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UNREVIEWED DISPOSAL QUESTION EVALUATION: Disposal of the Idaho National Laboratory Classified Mockup Low-Level Waste, Revision 1, at the Area 5 Radioactive Waste Management Site, Nevada National Security Site, Nye County, Nevada

This Unreviewed Disposal Question Evaluation (UDQE) assesses whether the Idaho National Laboratory (INL) Classified Mockup Low-Level Waste (LLW) (INEL208599QR0, Revision 1 [INL 2021]) is suitable for shallow land burial (SLB) at the Area 5 Radioactive Waste Management Site (RWMS) on the Nevada National Security Site (NNSS). Disposal of the INL Classified Mockup LLW meets all performance objectives of U.S. Department of Energy (DOE) Manual DOE M 435.1-1, Radioactive Waste Management Manual, Chapter IV, Section P (DOE 1999). The INL Classified Mockup LLW stream is recommended for acceptance without conditions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Critical Review of Challenges Faced by Converting Food Waste to Bioenergy Through Anaerobic Digestion and Hydrothermal Liquefaction

Here, the conventional approaches for handling food waste has been incineration, composting, landfilling, and anaerobic digestion for producing biogas. In light of organic waste bans and newly discovered presence of per- and polyfluorinated substances (PFAS) in food, food packaging materials, and compost, this review provides a critical summary of what has been investigated and reported and what needs to be considered when choosing suitable pathways for food waste. In addition to the fundamental principles inherent to anaerobic digestion and hydrothermal liquefaction, challenges for each process are identified followed by discussion of potential solutions to resolve the bottlenecks.

09 BIOMASS FUELS↗

PORFLOW Implementation of Special Waste from Models for Slit and Engineered Trenches in the E-Area Low Level Waste Facility Performance Assessment

The implementation of special waste forms (SWFs) in the deterministic PORFLOW Slit Trench (ST) and Engineered Trench (ET) models to be used in the next revision of the E-Area Low Level Waste Facility’s (ELLWFs) Performance Assessment (PA) is outlined in this report. Four SWF implementation methods will be used: effective K d , delayed release, solubility-controlled/diffusion-controlled release, and complex SWF model updates. In addition, the implementation of models that address the presence of tall used equipment storage boxes in ST08-10 is considered a special waste form and will be described.

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Nevada National Security Site 2019 Waste Management Monitoring Report Area 3 and Area 5 Radioactive Waste Management Sites

Environmental monitoring data are collected at and around the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) within the Nevada National Security Site (NNSS). This report summarizes the 2019 environmental data to provide an overall evaluation of RWMS performance and to support environmental compliance and performance assessment (PA) activities. Some of these data (e.g., radiation exposure, air, and groundwater) are presented in other reports (Mission Support and Test Services, LLC 2019, 2020a, 2020b). Direct radiation monitoring data indicate exposure levels at the Area 3 and Area 5 RWMSs are within the range of background levels measured at the NNSS. Slightly elevated exposure levels outside the Area 3 RWMS are attributed to nearby historical aboveground nuclear weapons tests. Air monitoring data at the Area 3 and Area 5 RWMSs show that tritium concentrations in water vapor and americium and plutonium concentrations in air particles are below Derived Concentration Standards for these radionuclides. Groundwater monitoring data indicate the groundwater in the uppermost aquifer beneath the Area 5 RWMS is not impacted by RWMS operations. Results of groundwater analysis from wells around the Area 5 RWMS are below established investigation levels. Leachate samples collected from the leachate collection systems at the Area 5 mixed low-level waste disposal unit are below established contaminant regulatory limits. During 2019, precipitation at the Area 3 RWMS was 77 percent above average, and precipitation at the Area 5 RWMS was 69 percent above average. Water balance measurements indicate that evapotranspiration from the vegetated weighing lysimeter at the Area 5 RWMS dries the soil and prevents downward percolation of precipitation more effectively than evaporation as measured from the bare-soil weighing lysimeter. Vadose zone monitoring in the Area 3 and Area 5 RWMS soil covers shows no evidence of precipitation percolating through the covers to the waste. Moisture from precipitation did not percolate below 120 centimeters (3.9 feet [ft]) in the vegetated final cover on the U-3ax/bl disposal unit at the Area 3 RWMS during 2019. There was no drainage through 2.4 meters (8 ft) of soil as indicated from the Area 3 drainage lysimeters that received only natural precipitation. At the Area 3 RWMS, which received three times the natural precipitation, 57 percent of the applied precipitation and irrigation drained from the bare-soil drainage lysimeter. All 2019 monitoring data indicate that the Area 3 and Area 5 RWMSs are performing within expectations of the model and parameter assumptions for the facilities’ PAs.

