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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Integrating crystallographic and computational approaches to carbon-capture materials for the mitigation of climate change

Here, this article presents an overview of the current state of the art in the structure determination of microporous carbon-capture materials, as discussed at the recent NIST workshop “Integrating Crystallographic and Computational Approaches to Carbon-Capture Materials for the Mitigation of Climate Change”. The continual rise in anthropogenic CO 2 concentration and its effect on climate change call for the implementation of carbon capture technologies to reduce the CO 2 concentration in the atmosphere. Porous solids, including metal–organic frameworks (MOFs), are feasible candidates for gas capture and storage applications. However, determining the structure of these materials represents a significant obstacle in their development into advanced sorbents. The existing difficulties can be overcome by integrating crystallographic methods and theoretical modeling. The workshop gathered experimentalists and theorists from academia, government, and industry to review this field and identify approaches, including collaborative opportunities, required to develop tools for rapid determination of the structures of porous solid sorbents and the effect of structure on the carbon capture performance. We highlight the findings of that workshop, especially in the need for reference materials, standardized procedures and reporting of sorbent activation and adsorption measurements, standardized reporting of theoretical calculations, and round-robin structure determination.

36 MATERIALS SCIENCE↗

A Sec14 domain protein is required for photoautotrophic growth and chloroplast vesicle formation in Arabidopsis thaliana

In eukaryotic photosynthetic organisms, the conversion of solar into chemical energy occurs in thylakoid membranes in the chloroplast. How thylakoid membranes are formed and maintained is poorly understood. However, previous observations of vesicles adjacent to the stromal side of the inner envelope membrane of the chloroplast suggest a possible role of membrane transport via vesicle trafficking from the inner envelope to the thylakoids. Here we show that the model plant Arabidopsis thaliana has a chloroplast-localized Sec14-like protein (CPSFL1) that is necessary for photoautotrophic growth and vesicle formation at the inner envelope membrane of the chloroplast. The cpsfl1 mutants are seedling lethal, show a defect in thylakoid structure, and lack chloroplast vesicles. Sec14 domain proteins are found only in eukaryotes and have been well characterized in yeast, where they regulate vesicle budding at the trans -Golgi network. Like the yeast Sec14p, CPSFL1 binds phosphatidylinositol phosphates (PIPs) and phosphatidic acid (PA) and acts as a phosphatidylinositol transfer protein in vitro, and expression of Arabidopsis CPSFL1 can complement the yeast sec14 mutation. CPSFL1 can transfer PIP into PA-rich membrane bilayers in vitro, suggesting that CPSFL1 potentially facilitates vesicle formation by trafficking PA and/or PIP, known regulators of membrane trafficking between organellar subcompartments. These results underscore the role of vesicles in thylakoid biogenesis and/or maintenance. CPSFL1 appears to be an example of a eukaryotic cytosolic protein that has been coopted for a function in the chloroplast, an organelle derived from endosymbiosis of a cyanobacterium.

59 BASIC BIOLOGICAL SCIENCES↗

Close Major-merger Pairs at z = 0: Star-forming Galaxies with Pseudobulges

Abstract We present a study of star-forming galaxies (SFGs) with pseudobulges (bulges with Sérsic indexn< 2) in a local close major-merger galaxy pair sample (H-KPAIR). With data from new aperture photometries in the optical and near-infrared bands (aperture size of 7 kpc) and from the literature, we find that the mean Age of central stellar populations in Spirals with pseudobulges is consistent with that of disky galaxies and is nearly constant against the bulge-to-total ratio (B/T). Paired Spirals have a slightly lower fraction of pure disk galaxies (B/T ≤ 0.1) than their counterparts in the control sample. Compared to SFGs with classical bulges, those with pseudobulges have a higher (>2σ) mean of specific star formation rate (sSFR) enhancement (sSFR enh = 0.33 ± 0.07 versus sSFR enh = 0.12 ± 0.06) and broader scatter (by ∼1 dex). The eight SFGs that have the highest sSFR enh in the sample all have pseudobulges. A majority (69%) of paired SFGs with strong enhancement (having sSFR more than 5 times the median of the control galaxies) have pseudobulges. The Spitzer data show that the pseudobulges in these galaxies are tightly linked to nuclear/circum-nuclear starbursts. Pseudobulge SFGs in S+S and in S+E pairs have significantly (>3σ) different sSFR enhancement, with the means of sSFR enh = 0.45 ± 0.08 and −0.04 ± 0.11, respectively. We find a decrease in the sSFR enhancements with the density of the environment for SFGs with pseudobulges. Since a high fraction (5/11) of pseudobulge SFGs in S+E pairs are in rich groups/clusters (local density N 1Mpc ≥ 7), the dense environment might be the cause for their low sSFR enh .

