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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Editorial: Achieving Water-Energy-Food Nexus Sustainability: A Science and Data Need or a Need for Integrated Public Policy?

The benefits of addressing the water, energy, and food sectors in an integrated manner is gaining significant recognition. An integrated approach can provide improved resource use efficiencies, more coherent environmental policies, and an overall strategy for achieving sustainability in the three sectors, as outlined in the United Nations Sustainable Development Goals (SDG) 2 (Food), 6 (Water), and 7 (Energy). Societies are concerned with ensuring food security, avoiding wars over water, and creating opportunity by ensuring access to energy. To be effective, however, this approach needs to be adopted at all levels of societies including government, private and civil society and reinforced by management and planning methods. This special issue identifies different approaches that are either being conceptualized or tested to support the Water-Energy-Food (WEF) Nexus approach. The articles contribute to answering the question, “Is achieving Water-Energy-Food (WEF) Nexus Sustainability a science and data need or an integrated public policy need?” In either case, both natural and social sciences will need to combine to support science issues or integrated policy issues. The papers explore the ways in which science, data, and policy development could help to define integrative principles and policies for the three sectors. This approach could expand beyond the water, energy, and food sectors to include health, environment, trade, commerce, and international assistance thereby providing broad support to the SDGs. Moreover, this issue demonstrates that data combined with new technologies (tools and models) can support better decision-making when adopted by governments and the sectors.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗
DOE OSTI2021

Engineering Tunneling Selector to Achieve High Non-linearity for 1S1R Integration

Memristor devices have been extensively studied as one of the most promising technologies for next-generation non-volatile memory. However, for the memristor devices to have a real technological impact, they must be densely packed in a large crossbar array (CBA) exceeding Gigabytes in size. Devising a selector device that is CMOS compatible, 3D stackable, and has a high non-linearity (NL) and great endurance is a crucial enabling ingredient to reach this goal. Tunneling based selectors are very promising in these aspects, but the mediocre NL value limits their applications in large passive crossbar arrays. In this work, we demonstrated a trilayer tunneling selector based on the Ge/Pt/TaN 1+x /Ta 2 O 5 /TaN 1+x /Pd layers that could achieve a NL of 3 × 10 5 , which is the highest NL achieved using a tunnel selector so far. The record-high tunneling NL is partially attributed to the bottom electrode's ultra-smoothness (BE) induced by a Ge/Pt layer. We further demonstrated the feasibility of 1S1R (1-selector 1-resistor) integration by vertically integrating a Pd/Ta 2 O 5 /Ru based memristor on top of the proposed selector.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2020

Restoring Pre-Industrial CO2 Levels While Achieving Sustainable Development Goals

Unless humanity achieves United Nations Sustainable Development Goals (SDGs) by 2030 and restores the relatively stable climate of pre-industrial CO2 levels (as early as 2140), species extinctions, starvation, drought/floods, and violence will exacerbate mass migrations. This paper presents conceptual designs and techno-economic analyses to calculate sustainable limits for growing high-protein seafood and macroalgae-for-biofuel. We review the availability of wet solid waste and outline the mass balance of carbon and plant nutrients passing through a hydrothermal liquefaction process. The paper reviews the availability of dry solid waste and dry biomass for bioenergy with CO2 capture and storage (BECCS) while generating Allam Cycle electricity. Sufficient wet-waste biomass supports quickly building hydrothermal liquefaction facilities. Macroalgae-for-biofuel technology can be developed and straightforwardly implemented on SDG-achieving high protein seafood infrastructure. The analyses indicate a potential for (1) 0.5 billion tonnes/yr of seafood; (2) 20 million barrels/day of biofuel from solid waste; (3) more biocrude oil from macroalgae than current fossil oil; and (4) sequestration of 28 to 38 billion tonnes/yr of bio-CO2. Carbon dioxide removal (CDR) costs are between 25–33% of those for BECCS with pre-2019 technology or the projected cost of air-capture CDR.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Two Year Cosmology Large Angular Scale Surveyor (CLASS) Observations: Long Timescale Stability Achieved with a Front-end Variable-delay Polarization Modulator at 40 GHz

