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At least 109 records · Page 6

Quantifying Negative Effects of Carbon-Binder Networks from Electrochemical Performance of Porous Li-Ion Electrodes

Porous Li-ion electrodes contain active particles, ion transporting electrolyte, and carbon-binder networks. While macrohomogeneous models are often used to predict electrode behavior, accurate predictions remain challenging, owing to the incomplete understanding of the critical role of carbon-binder networks and how they affect the electrochemical response. The present study systematically characterizes these effects in terms of effective properties by utilizing macrohomogeneous models to analyze the measured responses for electrodes with different carbon-binder content, electrode thickness, and porosity but with identical materials. We find that the impact of the carbon-binder network is more severe than previously thought. Even for low carbon-binder content (5 %wt. dry electrode), the presence of the network decreases the reaction area and increases the ion transport resistance, negatively impacting electrode performance. These effects scale with not just porosity or active material volume but also with carbon-binder content. The findings underscore the importance of connecting all effective properties to electrode specifications in a full factorial sense to transform the electrode design paradigm.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Review and Summary of Corrosion Behavior for Aluminum-Clad Spent Nuclear Fuel in Dry Storage

A description of the corrosion behavior of aluminum alloys used for cladding on aluminum-based, aluminum-clad nuclear fuel used in research reactors under potential dry storage conditions has been compiled. An evaluation is made of potential additional corrosion with water postulated to not be removed during drying. The relative humidity (RH) produced by typical dryness criteria for industrial spent nuclear fuel drying is expected to be low, particularly at high temperatures (17% RH at 20°C and lower at higher temperatures). Existing corrosion data suggests that negligible vapor-phase corrosion of aluminum is expected at such low humidity, even for nominally bare aluminum surfaces. That is, the predicted relative humidity from free water (e.g., 17% RH) is below the “critical” relative humidity (~40% RH at room temperature), below which no significant corrosion is observed for bare aluminum. Furthermore, reported room-temperature corrosion rates are very low even under saturated (100% RH) water vapor. Existing results showing significant vapor-phase corrosion corresponded specifically to conditions of high temper ed with high relative humidity. A relatively large reservoir of (chemically bound) water exists in the aluminum (oxy)hydroxide films on the SNF cladding surface. The estimated total could saturate the gas even at relatively high temperature if fully released; however, its release as molecular water is expected to only be plausible if the temperature during storage exceeds both the drying temperature and the threshold for thermal decomposition of the trihydroxides (~220°C). Therefore, the combination of high temperature and high relative humidity that could drive significant corrosion is considered implausible during sealed dry storage following an appropriate drying process, to include >220°C drying for canisters that may approach or exceed this temperature during storage. Vapor-phase testing of aluminum samples with an adherent (oxy)hydroxide layer, prepared in liquid water to resemble those on actual aluminum-clad spent nuclear fuel (ASNF), did not observe evidence of additional corrosion even at combined high-temperature (up to 180°C) and high-humidity (up to 100% RH) conditions. Instead, small net mass losses were observed for most specimens and attributed to dehydration of the samples, which had been air-dried only prior to testing. ASNF being moved to dry storage is expected to have an existing (oxy)hydroxide film, suggesting that the cladding will be less prone to additional corrosion than bare aluminum metal. If significant corrosion did occur during sealed storage, the overall extent and impact is expected to be small. Corrosion post-closure of a canister would not alter the total amount of hydrogen in the canister, so it would have no effect on the maximum H 2 release already assessed in existing bounding calculations. In addition, the total amount of water in a 25-µm dense bayerite film would consume a only ~8 µm additional aluminum metal on average, if fully consumed by oxidizing aluminum metal to Al 2 O 3 . These conclusions are consistent with ASNF-in-canister simulations to date, which included a reaction pathway for corrosion using kinetics from previous literature and believed to be conservative and predicted very low rates of corrosion.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Reinforcement Learning Control for Enhancing Marine Hydrokinetic Turbine Energy Generation

This paper proposes a reinforcement learning-based method to maximize power generation for a direct-drive marine hydrokinetic turbine. A high levelized cost of energy (LCOE) is preventative in the widespread adoption of many marine energy conversion technologies. A straightforward way to reduce LCOE is to increase conversion efficiency and ensure maximum energy generation. The proposed method utilizes a damping control methodology, varying applied generator torque via a linear relationship between the applied damping coefficient and rotor speed. A state-action-reward-state-action (SARSA) algorithm has been used to learn the optimal control action for a given flow velocity. The proposed SARSA methodology uses Gaussian radial basis functions to create a three-dimensional surface to estimate the relationship between damping coefficient, incoming flow velocity, and coefficient of power (C p ). Here, the SARSA algorithm was compared against a baseline optimal tip speed ratio controller over a year-long flow velocity case profile while considering the effects of biofouling on the turbine system, where the proposed RL method generated 0.92% more energy than the baseline.