2019↗

Repurposing Hanford Waste Tank AP-106 for Interim Storage of Treated Low-Activity Waste - 20044

Hanford Double-Shell Tank AP-106 is being repurposed to serve as the lag storage tank holding feed for the Direct Feed Low-Activity Waste (DFLAW) process at the Waste Treatment and Immobilization Plant (WTP). The repurposing process is the sequence of tank additions and transfers that will remove the Cs 137 inventory from AP-106. The repurposing process steps are designed to remove Cs-137 more effectively and efficiently as compared to regular supernatant transfers. The process steps are estimated to take 2-months to complete. (authors)

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Evaluation of sustainable waste management: An analysis of techno-economic and life cycle assessments of municipal solid waste sorting and decontamination

This study evaluates the economic and environmental feasibility of Municipal Solid Waste (MSW) sorting and decontamination technologies across urban, suburban, and rural areas. Using Techno-Economic Analysis (TEA) and Life Cycle Assessment (LCA), the research assesses cost-effectiveness and environmental impacts, with a focus on cost variability analyzed through Monte Carlo simulations. Findings indicate significant cost differences based on population density: rural areas incur high costs up to $$764/ton due to low waste volumes and limited infrastructure, whereas suburban and urban areas have more feasible costs ranging from $36.3 to $142.5/ton. Environmental impacts also vary, with greenhouse gas emissions at 171 kg CO 2 eq/ton for copy paper and 118.6 kg CO 2 eq/ton for plastics. PM2.5 levels are 9.1 g/ton for copy paper and 6.3 g/ton for plastics, with sorting lines being the main contributors. Monte Carlo simulations reveal a 50% probability of costs being below $$102.26/ton for copy paper and $115.8/ton for plastics in suburban settings. Further, the study underscores the importance of customized waste management strategies to improve economic viability and sustainability based on local conditions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Theoretical foundations of waste factor and waste figure with applications to fixed wireless access and relay systems

The growing energy demands of next-generation wireless systems call for unified, system-level metrics to evaluate and optimize energy efficiency. This paper advances the concept of the Waste Factor (W), or Waste Figure (WF) in decibel scale, as a general framework for modeling power loss across cascaded communication components. By integrating W into the Consumption Factor (CF)–the ratio of data rate to consumed power–we reveal how component inefficiencies influence the minimum achievable energy per bit. Closed-form expressions are derived for energy-per-bit consumption in both direct and relay-assisted links, along with a decision rule for selecting the more energy-efficient path. While not explicitly modeled, Reflective Intelligent Surfaces (RIS) are shown to fit naturally within this framework. The analysis is further applied to a Fixed Wireless Access (FWA) scenario, where asymmetries in traffic direction and hardware inefficiencies are jointly considered, demonstrating the utility of the Waste Factor in guiding energy-aware system design.

Sevim, Nurullah [Texas A&M University, College Sta↗

Waste Shipments to and from the Nevada National Security Site, Radioactive Waste Management Complex (Q3 Transportation Report, FY20) Transportation Report

This report satisfies the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office (NNSA/NFO) commitment to prepare a quarterly summary of waste shipments to the Nevada National Security Site (NNSS) Radioactive Waste Management Complex (RWMC) in Area 5.

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Waste Reduction Network Waste Glossary

This document contains relevant industry definitions to support partners in the Better Buildings, Better Plants Waste Reduction Network. Definitions were compiled using the CalRecycle Glossary, SWANA’s Waste Glossary, the U.S. Environmental Protection Agency, the State of Washington’s Department of Ecology, the Ellen MacArthur Foundation, and Metro Oregon. Some terms contain multiple complementary definitions.

Better Buildings, waste glossary, compost, waste d↗

Effects of composition and canister centerline cooling on microstructure, phase distribution, and chemical durability of dehalogenated iron phosphate waste forms

This paper discusses the effects of composition and canister centerline cooling (CCC) on the microstructures, phase distribution, and chemical durability of dehalogenated iron phosphate waste forms starting from chloride-based salt simulants including KCl (Simple-1), NdCl3 (Simple-2), SrCl2 (Simple-3), LaCl3 (Simple-4), LiCl (Simple-5), CsCl (Simple-6), as well as a complex simulant containing LiCl, KCl, NaCl, CsI, SrCl2, CeCl3, and NdCl3 called ERV2. The simulants represent salt constituents present in salt wastes from electrorefiners used for electrochemical reprocessing. These salts are reacted with ammonium dihydrogen phosphate (ADP) resulting in a NH4Cl (dechlorination) byproduct that is captured and phosphate product containing oxides of the salt cations. This product is further stabilized using Fe2O3 through vitrification at higher temperatures. The results presented herein describe the properties of CCC-treated materials following dechlorination and vitrification including phase identification and quantification, elemental distributions, and chemical durabilities. The chemical durability in the CCC-cooled samples are lower durability than quenched materials for the ERV2 samples. The phases formed upon CCC cooling are very complex compositionally and microstructurally.