The Cosmology Large Angular Scale Surveyor (CLASS) is a four-telescope array observing the largest angular scales (2≲ ℓ ≲ 200) of the cosmic microwave background (CMB) polarization. These scales encode information about reionization and inflation during the early universe. The instrument stability necessary to observe these angular scales from the ground is achieved through the use of a variable-delay polarization modulator as the first optical element in each of the CLASS telescopes. Here, we develop a demodulation scheme used to extract the polarization timestreams from the CLASS data and apply this method to selected data from the first 2 yr of observations by the 40 GHz CLASS telescope. These timestreams are used to measure the 1/f noise and temperature-to-polarization (T → P) leakage present in the CLASS data. We find a median knee frequency for the pair-differenced demodulated linear polarization of 15.12 mHz and a T → P leakage of <3.8 × 10 -4 (95% confidence) across the focal plane. We examine the sources of 1/f noise present in the data and find the component of 1/f due to atmospheric precipitable water vapor (PWV) has an amplitude of 203 ± 12 µK RJ $\sqrt{{s}}$ for 1 mm of PWV when evaluated at 10 mHz; accounting for ~17% of the 1/f noise in the central pixels of the focal plane. In conclusion, the low levels of T → P leakage and 1/f noise achieved through the use of a front-end polarization modulator are requirements for observing of the largest angular scales of the CMB polarization by the CLASS telescopes.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Achievement of the Planetary Defense Investigations of the Double Asteroid Redirection Test (DART) Mission

NASA's Double Asteroid Redirection Test (DART) mission was the first to demonstrate asteroid deflection, and the mission's Level 1 requirements guided its planetary defense investigations. Here, we summarize DART's achievement of those requirements. On 2022 September 26, the DART spacecraft impacted Dimorphos, the secondary member of the Didymos near-Earth asteroid binary system, demonstrating an autonomously navigated kinetic impact into an asteroid with limited prior knowledge for planetary defense. Months of subsequent Earth-based observations showed that the binary orbital period was changed by –33.24 minutes, with two independent analysis methods each reporting a 1 σ uncertainty of 1.4 s. Dynamical models determined that the momentum enhancement factor, β , resulting from DART's kinetic impact test is between 2.4 and 4.9, depending on the mass of Dimorphos, which remains the largest source of uncertainty. Over five dozen telescopes across the globe and in space, along with the Light Italian CubeSat for Imaging of Asteroids, have contributed to DART's investigations. These combined investigations have addressed topics related to the ejecta, dynamics, impact event, and properties of both asteroids in the binary system. A year following DART's successful impact into Dimorphos, the mission has achieved its planetary defense requirements, although work to further understand DART's kinetic impact test and the Didymos system will continue. In particular, ESA's Hera mission is planned to perform extensive measurements in 2027 during its rendezvous with the Didymos–Dimorphos system, building on DART to advance our knowledge and continue the ongoing international collaboration for planetary defense.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Achieving Diesel-Like Efficiency in a High Stroke-to-Bore Ratio DISI Engine under Stoichiometric Operation

This work explores pathways to achieve diesel-like, high-efficiency combustion with stoichiometric 3-way catalyst compatible spark ignition (SI). A high stroke-to-bore engine design (1.5:1) with cooled exhaust gas recirculation (EGR) and high compression ratio (r c ) was used to improve engine efficiency by up to 30% compared with a production turbocharged gasoline direct injection spark ignition engine. To achieve efficiency improvements, engine experiments were coupled with computational fluid dynamics simulations to guide and explain experimental trends between the original engine and the high stroke-to-bore ratio design (1.5:1). The effects of EGR and late intake valve closing (IVC) and fuel characteristics are investigated through their effects on knock mitigation. Direct injection of 91 RON E10 gasoline, 99 RON E0 gasoline, and liquified petroleum gas (i.e., propane/autogas) were evaluated with geometric rc ranging from 13.3:1 to 16.8:1. Finally, engine experiments demonstrated 47% gross thermal efficiency, and 45% net thermal efficiency at stoichiometric engine operation, at up to 17 bar IMEP and 2000 r/min with 16.8:1 rc.

42 ENGINEERING↗
DOE OSTI2022

Achieving Diesel Powertrain Ownership Parity in Battery Electric Heavy Duty Commercial Vehicles Using a Rapid Recurrent Recharging Architecture

