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At least 109 records · Page 6

VRA Modeling, phase 1

The destruction of organic contaminants in waste water for closed systems, such as that of Space Station, is crucial due to the need for recycling the waste water. A co-current upflow bubble column using oxygen as the gas phase oxidant and packed with catalyst particles consisting of a noble metal on an alumina substrate is being developed for this process. The objective of this study is to develop a plug-flow model that will predict the performance of this three phase reactor system in destroying a multicomponent mixture of organic contaminants in water. Mass balances on a series of contaminants and oxygen in both the liquid and gas phases are used to develop this model. These mass balances incorporate the gas-to-liquid and liquid-to-particle mass transfer coefficients, the catalyst effectiveness factor, and intrinsic reaction rate. To validate this model, a bench scale reactor has been tested at Michigan Technological University at elevated pressures (50-83 psig,) and a temperature range of 200 to 290 F. Feeds consisting of five dilute solutions of ethanol (approx. 10 ppm), chlorobenzene (approx. 20 ppb), formaldehyde (approx. 100 ppb), dimethyl sulfoxide (DMSO approx. 300 ppb), and urea (approx. 20 ppm) in water were tested individually with an oxygen mass flow rate of 0.009 lb/h. The results from these individual tests were used to develop the kinetic parameter inputs necessary for the computer model. The computer simulated results are compared to the experimental data obtained for all 5 components run in a mixture on the differential test column for a range of reactor contact times.

Kindt, Louis M.↗

Environmental impact statement for Manned Spacecraft Center and White Sands Test Facility

This environment has not only attracted people and increased payrolls, but has also created a broader base for the local economy. The activity of the center was a catalyst to private enterprise and has led to sizeable residential and commercial developments. Adequate treatment of domestic and industrial waste water was maintained. A feasibility study is now being conducted to establish a plan for a coordinated, centerwide plan for advanced treatment of domestic and industrial waste water.

Source record↗

Pre- and post-treatment techniques for spacecraft water recovery

Distillation-based waste water pretreatment and recovered water posttreatment methods are proposed for the NASA Space Station. Laboratory investigation results are reported for two nonoxidizing urine pretreatment formulas (hexadecyl trimethyl ammonium bromide and Cu/Cr) which minimize the generation of volatile organics, thereby significantly reducing posttreatment requirements. Three posttreatment methods (multifiltration, reverse osmosis, and UV-assisted ozone oxidation) have been identified which appear promising for the removal of organic contaminants from recovered water.

Putnam, David F.↗

Evaluation and comparison of alternative designs for water/solid-waste processing systems for spacecraft

Promising candidate designs currently being considered for the management of spacecraft solid waste and waste-water materials were assessed. The candidate processes were: (1) the radioisotope thermal energy evaporation/incinerator process; (2) the dry incineration process; and (3) the wet oxidation process. The types of spacecraft waste materials that were included in the base-line computational input to the candidate systems were feces, urine residues, trash and waste-water concentrates. The performance characteristics and system requirements for each candidate process to handle this input and produce the specified acceptable output (i.e., potable water, a storable dry ash, and vapor phase products that can be handled by a spacecraft atmosphere control system) were estimated and compared. Recommendations are presented.

Spurlock, J. M.↗

Prototype development and test results of a continuous ambient air monitoring system for hydrazine at the 10 ppb level

A Hydrazine Vapor Area Monitor (HVAM) system is currently being field tested as a detector for the presence of hydrazine in ambient air. The MDA/Polymetron Hydrazine Analyzer has been incorporated within the HVAM system as the core detector. This analyzer is a three-electrode liquid analyzer typically used in boiler feed water applications. The HVAM system incorporates a dual-phase sample collection/transport method which simultaneously pulls ambient air samples containing hydrazine and a very dilute sulfuric acid solution (0.0001 M) down a length of 1/4 inch outside diameter (OD) tubing from a remote site to the analyzer. The hydrazine-laden dilute acid stream is separated from the air and the pH is adjusted by addition of a dilute caustic solution to a pH greater than 10.2 prior to analysis. Both the dilute acid and caustic used by the HVAM are continuously generated during system operation on an "as needed" basis by mixing a metered amount of concentrated acid/base with dilution water. All of the waste water generated by the analyzer is purified for reuse by Barnstead ion-exchange cartridges so that the entire system minimizes the generation of waste materials. The pumping of all liquid streams and mixing of the caustic solution and dilution water with the incoming sample are done by a single pump motor fitted with the appropriate mix of peristaltic pump heads. The signal to noise (S/N) ratio of the analyzer has been enhanced by adding a stirrer in the MDA liquid cell to provide mixing normally generated by the high liquid flow rate designed by the manufacturer. An onboard microprocessor continuously monitors liquid levels, sample vacuum, and liquid leak sensors, as well as handles communications and other system functions (such as shut down should system malfunctions or errors occur). The overall system response of the HVAM can be automatically checked at regular intervals by measuring the analyzer response to a metered amount of calibration standard injected into the dilute acid stream. The HVAM system provides two measurement ranges (threshold limit value (TLV): 10 to 1000 parts per billion (ppb)/LEAK: 100 ppb to 10 parts per million (ppm)). The LEAK range is created by dilution of the sulfuric acid/hydrazine liquid sample with pure water. This dual range capability permits the analyzer to quantify ambient air samples whose hydrazine concentrations range from 10 ppb to as high as 10 ppm. The laboratory and field prototypes have demonstrated total system response times on the order of 10 to 12 minutes for samples ranging from 10 to 900 ppb in the lLV mode and is greater than 2 minutes for samples ranging from 100 to 1300 ppb in the LEAK mode. Service intervals of over 3 months have been demonstrated for continuous 24 hour/day, 7 day/week usage. The HVAM is made up of a purged cabinet that contains power supplies, RS422 signal transmission capabilities, a UPS, an on-site warning system, and a Line Replaceable Unit (LRU). The LRU includes all of the liquid flow system, the analyzer, the control/data system microprocessor and assorted flow and liquid-level sensors. The LRU is mounted on a track slide system so it can be serviced inplace or totally removed and quickly exchanged with another calibrated unit, thus minimizing analyzer downtime. Once an LRU is removed from an analyzer enclosure, it can be brought to a laboratory facility for complete calibration and periodic maintenance.