Damp↗

Accounting for Training Data Error in Machine Learning Applied to Earth Observations

Remote sensing, or Earth Observation (EO), is increasingly used to understand Earth system dynamics and create continuous and categorical maps of biophysical properties and land cover, especially based on recent advances in machine learning (ML). ML models typically require large, spatially explicit training datasets to make accurate predictions. Training data (TD) are typically generated by digitizing polygons on high spatial-resolution imagery, by collecting in situ data, or by using pre-existing datasets. TD are often assumed to accurately represent the truth, but in practice almost always have error, stemming from (1) sample design, and (2) sample collection errors. The latter is particularly relevant for image-interpreted TD, an increasingly commonly used method due to its practicality and the increasing training sample size requirements of modern ML algorithms. TD errors can cause substantial errors in the maps created using ML algorithms, which may impact map use and interpretation. Despite these potential errors and their real-world consequences for map-based decisions, TD error is often not accounted for or reported in EO research. Here we review the current practices for collecting and handling TD. We identify the sources of TD error, and illustrate their impacts using several case studies representing different EO applications (infrastructure mapping, global surface flux estimates, and agricultural monitoring), and provide guidelines for minimizing and accounting for TD errors. To harmonize terminology, we distinguish TD from three other classes of data that should be used to create and assess ML models: training reference data, used to assess the quality of TD during data generation; validation data, used to iteratively improve models; and map reference data, used only for final accuracy assessment. We focus primarily on TD, but our advice is generally applicable to all four classes, and we ground our review in established best practices for map accuracy assessment literature. EO researchers should start by determining the tolerable levels of map error and appropriate error metrics. Next, TD error should be minimized during sample design by choosing a representative spatio-temporal collection strategy, by using spatially and temporally relevant imagery and ancillary data sources during TD creation, and by selecting a set of legend definitions supported by the data. Furthermore, TD error can be minimized during the collection of individual samples by using consensus-based collection strategies, by directly comparing interpreted training observations against expert-generated training reference data to derive TD error metrics, and by providing image interpreters with thorough application-specific training. We strongly advise that TD error is incorporated in model outputs, either directly in bias and variance estimates or, at a minimum, by documenting the sources and implications of error. TD should be fully documented and made available via an open TD repository, allowing others to replicate and assess its use. To guide researchers in this process, we propose three tiers of TD error accounting standards. Finally, we advise researchers to clearly communicate the magnitude and impacts of TD error on map outputs, with specific consideration given to the likely map audience.

58 GEOSCIENCES↗

Peeking Between the Pulses: The Far-UV Spectrum of the Previously Unseen White Dwarf in AR Scorpii

The compact object in the interacting binary AR Sco has widely been presumed to be a rapidly rotating, magnetized white dwarf (WD), but it has never been detected directly. Isolating its spectrum has proven difficult because the spin-down of the WD generates pulsed synchrotron radiation that far outshines the WD's photosphere. As a result, a previous study of AR Sco was unable to detect the WD in the averaged far-ultraviolet spectrum from a Hubble Space Telescope (HST) observation. In an effort to unveil the WD's spectrum, we reanalyze these HST observations by calculating the average spectrum in the troughs between synchrotron pulses. We identify weak spectral features from the previously unseen WD and estimate its surface temperature to be 11,500 ± 500 K. Additionally, during the synchrotron pulses, we detect broad Lyα absorption consistent with hot WD spectral models. We infer the presence of a pair of hotspots, with temperatures between 23,000 and 28,000 K, near the magnetic poles of the WD. As the WD is not expected to be accreting from its companion, we describe two possible mechanisms for heating the magnetic poles. Here, the Lyα absorption of the hotspots appears relatively undistorted by Zeeman splitting, constraining the WD's field strength to be ≲100 MG, but the data are insufficient to search for the subtle Zeeman splits expected at lower field strengths.