Battery electric vehicles (BEV) in heavy duty (HD) commercial freight transport face challenging technoeconomic barriers to adoption. Specifically, beyond safety and compliance, fleet and operational logistics require both high up-time and parity with diesel system productivity/Total Cost of Ownership (TCO) to enable strong adoption of electrified powertrains. At present, relatively high energy storage prices coupled with the increased weight of BEV systems limit the practicality of HD commercial freight transport to shorter range applications, where smaller batteries will suffice for the mission energy requirements (single operational shift). This paper presents an approach to extend the feasibility of BEV HD trucking for a broad range of applications. The concept is based on the leveraging rapid and recurrent recharging of a BEV HD truck that may either already make frequent stops due to shipment drop-offs/reloading or be required to make frequent stops along with longer missions for recharging. While the challenges of the latter are well appreciated, the concept proposed explores making minimal impact to overall mission time by targeting high C-rate charging while optimizing the frequency (miles) through which these events must occur. The concept optimizes battery size and chemistry, such that the expected life (years and total energy throughput) is balanced with the depth of discharge between recharging events, thus making complete use of the energy available through the life of the battery system. The solution is constrained to minimize the impact on payload capacity. The paper analyzes critical levers in achieving diesel price parity (based on a simplified vehicle TCO), achieved through different purchase options (including lease versus buy) and operational models (half-life swap out). Finally, the paper identifies the application design domain where these solutions are viable with limited impact on fleet operations.

Sujan, Vivek↗
DOE OSTI2020

Achievements and Ongoing Challenges for advanced CFD Boiling Closure Model Development using Physical Insights from Validation-Oriented High-Fidelity Boiling Experiment

The fundamental understanding of the boiling-associated heat transfer, including sliding bubble effect, is still challenging despite the intensive research for decades in both experimental and computational boiling research communities. One of the main difficulties of boiling experiment come from the fact that direct observation of the underlying principle through experiment is very difficult due to the high complexity of the boiling phenomenon. Also, since the heat transfer characteristics associated with boiling is the result of non-linear interaction of various physical parameters coupled to each other, it is challenging to find the relationship between the parameters for modeling. This paper discusses the authors’ past and ongoing boiling research under CASL (Consortium for Advanced Simulation of Light Water Reactors) program, including the efforts to overcome the difficulties of boiling measurement and model development. In particular, we focus on describing the major achievements, lessons learnt, and ongoing challenges for the CFD boiling closure model development based on the high-fidelity subcooled flow boiling experiment at Texas A&M University (TAMU). The major research achievements discussed through this paper include (i) novel boiling measurement strategy and high-fidelity validation data production, (ii) dedicated effort to identify the critical measurement issues in boiling experiment, (iii) new physical insight into sliding bubble heat transfer mechanisms, and (iv) new boiling closure model development. Discussion is also made on the ongoing challenges for the boiling closure model development and the future research plan based on the lessons learnt.

42 ENGINEERING↗
DOE OSTI2022

Achieving American Leadership in the Hydrogen Supply Chain Factsheet

Hydrogen has been identified as a key energy option to enable full decarbonization of the energy system. A secure, resilient supply chain will be critical to achieving emissions reductions and capturing the economic opportunity inherent in the energy sector transition. Electrolyzers and fuel cells are two critical components of the hydrogen supply chain that today are largely nascent industries with limited data on supply chain needs and constraints. This fact sheet summarizes findings from an accompanying report that is one in a series of deep dive assessments of the energy industrial base called for in Executive Order 14017 on America’s supply chains. The report identifies key considerations for the development of water electrolyzer and fuel cell supply chains and materials, focusing on polymer electrolyte and solid oxide technologies, to meet future demand for hydrogen produced by electrolysis and achieve U.S. decarbonization goals.

Source record↗
DOE OSTI2022

Achieving American Leadership in the Nuclear Energy Supply Chain Factsheet

The United States is committed to achieving a 50 to 52 percent reduction from 2005 levels in economy-wide net greenhouse gas pollution by 2030, creating a carbon pollution-free power sector by 2035, and achieving net zero emissions economy-wide by no later than 2050. Nuclear energy is essential to meeting those goals. That includes the existing fleet and advanced reactors that are moving forward for deployment and under development. Nuclear power plants produce 20 percent of the total electricity supply in the United States today and are the largest source of carbon-free energy. However, we have an opportunity to expand significantly nuclear energy’s percentage of electricity generated in the United States. The U.S. Department of Energy (DOE) Office of Nuclear Energy (NE) report - developed in response to President Biden’s Executive Order “America’s Supply Chains” signed in 2021 - describes the nuclear supply chain and investigates challenges for continued operation of today’s 93 reactors and construction of advanced reactors. The supply chain is critical for successfully enabling the continued operation of the existing domestic fleet of light-water reactors as well as supporting deployment of advanced nuclear technologies.

Source record↗
DOE OSTI2023

Achieving Economy-wide Net-Zero Emissions: Is it an impossible goal?

