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At least 109 records · Page 6

Composition Quantification of SiGeSn Alloys Through Time-of-Flight Secondary Ion Mass Spectrometry: Calibration Methodologies and Validation With Atom Probe Tomography

Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS) is a powerful technique for elemental compositional analysis and depth profiling of materials. However, it encounters the problem of matrix effects that hinder its application. In this work, we introduce a pioneering ToF-SIMS calibration method tailored for SixGeySnz ternary alloys. SixGe1-x and Ge1-zSnz binary alloys with known compositions are used as calibration reference samples. Through a systematic SIMS quantification study of SiGe and GeSn binary alloys, we unveil a linear correlation between secondary ion intensity ratio and composition ratio for both SiGe and GeSn binary alloys, effectively mitigating the matrix effects. Extracted relative sensitivity factor (RSF) value from SixGe1-x (0.07 < x < 0.83) and Ge1-zSnz (0.066 < z < 0.183) binary alloys are subsequently applied to those of SixGeySnz (0.011 < x < 0.113, 0.863 < y < 0.935 and 0.023 < z < 0.103) ternary alloys for elemental compositions quantification. These values are cross-checked by Atom Probe Tomography (APT) analysis, an indication of the great accuracy and reliability of as-developed ToF-SIMS calibration process. Furthermore, the proposed method and its reference sample selection strategy in this work provide a low-cost as well as simple-to-follow calibration route for SiGeSn composition analysis, thus driving the development of next-generation multifunctional SiGeSn-related semiconductor devices.

36 MATERIALS SCIENCE↗

Evidence of off-shell Higgs boson production from ZZ leptonic decay channels and constraints on its total width with the ATLAS detector

This Letter reports on a search for off-shell production of the Higgs boson using 139 fb —1 of $pp$ collision data at $\sqrt{s}$ = 13 TeV collected by the ATLAS detector at the Large Hadron Collider. The signature is a pair of $\overline{Z}$ bosons, with contributions from both the production and subsequent decay of a virtual Higgs boson and the interference of that process with other processes. The two observable final states are $\overline{Z}$ $\overline{Z}$ → 4$\ell$ and $\overline{Z}$ $\overline{Z}$ → 2$\ell$2$ν$ with $\ell$ = $e$ or $μ$. In the $\overline{Z}$ $\overline{Z}$ → 4$\ell$ final state, a dense Neural Network is used to enhance analysis sensitivity with respect to matrix element-based discrimination. The backgroundonly hypothesis is rejected with an observed (expected) significance of 3.3 (2.2) standard deviations, representing experimental evidence for off-shell Higgs boson production. Assuming that no new particles enter the production of the virtual Higgs boson, its total width can be deduced from the measurement of its off-shell production cross-section. The measured total width of the Higgs boson is ${4.5}_{—2.5}^{+3.3}$ MeV, and the observed (expected) upper limit on the total width is found to be 10.5 (10.9) MeV at 95% confidence level.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Multiple boundary condition testing error analysis

Techniques for interpreting data from multiple-boundary-condition (MBC) ground tests of large space structures are developed analytically and demonstrated. The use of MBC testing to validate structures too large to stand alone on the ground is explained; the generalized least-squares mass and stiffness curve-fitting methods typically applied to MBC test data are reviewed; and a detailed error analysis is performed. Consideration is given to sensitivity coefficients, covariance-matrix theory, the correspondence between test and analysis modes, constraints and step sizes, convergence criteria, and factor-analysis theory. Numerical results for a simple beam problem are presented in tables and briefly characterized. The improved error-updating capabilities of MBC testing are confirmed, and it is concluded that reasonably accurate results can be obtained using a diagonal covariance matrix.

Glaser, R. J.↗

Polarization analysis of a balloon-borne solar magnetograph

The 10(exp -5) polarization specification for the Balloon-borne Vector Magnetograph (BVM) can be met. The 10(exp -5) specification is shown to be a limitation on the diattenuation and retardance along the chief ray path through the optical system, such that the magnitude of the polarization aberration piston term is constrained to be less than .5(10)(exp -5). Coating specification sheets are provided which will ensure that the polarization sensitivity of the BVM will be less than 10(exp -5). An optical design is provided for a vector magnetograph. Finally, to provide a concrete mathematical meaning for polarization sensitivity, the polarization aberration matrix is averaged of the exit pupil. This shows that the coupling between circular and linear states depends only on the magnitude of the polarization aberration piston term.

