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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Investigation of competitive sorption and plasticization of hyperaged CANAL ladder polymers for acid gas purification

Identifying membrane materials that have exceptional separation performance and stability to complex CO 2 -containing mixtures is a pressing topic in separation science. In this work, the membrane separation performance for a recently discovered class of contorted polymers synthesized via catalytic arene-norbornene annulation (CANAL) polymerization is presented. These CANAL polymers achieve high CO 2 /CH 4 selectivity of 68 after physical aging (up to ∼1 year), which significantly augments the size-sieving capabilities of the membranes. Binary CO 2 /CH 4 and ternary H 2 S/CO 2 /CH 4 testing result in a 41 % and 50 % enhancement in selectivities, respectively, for hyperaged (∼1 year) contorted CANAL polymers, highlighting their size-sieving capabilities. The remarkably high CO 2 /CH 4 mixed-gas and combined acid gas (CAG, (CO 2 +H 2 S)/CH 4 ) selectivities of 88 and 95, respectively, for CANAL-Me-S 5 F in particular surpass both the 2018 CO 2 /CH 4 mixed-gas and CAG upper bounds. Performance stability was also investigated for high concentrations of CO 2 , revealing a reduction in CO 2 /CH 4 mixed-gas selectivity without compromising CO 2 permeability, suggesting strong sorption of CO 2 but minimal plasticization effects for short testing periods. In addition, time-dependent plasticization shows negligible effects on CO 2 /CH 4 mixed-gas selectivity despite an increase in CO 2 permeability when exposed to high concentrations of plasticizing CO 2 over an extended period of 170 h. This study provides valuable insights into hyperaged CANAL polymers and their performance in practical industrial processes.

03 NATURAL GAS↗
DOE OSTI2025

Liquid Sorption-Enhanced Haber–Bosch Process

The use of a liquid sorbent in a traditional Haber-Bosch process enables significant improvements in energy efficiency and potential cost savings for arguably the most important chemical process on the planet. The approach presented in this report employs an incompressible liquid sorbent that absorbs and releases ammonia (NH 3 ) under specific conditions. To achieve this, we investigate reactions of ammonia and pure phosphoric acid (H 3 PO 4 , PA), which rapidly neutralize to form an equilibrated solution of monoammonium phosphate (MAP) and diammonium phosphate (DAP) that functions as a reversible and regenerable sorbent. Through intimate contact of the gas-phase Haber-Bosch reaction mixture with this liquid absorbent, complete equilibrium uptake may be achieved in an appropriately sized separator, and facile separation occurs through the use of independent liquid and gas phases. Following depressurization and release of the ammonia product, only the incompressible fluid needs to be repressurized and returned to the reactor. This study documents proof-of-concept absorption and desorption experiments carried out in 75 mL batch reactors, predominantly charged with precise MAP and DAP mixtures that equilibrate at process-relevant temperatures and pressures. We then assemble the first thermodynamic relationships that underlie this advantaged separation strategy, validated by reactive force field (ReaxFF) interatomic potential simulations, and benchmarked with traditional separation routes via process modeling and technoeconomic analysis. The scale of energy consumption in the century-old Haber-Bosch process is massive, and the elegant liquid sorption approach reported here offers opportunities to enhance its energy efficiency for the next frontier of ammonia synthesis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Final Report: Process Intensification of Hydrogen Production through Sorption-Enhanced Gasification of Biomass

The University of Utah, in partnership with Idaho National Laboratory (INL), evaluated Sorption-Enhanced Gasification (SEG) as a transformative pathway for producing hydrogen with the potential for negative CO 2 emissions. SEG integrates gasification, water-gas shift, and in-situ carbon capture within a dual fluidized bed reactor to enable efficient clean hydrogen production. Key challenges related to biomass variability and process complexity were addressed through feedstock engineering, reaction optimization, and process validation. A co-pelletized biomass–limestone feedstock was developed to simplify feeding and introduction of makeup limestone. Kinetic and sorbent studies identified optimal operating conditions and confirmed the suitability of low-cost limestone, while catalysts were developed to reduce tar formation. Reactor modeling and techno-economic analysis indicated that SEG can achieve competitive hydrogen production costs, particularly when combined with carbon incentives, supporting its potential for scale-up and carbon-negative operation.

08 HYDROGEN↗
NASA NTRS1967

A study of a sorption process.

Sorption process for determining sticking probability of molecules on surface of sorbents, diffusion coefficient of molecules through sorbents and adsorption isotherms

DIFFUSION COEFFICIENT↗
NASA NTRS2002

Evaluation of hydride compressor elements for the Planck sorption cryocooler

Hydrogen sorption crycoolers are being developed for the European Space Agency Planck mission to provide nominal 19 K cooling to instruments for measuring the temperature anisotropy of the cosmic microwave background with extreme sensitivity and resolution.

sorption cryocoolers metal hydides gas gap heat sw↗
NASA NTRS2000

Performance prediction of the Planck sorption cooler and initial validation

Two continuous operation 18 K/20 K sorption coolers are being developed by JPL for the ESA Planck mission to provide about 200 mW of cooling at 18 K and 1.4 W at 20 K. A detailed performance prediction model has been developed to support the design process and to evaluate the results of a prototype testing.

sorption cryocoolers thermal model analyses metal ↗
NASA NTRS1997

Post-Flight Analysis of a 10K Sorption Cryocooler

In May 1996, the Brilliant Eyes Ten-Kelvin Sorption Cryocooler Experiment (BETSCE) was flown aboard the Space Shuttle flight STS-77 in the first space-flight demonstration of chemisorption cryocooler technology. While on orbit, BETSCE successfully met its science objectives of cooling from 70 K to 10 K in less than two minutes, sustaining a 100 mW heat load below 11 K for over then minutes, and demonstrating recycle times of approximately eleven hours.

sorption crycooler chemisorption cryocooler↗
NASA NTRS1995

Development of a Periodic 10 K Sorption Cryocooler

The design and fabrication of a small, closed-cycle, periodic 10 K sorption cyrocooler laboratory system is described. The cooler is designed to provide cooldown from 60 to <10 K in under 2 minutes, maintain a simulated detector heat load of 100 mW below 10 K for over 10 minutes, and have the ability to be recycled in under 6 hours.

10 K Sorption Cryocooler↗
NASA NTRS2003

20 K continuous cycle sorption coolers for the Planck flight mission

In this paper we present the level of maturity of the hydrogen sorption cooler technology at JPL by describing the design and how it has been validated at the subsystem and system levels. In addition, we will describe how such systems could be advantageously used for other space missions with similar needs and cooler attributes.

sorption cooler 20 K hydride Planck↗
NASA NTRS1999

Hydrogen Sorption Cryocoolers for the Planck Mission

Two continuous opertation 18K/20K sorption coolers are being developed by the Jet Propulsion Laboratory (JPL) as a NASA contribution to the European Space Agency (ESA) Planck mission that is currently planned for a 2007 launch.

Cryocooler sorption coolers↗