Meeting growing energy demands while eliminating emissions, maintaining affordability, and ensuring energy justice is one of the most significant grand challenges of our time. Governments and private industry around the world have established aggressive goals to achieve net-zero emissions by mid-century. In the U.S., this equates to a net-zero electricity sector by 2035 and across all energy use sectors—including electricity, industry, and transportation—by 2050. The key question then becomes: Can we get there from here? Meeting these aggressive goals demands immediate action, and they require us to think more holistically about our clean energy options. Currently, almost 85% of global energy demands are met by unabated fossil fuels. That means we have a lot of work to do, and we need to consider all of the non-emitting generation options available in each region—including fossil with carbon capture, renewables, and nuclear. And we need to reach our goal while establishing energy justice, which refers to the goal of achieving equity in social and economic participation in the energy system, while remediating past social, economic, and health burdens on communities that have been brought about by our energy system. This presentation will describe U.S. and global efforts focused on novel energy system solutions that strive to maximize use of all clean energy generation options to meet our energy demands, while ensuring sustainability, customer affordability, and a just energy system.

08 HYDROGEN↗
DOE OSTI2020

Opportunities to Implement Solutions to Achieve Remedial Action Objectives in Consideration of Stakeholder Interests - 20365

A case study in the implementation of a soils excavation and removal project conducted at a Formerly Utilized Sites Remedial Action Program (FUSRAP) Maywood Superfund Site (FMSS) vicinity property; an active commercial business, in a densely populated area, with significant operational, technical and, logistical constraints that were expected to limit areas that could be remediated. The United States Army Corps of Engineers-led (USACE) team successfully navigated complex overlapping stakeholder interests to achieve a more efficient and complete removal of contaminated soils and debris while minimizing unnecessary excess costs to the Government. This paper centers on FUSRAP activities at the FMSS vicinity property located at 149-151 Maywood Avenue, Maywood, Bergen County, New Jersey. For most of its FUSRAP history, this ∼109,000 square meter (27-acre) property housed a now-demolished ∼26,000 square meter (6.5-acre) warehouse operated by Sears Logistics Services, a unit of the Sears Roebuck Company (Figure 2). Sears ended its property lease and vacated the warehouse in December 2016. Given that long history and for the purposes of this paper, the property will be referred to as the 'Sears property' or simply 'the property.' The Sears property is approximately 109,000 square meters (27-acres) and is currently zoned for commercial use. The property is bound to the north and northwest by 100 West Hunter Avenue (the Stepan Company), to the northeast by 205 Maywood Avenue, to the east by Maywood Avenue, to the south by 23 West Howcroft Road, and to the west by businesses on NJ Route 17 and the NJ Route 17 roadway. Until December 2016, the property housed a warehouse and distribution center operated by Sears Logistical Services. On-site structures were demolished by the property owner in 2017. The warehouse covered the north section of the property along the Stepan Company property line. A railroad spur from the adjacent property now known as the Maywood Interim Storage Site (MISS) ended at the northeast corner of the warehouse. Wetlands were located east of the warehouse; the rest of the property was covered with paved parking lots and grassed areas. During remediation at the property, opportunities frequently arose where the project team was able to coordinate effectively with stakeholders to sequence remediation activities to facilitate removal of otherwise inaccessible soils and identify opportunities for materials reuse when supported by residual radiological and chemical levels. Some specific opportunities include: - remediating individual truck loading dock bays to maintain tenant operations; - working along a busy highway and in a utility corridor containing a 30-inch high pressure gas main; - remediating Lodi Brook and associated wetlands requiring bypass pumping and other diversionary structures to maintain local community stormwater drainage; - protecting during remediation and supporting access to facilitate tenant/owner maintenance of critical fire protection and water supply system service lines buried in contaminated soils and necessary for safe warehouse operations; and - coordinating with stakeholders to ensure non-radiological contaminants of concern for the site (unaffiliated with FUSRAP) were addressed by the responsible party in a manner that maximized benefit to all parties while supporting an efficient overall site remediation program. Once the property was vacant and the warehouse structure and radiologically non-impacted above-grade structures were demolished, the project identified an opportunity to significantly reduce the volume of waste associated with the foundation of the former warehouse, a foundation suspected of being partially constructed in radiologically contaminated soils. The project developed and implemented supplemental radiological verification survey and sampling strategies based on radiological cross-contamination risk potential with process flow-charts and screening-level based decision points; a program that classified saw-cut sections of concrete based on observed residual surface radioactivity conditions using a combination of gamma sensitive sodium-iodide scans and beta sensitive Geiger-Muller direct measurements. The proposed approach was reviewed with stakeholders with feedback, including consideration of applicable State of New Jersey Site Remediation Program criteria and guidance before implementation. Once classified, additional sampling was performed at frequencies driven by screening. The sampling methods, stockpile sampling frequencies, criteria and, approach to data evaluation were developed in consideration of existing site cleanup standards, regional background ranges, State of New Jersey radiological remediation program guidance, and specific stakeholder input With the property remediation and survey efforts nearly completed, it is relevant to examine retrospectively the objectives, assumptions and limitations in the remedial design (i.e., what was planned) versus what was able to be accomplished through effective teaming. Benefits to other environmental remediation site programs include better understanding of how to work effectively with stakeholders to achieve win-win outcomes, and approaches to site remediation, waste minimization and materials reuse that were successful in their overall outcomes. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