Reiley, Daniel J.↗

ISS-Crystal Growth of Photorefractive Materials (BSO): Critical Design Issues for Optimized Data Extraction from Space Experiments

Realization of the full potential of photorefractive materials in device technology is seriously impeded by our inability to achieve controlled formation of critical defects during single crystal growth and by difficulties in meeting the required degree of compositional uniformity on a micro-scale over macroscopic dimensions. The exact nature and origin of the critical defects which control photorefractivity could not as yet be identified because of gravitational interference. There exists, however, strong evidence that the density of defect formation and their spatial distribution are adversely affected by gravitational interference which precludes the establishment of quantifiable and controllable heat and mass transfer conditions during crystal growth. The current, NASA sponsored research at MIT is directed at establishing a basis for the development of a comprehensive approach to the optimization of property control during melt growth of photorefractive materials, making use of the m-g environment, provided in the International Space Station. The objectives to be pursued in m-g research on photorefractive BSO (Bi12SiO20) are: (a) identification of the x-level(s) responsible for photorefractivity in undoped BSO; (b) development of approaches leading to the control of x-level formation at uniform spatial distribution; (c) development of doping and processing procedures for optimization of the critical, application specific parameters, spectral response, sensitivity, response time and matrix stability. The presentation will focus on: the rationale for the justification of the space experiment, ground-based development efforts, design considerations for the space experiments, strategic plan of the space experiments, and approaches to the quantitative analysis of the space experiments.

Hyers, Robert W.↗

Uncertainty quantification for competing failure mechanisms in unidirectionally reinforced carbon–carbon composites

Microstructure-informed finite element models play a key role in the carbon–carbon composite design process. Variability in manufacturing process parameters and experimental limitations introduce model parameter uncertainty. This study quantifies the effect of model parameter uncertainty on transverse tensile fracture behavior and proposes a methodology to predict the failure mode based on competing microscale damage mechanisms. Finite element simulations incorporate fiber–matrix interface debonding with cohesive zones and matrix damage with a smeared crack band approach in a unidirectional carbon–carbon composite. Results from a variance-based global sensitivity analysis identifies interfacial and matrix damage parameters as the primary source of variability in fracture behavior. Sobol’ indices indicate that matrix and cohesive zone strengths contribute 94% of the variance in the effective ultimate stress. A local analysis elucidates the relationship between these constituent strength parameters and failure mode by estimating the probability of cohesive, matrix, and mixed-mode dominated failure. Based on the results for 4000 simulations, 93% exhibit mixed-mode or interfacial dominated failure, which underscores the crucial role of fiber–matrix interface debonding in the transverse tensile failure of carbon–carbon composites. These uncertainty quantification results facilitate more efficient model calibration and provide a framework for microstructure-informed failure predictions in the face of manufacturing-induced uncertainty.

36 MATERIALS SCIENCE↗

Mechanical Behavior of Notched SiC/SiC Composites

Gas turbine components such as combustor liners or turbine vanes are subject to regions of high stress-concentration, e.g., attachment to the frame or at cooling holes. Ceramic matrix composites (CMCs) are potential materials for high temperature applications in gas turbines. They offer some capability to relieve stress at regions of high stress-concentration via matrix damage accumulation. In this study notch sensitivity was examined for woven SiC fiber reinforced, melt-infiltrated SiC matrix composites with a BN interphase, utilizing either Hi-Nicalo(TM) fibers or the stiffer Sylramic fibers. The double-edge notched tensile test approach was used for a wide range of notch sizes and specimen widths. Both composite systems exhibited mild notch sensitivity similar to other CMC systems. Acoustic emission, detected during the tensile tests, indicated that matrix cracking occurred around notches at net-section stresses below the stress where matrix cracking first occurs in unnotched specimens. However, thermoelastic stress analysis did not show any measurable stress relief around notches after the specimens were preloaded.

Morscher, Gregory N.↗

Statistical uncertainty of fission matrix eigenvalues using perturbation theory

Eigenvalue search of high dominance ratio systems may be slow to converge. The fission matrix element is defined by its element (FM){sub ij}, which are the probability for a neutron born in cell i to create a fission in cell j for a spatial mesh of n{sub i}*n{sub j} elements. Fission matrices are used in Monte Carlo criticality simulations to enhance computing speed, but also to find higher order eigenvalues. However, few studies have been made on the link between statistical uncertainties of fission matrix elements and eigenvalues uncertainties. Thus, dominance ratio statistical uncertainties remain unknown. This paper uses a new generalized perturbation theory (GPT) method to estimate sensitivities of eigenvalues to fission matrix elements and then to calculate dominance ratio uncertainties.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Polarization sensitivity analysis of an earth remote sensing instrument - The MODIS-N phase B study

Polarization analysis software that employs Jones matrix formalism to calculate the polarization sensitivity of an instrument design was developed at Hughes Danbury Optical Systems. The code is capable of analyzing the full ray bundle at its angles of incidence for each optical surface. Input is based on the system ray trace and the thin film coating design at each surface. The MODIS-N (Moderate Resolution Imaging Spectrometer) system is used to demonstrate that it is possible to meet stringent requirements on polarization insensitivity associated with planned remote sensing instruments. Analysis indicates that a polarization sensitivity less than or equal to 2 percent was achieved in all desired spectral bands at all pointing angles, per specification. Polarization sensitivities were as high as 10 percent in similar remote sensing instruments.

