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At least 109 records · Page 6

Monolithic Two-Terminal All-Perovskite Tandem Solar Cells with Power Conversion Efficiency Exceeding 21%

Monolithic two-terminal (2-T) all-perovskite tandem solar cells are a promising candidate for the next generation solar cells with ultrahigh efficiency and low fabrication cost. Here, we report on the fabrication of 2-T all-perovskite tandem solar cells consisting of solution-processed wide-bandgap and low-bandgap perovskite subcells connected by a vacuum processed interconnection layer. We employed a bulk-passivation strategy to enlarge the grain size, increase carrier mobilities, reduce electronic disorder, and suppress trap-assisted recombination in the low bandgap mixed Sn-Pb perovskite films, which leads to improved performance of low bandgap perovskite solar cells with an absorber thickness over 750 nm. This advance in high-quality low-bandgap perovskite layers enables the fabrication of efficient 2-T all-perovskite solar cells with power conversion efficiencies of more than 21% and decent stability. Our approach provides a suitable pathway to realize ultra-high efficiency 2-T all-perovskite tandem solar cells.

14 SOLAR ENERGY↗

A simplified, efficient approach to hybrid wind and solar plant site optimization

Abstract. Wind plant layout optimization is a difficult, complex problem with a large number of variables and many local minima. Layout optimization only becomes more difficult with the addition of solar generation. In this paper, we propose a parameterized approach to wind and solar hybrid power plant layout optimization that greatly reduces problem dimensionality while guaranteeing that the generated layouts have a desirable regular structure. Thus far, hybrid power plant optimization research has focused on system sizing. We go beyond sizing and present a practical approach to optimizing the physical layout of a wind–solar hybrid power plant. We argue that the evolution strategy class of derivative-free optimization methods is well-suited to the parameterized hybrid layout problem, and we demonstrate how hard layout constraints (e.g., placement restrictions) can be transformed into soft constraints that are amenable to optimization using evolution strategies. Next, we present experimental results on four test sites, demonstrating the viability, reliability, and effectiveness of the parameterized evolution strategy approach for generating optimized hybrid plant layouts. Completing the tool kit for parameterized layout generation, we include a brief tutorial describing how the parameterized evolutionary approach can be inspected, understood, and debugged when applied to hybrid plant layouts.

14 SOLAR ENERGY↗

Hybrid Power Plants: Status of Installed and Proposed Projects [Slides]

As battery prices fall and wind and solar generation rises, power plant developers are increasingly combining wind and solar projects with on-site batteries, creating “hybrid” power plants. But hybrid or co-located plants have been part of the U.S. electricity mix for decades, with widely ranging configurations that extend beyond pairing a generator with a battery. This new summary tracks and maps existing hybrid and co-located plants across the United States while also synthesizing data from generation interconnection queues to illustrate developer interest in the next wave of plants. The scope is inclusive of co-located hybrid plants that pair two or more generators and/or that pair generation with storage at a single point of interconnection, and also full hybrids that feature co-location and co-control. The focus is on larger, 1 MW+ systems: smaller (often behind-the-meter) projects are also increasingly common, but are not included in the data synthesis. Based in part on EIA Form 860 data, there were at least 125 co-located hybrid plants (>1 MW) already operating across the United States at the end of 2019, totaling over 14 GW of aggregate capacity. Some of the most common configurations include wind+storage (13 projects, 1,290 MW wind, 184 MW storage), PV+storage (40 projects, 882 MW PV, 169 MW storage), and fossil+storage (10 projects, 2,414 MW fossil, 91 MW storage). Data from interconnection queues demonstrates the considerable commercial interest that exists in hybrid power plants, especially solar co-located with storage. By the end of 2019, there were at least 367 GW of solar plants in the nation’s queues; 102 GW (~28%) of this capacity was proposed as a hybrid, most typically pairing PV with battery storage. For wind, 225 GW of capacity sat in the queues, with 11 GW (~5%) proposed as a hybrid, again most-often pairing wind with storage. The proposed solar+storage plants are located throughout the United States, but with California and the non-ISO West being the most prominent areas of commercial interest. Proposed wind+storage and standalone storage plants also center to a degree on these regions of the country.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Comparing different generations of idealized solar geoengineering simulations in the Geoengineering Model Intercomparison Project (GeoMIP)