The Essential Role of Integrated Nuclear-Renewable Energy Systems in Achieving Economy-wide Net Zero Solutions

Background/Objectives. The Biden administration has committed to full decarbonization of the U.S. electricity grid by 2035 and economy-wide net zero emissions by 2050. These aggressive goals demand immediate action if we are to be successful, and they require us to think more holistically about our clean energy options. Focused laboratory initiatives, such as the INL Integrated Energy Systems (IES) Initiative, and multiple programs within the Department of Energy are working together to address these holistic solutions. Approach/Activities. Traditionally, electricity generation and management and meeting energy demands for industry and transportation are considered independently. As we seek to achieve net zero, we need to reassess our energy demands. When we consider overall energy use, only one-third is in the form of electricity. Additional energy demands are in the form of heat or steam for industrial processes, as well as transportation. Emissions across these sectors are much harder to abate, and electrification may not be the best option. Reducing environmental emissions at an affordable cost, while maintaining grid reliability and resilience, will require us to use all of the clean energy resources that we have available. That means coordinating the use of nuclear, renewables, and fossil fuels with carbon capture to meet growing demands for electricity, industrial applications, and mobility. The primary focus of IES research is to assess the technical and economic potential of various IES solutions to enhance the flexibility and utilization of nuclear energy generators working alongside renewable generators to meet an array of energy demands—thereby maximizing the utilization of clean energy resources across all energy sectors. Various energy applications and product streams beyond electricity are being evaluated, ranging from generation of potable water to production of hydrogen, fertilizers, synthetic fuels, and various chemicals. Results/Lessons Learned. This presentation will highlight the wide array of RD&D being conducted to develop and deploy nuclear-based IES that will be key to achieving our net zero goals. By working with key collaborators in the nuclear industry, analytical studies are now becoming a reality in multiple demonstration projects.

08 HYDROGEN↗
DOE OSTI2024

Achieving a Net-Zero Future: The Role of Nuclear Energy

Governments and private industry around the world have established aggressive goals to achieve net-zero emissions for the power, industrial, and transportation sectors by 2050. These aggressive goals demand immediate action if we are to be successful, and they require us to think more holistically about our clean energy options. Programs within the U.S. Department of Energy (DOE) are addressing these holistic solutions. Traditionally, electricity generation and management are considered independently from meeting energy demands for industry and transportation. As we seek to eliminate emissions across all energy use sectors we need to reassess how energy demands are met. When we consider overall energy use, only one-third is in the form of electricity. Additional energy demands are in the form of heat or steam for industrial processes, in addition to direct fuel use for transportation. These sectors are much harder to abate, and electrification may not be the best option. Reducing environmental emissions at an affordable cost, while maintaining grid reliability and resilience, will require us to leverage all of the clean energy resources available. The DOE Office of Nuclear Energy (DOE-NE) program on Integrated Energy Systems (IES) is led by researchers at Idaho National Laboratory (INL), and work is conducted in partnership with an array of other DOE laboratories, industry, and academia. The primary focus of IES research is to assess the technical and economic potential of nuclear-driven IES to enhance the flexibility and utilization of nuclear reactors working alongside renewable generators to meet an array of energy demands—thereby maximizing the utilization of clean energy resources across all energy sectors. Various energy applications and product streams beyond electricity are being evaluated, ranging from generation of potable water to production of hydrogen, fertilizers, synthetic fuels, and various chemicals. The DOE-NE program additionally partners with the Hydrogen and Fuel Cell Technologies Office under the DOE Office of Energy Efficiency and Renewable Energy to jointly fund the development of analysis tools, technologies, and nuclear-integrated hydrogen demonstration projects. This presentation will highlight the wide array of R&D being conducted across multiple DOE-funded programs to develop and deploy nuclear-based IES that will be key to achieving our net-zero goals. By working with key collaborators in the nuclear industry, analytical studies are now becoming a reality in demonstration projects.