iron phosphate glass, iron phosphate waste forms, ↗

Pilot-Scale Continuous Plug-Flow Hydrothermal Liquefaction of Food Waste for Biocrude Production

Pilot-scale hydrothermal liquefaction (HTL) of biowaste is a critical step toward commercialization of the HTL technology. Despite many HTL studies conducted with wet biomass, including food waste, few were performed with a pilot-scale continuous plug-flow reactor (PFR), with the biocrude yield and quality analysis based on dewatering (ASTM D2892 Annex X1). This paper describes the development and performance evaluation of a mobile pilot-scale HTL continuous PFR, with a processing capacity of 60 L/h of wet feedstock and 6 L/h of biocrude production. The reactor system was designed for reaction conditions of up to 325 °C and 17.25 MPa. The reactor has a volume of 28.88 L with an additional counterflow heat exchanger volume of 18.07 L. Two types of food wastes, from a food processing plant and grocery store, were processed at 280 °C for 30 min, producing biocrude oil yields of 52.19 and 47.06 wt %, energy recoveries of 68.17 and 70.77%, and carbon recoveries of 66.91 and 64.78%, respectively. Furthermore, due to its high feedstock capacity and reaction volume, large amounts of biocrude oil and post-HTL wastewater (PHW) were obtained from this pilot-scale reactor to allow downstream research on upgrading biocrude oil for transportation fuel as well as PHW treatment and nutrient recovery.

09 BIOMASS FUELS↗

Nanohybrid of Cu2O-Ti3C2Tx as a Silver-Free MXene Sorbent for Iodine Gas Capture from Nuclear Waste

The capture of volatile radioiodine from nuclear fuel reprocessing off-gas streams remains a critical challenge due to the high volatility, long half-life of 129I, and biological uptake of iodide from the environment. Although silver-based sorbents provide strong iodine chemisorption, their high cost and regulatory classification as mixed radioactive-hazardous waste motivate the development of alternative materials. Here, we report a silver-free Cu2O-Ti3C2Tx MXene hybrid for iodine gas capture at 150 °C. Structural and compositional analyses confirm the formation of Cu2O nanoparticles on Ti3C2Tx nanosheets and their subsequent conversion to thermodynamically stable CuI upon static iodine gas exposure, achieving an iodine mass loading of up to 1115 mg/g. These results demonstrate the potential of Cu2O-Ti3C2Tx MXene as a copper-based alternative to silver sorbents for elevated-temperature iodine gas capture.

iodine gas capture↗

Modeling Geologic Waste Repository Systems Below Residual Saturation

The heat generated by high-level radioactive waste can pose numerical and physical challenges to subsurface flow and transport simulators if the liquid water content in a region near the waste package approaches residual saturation due to evaporation. Here, residual saturation is the fraction of the pore space occupied by liquid water when the hydraulic connectivity through a porous medium is lost, preventing the flow of liquid water. While conventional capillary pressure models represent residual saturation using asymptotically large values of capillary pressure, here, residual saturation is effectively modeled as a tortuosity effect alone. Treating the residual fluid as primarily dead-end pores and adsorbed films, relative permeability is independent of capillary pressure below residual saturation. To test this approach, PFLOTRAN is then used to simulate thermal-hydrological conditions resulting from direct disposal of a dual-purpose canister in unsaturated alluvium using both conventional asymptotic and revised, smooth models. Importantly, while the two models have comparable results over 100 000 years, the number of flow steps required is reduced by approximately 94%.

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Waste Shipments to and from the Nevada National Security Site, Radioactive Waste Management Complex (Transportation Report, Q1 FY2020)

This report satisfies the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office commitment to prepare a quarterly summary of waste shipments to the Nevada National Security Site Radioactive Waste Management Complex in Area 5. This report summarizes the first quarter of fiscal year 2020.

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Immobilization of high-level waste salt in dechlorinated zeolite waste forms. Final report

This project addressed the main challenges associated with the disposal of electrorefiner salt: maximization of fission products in a final waste form and the associated processing costs. Since over half of the mass of the ER salt is chlorine in the form of non-radioactive chloride ions, our approach for achieving dechlorination is through the formation of HCl gas during the exchange of the metal ions into ultrastable H-Y (USHY) zeolite. The zeolite containing the fission products was then sintered into a chemically durable waste form.

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