Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Structure elucidation”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

From Remotely-Sensed SIF to Ecosystem Structure, Function, and Service: Part I - Harnessing Theory

Solar-induced chlorophyll fluorescence (SIF) is a remotely sensed optical signal emitted during the light reactions of photosynthesis. The past two decades have witnessed an explosion in availability of SIF data at increasingly higher spatial and temporal resolutions, sparking applications in diverse research sectors (e.g., ecology, agriculture, hydrology, climate, and socioeconomics). These applications must deal with complexities caused by tremendous variations in scale and the impacts of interacting and superimposing plant physiology and three-dimensional vegetation structure on the emission and scattering of SIF. At present, these complexities have not been overcome. To advance future research, the two companion reviews aim to (1) develop an analytical framework for inferring terrestrial vegetation structures and function that are tied to SIF emission, (2) synthesize progress and identify challenges in SIF research via the lens of multi-sector applications, and (3) map out actionable solutions to tackle these challenges and offer our vision for research priorities over the next 5–10 years based on the proposed analytical framework. This paper is the first of the two companion reviews, and theory oriented. It introduces a theoretically rigorous yet practically applicable analytical framework. Guided by this framework, we offer theoretical perspectives on three overarching questions: (1) The forward (mechanism) question—How are the dynamics of SIF affected by terrestrial ecosystem structure and function? (2) The inference question: What aspects of terrestrial ecosystem structure, function, and service can be reliably inferred from remotely sensed SIF and how? (3) The innovation question: What innovations are needed to realize the full potential of SIF remote sensing for real-world applications under climate change? The analytical framework elucidates that process complexity must be appreciated in inferring ecosystem structure and function from the observed SIF; this framework can serve as a diagnosis and inference tool for versatile applications across diverse spatial and temporal scales.

carbon fluxes↗

Modeling human target acquisition in ground-to-air weapon systems

The problems associated with formulating and validating mathematical models for describing and predicting human target acquisition response are considered. In particular, the extension of the human observer model to include the acquisition phase as well as the tracking segment is presented. Relationship of the Observer model structure to the more complex Standard Optimal Control model formulation and to the simpler Transfer Function/Noise representation is discussed. Problems pertinent to structural identifiability and the form of the parameterization are elucidated. A systematic approach toward the identification of the observer acquisition model parameters from ensemble tracking error data is presented.

Phatak, A. V.↗

Comparison of the contact stress and friction behavior of SiC and ZrO2 materials

Studies were performed to further elucidate the friction and contact-stress characteristics of structural ceramic materials. New data for fully stabilized and partially stabilized zirconia ceramics are compared with prior test results for sintered SiC. The comparison provides further evidence that the high temperature friction characteristics of sintered SiC are strongly influenced by the presence of a viscous surface layer. The results also show that a ceramic material with lower coefficient of friction and higher fracture toughness has increased resistance to strength-reducing surface damage due to contact stress.

Lindberg, L. J.↗

Investigation of an excited jet diffusion flame at elevated pressure

Experiments are carried out for studying the relationship between flow structure, flow excitation, and the reaction process in the near field of a low-speed coflowing jet diffusion flame. The effect of axial forcing and increasing pressure on the structure and controllability of the flame is studied to elucidate some of the underlying control mechanisms. The experiments are conducted in a variable-pressure flow facility permitting the study of reacting flows in the 10-1000 kPa (0.1-10 atm) pressure range. The flame is excited by a small-amplitude periodic fluctuation added to the central fuel jet exit velocity. Among the varied excitation frequencies employed, a narrow band is found in which several of the flow instabilities seem to be in coincidence, causing periodic breakup of the flame into a series of distinct eddies. This is called the strongly-coupled state. Effects of excitation frequencies at and above the strongly-coupled range are presented.