Abstract. Solar geoengineering has been receiving increased attention in recent years as a potential temporary solution to offset global warming. One method of approximating global-scale solar geoengineering in climate models is via solar reduction experiments. Two generations of models in the Geoengineering Model Intercomparison Project (GeoMIP) have now simulated offsetting a quadrupling of the CO2 concentration with solar reduction. This simulation is idealized and designed to elicit large responses in the models. Here, we show that energetics, temperature, and hydrological cycle changes in this experiment are statistically indistinguishable between the two ensembles. Of the variables analyzed here, the only major differences involve highly parameterized and uncertain processes, such as cloud forcing or terrestrial net primary productivity. We conclude that despite numerous structural differences and uncertainties in models over the past two generations of models, including an increase in climate sensitivity in the latest generation of models, the models are consistent in their aggregate climate response to global solar dimming.

54 ENVIRONMENTAL SCIENCES↗

Large Scale Pumped Storage to Support Renewable Deployment; PSH Resource Assessment and Complementary Analysis for Alaska

The State of Alaska has a rather unique electric power system, as it has two larger transmission grids (Railbelt and Southeast Alaska) and over 150 islanded stand-alone power systems that are serving remote rural communities. In 2010, the Alaska legislature enacted a non-binding goal for 50% of renewable electricity generation by 2025. With the expected increase in wind and solar generation in the future, the role of energy storage becomes increasingly important. Considering the specific power system characteristics in Alaska, energy storage technologies that can supply electricity over an extended period of time, such as pumped storage hydropower (PSH), may play a key role in enabling the reliability and resiliency of both integrated and rural power systems. The overarching objective of the subject study of this presentation is to investigate the prospects and opportunities for PSH in Alaska.

Alaska↗

Energy Northwest – Horn Rapids Solar and Storage: A Techno-economic Assessment

In 2017, as part of the second round of funding from the Washington State Clean Energy Fund, the Washington State Department of Commerce granted up to $\$3$ million in matching funds to develop an estimated $6.5 million project that deployed a 4-MW, 20-acre solar generating array of photovoltaic (PV) panels coupled with a 1 MW/4 MWh (nameplate capacity) lithium-iron-phosphate battery energy storage system (BESS) in Richland, Washington. The combination of PV and BESS will provide a predictable, renewable generating source and will also serve as a training ground for solar and battery technicians throughout the nation. This report documents the techno-economic assessment of the integrated system, including the definition of use cases and applications, collection and preparation of data and input parameters, development of modeling and optimization methods, case studies, and analysis results.

14 SOLAR ENERGY↗

U.S. Wind and Solar PV Supply Curves with Future Land-use Change

This dataset provides future supply curves representing the total resource potential for land-based wind and solar photovoltaic (PV) deployment in the conterminous United States after accounting for the impact of land-use and land-cover change (LULC). We use LULC projections from 2010 to 2050 developed based on the Intergovernmental Panel on Climate Change (IPCC) Special Report on Emission Scenarios. The LULC projections are subsequently fed into the renewable energy potential model (reV), which estimates total available wind and solar capacity after excluding non-developable land. Supply curves are provided for four IPCC scenarios in 2050: A1B, A2, B1, and B2. As a baseline, we also provide the supply curve from the B2 scenario in 2010. In addition to the supply curves, we also provide representative wind and solar generation profiles for each supply curve point. These generation profiles are provided as capacity factors and are based on a 2012 weather year using NSRDB and WindToolkit resource data. For more details on the supply curve and profile datasets included here please refer to README. Additional information on the supply curves and the LULC projections used to generate them, as well as an analysis of their impact on wind and solar deployment under decarbonization can be found in the publication linked below: "U.S. Wind and Solar PV Supply Curves with Future Land-use Change Publication".