Meneghelli, Barry↗

Synthetic Biological Membrane

The ultimate goal of the Synthetic Biological Membrane project is to develop a new type of membrane (using FOST - Forward Osmosis Secondary Treatment) that will enable the waste water treatment system required on exploration missions to operate for extended periods while requiring no maintenance, and using only available resources. Because current water treatment systems have a lifetime of less than 1 year, extending membrane life will benefit exploration missions by reducing upmass and crew time requirements associated with maintenance and resupply/replacement of membranes. The project will use synthetic biology to engineer organisms that protect and replenish the membrane, and this new technology can be easily adapted for use in terrestrial waste water treatment plants.

Biomimetic membrane↗

Rheology Investigations with Sludges from Metro Vancouver

Rheological investigation were performed with primary and secondary waste water treatment sludge. Using a rheometer equipped with a high pressure/temperature cell, flow curves were generated over shear rate at 0 to 1000 s-1. Temperature sweeps spanning 25 to 300 C were also performed are are reported here. The original release, PNNL-SA-185826, is being revised. The revision include a revision table, a disclaimer, and the underlying data set is being added.

sludge wastewater treatment plant sludge character↗

Pollution detection in Lake Champlain using ERTS-1 imagery

The author has identified the following significant results. A major waste water discharge plume generated by a large paper mill along the New York shore of Lake Champlain was visually detected on ERTS-1 imagery. The plume is best displayed in 9.5 inch positive transparencies of MSS bands 4 and 5. Observation of the magnitude and extent of this plume is feasible, under magnification of 4 times. The chemical parameters of this plume have been documented by limnological studies. An enhancement technique useful for documenting the presence of waste water discharge plumes in Lake Champlain utilizes Polaroid MP-3 copy camera equipment and Spectral Data Corporation's multispectral viewer. The 9.5 inch, ERTS-1, positive transparency is enlarged using the Polaroid MP-3 copy camera to produce an enlarged lantern slide size positive transparency. These are projected through the multispectral viewer for enhancement and the scene is viewed directly on the screen or copied by an additional photographic step. The technique is simple and produces rapid results.

Lind, A. O.↗

Estimation of old field ecosystem biomass using low altitude imagery

Color-infrared photography was used to evaluate the biomass of experimental plots in an old-field ecosystem that was treated with different levels of waste water from a sewage treatment facility. Cibachrome prints at a scale of approximately 1:1,600 produced from 35 mm color infrared slides were used to analyze density patterns using prepared tonal density scales and multicell grids registered to ground panels shown on the photograph. Correlation analyses between tonal density and vegetation biomass obtained from ground samples and harvests were carried out. Correlations between mean tonal density and harvest biomass data gave consistently high coefficients ranging from 0.530 to 0.896 at the 0.001 significance level. Corresponding multiple regression analysis resulted in higher correlation coefficients. The results of this study indicate that aerial infrared photography can be used to estimate standing crop biomass on waste water irrigated old field ecosystems. Combined with minimal ground truth data, this technique could enable managers of wastewater irrigation projects to precisely time harvest of such systems for maximal removal of nutrients in harvested biomass.

Nor, S. M.↗

Phase 3 integrated water recovery testing at MSFC: Single loop test results and lessons learned

A series of tests has been conducted at the NASA Marshall Space Flight Center (MSFC) to evaluate the performance of the Space Station Freedom (SSF) water recovery system. Potable and urine reclamation processors were integrated with waste water generation equipment and sucessfully operated for a total of 144 days. This testing marked the first occasion in which the waste feed sources for the previous potable and hygiene loops were combined into a single loop and processed to potable water quality. Reclaimed potable water from the combined waste waters routinely met the SSF water quality specifications.In the last stage of testing, data was obtained that indicated that the water processor (WP) presterilizer may not be required to meet the potable water quality specification. The removal of the presterilizer from the Water Processor design would provide a significant power savings, though an increase in the residence time of the catalytic oxidation reactor may be required to meet the potable microbial and total Organic Carbon specifications. This paper summarizes the test objectives, system design, test activities/protocols, significant results/anomalies and major lessons learned.