Strawa, Anthony W.↗

Acoustical properties of highly porous fibrous materials

Highly porous, fibrous bulk sound absorbing materials are studied with a view toward understanding their acoustical properties and performance in a wide variety of applications including liners of flow ducts. The basis and criteria for decoupling of acoustic waves in the pores of the frame and compressional waves in the frame structure are established. The equations of motion are recast in a form that elucidates the coupling mechanisms. The normal incidence surface impedance and absorption coefficient of two types of Kevlar 29 and an open celled foam material are studied. Experimental values and theoretical results are brought into agreement when the structure factor is selected to provide a fit to the experimental data. A parametric procedure for achieving that fit is established. Both a bulk material quality factor and a high frequency impedance level are required to characterize the real and imaginary part of the surface impedance and absorption coefficient. A derivation of the concepts of equivalent density and dynamic resistance is presented.

Lambert, R. F.↗

A static model of chromospheric heating in solar flares

The response of the solar chromosphere to flare processes, namely nonthermal electrons, thermal conduction, and coronal pressure, is modeled. Finite difference methods employing linearization and iteration are used in obtaining simultaneous solutions to the equations of steady-state energy balance, hydrostatic equilibrium, radiative transfer, and atomic statistical equilibrium. The atmospheric response is assumed to be confined to one dimension by a strong vertical magnetic field. A solution is obtained to the radiative transfer equation for the most important optically thick transitions of hydrogen, magnesium, and calcium. The theoretical atmospheres discussed here are seen as elucidating the role of various physical processes in establishing the structure of flare chromospheres. At low coronal pressures, conduction is found to be more important than nonthermal electrons in establishing the position of the transition region. Only thermal conduction can adequately account for the chromospheric evaporation in compact flares. Of the mechanisms considered, only nonthermal electrons bring about significant heating below the flare transition region.

Ricchiazzi, P. J.↗

Composition-property correlations in NiTi-based shape memory alloys from the first principles

Development of shape memory alloys (SMA) has been traditionally accomplished by means of extensive empirical efforts, with a very limited support from phenomenological models and related tools. We present a theoretical framework based on the Hamiltonian formalism, which connects important thermodynamic properties directly to the relative energies (the eigenvalues of the Hamiltonian), computed from the first principles using density functional theory. The estimates based on this formalism allow to establish correlations between composition and physical properties, such as relative energies, phase transition temperatures, hysteresis, thermal expansion, and other thermodynamic information. Importantly, estimates and correlations not only provide a fast answer, but also elucidate underpinning of thermodynamic features in terms of the electronic structure. Using this framework, we consider phase transformations and correlations between the selected properties and composition in the NiTi-based ternary and multicomponent shape memory alloys. Our theoretical guidance facilitates design and development of future alloys.

shape memory alloys↗

Contribution of Spaceflight Environmental Factors to Vision Risks

The risk of visual impairment and elevated intracranial pressure as a result of low-earth orbit microgravity exposure has directed our attention and research efforts to the eye. While the alterations observed in astronauts returning from long duration missions include vision and neuroanatomical changes observed by non-invasive methods, other effects and subsequent tissue responses at the molecular and cellular level can only be studied by accessing the tissue itself. As a result of this need, several studies are currently taking place within the Human and Health Countermeasures Element (HHC) that use animal models for eye research. The rodent eye has many similarities to the human eye, and both rats and mice have historically been used as models of human eye disease, aiding in the identification of the disease genes, elucidation of mechanisms of disease, as well as in the assessment of therapeutic treatments. These studies attempt to answer two central questions in the etiology of possible vision alterations in the environment of space exploration missions. The first is: what effects and response mechanisms take place in the different eye structures at the cellular and molecular level? The second question is directed to elucidate the contribution of the various environmental stressors (radiation, nutrition, fluid shift) to these effects. Collaborative approaches with internal and external investigators have allowed performing these studies in a most cost-effective fashion, providing preliminary data and laying the bases for testing further hypotheses in future and specifically designed animal experiments. From a study centered on the radioadaptive response in mice, we have learned that the retina responds to low and high dose gamma radiation by elevating antioxidant-related genes at early time points (4hrs) and that this response returns to control levels after 1 day post-irradiation. We are expanding this research with another collaborative study that investigates the combined effects of radiation exposure and iron overload on sensitivity to radiation injury in rat eyes. All main eye structures will be analyzed in this study: retina, lens and cornea. A study in collaboration with the Space Human Factors and Habitability Element (SHFH) investigates the effects of lunar dust exposure on the rat cornea. It is anticipated that common underlying oxidative stress mechanisms of damage may be observed as a result of these three stressors: radiation, nutritional iron and lunar dust. The contribution of fluid shift is addressed by a study using rats subjected to hindlimb suspension. The hypothesis to be tested in this study is that the mechanical stress imparted by the pressure differential across the optic disc and lamina cribosa will impact oxygenation (therefore causing oxidative stress and hypoxia) and cell survival. This study also includes the assessment of two nutritional antioxidant countermeasures: epigallocatechin gallate (green tea) and resveratrol. Finally, as a result of two successful tissue sharing efforts, we are proceeding with the analysis of eye samples of mice aboard two shuttle missions: STS-133 and STS-135. Results from the STS-133 study are presented in an independent abstract. Briefly, the results show that spaceflight represents a source of environmental stress that directly translates into oxidative and cellular stress in the retina. Similar analysis is also planned for the cornea. These samples add large value to our current vision research as they provide data on the direct effects of low-earth orbit spaceflight on eye structures and physiology.

