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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Atomic photoionization

After a brief historical review, this work discusses in detail the experimental techniques available for the investigation of photoionization processes, presents results on typical atoms, and examines some of the problems yet unsolved; in general, the discussion is concerned primarily with the photoionization of atoms in the spectral range from ionization threshold to about 100 A. The examination of experimental techniques treats such topics as light sources, monochromators and spectrographs, absorption and photoionization cells, branching-ratio studies, and electron-impact 'photoionization'. Photoionization measurements are discussed with reference to total and partial photoionization cross sections.

Samson, J. A. R.↗
NASA NTRS1989

Photodissociation of CO in the thermosphere of Venus

Recent investigations of CO photoabsorption demonstrate that photodissociation longward of the ionization threshold at 88.5 nm occurs primarily through line absorptions rather than continuous processes. High-resolution photoabsorption cross sections for CO at rotational temperatures near 250 K have been constructed from the improved data on dissociating transitions. The effects of the new cross sections on the rate of solar photodissociation of CO in the thermosphere of Venus are examined, and the results are compared to values obtained with the lower resolution cross sections available previously. It is found that the photodissociation profile peaks slightly higher in the atmosphere and the peak value and integrated total rate both decrease by about a factor of two.

Fox, J. L.↗
NASA NTRS1989

Jet-resolved vibronic structure in the higher excited states of N2O - Ultraviolet three-photon absorption spectroscopy from 80,000 to 90,000/cm

Ionization-detected UV multiphoton absorption spectroscopy of the excited states of N2O is presented, showing Rydberg structure within 20,000/cm of the first ionization threshold. Despite evidence for strong Rydberg-continuum coupling in the form of broadened bands and Fano line-shapes, the Rydberg structure persists, with atomic-like quantum defects and vibration structure well-matched with that of the ion. In the most clearly resolved spectrum, corresponding to the 3p(delta)1Pi state, Renner-Teller and Herzberg-Teller coupling of electronic and vibrational angular momentum are revealed. It is suggested that these mixings are properties of the N2O(+)Pi ion core.

Patsilinakou, E.↗
NASA NTRS1991

Photoabsorption and photoionization cross sections of NH3, PH3, H2S, C2H2, and C2H4 in the VUV region

Using synchrotron radiation as a continuum light source, the photoabsorption and photoionization cross sections of NH3, PH3, H2S, C2H2, and C2H4 have been measured from their respective ionization thresholds to 1060 A. The vibrational constants associated with the nu(2) totally symmetric, out-of-plane bending vibration of the ground electronic state of PH3(+) have been obtained. The cross sections and quantum yields for producing neutral products through photoexcitation of these molecules in the given spectral regions have also been determined. In the present work, autoionization processes were found to be less important than dissociation and predissociation processes in NH3, PH3, and C2H4. Several experimental techniques have been employed in order to examine the various possible systematic errors critically.

Xia, T. J.↗
NASA NTRS1992

Impulsive phase Fe K-alpha emission in a flare of 1989 March

Evidence for enhanced Fe K-alpha line emission that is coincident (to within 15 s) of an intense hard X-ray (greater than 50 keV) burst is presented on the basis of observations of the Fe K-alpha soft X-ray line made with the SMM. Three different models for explaining the K-alpha enhancement are investigated, namely, photoexcitation by soft X-ray thermal bremsstrahlung radiation from an isothermal source, collisional excitation by nonthermal thick-target electrons, and photoexcitation by a nonthermal hard X-ray flux distribution which extends with a power-law spectrum down to the Fe K-alpha ionization threshold at 7.1 keV. It is found that, to within the limits of isothermal temperature and emission measure set by soft X-ray observations, the thermal photoexcitation model cannot reproduce satisfactorily the intensity of enhanced K-alpha emission during the hard X-ray impulsive phase. The impulsive phase K-alpha flux exceeds that predicted by the thermal photoexcitation model by about 3 sigma. The implications of these results for the nonthermal interpretation of impulsive hard X-ray bursts in solar flares are discussed.

Zarro, D. M.↗
DOE OSTI2019

A boron-coated CCD camera for direct detection of Ultracold Neutrons (UCN)

A new boron-coated CCD camera is described for direct detection of ultracold neutrons (UCN) through the capture reactions $^{10}$B (n,$\alpha$0$\gamma$)$^7$Li (6%) and $^{10}$B(n,$\alpha$1$\gamma$)$^7$Li (94%). The experiments, which extend earlier works using a boron-coated ZnS:Ag scintillator, are based on direct detections of the neutron-capture byproducts in silicon. The high position resolution, energy resolution and particle ID performance of a scientific CCD allows for observation and identification of all the byproducts $\alpha$, $^7$Li and $\gamma$ (electron recoils). A signal-to-noise improvement on the order of 10$^4$ over the indirect method has been achieved. Sub-pixel position resolution of a few microns is demonstrated. The technology can also be used to build UCN detectors with an area on the order of 1 m$^2$. The combination of micrometer scale spatial resolution, few electrons ionization thresholds and large area paves the way to new research avenues including quantum physics of UCN and high-resolution neutron imaging and spectroscopy.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