Array↗

Dynamic Interaction of Grid-Forming and Grid-Following Inverters with Synchronous Generators in Hybrid Power Plants

As the integration of renewable energy resources such as wind and solar generation continues to grow, the use of hybrid power plants with both synchronous machines and power electronic inverters operating in parallel becomes more common. This paper studies the impact on small-signal stability for these pairs of devices, first as an isolated two-device system and then as part of a 9-bus test system. Each operational scenario was studied with both a grid-following inverter and a grid-forming inverter. In each scenario, the state variables associated with the synchronous generator's excitation system were found to be responsible for the inception of instability. These results underscore the importance of accurate modeling of excitation systems when modeling power systems with hybrid power plants.

hybrid power plant↗

Local Power: Comparing County-Level Renewable Energy Potential to Consumption Using the SLOPE Platform

Wide-scale deployment of renewable energy technologies has the potential to significantly reduce greenhouse gas emissions and mitigate the effects of climate change. Many communities have ambitious clean energy goals with targets for locally generated renewable energy. To inform state and local clean energy planning, analysts from the Joint Institute for Strategic Energy Analysis (JISEA) and National Renewable Energy Laboratory (NREL) used data from NREL's State and Local Planning for Energy (SLOPE) platform to compare annual technical generation potential of renewable energy technologies to modeled electricity consumption in every county of the contiguous United States. Annual costs were calculated to produce a 20% share of electricity consumed annually from each technology to examine localized cost effectiveness of a diversified mix of generation sources. For example, combining distributed and utility-scale wind and solar generation can offset the need for storage and nonintermittent fossil resources to achieve high deployment of renewables. This county-level analysis provides insight into where localized renewable energy generation could cost-effectively match annual electricity consumption.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Sensitivity Study for Forecasting Variables of WRF-Solar Using a Tangent Linear Approach

Integrating solar generation in recent years has highlighted the need for improved accuracy in predicting solar power. Confidence in solar power forecasting can be achieved by designing an ensemble that provides reliable probabilistic information for solar radiation with reduced uncertainty and error. Ideally, ensemble members are created through the optimized perturbation of the initial conditions in numerical weather prediction (NWP) models. Tangent linear models are capable of efficiently investigating the sensitivity of solar radiation to model input parameters because they do not require individual perturbation of each variable. This sensitivity study using tangent linear models provide us the capability to identify the right variables to perturb in an ensemble prediction system. In this study, we developed tangent linear models for WRF-Solar modules that directly impact the computation of solar radiation and the simulation of cloud formation and dissipation including the Fast All-sky Model for Solar Applications (FARMS), the Noah land surface model (LSM), the Thompson microphysics, the Mello-Yamada-Nakanishi-Niino (MYNN) boundary layer parameterization, and the Deng scheme for a shallow-convection parameterization. A sensitivity analysis was conducted under various scenarios based on satellite observations and model simulations from the National Solar Radiation Data Base (NSRDB) and WRF-Solar, respectively. Critical forecasting variables that are highly sensitive to the forecasting of global horizontal irradiance (GHI), direct normal irradiance (DNI), cloud mixing ratio, cloud tendency, cloud fraction, and sensible and latent heat fluxes were determined using the relevant WRF-Solar module. This study will be used as a guidance on future research leading to high-quality probabilistic solar forecasting. In this presentation, we discuss the validation of tangent linear approach for WRF-Solar modules and illustrate how the sensitivity results are valuable in the improvement of probabilistic solar prediction.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Hybrid Power Plants: Status of Operating and Proposed Plants, 2023 Edition [Slides]