Zanello, Susana B.↗

Experiments and Models for Polymeric Microsphere Foams

The current project was performed under the direction of Dr. Byron Pipes as its lead investigator from January 2001 to August 2004. With the permission of the NASA, the project was transferred to Dr. Thein Kyu as the principle investigator for the period of September 2004 - June 2005. There were two major thrust areas in the original proposal; (1) experimental characterization and kinematics of foam structure formation and (2) determination of the mechanical, physical, and thermal properties, although these thrust areas were further sub- divided into 7 tasks. The present project has been directed primarily to elucidate kinematics of micro-foam formation (tasks 1 and 3) and to characterize micro-foam structures, since the control of the micro-structure of these foams is of paramount importance in determining their physical, mechanical and thermal properties. The first thrust area was accomplished in a timely manner; however, the second thrust area of foam properties (tasks 2,4-7) has yet to be completed because the area of kinematics of foam structure formation turned out to be extremely complex and thus consumed more time than what have been anticipated. As will be reported in what follows, the present studies have greatly enhances the in-depth understanding of mechanisms and kinematics of the micro-foam formation from solid powders. However, in order to implement all objectives of the second thrust areas regarding investigations of mechanical, physical, and thermal properties and establishment of the correlation of structure - properties of the foams, the project needs additional time and resources. The technical highlights of the accomplishment are summarized as follows. The present study represents a first approach to understanding the complexities that act together in the powder foaming process to achieve the successful inflation of polyimide microstructures. This type of study is novel as no prior work had dissected the fundamentals that govern the inflation process in this type of systems. The systematic approach to each of the different phenomena (i.e. morphological, diffusive, kinetic and dynamic) brings into context each of them in a way that allows separate understanding and analysis. Of the different phenomena studied, probably the one that gives a higher level of control over the inflation process has been shown to be the morphological aspects of the precursor particles. It is a major contribution of the present work to isolate and identify this phenomenon and highlight the features that with careful control during the synthesis of the precursor material can lead to a highly optimized and specialized final product (neat foam or microstructure). Some of these accomplishments have been presented in various national meetings and some of which are either published in refereed journals or still in various stages of publications. One of the presentations was selected for "Best of ANTEC 2004" Online Presentation Series of the Society of Plastics Engineers (SPE) (September 2004)

Pipes, R. Byrona↗

Space Shuttle Tail Service Mast Concept Verification

Design studies and analyses were performed to describe the loads and dynamics of the space shuttle tail service masts (TSMs). Of particular interest are the motion and interaction of the umbilical carrier plate, lanyard system, vacuum jacketed hoses, latches, links, and masthead. A development test rig was designed and fabricated to obtain experimental data. The test program is designed to (1) verify the theoretical dynamics calculations, (2) prove the soundness of design concepts, and (3) elucidate problem areas (if any) in the design of mechanisms and structural components. Design, fabrication, and initiation of TSM development testing at Kennedy Space Center are described.