Carter, Donald Layne↗

Save or spend? Diverging water‐use strategies of grasses and encroaching clonal shrubs

Abstract Shrub encroachment is one of the primary threats to mesic grasslands around the world. This dramatic shift in plant cover has the potential to alter ecosystem‐scale water budgets and responses to novel rainfall regimes. Understanding divergent water‐use strategies among encroaching shrubs and the grasses they replace is critical for predicting shifts in ecosystem‐scale water dynamics as a result of shrub encroachment, particularly if drought events become more frequent and/or severe in the future. In this study, we assessed how water‐use traits of a rapidly encroaching clonal shrub (Cornus drummondii) and a dominant C 4 grass (Andropogon gerardii) impact responses to changes in water availability in tallgrass prairie. We assessed intra‐annual change in depth of water uptake, turgor loss point and stomatal regulation in each species. Sampling took place at Konza Prairie Biological Station (northeastern KS, USA) during the 2021 and 2022 growing seasons. Cornus drummondiishifted from shallow to deep soil water sources across the 2021 and 2022 growing seasons. This plasticity in depth of water uptake facilitated a ‘wasteful’ water‐use strategy inC. drummondii, where stomatal conductance and transpiration rates continued to increase even when no further gain in photosynthetic rate occurred.A. gerardiiphotosynthetic rates and stomatal conductance were more variable through time and were more responsive to changes in leaf water potential thanC. drummondii. However, intra‐annual adjustment of turgor loss point was more pronounced inC. drummondii(Δπ TLP = −0.48 MPa ± 0.15 SD) than inA. gerardii(Δπ TLP = −0.29 MPa ± 0.19 SD). Synthesis. These results suggest thatC. drummondiiis highly resilient to changes in water availability in surface soils and will likely remain unaffected by future droughts unless they are severe enough to reduce the availability of deep soil water. Given that clonal shrubs are key invaders of grasslands world‐wide, increased leaf‐level water loss is expected to accelerate ecosystem‐level drying as clonal shrub encroachment proceeds in mesic grasslands.

Environmental Sciences & Ecology↗

Domestic wash-water reclamation using an aerospace-developed water recovery subsystem

A prototype aerospace distillation water recovery subsystem was tested to determine its capability to recover potable water from domestic wash water. A total of 0.0994 cu m (26.25 gallons) of domestic wash water was processed over a 7-day period at an average process rate of 0.0146 cu m per day (3.85 gallons per day). The subsystem produced water that met all United States Public Health Standards for drinking water with the exception of two standards which could not be analyzed at the required sensitivity levels. Average energy consumption for this evaluation to maintain both the recovery process and microbial control in the recovered water was approximately 3366 kilowatt-hours per cubic meter (12.74 kilowatt-hours per gallon) of water recovered. This condition represents a worst case energy consumption since no attempt was made to recover heat energy in the subsystem. An ultraviolet radiation cell installed in the effluent line of the subsystem was effective in controlling coliform micro-organisms within acceptable levels for drinking water. The subsystem recovered virtually 100 percent of the available water in the waste-water process. In addition, the subsystem removed 99.6 percent and 98.3 percent of the surfactants and phosphate, respectively, from the wash water.

Hall, J. B., Jr.↗

Regenerative Life Support Evaluation

This paper describes the development plan and design concept of the Regenerative Life Support Evaluation (RLSE) planned for flight testing in the European Space Agency Spacelab. The development plan encompasses the ongoing advanced life support subsystem and a systems integration effort to evolve concurrently subsystem concepts that perform their function and can be integrated with other subsystems in a flight demonstration of a regenerative life support system. The design concept for RLSE comprises water-electrolysis O2 generation, electrochemically depolarized CO2 removal, and Sabatier CO2 reduction for atmosphere regeneration, urine vapor-compression distillation, and wash-water hyperfiltration for waste-water recovery. The flight demonstration by RLSE is an important step in qualifying the regenerative concepts for life support in space stations.

Kleiner, G. N.↗

Independent Orbiter Assessment (IOA): Analysis of the life support and airlock support subsystems

The results of the Independent Orbiter Assessment (IOA) of the Failure Modes and Effects Analysis (FMEA) and Critical Items List (CIL) are presented. The IOA approach features a top-down analysis of the hardware to determine failure modes, criticality, and potential critical items. To preserve independence, this analysis was accomplished without reliance upon the results contained within the NASA FMEA/CIL documentation. This report documents the independent analysis results corresponding to the Orbiter Life Support System (LSS) and Airlock Support System (ALSS). Each level of hardware was evaluated and analyzed for possible failure modes and effects. Criticality was assigned based upon the severity of the effect for each failure mode. The LSS provides for the management of the supply water, collection of metabolic waste, management of waste water, smoke detection, and fire suppression. The ALSS provides water, oxygen, and electricity to support an extravehicular activity in the airlock.

Arbet, Jim↗