Improving battery technology and the growth of variable renewable generation are driving a surge of interest in “hybrid” power plants that combine, for example, wind or solar generating capacity with co-located batteries. While most of the current interest involves pairing photovoltaic (PV) plants with batteries, other types of hybrid or co-located plants with wide-ranging configurations have been part of the U.S. electricity mix for decades. This annually updated briefing tracks and maps existing hybrid or co-located plants across the United States while also synthesizing data from power purchase agreements (PPAs) and generation interconnection queues to shed light on near- and long-term development pipelines. The scope includes “co-located hybrids” that pair two or more resources (e.g., multiple types of generation and/or generation with storage) that are operated largely independently behind a single point of interconnection, and “full hybrids” that also feature coordinated operations of the co-located resources. The focus is on plants with one megawatt (MW) or more of capacity; smaller (often behind-the-meter) projects are also increasingly common, but are not included in this data synthesis. Key findings from the latest briefing include: -At the end of 2022, there were 374 hybrid plants (>1 MW) operating across the United States (+25% compared to the end of 2021), totaling nearly 41 GW of generating capacity (+15%) and 5.4 GW/15.2 GWh of energy storage (+69%/+88%). PV+storage plants are by far the most common, dominating in terms of plant number (213), storage capacity (4.0 GW/12.5 GWh), storage:generator capacity ratio (49%), and storage duration (3.1 hours). But there are nearly twenty other hybrid plant configurations as well, including several different fossil hybrid categories (each dominated by the fossil component) as well as wind+storage, wind+PV, wind+PV+storage, geothermal+PV, and others. -Last year was another strong year for PV+storage hybrids in particular: 59 of the 62 hybrids added in 2022 were PV+storage. As of the end of 2022, there was roughly as much storage capacity operating within PV+storage hybrid plants as in standalone storage plants (~4 GW each). In storage energy terms, however, PV+storage edged out standalone storage by ~2 GWh (12.5 GWh vs. 10.4 GWh, respectively). -Interconnection queue data show continued strong developer interest in hybridization. At the close of 2022, there were 51% more hybrid plants—representing 59% more generating capacity—in interconnection queues across the United States than there were at the end of 2021. Solar dominates these proposed plants as well: at the close of 2022, there were 457 GW of solar capacity proposed as a hybrid (representing ~48% of all solar capacity in the queues), most typically pairing PV with battery storage. At the same time, there were 24 GW of wind capacity proposed as a hybrid (representing ~8% of all wind capacity in the queues), again most-often pairing wind with storage. Meanwhile, more than half of all storage in the queues is estimated to be part of a hybrid plant. While many of the plants proposed in the queues will not ultimately reach commercial operations, the depth of interest in hybrid plants—especially PV+storage—is notable, particularly in certain regions. For example, in CAISO, 97% of all solar capacity and 45% of all wind capacity in the queues is proposed as a hybrid. -The report also surveys power purchase agreement (PPA) price data from a sample of operating and proposed PV+storage plants. Though PV+storage PPA prices have fallen over time, “levelized storage adders” have recently increased somewhat to ~$\$ $7000/MW-month, ~$\$ $60/MWh-stored (assuming one full cycle per day), or ~$\$ $15/MWh-PV. Some of the recent price increase could simply reflect a trend towards higher battery:PV capacity ratios over time, which increases costs, all else being equal. The well-publicized impact of inflationary and supply chain pressures on battery prices is no doubt a contributor as well.

25 ENERGY STORAGE↗

Demonstrating SolarPILOT’s Python API Through Heliostat Optimal Aimpoint Strategy Use Case

SolarPILOT is a software package that generates solar field layouts and characterizes the optical performance of concentrating solar power (CSP) tower systems. SolarPILOT was developed by the National Renewable Energy Laboratory (NREL) as a stand-alone desktop application but has also been incorporated into NREL’s1 System Advisor Model (SAM) in a simplified format. Prior means for user interaction with SolarPILOT have included the application’s graphical interface, the SAM routines with limited configurability, and through a built-in scripting language called “LK.” This paper presents a new, full-featured, Python-based application programmable interface (API) for SolarPILOT, which we hereafter refer to as CoPylot. CoPylot provides access to all SolarPILOT’s capabilities to generate and characterize power tower CSP systems seamlessly through Python. Supported capabilities include (i) creating and destroying a model instance with message reporting tools; (ii) accessing and setting any SolarPILOT variable including custom land boundaries for field layouts; (iii) programmatically managing receiver and heliostat objects with varied attributes for systems with multiple receiver or heliostat types; (iv) generating, assigning, and modifying solar field layouts including the ability to set individual heliostat locations, aimpoints, soiling rates, and reflectivity levels; (v) simulating solar field performance; (vi) returning detailed results describing performance of individual heliostats, the aggregate field, and receiver flux distribution; and, (vii) exporting Python-based model instances to multiple file formats. CoPylot enables Python users to perform detailed CSP tower analysis utilizing either the Hermite expansion technique (analytical) or the SolTrace ray-tracing engine. In addition to CoPylot’s functionality, Python users have access to the over 100,000 open-source libraries to develop, analyze, optimize, and visualize power tower CSP research. This enables CSP researchers to perform analysis that was previously not possible through SolarPILOT’s existing interfaces. This paper discusses the capabilities of CoPylot and presents a use case wherein we demonstrate optimal solar field aiming strategies.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Enhancing Power Resilience for Remote Communities: A Comprehensive Renewable Energy Solution for Itbayat Island