79 ASTRONOMY AND ASTROPHYSICS↗

Dependence of the Ratio of Total to Visible Mass on Observable Properties of Sloan Digital Sky Survey MaNGA Galaxies

Abstract Using spectroscopic observations from the Sloan Digital Sky Survey Mapping Nearby Galaxies at Apache Point Observatory Data Release 15, we study the relationships between the ratio of total to visible mass and various parameters characterizing the evolution and environment of the galaxies in this survey. Measuring the rotation curve with the relative velocities of the H α emission line across a galaxy’s surface, we estimate each galaxy’s total mass. We develop a statistical model to describe the observed distribution in the ratio of total to visible mass, from which we extract the most probable value of this mass ratio for a given sample of galaxies. We present the relationships between the ratio of total to visible mass and several characteristics describing galactic evolution, such as luminosity, gas-phase metallicity, distance to the nearest neighbor, and position on the color–magnitude diagram. We find that faint galaxies with low metallicities, typically in the blue cloud, have the highest ratios of total to visible mass. This mass ratio is significantly reduced when we include the H i mass in the total visible mass, implying that feedback mechanisms are not as strong in low-mass galaxies as previously thought. Those galaxies that exhibit the second-highest ratios of total to visible mass are the brightest with high metallicities, typically members of the red sequence or green valley. Active galactic nucleus activity is likely both the quenching mechanism and the feedback that drives the mass ratio higher in these massive galaxies. Finally, we introduce a parameterization that predicts a galaxy’s ratio of total to visible mass based only on its photometry and luminosity.

79 ASTRONOMY AND ASTROPHYSICS↗

The Global Methane Budget 2000–2017

Understanding and quantifying the global methane (CH 4 ) budget is important for assessing realistic pathways to mitigate climate change. Atmospheric emissions and concentrations of CH 4 are continuing to increase, making CH 4 the second most important human-influenced greenhouse gas in terms of climate forcing, after carbon dioxide (CO 2 ). Assessing the relative importance of CH 4 in comparison to CO 2 is complicated by its shorter atmospheric lifetime, stronger warming potential, and atmospheric growth rate variations over the past decade, the causes of which are still debated. Two major difficulties in reducing uncertainties arise from the variety of geographically overlapping CH 4 sources and from the destruction of CH 4 by short-lived hydroxyl radicals (OH). To address these difficulties, we have established a consortium of multi-disciplinary scientists under the umbrella of the Global Carbon Project to synthesize and stimulate new research aimed at improving and regularly updating the global methane budget. Following Saunois et al. (2016), we present here the second version of the living review paper dedicated to the decadal methane budget, integrating results of top-down studies (atmospheric observations within an atmospheric inverse-modelling framework) and bottom-up estimates (including process-based models for estimating land surface emissions and atmospheric chemistry, inventories of anthropogenic emissions, and data-driven extrapolations).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Examining the Impacts of Great Lakes Temperature Perturbations on Simulated Precipitation in the Northeastern United States

Most inland water bodies are not resolved by general circulation models, requiring that lake surface temperatures be estimated. Given the large spatial and temporal variability of the surface temperatures of the North American Great Lakes, such estimations can introduce errors when used as lower boundary conditions for dynamical downscaling. Lake surface temperatures (LSTs) influence moisture and heat fluxes, thus impacting precipitation within the immediate region and potentially in regions downwind of the lakes. For this study, the Advanced Research version of the Weather Research and Forecasting Model (WRF-ARW) was used to simulate precipitation over the six New England states during a 5-yr historical period. The model simulation was repeated with perturbed LSTs, ranging from 10°C below to 10°C above baseline values obtained from reanalysis data, to determine whether the inclusion of erroneous LST values has an impact on simulated precipitation and synoptic-scale features. Results show that simulated precipitation in New England is statistically correlated with LST perturbations, but this region falls on a wet–dry line of a larger bimodal distribution. Wetter conditions occur to the north and drier conditions occur to the south with increasing LSTs, particularly during the warm season. Additionally, the precipitation differences coincide with large-scale anomalous temperature, pressure, and moisture patterns. Care must therefore be taken to ensure reasonably accurate Great Lakes surface temperatures when simulating precipitation, especially in southeastern Canada, Maine, and the mid-Atlantic region.