SuperCDMS Background Models for Low-Mass Dark Matter Searches

An abundance of astrophysical and cosmological evidence indicates the existence of a non-luminous, non-baryonic form of matter, called dark matter, that is approximately a quarter of all energy in the universe. One promising candidate for dark matter is the Weakly Interacting Massive Particle (WIMP) which interacts with baryonic matter at most on the scale of the weak force. The Cryogenic Dark Matter Search (CDMS) experiment aims to detect the nuclear recoils induced by the elastic scattering of WIMPs off of germanium nuclei. This is a rare signal and difficult to detect, especially the low-energy recoils that are produced by low-mass dark matter. The CDMS project operated at the Soudan Underground Laboratory from 2003--2015, with an upgrade to the SuperCDMS experiment in 2012. The germanium detectors were operated at 50~mK and able to measure both the ionization and athermal phonons produced in a particle interaction. Measuring two signals enables discrimination between electron recoil and nuclear recoil events. An alternative operating mode for the detectors is called the CDMS low ionization threshold experiment (CDMSlite), where a higher bias was applied to the detectors and only the phonon signal analyzed. This method increased sensitivity to low-mass dark matter interactions, but sacrificed discrimination capability. The CDMSlite spectrum had a large contribution from electron recoil background events. From the information gained during the first two CDMSlite Runs, a background model was developed for the third and final CDMSlite Run. Analytical descriptions were identified for those backgrounds that were theoretically known, e.g. tritium $\beta$-spectrum, and Geant simulations were used to understand and predict the low-energy spectra from other sources, e.g. Compton scattering. Multiple new models were developed for detectors operated in CDMSlite at Soudan. These include the analytical formula for Compton scattering, and empirical models for surface backgrounds from $^{210}$Pb contamination of the germanium crystals and detector housing. In order to accurately describe the surface events, a new detector response function was developed that included information about the electric field and energy resolution of the detector. These models were essential to the implementation of a profile likelihood analysis of the CDMSlite Run 3 data, which improved on the sensitivity to dark matter over the Run 2 optimum interval analysis for WIMP masses above 2.5~GeV/$c^2$. This demonstrated a successful application of a likelihood analysis to the high-voltage operating mode, and the potential for these analyses in the future SuperCDMS SNOLAB experiment. For the SuperCDMS SNOLAB experiment, the change in background rates from radiogenic neutrons was considered as additional towers of detectors were added, and the feasibility of an active neutron veto as a potential upgrade for large payloads was studied. This veto could be constructed of plastic scintillator with layers of gadolinium resin, and would aid in reducing the nuclear recoil single scatter background that is indistinguishable from the WIMP signal.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2025

Spectroscopic and Computational Studies of Spin-Orbit Coupling of Lanthanide Oxides

Spin-orbit (SO) coupling makes it possible for spin forbidden transitions or reactions within non-relativistic quantum theory feasible. Thus, quantification of such interactions has important implications in photophysics and chemical catalysis. This work aims to quantify SO interactions using lanthanide (Ln) oxides as target molecular systems. Through these systems, we examine the impact on the SO coupling by electron configurations and 4f orbital occupancies of Ln elements and sizes of the metal oxides. By examining these factors, we explore how SO coupling is affected by the number of Ln 4f electrons for a given size of molecules and if the Ln 4f orbitals remain atomic in nature in these small clusters. Ln oxides are produced in laser ablation molecular beams, identified with time-of-fight mass spectrometry, and characterized with laser spectroscopy and relativistic quantum chemical computations. Spectroscopic measurements include mass-analyzed threshold ionization (MATI), zero electron kinetic energy, and slow electron velocity-map imaging spectroscopies. Relativistic computations treat scalar relativistic corrections, electron correlations, and SO interactions. The main results are SO terms and energies of the neutral molecules and singly charged cations, ionization energies of the neutral species, metal-metal and metal-oxygen vibrational frequencies of the ions and, in some cases, neutrals as well, and charge effects on the bonding and structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2019

Plasma environment effects on K lines of astrophysical interest II. Ionization potentials, K thresholds, radiative rates, and Auger widths in Ne- through He-like iron ions (Fe xvii – Fe xxv)

Aims. In the context of accretion disks around black holes, we estimate plasma-environment effects on the atomic parameters associated with the decay of K-vacancy states in highly charged iron ions, namely Fe XVII – Fe XXV. Methods. Within the relativistic multiconfiguration Dirac–Fock (MCDF) framework, the electron–nucleus and electron–electron plasma screenings were approximated with a time-averaged Debye–Hückel potential. Results. Modified ionization potentials, K thresholds, wavelengths, radiative emission rates, and Auger widths are reported for astrophysical plasmas characterized by electron temperatures and densities in the ranges 10^5 − 10^7 K and 10^18 − 10^22 per cu.cm, respectively. Conclusions. We conclude that the high-resolution microcalorimeters on board future X-ray missions such as XRISM and ATHENA are expected to be sensitive to the lowering of the iron K edge due to the extreme plasma conditions occurring in accretion disks around compact objects.