The island of Itbayat, Philippines, faces significant challenges in maintaining a reliable and resilient power supply due to its current reliance on a vulnerable power distribution system managed by a local electric cooperative. The existing infrastructure, which includes diesel generators and a radial network configuration with some above-ground lines, is highly susceptible to frequent typhoons and adverse weather conditions. These factors, combined with inadequate staffing and high operational costs, result in frequent power outages that disrupt daily life and hinder economic development. This white paper proposes a comprehensive solution to enhance the resilience and reliability of Itbayat's power system by integrating renewable energy sources, specifically solar photovoltaic (PV) systems, battery storage, and a microgrid controller. The proposed solution aims to reduce dependency on diesel fuel, optimize energy use, and provide a sustainable and robust power supply for the island. Key components of the solution include: 1. Solar PV Installation: Deploying solar PV panels to harness abundant solar energy, reducing reliance on diesel fuel. 2. Battery Storage Systems: Installing battery storage to store excess solar energy and ensure a continuous power supply during low solar generation periods. 3. Microgrid Controller: Implementing a microgrid controller to manage and optimize the integration of solar PV, battery storage, and existing diesel generators. The proposed solution addresses several critical issues, including system vulnerability, generator dependency, and operational inefficiencies. By adopting this innovative approach, Itbayat Island can achieve a more resilient, efficient, and sustainable energy infrastructure, ensuring a stable power supply for its residents and enhancing overall energy security.

14 SOLAR ENERGY↗

Hybrid Power Plants: Status of Operating and Proposed Plants, 2024 Edition [Slides]

Improving battery technology and the growth of variable renewable generation are driving a surge of interest in “hybrid” power plants that combine, for example, wind or solar generating capacity with co-located batteries. While most of the current interest involves pairing photovoltaic (PV) plants with batteries, other types of hybrid or co-located plants with wide-ranging configurations have been part of the U.S. electricity mix for decades. This annually updated briefing tracks and maps existing hybrid or co-located plants across the United States while also synthesizing data from power purchase agreements (PPAs) and generation interconnection queues to shed light on near- and long-term development pipelines. The scope includes “co-located hybrids” that pair two or more resources (e.g., multiple types of generation and/or generation with storage) that are operated largely independently behind a single point of interconnection, and “full hybrids” that also feature coordinated operations of the co-located resources. The focus is on plants with one megawatt (MW) or more of capacity; smaller (often behind-the-meter) projects are also increasingly common, but are not included in this data synthesis.

14 SOLAR ENERGY↗

Hybrid Power Plants: Status of Operating and Proposed Plants, 2022 Edition [Slides]

Falling battery prices and the growth of variable renewable generation are driving a surge of interest in “hybrid” power plants that combine, for example, wind or solar generating capacity with co-located batteries. While most of the current interest involves pairing photovoltaic (PV) plants with batteries, other types of hybrid or co-located plants with wide-ranging configurations have been part of the U.S. electricity mix for decades. This annually updated briefing tracks and maps existing hybrid or co-located plants across the United States while also synthesizing data mined from power purchase agreements (PPAs) and generation interconnection queues to shed light on near- and long-term development pipelines. The scope includes co-located hybrid plants that pair two or more generators and/or that pair generation with storage at a single point of interconnection, and full hybrids that feature co-location and co-control. The focus is on plants with one megawatt (MW) or more of capacity; smaller (often behind-the-meter) projects are also increasingly common, but are not included in this data synthesis. Key findings from the latest briefing include: -At the end of 2021, there were nearly 300 hybrid plants (>1 MW) operating across the United States, totaling nearly 36 gigawatts (GW) of generating capacity and 3.2 GW/8.1 GWh of energy storage. PV+storage plants are by far the most common, dominating in terms of plant number (140), storage capacity (2.2 GW/7.0 GWh), storage:generator ratio (53%), and storage duration (3.2 hours). But there are nearly twenty other hybrid plant configurations as well, including several different fossil hybrid categories (each dominated by the fossil component) as well as wind+storage, wind+PV, wind+PV+storage, geothermal+PV, and others. -Last year was a breakout year for PV+storage hybrids in particular: 67 of the 74 hybrids added in 2021 were PV+storage. By the end of 2021, there were more GW of battery capacity installed in PV+storage hybrids (2.2 GW) than as standalone storage plants (1.8 GW). The difference is even starker in energy terms, with PV+storage plants hosting twice as much battery capacity as standalone storage plants (7 GWh vs. 3.5 GWh, respectively). Much of the battery capacity added in hybrid form in 2021 was a battery retrofit to a pre-existing PV plant. -Data on plants under development from the interconnection queues of all seven ISOs/RTOs plus 35 individual utilities suggest that these hybridization trends are likely to continue. At the close of 2021, there were more than 670 GW of solar plants in the nation’s queues; 285 GW (~42%) of this capacity was proposed as a hybrid, most typically pairing PV with battery storage (PV+storage represented nearly 90% of all hybrid capacity in the queues). For wind, 247 GW of capacity sat in the queues, with 19 GW (~8%) proposed as a hybrid, again most-often pairing wind with storage (wind+storage represented ~4% of all hybrid capacity in the queues). Meanwhile, nearly half of all storage in the queues is estimated to be part of a hybrid plant. While many of these proposed plants will not ultimately reach commercial operations, the depth of interest in hybrid plants—especially PV+storage—is notable.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Particle Flow Distribution in a Fluidized-Particles Multitube Solar Receiver