54 ENVIRONMENTAL SCIENCES↗

Stellar Mass and Stellar Mass-to-light Ratio–Color Relations for Low Surface Brightness Galaxies

We estimate the stellar mass for a sample of low surface brightness galaxies (LSBGs) by fitting their multiband spectral energy distributions (SEDs) to the stellar population synthesis model. The derived stellar masses (log M {sub *}/M {sub ⊙}) span from 7.1 to 11.1, with a mean of log M {sub *}/M {sub ⊙} = 8.5, which is lower than that for normal galaxies. The stellar mass-to-light ratio (γ*) in each band varies little with the absolute magnitude but increases with higher M {sub *}. This trend of γ* with M {sub *} is even stronger in bluer bands. In addition, the γ* for our LSBGs slightly declines from the r band to the longer-wavelength bands. The log γ{sub ∗}{sup j} (j = g, r, i, and z) have relatively tight relations with optical colors of g − r and g − i. Compared with several representative γ*–color relations (MLCRs) from the literature, our MLCRs based on LSBG data are consistently among those literature MLCRs previously defined on diverse galaxy samples, and the existing minor differences between the MLCRs are caused by the differences in the SED model ingredients (including initial mass function, star formation history, and stellar population model), line fitting techniques, galaxy samples, and photometric zero-point, rather than the galaxy surface brightness itself, which distinguishes LSBGs from high surface brightness galaxies. Our LSBGs would be very likely to follow those representative MLCRs previously defined in diverse galaxy populations, if those main ingredients were taken into account.

79 ASTRONOMY AND ASTROPHYSICS↗

TP099-CT-800DR Comparison Between SIRZ-2 and Surface Fit Method ($ρ_{e},Ζ_{e}$) Estimation

The primary objective of this test plan is to acquire dual-energy computed tomography (CT) data of 33 well-known specimens using the Leidos Reveal CT-80DR+ baggage scanner housed at LLNL (hereafter referred to as CT-80DR). These data sets will allow us to compare, for each specimen, the accuracy and precision of electron density ($ρ_{e}$) and effective atomic number ($Z_{e}$) estimates obtained from two different algorithmic methods— from TSL’s surface fits and from LLNL’s SIRZ-2 decomposition. A secondary objective is to determine how often it is necessary to acquire CT-80DR spectral response information.

42 ENGINEERING↗

Algebraic expressions for estimating the impact depths of a surface barrier over a homogeneous soil

Engineered surface barriers are used to isolate subsurface contaminants for effective long-term containment of municipal solid waste, other nonhazardous solid and liquid waste, hazardous and toxic wastes, and radioactive waste. The impact depths of a surface barrier are affected by the pre-barrier recharge rate and the properties of the soil beneath the barrier. In this paper, the pore-size-specific (PSS) water velocity is defined and an algebraic expression of PSS velocity is derived based on the stream tube concept and the Brooks and Corey hydraulic retention model. Algebraic expressions are developed to estimate drainage velocities and barrier impact depths after the emplacement of a surface barrier. Four impact depth terms are used to convey the protective effect: drainage front, average drainage, the location with 50% impact, and drainage tail. The drainage front depth is the deepest point at which the barrier has a detectable impact at a specific time (also called the near zero-impact depth). The average-impact depth is the depth at which average drainage occurs. At the 50% impact depth, the water flux rate is reduced by half because of the surface barrier. Lastly, the drainage tail depth (also called the full-impact depth) is the deepest depth at which the water conditions above it are in equilibrium with the barrier. The algebraic expressions show that the average-impact depth is no more than 1/3 of near zero-impact depth, while the 50% impact depth is slightly larger than 1/2 of the near zero-impact depth. The full-impact depth, depending on the final recharge rate from the surface barrier, is usually much smaller than the other impact depths. These differences lead to a very large transition zone beneath a surface barrier. Numerical simulations were conducted to replicate the same conditions. The numerical results corroborated the analytical models by predicting very similar water content profiles and near zero-, average-, 50%, and full-impact depths. The algebraic expressions provided in this paper are useful for quickly identifying sites where the depth of the existing contaminants could be beyond the protection of a surface barrier.