Astronomy & Astrophysics↗

δ 13 C methane source signatures from tropical wetland and rice field emissions

The atmospheric methane (CH 4 ) burden is rising sharply, but the causes are still not well understood. One factor of uncertainty is the importance of tropical CH 4 emissions into the global mix. Isotopic signatures of major sources remain poorly constrained, despite their usefulness in constraining the global methane budget. Here, a collection of new δ 13 C CH 4 signatures is presented for a range of tropical wetlands and rice fields determined from air samples collected during campaigns from 2016 to 2020. Long-term monitoring of δ 13 C CH 4 in ambient air has been conducted at the Chacaltaya observatory, Bolivia and Southern Botswana. Both long-term records are dominated by biogenic CH 4 sources, with isotopic signatures expected from wetland sources. From the longer-term Bolivian record, a seasonal isotopic shift is observed corresponding to wetland extent suggesting that there is input of relatively isotopically light CH 4 to the atmosphere during periods of reduced wetland extent. This new data expands the geographical extent and range of measurements of tropical wetland and rice δ 13 C CH 4 sources and hints at significant seasonal variation in tropical wetland δ 13 C CH 4 signatures which may be important to capture in future global and regional models.

54 ENVIRONMENTAL SCIENCES↗

An Integrated Feasibility Study of Reservoir Thermal Energy Storage (RTES) in Portland, OR, USA

In regions with long cold overcast winters and sunny summers, Deep Direct-Use (DDU) can be coupled with Reservoir Thermal Energy Storage (RTES) technology to take advantage of pre-existing subsurface permeability to save summer heat for later use during cold seasons. Many aquifers worldwide are underlain by permeable regions (reservoirs) containing brackish or saline groundwater that has limited beneficial use due to poor water quality. We investigate the utility of these relatively deep, slow flowing reservoirs for RTES by conducting an integrated feasibility study in the Portland Basin, Oregon, USA, developing methods and obtaining results that can be widely applied to RTES systems elsewhere. As a case study, we have conducted an economic and social cost-benefit analysis for the Oregon Health and Science University (OHSU), a teaching hospital that is recognized as critical infrastructure in the Portland Metropolitan Area. Our investigation covers key factors that influence feasibility including 1) the geologic framework, 2) heat and fluid flow modeling, 3) capital and maintenance costs, 4) the regulatory framework, and 5) operational risks. By pairing a model of building seasonal heat demand with an integrated model of RTES resource supply, we determine that the most important factors that influence RTES efficacy in the study area are operational schedule, well spacing, the amount of summer heat stored (in our model, a function of solar array size), and longevity of the system. Generally, heat recovery efficiency increases as the reservoir and surrounding rocks warm, making RTES more economical with time. Selecting a base-case scenario, we estimate a levelized cost of heat (LCOH) to compare with other sources of heating available to OHSU and find that it is comparable to unsubsidized solar and nuclear, but more expensive than natural gas. Additional benefits of RTES include energy resiliency in the event that conventional energy supplies are disrupted (e.g., natural disaster) and a reduction in fossil fuel consumption resulting in a smaller carbon footprint. Key risks include reservoir heterogeneity and a possible reduction in permeability through time due to scaling (mineral precipitation). Lastly, a map of thermal energy storage capacity for the Portland Basin yields a total of 43,400 GWh, suggesting tremendous potential for RTES in the Portland Metropolitan Area.

14 SOLAR ENERGY↗

Are All Post-starbursts Mergers? HST Reveals Hidden Disturbances in the Majority of PSBs

How do galaxies transform from blue, star-forming spirals to red, quiescent early-type galaxies? To answer this question, we analyzed a set of 26 gas-rich, shocked post-starburst galaxies with Hubble Space Telescope (HST) imaging in $B$, $I$, and $H$ bands and Sloan Digital Sky Survey (SDSS) $i$-band imaging of similar depth but lower resolution. We found that post-starbursts in our sample have intermediate morphologies between disk- and bulge dominated (Sérsic $n$ = ${1.7}_{-0.0}^{+0.3}$ ) and have red bulges, likely due to dust obscuration in the cores. A majority of galaxies in our sample are more morphologically disturbed than regular galaxies (88%, corresponding to >3$σ$ significance) when observed with HST, with asymmetry and Sérsic residual flux fraction being the most successful measures of disturbance. Most disturbances are undetected at the lower resolution of SDSS imaging. Although ~27% galaxies are clear merger remnants, we found that disturbances in another ~30% of the sample are internal, caused by small-scale perturbations or dust substructures rather than tidal features, and require high-resolution imaging to detect. We found 2.8$σ$ evidence that asymmetry features fade on timescales ~200 Myr, and may vanish entirely after ~750 Myr, so we do not rule out a possible merger origin of all post-starbursts given that asymmetric features may have already faded. This work highlights the importance of small-scale disturbances, detected only in high-resolution imaging, in understanding structural evolution of transitioning galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗

