The initial formation and growth of intermetallic phases in the Cu-Zn system
Diffusion kinetics of beta, gamma, and epsilon intermetallic phases in copper-zinc system
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Diffusion kinetics of beta, gamma, and epsilon intermetallic phases in copper-zinc system
Zirconium and titanium additions for improved mechanical properties and corrosion resistance of aluminum alloy sheet
Silver zinc battery with improved platelock for sealed Mariner cells
Chemisorbed oxygen effect on electrical conductivity of zinc doped polycrystalline tin oxides
Radiative lifetime for atomic transitions in UV multiplets of zinc and cadmium atoms and ions measured using phase shift method
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It is shown that zinc in gallium nitride forms an efficient radiative center emitting blue light at 2.86 plus or minus 0.02 eV and acts as a deep acceptor that can render the crystal insulating. A systematic variation of growth conditions indicates that an optimization of the photoluminescence efficiency is possible. Under nonoptimal conditions lower photon energy emission is obtained.
An evaluation of 5 Ah and 21 Ah Silver-Zinc batteries was made to determine their suitability to meet the energy storage requirements of the bus vehicle, 3 small probes and large probe for the Venus multi-probe mission. The evaluation included a 4 Ah battery for the small probe, a 21 Ah battery for the large probe, one battery of each size for the bus vehicle power, a periodic cycling test on each size battery and a wet stand test of charged and discharged cells of both cell designs. The study on the probe batteries and bus vehicle batteries included both electrical and thermal simulation for the entire mission. The effects on silver migration and zinc penetration of the cellophane separators caused by the various test parameters were determined by visual and X-ray fluorescence analysis. The 5 Ah batteries supported the power requirements for the bus vehicle and small probe. The 21 Ah large probe battery supplied the required mission power. Both probe batteries delivered in excess of 132 percent of rated capacity at the completion of the mission simulation.
Relatively good GaAs solar cells can be made from poor quality substrates by making the junction deep (more than 1 micron) instead of shallow and by leaching both the p and n GaAs regions during the growth process. Air-mass-zero efficiencies of 14.7% (19% AM1) have been obtained from substrates with starting substrate thickness of 0.6 micron.
Preliminary tests were performed on 300 amphere-hour nickel-zinc cells containing the Lewis improved inorganic-organic (I/O) separator. These cells also have other design features included to optimize performance and cycle life. The tests carried out were formation tests and characteristic discharge tests. Information obtained include case temperature and maximum power delivered.
Transitions of the type 2s-2p in the F I, O I, N I, and C I isoelectronic sequences of copper, zinc, gallium, and germanium have been identified in the spectra from plasmas produced by the Omega laser system at the University of Rochester. The wavelengths are in the range 50 to 112 A and are measured using silicon and oxygen lines as wavelength standards for gallium and using several lines from the F I, O I, and Na I isoelectronic sequences as wavelength standards for copper, zinc, and germanium. The energy levels that are determined from the measured wavelengths are also presented. Based on these measurements, the wavelengths for a number of magnetic-dipole transitions within the ground configurations of the F I, O I, and N I isoelectronic sequences are predicted.
Hg sub 1-xZn sub xSe alloys of composition x=0.10 were grown in a Bridgman-Stockbarger growth furnace at translation rates of 0.3 and 0.1 micron sec. The axial and radial composition profiles were determined using precision density measurements and IR transmission-edge-mapping, respectively. A more radially homogeneous alloy was produced at the slower growth rate, while the faster growth rate produced more axially homogeneous alloys. A determination of the electrical properties of the Hg sub 1-xZn sub xSe samples in the temperature range 300K-20K was also made. Typical carrier concentrations were on the order of magnitude of 10 to the 18th power cu/cm, and remained fairly constant as a function of temperature. A study was also made of the temperature dependence of the resistivity and Hall mobility. The effect of annealing in a selenium vapor on both the IR transmission and the electrical properties was determined. Annealing was effective in reducing the number of native donor defects and at the resulting lower carrier concentrations, charge carrier concentration was shown to be a function of temperature. Annealing caused the mobility to increase, primarily at the lower temperature, and the room temperature resistivity to increase. Annealing was also observed to greatly enhance the % IR transmittance of the samples. This was due primarily to the effect of annealing on decreasing the charge carrier concentration.
The Lead-Zinc binary equilibrium system is currently being investigated. Ground based studies of this system were performed to examine the possibility of obtaining a couple which, after diffusion, could be examined continuously along the diffusion axis by quantitative metallography to determine the extent of diffusion. The specimens were analyzed by X-ray fluorescence in the scanning electron microscope to provide exact information on the chemical composition gradient. Two diffusion experiments were run simultaneously in the multipurpose furnace, each in its own isothermal cavity. Two flight samples, two flight backup samples, and two flight space samples were generated.
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The Extravehicular Mobility Unit (EMU) silver/zinc (Ag/Zn) battery is an 11 cell battery of approximately 30 AH. The Ag/Zn battery is comprised of two 4-cell monoblocks and one 3-cell monoblock. A discussion of a wet-life extension test performed on the battery is given in viewgraph form.
The objectives of this paper are to learn: (1) what information a binary phase diagram can yield; (2) how to construct and heat treat a simple diffusion couple; (3) how to prepare a metallographic sample; (4) how to operate a metallograph; (5) how to correlate phases found in the diffusion couple with phases predicted by the phase diagram; (6) how diffusion couples held at various temperatures could be used to construct a phase diagram; (7) the relation between the thickness of an intermetallic phase layer and the diffusion time; and (8) the effect of one species of atoms diffusing faster than another species in a diffusion couple.
The present study evaluates the effect of the systematic variation of copper, chromium, and zirconium contents on the microstructure and mechanical properties of a 7000-type aluminum alloy. Fracture toughness and tensile properties are evaluated for each alloy in both the peak aging, T8, and the overaging, T73, conditions. Results show that dimpled rupture essentially characterize the fracture process in these alloys. In the T8 condition, a significant loss of toughness is observed for alloys containing 2.5 pct Cu due to the increase in the quantity of Al-Cu-Mg-rich S-phase particles. An examination of T8 alloys at constant Cu levels shows that Zr-bearing alloys exhibit higher strength and toughness than the Cr-bearing alloys. In the T73 condition, Cr-bearing alloys are inherently tougher than Zr-bearing alloys. A void nucleation and growth mechanism accounts for the loss of toughness in these alloys with increasing copper content.