Uda, R. T.↗

Study on solidification of immisible alloys (M-10)

Alloying of immiscible alloys under microgravity is of interest in metallurgical processes. Several experiments investigating the alloying of immiscible alloys, such as Al-In, Al-Bi, Zn-Bi, and Zn-Pb, were done in space. Homogeneous distribution of small L2 particles in the matrix, such as an emulsion structure, was expected in the space-solidifed alloys. However, the alloys demonstrated an extremely segregated structure. To date insufficient information was obtained to explain these unexpected results. Our experiment was proposed to clarify the solidification manner of immiscible alloys and to obtain fundamental information concerning structural control of the alloys. In space, density differences between the two liquids separated in immiscible regions can be neglected, so that no sedimentation of L(sub 2) phase will take place. When the growth of the alloys is interrupted and this status is frozen by an adequate rapid cooling procedure, it will provide much information concerning decomposing homogeneous liquid and the interaction between the monotectic growth front morphology and the distribution of L(sub 2) phase. It is anticipated that the results will be useful for elucidating the monotectic solidification manner and it will be instructive to explain the segregated structures obtained in the past space experiments.

Kamio, Akihiko↗

Temperatures and Composition in the Saturn System from Cassini CIRS

We summarize recent observations by the Composite Infrared Spectrometer of Saturn, its rings, Titan, and the icy satellites. Limb observations of Saturn show vertical oscillations of temperatures and zonal-wind shears in the equatorial region that may be related to a temporal oscillation similar to the terrestrial QBO and Jupiter's QQO. There is also evidence of subsidence at mid-northern latitudes driven by the equatorial activity. Nadir-viewing observations show compact warm spots in the troposphere and stratosphere at both (summer and winter) poles, likely associated with subsidence. Observations of Titan have defined better the characteristics of the northern winter polar vortex, with 190 m/s winds surrounding a cold atmosphere at 1 microbar. The very warm polar stratopause at 10 microbar and the enhanced abundances of organic compounds suggest subsidence within the vortex. Analysis of the zonal structure in temperature indicates that the stratospheric zonal winds rotate about an axis that is displaced approximately 4.1 deg from the IAU pole. Additional flybys, including a close one in March 2008, continue to characterize the endogenic activity in Enceladus s south polar region. Temperature maps of bright and dark terrains on Iapetus indicate that its ice is approximately stable to sublimation in the bright regions and highly unstable in the dark regions. Thermal mapping of Saturn s rings continues to constrain their composition, and observations at different solar phase angles, spacecraft elevations, solar elevations, and local hour angles have elucidated the effects of ring-particle shadowing and vertical motions on the thermal structure, and revealed the presence of small-scale structure associated with self-gravity wakes.

Flasar, F. Michael↗

A three-dimensional model of co-rotating streams in the solar wind. 2: Hydrodynamic streams

Theoretical aspects of corotating solar wind dynamics on a global scale are explored by means of numerical simulations executed with a nonlinear, inviscid, adiabatic, single-fluid, three-dimensional (3-D) hydrodynamic formulation. A simple, hypothetical 3-D stream structure is defined on a source surface located at 35 solar radius and carefully documents its evolution to 1 AU under the influence of solar rotation. By manipulating the structure of this prototype configuration at the source surface, it is possible to elucidate the factors most strongly affecting stream evolution: (1) the intrinsic correlations among density, temperature, and velocity existing near the source; (2) the amplitude of the stream; (3) the longitudinal breadth of the stream; (4) the latitudinal breadth of the stream; and (5) the heliographic latitude of the centroid of the stream.

Pizzo, V. J.↗

Fully nonlinear development of the most unstable goertler vortex in a three dimensional boundary layer

The nonlinear development is studied of the most unstable Gortler mode within a general 3-D boundary layer upon a suitably concave surface. The structure of this mode was first identified by Denier, Hall and Seddougui (1991) who demonstrated that the growth rate of this instability is O(G sup 3/5) where G is the Gortler number (taken to be large here), which is effectively a measure of the curvature of the surface. Previous researchers have described the fate of the most unstable mode within a 2-D boundary layer. Denier and Hall (1992) discussed the fully nonlinear development of the vortex in this case and showed that the nonlinearity causes a breakdown of the flow structure. The effect of crossflow and unsteadiness upon an infinitesimal unstable mode was elucidated by Bassom and Hall (1991). They demonstrated that crossflow tends to stabilize the most unstable Gortler mode, and for certain crossflow/frequency combinations the Gortler mode may be made neutrally stable. These vortex configurations naturally lend themselves to a weakly nonlinear stability analysis; work which is described in a previous article by the present author. Here we extend the ideas of Denier and Hall (1992) to the three-dimensional boundary layer problem. It is found that the numerical solution of the fully nonlinear equations is best conducted using a method which is essentially an adaption of that utilized by Denier and Hall (1992). The influence of crossflow and unsteadiness upon the breakdown of the flow is described.