A fluidized-particles two-tube solar receiver was tested at ambient temperature at PROMES Laboratory to investigate the influence of an inhomogeneous solar flux density on the particle mass flow rate between the tubes. The principle of this 3rd generation solar receiver is to fluidize the particles in a container, called dispenser, in which the tubes’ bottom are immersed. The fluidized particles are flowing upward the tubes by applying an overpressure in the dispenser. Air velocities are changed inside the tubes, thanks to air mass flow controllers, to represent temperature heterogeneity between the tubes. Air velocities from 0.05 up to 0.52 m/s were tested, both in homogeneous and heterogeneous conditions. In the heterogeneous ones, the differences in air velocity between the tubes aim to mimic a difference in temperature from 20 to 100 % with homogeneous air flow rates injected. The following conclusions were drawn. First, the particle mass flux in the tubes are the same with homogeneous air velocities, each one following a calibration map previously obtained. Second, different air velocities lead to different particle mass flux. Third, the rise of the total particle mass flux diminishes the pressure in the dispenser. Four, this diminution of pressure leads to a decrease of the particle mass flow rate of the tube with the lower air velocity. This influence can lead in some cases to the stop of the fluidized bed circulation in the affected tube.

Sahuquet, Guillaume (ORCID:0000000302752890)↗

Interface-modulated kinetic differentials in electron and hole transfer rates as a key design principle for redox photocatalysis by Sb2VO5/QD heterostructures

The efficient conversion of solar energy to chemical energy represents a critical bottleneck to the energy transition. Photocatalytic splitting of water to generate solar fuels is a promising solution. Semiconductor quantum dots (QDs) are prime candidates for light-harvesting components of photocatalytic heterostructures, given their size-dependent photophysical properties and band-edge energies. A promising series of heterostructured photocatalysts interface QDs with transition-metal oxides which embed midgap electronic states derived from the stereochemically active electron lone pairs of p-block cations. Here, we examine the thermodynamic driving forces and dynamics of charge separation in Sb2VO5/CdSe QD heterostructures, wherein a high density of Sb 5s2-derived midgap states are prospective acceptors for photogenerated holes. Hard-x-ray valence band photoemission spectroscopy measurements of Sb2VO5/CdSe QD heterostructures were used to deduce thermodynamic driving forces for charge separation. Interfacial charge transfer dynamics in the heterostructures were examined as a function of the mode of interfacial connectivity, contrasting heterostructures with direct interfaces assembled by successive ion layer adsorption and reaction (SILAR) and interfaces comprising molecular bridges assembled by linker-assisted assembly (LAA). Transient absorption spectroscopy measurements indicate ultrafast (<2 ps) electron and hole transfer in SILAR-derived heterostructures, whereas LAA-derived heterostructures show orders of magnitude differentials in the kinetics of hole (<100 ps) and electron (∼1 ns) transfer. The interface-modulated kinetic differentials in electron and hole transfer rates underpin the more effective charge separation, reduced charge recombination, and greater photocatalytic efficiency observed for the LAA-derived Sb2VO5/CdSe QD heterostructures.

Chemistry↗