08 HYDROGEN↗
DOE OSTI2024

Paths Forward: Approaches to Achieve Plug and Process Load Efficiency and Control in Commercial Buildings: Preprint

To accomplish net-zero carbon in the built environment by 2050, we must equitably decarbonize commercial buildings, which includes reducing plug and process loads (PPLs). PPLs are plug-in or hardwired electric and gas loads that are not directly associated with major building end uses like lighting and heating, ventilating, and air conditioning. PPLs account for a growing portion of U.S. commercial building energy consumption. Although commercial building PPL strategies and technologies are available today, they have not been adopted at a level sufficient to achieve significant savings and load flexibility across the building stock. In our "Pathways to Plug and Process Load Efficiency and Control" study, we investigated why these technologies and strategies have not seen widespread adoption and identified five behavior and technology pathways to increase PPL reduction in commercial buildings. In this paper, we expand beyond identifying the pathways and discuss approaches for achieving them. We discuss the importance of collecting and sharing data and case studies on PPL energy consumption and savings from control technology implementation, including code-required measures, for increasing adoption. Centralizing case studies and data, engaging industry organizations, and promoting awareness of PPL efficiency benefits to relevant groups are also key approaches. Additionally, funding, incentives, and rebate programs play important roles in driving PPL efficiency and control adoption. Finally, we discuss integrating PPL efficiency into broader company goals, such as environmental, social and governance (ESG) strategies and green building certifications, to further drive adoption.

adoption pathways↗
DOE OSTI2020

Synergy of Ion Doping and Spiral Array Architecture on Ti 2 Nb 10 O 29 : A New Way to Achieve High-Power Electrodes

Ameliorating electronic/ionic transport and structural stability of electrode materials is important to the development of power-intensive lithium ion batteries. Despite its great potential as a high-power anode, titanium niobium oxide (Ti 2 Nb 10 O 29 , TNO) still underperforms due to its unsatisfactory electronic/ionic conductivity. In this work, a powerful synergistic strategy by combining ion doping and spiral array architecture to boost high-rate performance of TNO is reported. Cr 3+ doped TNO nanoparticles (Cr-TNO) of 5-10 nm intimately grow on a conductive vertical graphene@TiC-C (VGTC) skeleton, forming novel Cr-TNO@VGTC spiral arrays. The unique spiral growth of TNO is achieved due to the confinement effect of VGTC skeleton. Meanwhile, a more open TNO crystal structure with faster ion transfer paths and enhanced structural stability is realized by Cr 3+ doping, demonstrated via density functional theory calculation and in situ synchrotron X-ray diffraction technique. Benefiting from the superior conductive network, enhanced intrinsic electronic/ionic conductivity of Cr-TNO and reinforced structural stability, the Cr-TNO@VTC arrays show prominent high-power performance with a large capacity of 220 mAh g -1 at 40 C (power density of ≈11 kW kg -1 ) and superior durability (91% retention after 500 cycles). This work provides a new path for the construction of widespread high-power electrodes for fast energy storage.

36 MATERIALS SCIENCE↗
DOE OSTI2024

A Pseudo Planar Heterojunction Structure for Eco‐Friendly Printable Organic Solar Cells Achieving 19.05% Efficiency

Abstract Obtaining a well‐accurate vertical distribution active layer morphology through the air‐printing process is an essential task for achieving efficient scalable large‐area organic solar cells (OSCs). In this target, the desired and controllable pseudo planar heterojunction (PPHJ) active layer structure with suitable phase separation is developed by pre‐deposited D18‐Cl layer under the PM6:BTP‐eC9 film via an eco‐friendly manufacturing method. The addition of the D18‐Cl regulates molecular crystallization and leads to an ideal vertical stratification while simultaneously suppressing voltage loss, optimizing energetic disorder, and carrier management. Impressively, the optimal PPHJ devices perform superior power conversion efficiencies (PCEs) of 19.05% (100 nm), 17.33% (300 nm), and 14.14% (4 cm 2 ) compared to the BHJ devices. Importantly, the PPHJ OSCs also exhibit an impressive extrapolated T 80 (the time required to reach 80% of initial PCE) of long‐time storage and operational stability, as well as thermal stability.

Chemistry↗