Waluschka, E.↗

Pendulum impact resistance of tungsten fiber/metal matrix composites.

The impact properties of copper, copper-10 nickel, and a superalloy matrix reinforced with tungsten fibers were studied. In most cases the following increased composite impact strength: increased fiber or matrix toughness, decreased fiber-matrix reaction, increased test temperature, hot working and heat treatment. Notch sensitivity was reduced by increasing fiber or matrix toughness. The effect of fiber content depended on the relative toughness of the fibers and matrix. Above 530 K a 60 volume per cent superalloy matrix composite had a greater impact strength than a turbine blade superalloy, whereas below 530 K a hot worked 56 volume per cent composite had a greater impact strength than the superalloy.

Winsa, E. A.↗

Altered Gravity and Early Heart Development in Culture

The macromolecules comprising the cytoskeleton and extracellular matrix of cells may be sensitive to gravitation. Since early development of organs depends on dynamic interactions across cell surfaces, altered gravity may disturb development. We investigated this possibility for heart development. Previous studies showed that the extracellular matrix glycoprotein fibronectin (Fn) is necessary for normal heart development. We cultured precardiac tissue explants in a high aspect ratio bioreactor vessel (HARV) to simulate microgravity. We observed tissue morphology, contraction, and Fn distribution by immunolocalization in HARV rotated and control (lxg) explants, cultured 18 hr. We also measured Fn amount by immunoassay. Explants in HARV were rotated at 6 rpm to achieve continuous freefall. Thirty-five of 37 control, but only 1 of 37 matched rotated explants exhibited contractions. Tissue architecture was identical. Immunolocalization of Fn showed remarkable differences which may be related to the development of contractions. The Fn staining in the HARV explants was less intense in all areas. Areas of linear staining along epithelia were present but shorter, and there was less intercellular staining in both mesenchymal tissue and myocardium. Initial immunoassay results of 5 matched pairs of explants showed a 22% reduction in total tissue Fn in the HARV rotated samples. Our results indicate that altered gravity in the HARV reduced the amount and distribution of Fn, as assessed by two independent criteria. This was correlated with a reduction in the development of contractile activity.

Wiens, Darrell J.↗

Sensitivity analysis of dynamic aeroelastic responses

This paper summarizes ongoing research on the sensitivity analysis of dynamic aeroelastic response of wings. Two approaches are being used to express the unsteady aerodynamic loads: (1) the frequency-domain approach, and (2) the state-space approach. The frequency-domain approach is demonstrated on a three-dimensional box wing and the state-space domain approach is demonstrated on a simple two-dimensional sectional model. Three different methods are used to find the sensitivities: (1) a purely finite difference approach, (2) a semi-analytical approach in which an analytical expression is used for calculating the sensitivity of an eigenvalue of the complex valued aeroelastic matrix, however, the derivatives of the components of the matrix are obtained using finite difference, and (3) a semi-analytic approach that differs from (2) in the sense that the sensitivity of the aerodynamic matrix is now obtained analytically. A good agreement is seen between the three sets of results. For the two-dimensional sectional model the results for the sensitivities of the flutter speed with respect to the various parameters are obtained.

Kapania, Rakesh K.↗

Computation and sensitivity considerations of the Ricatti equation in spacecraft CMG steering laws

The steady-state matrix Ricatti equation is studied with respect to sensitivity and computational burden for a linear regulator controller in spacecraft. The class of systems studied use control moment gyros (CMGs) as the torque driver, assuming that the CMGs are free of gimbal stops. Different solution techniques are evaluated relative to computation time and accuracy to determine which solution method is most acceptable with respect to the prescribed requirements. It is shown that it is not feasible to eliminate off-diagonal Ricatti equation terms in the relevent updata equation due to their high sensitivity, that Potter's algebraic technique requires the least computation time of the methods studied, and that the simple Euler method yields the best results when accuracy and computation time are equally weighted. If an optimal linear regulator formulation is employed, a full Ricatti equation solution of n(n + 1)2 elements of the symmetric positive definite gain matrix which is the solution to the matrix Ricatti equation must be computed at each update cycle.