The CO Emission in the Taffy Galaxies (UGC 12914/15) at 60 pc Resolution. I. The Battle for Star Formation in the Turbulent Taffy Bridge

We present Atacama Large Millimeter/submillimeter Array observations at a spatial resolution of $0^{"}_{.}2$ (60 pc) of CO emission from the Taffy galaxies (UGC 12914/5). The observations are compared with narrowband Paα, mid-IR, radio continuum and X-ray imaging, plus optical spectroscopy. The galaxies have undergone a recent head-on collision, creating a massive gaseous bridge that is known to be highly turbulent. The bridge contains a complex web of narrow molecular filaments and clumps. The majority of the filaments are devoid of star formation, and fall significantly below the Kennicutt–Schmidt relationship for normal galaxies, especially for the numerous regions undetected in Paα emission. Within the loosely connected filaments and clumps of gas we find regions of high velocity dispersion that appear gravitationally unbound for a wide range of likely values of X CO . Like the "Firecracker" region in the Antennae system, they would require extremely high external dynamical or thermal pressure to stop them dissipating rapidly on short crossing timescales of 2–5 Myr. We suggest that the clouds may be transient structures within a highly turbulent multiphase medium that is strongly suppressing star formation. Despite the overall turbulence in the system, stars seem to have formed in compact hotspots within a kiloparsec-sized extragalactic H ii region, where the molecular gas has a lower velocity dispersion than elsewhere, and shows evidence for a collision with an ionized gas cloud. Like the shocked gas in the Stephan's Quintet group, the conditions in the Taffy bridge shows how difficult it is to form stars within a turbulent, multiphase, gas.

79 ASTRONOMY AND ASTROPHYSICS↗

Information transfer and shared mental models for decision making

A study to determine how communication influences flight crew performance is presented. This analysis focuses on the content of communication, principally asking what an utterance does from a cognitive, problem solving viewpoint. Two questions are addressed in this study: how is language utilized to manage problems in the cockpit, and are there differences between two- and three-member crews in their communication and problem solving strategies?

Orasanu, Judith↗

Star formation activity in spiral galaxy disks and the properties of radio halos: Observational evidence for a direct dependence

In this article we address observationally the questions: how does star formation (SF) in the disks of galaxies lead to the creation of radio halos, and what minimum energy input into the interstellar medium (ISM) is needed to facilitate this? For the investigation we use a sample of five edge-on galaxies exhibiting radio continuum emmission in their halos and enhanced SF spread over large parts of their disks. In a detailed study of the two galaxies in our sample for which we have the best data, NGC 891 and NGC 4631, we show that the radio halos cut off abruptly at galactocentric radii smaller than those of the underlying thin radio disks. Our most important result is that the halo cutoffs are spatially coincident with the radii where the SF activity in the underlying disks drops sharply. The difference in radius of the emission distributions tracing ongoing SF in the disks (IRAS 50 micrometers, H alpha) versus that of the nonthermal radio continuum thin disks (tracing the distribution of cosmic-ray (CR) electrons) is typically a few kpc. This difference in extent is caused by CR diffusion. We have measured the CR diffusion coefficients in the thin disks of both NGC 891 and NGC 4631. For radial diffusion of CR electrons within the galactic disks the values are D(sub r) = 1.1-2.5 x 10 (exp 29) sq cm/s (NGC 4631) and D(sub r) = 1.2 x 10(exp 29) sq cm/s (NGC 891). For motions in the z-direction in areas within the thin disks where no outflows occur, we derive a firm upper limit of D(sub z) less than or equal to 0.2 x 10(exp 28) sq cm/s for NGC 891. The value for NGC 4631 is D(sub z = 1.4 x 10 (exp 28) sq cm/s. The other three galaxies in our sample, NGC 3044, NGC 4666, and NGC 5775 show (at the sensitivity of our data) less extended, more filamentary radio halos. Isolates spurs or filaments of nonthermal radio continuum emission in their halos are traced only above the most actively star-forming regions in the disks. This, in conjuction with the results obtained for NGC 891 and NGC 4631, suggests a direct connection between the shapes and radial extents of radio halos of normal galaxies and the level and the spatial distribution of the current SF in their disks. The existence of filamentary structures implies that expansion and convection of CR-heated plasma plays an important role even at low z-distances above the plane. Based on radio data we derive the disk-averaged mean energy input rates into the ISM due to supernova explosions per unit surface area in nine galaxies, including the ones in our sample. We find a clear trend in the sense that the galaxies with the highest mean energy input rates in the underlying disks have the most extended and pervasisve radio halos. Below a certain threshohld, outflows are inhibited. As a lower limit for this threshhold we derive an energy input rate of approximately 10 (exp -4) erg/s sq cm. The fact that radio halo emission is found only above the most luminous giant H 2 regions in late-type 'normal' galaxies (of type Sbc or later) indicates that only these are capable of initiating disk-halo interactions by locally exceeding the threshold. The distribution of the local outflows determines the overall shapes of the CR halos and leads to the observed filamentary structures.