Otto, S. R.↗

Thermal Stability of M x O y Doped Zirconia Aerogels (M = Y, Yb, Gd, Ce, Ca) Studied Through 1200°C

The high porosities and low densities of ceramic aerogels offer outstanding insulative performance in applications where weight is a critical factor. The high surface area-to-volume ratios and specific surface areas provide extremely low thermal conductivity, but also contribute to rapid densification of the pore structure at elevated temperatures. This densification diminishes their favorable properties and inhibits use of aerogels in high temperature applications. This work contributes to a design framework for thermally stable aerogels via the study of dopant chemistry (Y, Yb, Gd, Ca, Ce) in zirconia aerogels. The structural evolution was studied to 1200°C using nitrogen physisorption, scanning electron microscopy, and x-ray diffraction. The role of dopant identity and concentration in thermal stability was elucidated. In context of the design framework, dopant chemistry is an aggregate for many closely related material properties, each of which may contribute to aerogel structural evolution. To develop a truly predictive design framework for ceramic-based aerogels, systematic and comprehensive evaluation of thermodynamic and kinetic properties must be performed in conjunction with studies on structural evolution.

aerogel↗

Understanding thermal stability in doped zirconia aerogels for high temperature applications

The high porosities and low densities of ceramic aerogels offer outstanding insulative performance in applications where weight is a critical factor. The high surface-to-volume ratios and specific surface areas provide extremely low thermal conductivity, but also contribute to rapid densification of the pore structure at elevated temperatures. This densification diminishes their favorable properties and inhibits use of aerogels in high temperature applications. The purpose of this work is the establishment of a design framework for thermally stable, highly porous materials. Here we will review our recent studies on the effects of synthetic parameters and dopant chemistry on the evolution of zirconia-based aerogels. The structural evolution was studied to 1200 °C using nitrogen physisorption, scanning and transmission electron microscopy, and x-ray diffraction. The role of dopant identity and concentration in thermal stability was elucidated. In context of the design framework, dopant chemistry is an aggregate for many closely related material properties, each of which may contribute to aerogel structural evolution. To develop a truly predictive design framework for ceramic-based aerogels, systematic and comprehensive evaluation of thermodynamic and kinetic properties must be performed in conjunction with studies on structural evolution.

aerogel↗

Origin and development of plasma membrane derived invaginations in Vinca rosea l.

The occurrence, morphology, and possible ontogeny of plasma-membrane-related structures are described which can develop into invaginations or intravacuolar formations. An underlying study of meristematic tissues from the shoot of Vinca rosea supports the interpretation that endocytosis does occur in plant cells and that it is appropriate to refer to these structures as endocytoses. The function of these invaginations or their content remains to be elucidated.

Mahlberg, P.↗

Experiments on confined turbulent jets in cross flow.

Results are reported of experiments on the effects of an opposite wall on the characteristics of turbulent jets injected into a cross flow, for unheated and heated jets. Longitudinal and transverse distributions of velocity and temperature are presented for single and multiple circular jets, and trajectories are presented for two-domensional jets. The opposite wall has relatively little effect on a single jet unless the ratio of jet to cross flow momentum flux is large enough for the jet to impinge on the opposite wall. For a row of jets aligned perpendicularly to the cross flow, the opposite wall exerts progressively larger influence as the spacing between jets decreases. Much of the effect of jet and wall proximity can be understood by considering the interaction of the vortex flow which is the major feature of the structure of a single jet in a cross flow. Smoke photographs are shown to elucidate some of the interaction patterns.

Kamotani, Y.↗