Colburn, B. K.↗

Effect of polarization on superfluidity in low density neutron matter

The singlet-state quasi-particle interaction in neutron matter is examined on the basis of results of a detailed evaluation of the Landau Fermi-liquid parameters for pure neutron effects, including polarization effects. This means that the interaction induced by exchange of density and spin-density excitations is taken into account. It is shown that polarization actually works to suppress the pairing matrix elements, owing to the spin dependence of the quasi-particle interaction and, ultimately, the balance of attraction, repulsion, and spin dependence in the fundamental two-neutron interaction. Since the isotropic energy gap and the condensation energy in low-density neutron-star matter are extremely sensitive functions of the pairing matrix elements, they will also be suppressed by the polarizability of the neutron medium.

Clark, J. W.↗

Comparison of the Sensitivity of Surface Downward Longwave Radiation to Changes in Water Vapor at Two High Elevation Sites

Among the potential reasons for enhanced warming rates in many high elevation regions is the nonlinear relationship between surface downward longwave radiation (DLR) and specific humidity (q). In this study we use ground-based observations at two neighboring high elevation sites in Southwestern Colorado that have different local topography and are 1.3 kilometers apart horizontally and 348 meters vertically. We examine the spatial consistency of the sensitivities (partial derivatives) of DLR with respect to changes in q, and the sensitivities are obtained from the Jacobian matrix of a neural network analysis. Although the relationship between DLR and q is the same at both sites, the sensitivities are higher when q is smaller, which occurs more frequently at the higher elevation site. There is a distinct hourly distribution in the sensitivities at both sites especially for high sensitivity cases, although the range is greater at the lower elevation site. The hourly distribution of the sensitivities relates to that of q. Under clear skies during daytime, q is similar between the two sites, however under cloudy skies or at night, it is not. This means that the DLR-q sensitivities are similar at the two sites during daytime but not at night, and care must be exercised when using data from one site to infer the impact of water vapor feedbacks at another site, particularly at night. Our analysis suggests that care should be exercised when using the lapse rate adjustment to infill high frequency data in a complex topographical region, particularly when one of the stations is subject to cold air pooling as found here.

elevation↗

Sensitivity of Next-Generation CMB Surveys to Neutrinos and Other Light Relics

Neutrinos and other light relics leave characteristic imprints in the cosmic microwave background anisotropies, making their observation a sensitive probe of the particle content and thermal history of the early universe. The energy density in these relativistic species is parameterized by their effective number $N_\mathrm{eff}$. Measuring this parameter at the percent level, which is a long-standing science goal of CMB-S4 and other experiments, would test a wide range of well-motivated physics within and beyond the Standard Model of particle physics. In this paper, we present Fisher-matrix forecasts of the projected sensitivity to $N_\mathrm{eff}$ of several CMB-S4 survey configurations considered during its extensive design phase. The conceptual design reaches $σ(N_\mathrm{eff}) < 0.03$ over its seven-year observing period, while the revised configuration achieves the same precision over a longer timescale. We complement these results with a cosmic-variance-limited survey over the same multipole range to quantify the room for improvement accessible with additional instrumental, observational, and theoretical efforts. Finally, we discuss the broad implications of precise $N_\mathrm{eff}$ measurements for the radiation sector, big bang nucleosynthesis, light thermal relics, and other early-universe physics. The forecasts presented in this work are performed with the publicly released DRAFT (Dark Radiation Anisotropy Flowdown Team) tool. It provides an end-to-end pipeline from simulated foreground maps and component separation to delensing and projected sensitivities for any cosmological parameter, and it can be directly applied to other cosmic microwave background survey designs.

Trendafilova, Cynthia [Case Western Reserve U., CE↗

Thermoluminescence and the origin of the dark matrix of Fayetteville and similar meteorites

The paper presents measurements of the induced thermoluminescence properties and carbon contents of the dark matrix and light clasts of six regolith breccias. For all of the meteorites, the dark matrix has a lower mean thermoluminescence sensitivity than the light clasts; the extent of the difference depends on the meteorite. The data suggest the formation of the dark matrix by comminution of the light clasts with the addition of a component, perhaps CM-like chondrites, with thermoluminescence properties distinct from those of ordinary chondrites.

Haq, Munir↗

Thermal stresses in composite tubes using complementary virtual work

This paper addresses the computation of thermally induced stresses in layered, fiber-reinforced composite tubes subjected to a circumferential gradient. The paper focuses on using the principle of complementary virtual work, in conjunction with a Ritz approximation to the stress field, to study the influence on the predicted stresses of including temperature-dependent material properties. Results indicate that the computed values of stress are sensitive to the temperature dependence of the matrix-direction compliance and matrix-direction thermal expansion in the plane of the lamina. There is less sensitivity to the temperature dependence of the other material properties.

Hyer, M. W.↗