Dahlem, Michael↗

Distributed problem solving by pilots and dispatchers

The study addressed the following question: Are flight planning problems solved differently by PILOTS and DISPATCHERS when they work alone versus when they work together? Aspect of their performance that were of interest include the following: Problem perception and definition; Problem solving strategies and information use; Options considered; Solution and rational; and errors.

Orasanu, Judith↗

A taxonomy of decision problems on the flight deck

Examining cases of real crews making decisions in full-mission simulators or through Aviation Safety Reporting System (ASRS) reports shows that there are many different types of decisions that crews must make. Features of the situation determine the type of decision that must be made. The paper identifies six types of decisions that require different types of cognitive work and are also subject to different types of error or failure. These different requirements, along with descriptions of effective crew strategies, can serve as a basis for developing training practices and for evaluating crews.

Orasanu, Judith M.↗

Efficient decision strategies on the flight deck

Both crew productivity and flight safety depend critically on efficient crew problem solving and decision making. But what constitutes efficient problem solving and decision making behavior? Previous work has focused on crew performance in the context of a specific problem type. The present study differs from these analyses in two respects. First, we describe how aircraft crews cope with different types of problems. And second, we attempt to discern characteristics of optimal task management behavior. For this reason, we contrasted the behavior of more effective and less effective crews. Underlying this approach is the assumption that crews whom commit few operational errors also demonstrate most efficient problem solving and decision making behavior.

Fischer, Ute↗

Geostatistical evaluation of satellite radar altimetry for high-resolution mapping of Lambert Glacier, Antarctica

The potential of satellite radar altimetry for high-resolution mapping of Antarctic ice streams is evaluated, using retracked and slope-corrected data from the Lambert Glacier and Amery Ice Shelf area, East Antarctica, acquired by Geosat during the Exact Repeat Mission (ERM), 1986-89. The map area includes lower Lambert Glacier north of 72.18 deg S, the southern Amery Ice Shelf, and the grounded inland ice sheet on both sides. The Geosat ERM altimetry is found to provide substantially more complete coverage than the 1978 Seasat altimetry, due to improved tracking. Variogram methods are used to estimate the noise levels in the data as a function of position throughout the map area. The spatial structure in the data is quantified by constructing experimental variograms using altimetry from the area of the grounding zone of Lambert Glacier, which is the area chiefly of interest in this topographically complex region. Kriging is employed to invert the along-track height measurements onto a fine-scale 3 km grid. The unsmoothed along-track Geosat ERM altimetry yields spatially continuous maps showing the main topographic features of lower Lambert Glacier, upper Amery Ice Shelf and the adjacent inland ice sheet. The probable position of the grounding line of Lambert Glacier is identified from a break in slope at the grounded ice/floating ice transition. The approximate standard error of the kriged map is inferred from the data noise levels.

Herzfeld, Ute C.↗

Geostatistical approaches to interpolation and classification of remote-sensing data from ice surfaces

Geostatistical methods for interpolation and extrapolation techniques are used in glaciological data analysis. The results of a program involving the mapping of the Antarctica from satellite radar altimeter data are discussed. A combination of high and low resolution techniques was applied in the analysis of the Bering Glacier (Alaska). The global positioning system (GPS) located video data collected from small aircraft and the ERS-1 synthetic aperture radar (SAR) images were used. From the perspective of SAR data analysis, the Bering Glacier surge was the opportunity to characterize the surface of fast flowing ice and the rapid changes in the surface roughness.

Herzfeld, Ute Christina↗

New results from mapping Antarctica at high resolution from radar altimeter data

The limits of the altimeter data evaluation were analyzed using geostatistical methods. It is often argued that satellite radar altimeter data over ice can not be used to map ice surfaces with a slope exceeding 0.5 deg. The maps presented, obtained from the Geosat satellite geodetic mission, concern the Antarctica north of 72.1 deg South. The grids constructed from other satellite observations facilitate the analysis of the changes in the Antarctic ice stream/ice shelf systems. The evaluation was applied to the Lambert Glacier/Amery Ice Shelf system.

Matassa, Michael↗