J. Deprince↗
NASA NTRS1987

On the turbulent heating and the threshold condition in the critical ionization velocity interaction

On the basis of the nonlinear treatment of the ion beam instability and the modified two-stream instability, threshold conditions for the critical ionization velocity interaction are derived. There are three different regimes of interaction: (1) additional ionization for relative velocities smaller than the critical velocity, (2) the self-sustained discharge for velocities greater than the critical velocity which indeed turns out as a sharp threshold, and (3) an explosive growth regime for velocities exceeding 1.5 times the critical velocity. Additional charge exchange collisions of ions and energy loss of electrons due to excitation do not change the basic threshold behavior but modify the value of the critical velocity.

Moebius, E.↗
NASA NTRS1984

Mass spectrometric determination of partial and total electron impact ionization cross sections of SO2 from threshold up to 200 eV

The partial and total ionization cross section for the formation of O(+), S(+), SO(+) and SO2(+) from the impact ionization of SO2 are reported, extending the electron impact energies to 200 eV. The relative flow technique is used to determine the cross section values. The threshold potentials for the products are 23.5 eV for O(+), 16.5 eV for S(+), 16.5 eV for SO(+), and 12.5 eV for SO2(+). Good agreement with the literature is found for SO(+) and SO2(+).

Orient, O. J.↗
DOE OSTI2023

First measurement of the nuclear-recoil ionization yield in silicon at 100 eV

We measured the nuclear--recoil ionization yield in silicon with a cryogenic phonon-sensitive gram-scale detector. Neutrons from a mono-energetic beam scatter off of the silicon nuclei at angles corresponding to energy depositions from 4 keV down to 100 eV, the lowest energy probed so far. The results show no sign of an ionization production threshold above 100 eV. These results call for further investigation of the ionization yield theory and a comprehensive determination of the detector response function at energies below the keV scale.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

First Measurement of the Nuclear-Recoil Ionization Yield in Silicon at 100 eV

We measured the nuclear-recoil ionization yield in silicon with a cryogenic phonon-sensitive gram-scale detector. Neutrons from a mono-energetic beam scatter off of the silicon nuclei at angles corresponding to energy depositions from 4 keV down to 100 eV, the lowest energy probed so far. The results show no sign of an ionization production threshold above 100 eV. In conclusion, these results call for further investigation of the ionization yield theory and a comprehensive determination of the detector response function at energies below the keV scale.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1982

Threshold law for electron-atom impact ionization

A derivation of the explicit form of the threshold law for electron impact ionization of atoms is presented, based on the Coulomb-dipole theory. The important generalization is made of using a dipole function whose moment is the dipole moment formed by an inner electron and the nucleus. The result is a modulated quasi-linear law for the yield of positive ions which applies to positron-atom impact ionization.

Temkin, A.↗
DOE OSTI2025

Sheath transitions in a cylindrical filament discharge: Axisymmetric 1D3V PIC-MCC simulations

We present the first nonplanar hot cathode discharge simulations that capture the role of the trapped-ions plasma, elucidating new phenomena unobservable in planar geometric discharges. A discharge struck between a single emitting wire filament cathode and a bounding anode is simulated in cylindrical geometry using an axisymmetric (radial) particle-in-cell Monte-Carlo collisions code. Operating the discharge near its ionization energy threshold can lead to the formation of a two plasma mode (TPM). One plasma forms in the conventional upstream region through electron impact ionization of background neutrals. A second plasma, whose global effect on the discharge was not previously well understood, forms downstream through the trapping of cold ions in the potential well of the filament’s virtual cathode, a process enabled by ion-neutral charge exchange collisions. Three space charge regions intersperse the electrode gap—an emissive sheath between the cathode filament and trapped-ions plasma, a double layer between the two plasmas, and a classical sheath between the upstream plasma and the outer anode. Simulations exhibit mode transitions and quenching instabilities that transform the discharge between the TPM and other single-plasma sheath modes that include classical (temperature-limited), space charge limited, and inverse (anode glow) modes. The transitions are explained via “aid-and-compete” dynamics wherein the growth of one plasma enhances growth in the other while concurrently exhibiting expansion dynamics antagonistic to each other. The system exhibits strong hysteresis memory during the mode transitions. Improved understanding and control of these sheath mode transitions are expected to benefit plasma applications with hot cathodes.

Electrical hysteresis↗