovations in lithium-ion (Li + ) separations. Traditional solar evaporation methods for lithium recovery are slow and consume tremendous volumes of water and secondary chemicals (acids and bases). This study introduces a bipolar membrane capacitive deionization (BPM-CDI) unit for direct lithium extraction and LiOH production without the external addition of acids and bases. Utilizing de-lithiated lithium-iron-phosphate (LFP) coated carbon cloth electrodes, the BPM-CDI unit demonstrates selective Li + capture over competing ions. Molecular dynamics simulations and H-cell experiments elucidate pH inversion mechanisms during Li + release, yielding LiOH. The BPM-CDI platform efficiently removes Li + from synthetic brines featuring 8x higher Mg 2+ concentrations (200 ppm Mg 2+ ) and 26x higher Na + concentrations (682 ppm Na + ), achieving a LiOH concentration of 124 ppm (36 ppm Li + ) after 8 cycles of recirculation. Post-mortem analysis confirms electrode integrity and stability. BPM-CDI integrated with selective electrodes is a promising electrochemical separation-reactor platform for lithium recovery while producing LiOH.

Kulkarni, Tanmay↗
DOE OSTI2020

FY20 Update on Brine Availability Test in Salt. Revision 4

This report summarizes the 2020 fiscal year (FY20) status of the borehole heater test in salt funded by the US Department of Energy Office of Nuclear Energy (DOE-NE) Spent Fuel and Waste Science & Technology (SFWST) campaign. This report satisfies SFWST level-two milestone number M2SF-20SNO10303032. This report is an update of an August 2019 level-three milestone report to present the final as-built description of the test and the first phase of operational data (BATS la, January to March 2020) from the Brine Availability Test in Salt (BATS) field test.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2021

Brine Availability Test in Salt (BATS) FY21 Update

This report summarizes the 2021 fiscal year (FY21) status of ongoing borehole heater tests in salt funded by the disposal research and development (R&D) program of the Office of Spent Fuel & Waste Science and Technology (SFWST) of the US Department of Energy’s Office of Nuclear Energy’s (DOE-NE) Office of Spent Fuel and Waste Disposition (SFWD). This report satisfies SFWST milestone M2SF- 21SN010303052 by summarizing test activities and data collected during FY21. The Brine Availability Test in Salt (BATS) is fielded in a pair of similar arrays of horizontal boreholes in an experimental area at the Waste Isolation Pilot Plant (WIPP). One array is heated, the other unheated. Each array consists of 14 boreholes, including a central borehole with gas circulation to measure water production, a cement seal exposure test, thermocouples to measure temperature, electrodes to infer resistivity, a packer-isolated borehole to add tracers, fiber optics to measure temperature and strain, and piezoelectric transducers to measure acoustic emissions. The key new data collected during FY21 include a series of gas tracer tests (BATS phase 1b), a pair of liquid tracer tests (BATS phase 1c), and data collected under ambient conditions (including a period with limited access due to the ongoing pandemic) since BATS phase 1a in 2020. A comparison of heated and unheated gas tracer test results clearly shows a decrease in permeability of the salt upon heating (i.e., thermal expansion closes fractures, which reduces permeability).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Dimensionally Reduced Model for Rapid and Accurate Prediction of Gas Saturation, Pressure, and Brine Production in a CO 2 Storage Application: Case Study Using the SACROC Field as Part of SMART Task 5

This technical report presents work conducted by the sub surface analysis team of the Strategic Systems Analysis & Engineering group at NETL for Task 5 of SMART Phase 1. This study involved the development of deep learning models for CO 2 geologic storage that are capable of accurate prediction of spatio-temporal outputs of CO 2 saturation, pressure, and brine production in three dimensional space over a storage operation's injection and post-injection timeframes. The model framework involves ensembling multi-layer encoder networks that provide dimesionality reduction of geologic inputs with fully connected long short-term memory (LSTM) neural networks that generate time-series prediction This approach offers a means to maximize training time efficiency, reduce computational memory burden, and minimize prediction turnaround.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Brine Availability Test in Salt (BATS) (FY25 Final Closeout)

This fiscal year 2025 (FY25) closeout report summarizes the final experiments conducted and data collected in phase 2 of the Brine Availability Test in Salt (BATS 2). The design and interpretation of the test was previously funded by the US Department of Energy’s Office of Nuclear Energy (DOE-NE) Spent Fuel and Waste Disposition Program, under the Disposal Research and Development (R&D) program of the Office of Spent Fuel & Waste Science and Technology (SFWST) but they are not funding it anymore (since May 2025). The experiment was located underground at the Waste Isolation Pilot Plant (WIPP), southeastern New Mexico, which is a DOE Office of Environmental Management (DOE-EM) site managed by the Carlsbad Field Office (CBFO). DOE-EM funds the WIPP Test Coordination Office (TCO), which provided critical implementation support for the continued execution of BATS. A high-level summary of processes expected in a salt repository are given in Kuhlman & Mills (2025).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Effects of Borate and Organics on U(VI) Solubility in WIPP Brine

This report provides an update to a previously issued report on the solubility of uranium (VI) at different borate concentrations and in the presence of organics. The solubility of uranium (VI) in the Waste Isolation Pilot Plant (WIPP)-relevant brine was determined to support ongoing WIPP recertification activities (CRA-2026). This research was performed by the Los Alamos National Laboratory-Carlsbad Operations (LANL-CO) Actinide Chemistry and Repository Science Program (ACRSP).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Neptunium (V) Solubility in WIPP Brine: Presence and Absence of WIPP-Relevant Organic and Inorganic Ligands

The oxidation state and solubility of neptunium (Np) in 5 M NaCl and high ionic strength synthetic WIPP (Waste Isolation Pilot Plant) brines were systematically investigated as a function of pCH+ (7-11) in the presence and absence of WIPP-relevant organic ligands, including EDTA (Ethylenediaminetetraacetic acid), oxalate, citrate, and acetate, as well as inorganic ligands such as borate and carbonate at a temperature of 23 ± 2°C. This study was conducted through long-term batch solubility experiments spanning approximately 950 days, using an undersaturation approach. A comprehensive set of experimental and spectroscopic techniques, including UV-VIS-NIR spectroscopy and Np L III -edge X-ray Absorption Spectroscopy (XAS), was employed to identify the solubility-controlling Np solid phases and the predominant aqueous Np species present in the samples.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