54 ENVIRONMENTAL SCIENCES↗

Joint Bayesian Inference for Near-Surface Explosion Yield and Height-of-Burst

Forensic capabilities to understand chemical and nuclear explosions are greatly aided by an accurate estimate of explosive yield with uncertainty. The relationship between explosive size and geophysical observations of seismic, acoustic, and optical waves can be exploited to provide an estimate of yield. Any near-surface yield estimate is complicated by the surface interaction, so an estimate for the explosion height-of-burst is necessarily included in the relationship. Additionally, the relationship dictates a trade-off between estimates of yield and height-of-burst. Fortunately, the surface interaction for each type of observation is different, which breaks the trade-off, and the inclusion of height-of-burst with multiple data types improves yield estimation. We define simple parametric forward models to relate seismoäcoustoöptic observations from a data set of known explosive yields and height-of-bursts. The parameters of the models and a prediction for the yield and height-of-burst of a new event can then be estimated given new observations via Bayesian inference. We report posterior distribution estimates of the parametric models using a Markov chain Monte Carlo sampling technique. These models are then used to predict the yield and height-of-burst of SUGAR, a historical near-surface nuclear explosion, using its reported historical observations. The reported yield of 1.2 ktonne Trinitrotoluene (TNT)-equivalent (Department of Energy, 2015) is within the estimated posterior. Yield uncertainty can be estimated from the spread of the posterior, which is between 0.9 and 2.1 ktonne TNT-equivalent. The posterior for height-of-burst has a wider range between 10 m below and 8 m above ground that includes the true height-of-burst of 1 m.

58 GEOSCIENCES↗

Effect of Coaxial Electrode Geometry on the Electric Field Enhancement Factor for a High Voltage Vacuum Gap

We present an experimental analysis of the change in the electric field enhancement factor with varying gap size and penetration depth (P.D) of cathode into anode for a coaxial vacuum gap, diagnosed using Fowler–Nordheim analysis and optical imaging via scanning electron microscope (SEM) and time integrated Digital single lens reflex camera (DSLR). Data were collected on the Coaxial Gap Breakdown Machine (240 A, 25 kV, 150 ns, 0.1 Hz). Experiments using five different gap sizes at nine different P.Ds are compared over runs comprising 50 shots for each case. The results show a strong link between enhancement factor and gap size, with P.D and surface topology. For large gap sizes, 150, 330, and 700 μm, the average enhancement factor value increases with increasing P.D. For smaller gap sizes, 50 and 100 μm, the average enhancement factor decreases with P.D. SEM imaging before and after plasma formation for each gap size allows for quantifying surface finish, microprotrusion growth, average blast diameter, and an estimation of the surface area breakdowns occupy. Time integrated DSLR imaging analysis of the gap at each shot allows for a determination of the distribution of breakdowns about the circumference of the gap for each case tested. Here, the Fowler–Nordheim analysis allows for a quantitative analysis of the surface roughness of all gap sizes tested. Results show that for large gap sizes, the gap geometry and increasing area of breakdown is the main cause for increasing average enhancement factor. For small gap sizes, the dominant driving factor for small average enhancement factors—that subsequently decrease with P.D—is significant changes in surface topology due to an increased number of breakdowns.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

High-Resolution Near-Surface Imaging at the Basin Scale Using Dark Fiber and Distributed Acoustic Sensing: Toward Site Effect Estimation in Urban Environments

Near-surface seismic structure, particularly the shear wave velocity (V s ), can strongly affect local site response, and should be accurately estimated for ground motion prediction during seismic hazard assessment. The Imperial Valley (California), occupying the southern end of the Salton Trough, is a seismically active basin with thick surficial lacustrine sedimentary deposits. In this study, we utilize ambient noise records and local earthquake events for high-resolution near-surface characterization and site effect estimation with an unlit fiber-optic telecommunication infrastructure (dark fiber) in Imperial Valley by using the distributed acoustic sensing (DAS) technique. We apply ambient noise interferometry to retrieve coherent surface waves from DAS records, and evaluate performances of three different surface wave methods on DAS ambient noise dispersion imaging. We develop a quality control workflow to improve the dispersion measurement of noisy portions of the DAS data set by using a data selection strategy. Using the joint inversion of both the fundamental mode and higher overtones of Rayleigh waves, a high resolution two-dimensional (2D) V s structure down to 70 m depth is obtained. We successfully achieve an improved V s 30 (the time-averaged shear-wave velocity in the top 30 m) model with higher spatial-resolution and reliability compared to the existing community model for the area. We also explore the potential for utilizing DAS earthquake events for site amplification estimation. The preliminary results reveal a clear anti-correlation between the approximated site response and the V s 30 profile. In conclusion, our results indicate the potential utility of DAS deployed on dark fiber for near-surface characterization in appropriate contexts.

58 GEOSCIENCES↗