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At least 109 records · Page 6

Evaluation of a multifiltration water reclamation subsystem to reclaim domestic clothes wash water

An evaluation has been performed of a multifiltration water reclamation subsystem to determine its capability to recover water from domestic clothes wash water. A total of 32.89 kg (72.5 lb) of clothes were washed during eight wash cycles which used 1.4 lb of detergent, 145 gallons of hot water and 133.9 gallons of cold water. Water recovered at a weighted average process rate of 3.81 gallons per hour met the majority of the 23 requirements established for potable water by the U.S. Public Health Service. Average power consumed during this evaluation was approximately 71 watt-hours per gallon of water recovered. Filter replacement, which was required primarily for the control of micro-organisms in the recovered water averaged 4.86 filters per 100 gallons of wash water processed. The subsystem removed approximately 98 percent and virtually 100 percent of the phosphates and surfactants, respectively, from the wash water.

Hall, J. B., Jr.↗

On particle track detectors

Aqueous sodium hydroxide is widely used to develop charged particle tracks in polycarbonate film, particularly Lexan. The chemical nature of the etching process for this system has been determined. A method employing ultra-violet absorbance was developed for monitoring the concentration of the etch products in solution. Using this method it was possible to study the formation of the etching solution saturated in etch products. It was found that the system super-saturates to a significant extent before precipitation occurs. It was also learned that the system approaches its equilibrium state rather slowly. It is felt that both these phenomena may be due to the presence of surfactant in the solution. In light of these findings, suggestions are given regarding the preparation and maintenance of the saturated etch solution. Two additional research projects, involving automated techniques for particle track analysis and particle identification using AgCl crystals, are briefly summarized.

Benton, E. V.↗

Domestic wash-water reclamation using an aerospace-developed water recovery subsystem

A prototype aerospace distillation water recovery subsystem was tested to determine its capability to recover potable water from domestic wash water. A total of 0.0994 cu m (26.25 gallons) of domestic wash water was processed over a 7-day period at an average process rate of 0.0146 cu m per day (3.85 gallons per day). The subsystem produced water that met all United States Public Health Standards for drinking water with the exception of two standards which could not be analyzed at the required sensitivity levels. Average energy consumption for this evaluation to maintain both the recovery process and microbial control in the recovered water was approximately 3366 kilowatt-hours per cubic meter (12.74 kilowatt-hours per gallon) of water recovered. This condition represents a worst case energy consumption since no attempt was made to recover heat energy in the subsystem. An ultraviolet radiation cell installed in the effluent line of the subsystem was effective in controlling coliform micro-organisms within acceptable levels for drinking water. The subsystem recovered virtually 100 percent of the available water in the waste-water process. In addition, the subsystem removed 99.6 percent and 98.3 percent of the surfactants and phosphate, respectively, from the wash water.

Hall, J. B., Jr.↗

Evaluation of RO modules for the SSP ETC/LSS.

During the past eight years the NASA Manned Spacecraft Center has supported the development of an Integrated Water and Waste Management System for use in the Space Station Prototype (SSP) Environmental Thermal Control/Life-Support System (ETC/LSS). This system includes the reverse osmosis (RO) process for recycling wash water and the compression distillation process for recovering useable water from urine, urinal flush water, humidity condensate, commode flush water and the wash water concentrated by RO. This paper summarizes the experimental work performed during the past four years to select the best commercially available RO module for this system and to also define which surfactants and germicides are most compatible with the selected module.

Jasionowski, W. J.↗

Evaluation of proposed Skylab and SSP soap products.

Four candidate cleansing agents evaluated in terms of potential hazards to crew members included two soaps (Neutrogena bar soap and Olive Leaf Liquid), one nonfoaming surfactant (Miranol JEM), and one laundry detergent (sodium dodecylbenzene sulfonate). None of the four exhibited adverse dermatological effects from skin patch tests or supported growth of potentially pathogenic microorganisms. Aqueous solutions of Neutrogena did support a mold species. Neutrogena and Miranol JEM were used in a simulated Skylab personal hygiene regimen with no adverse effects on skin or skin microflora. Based on our results, each of these agents appear to be a promising candidate material for the use intended.

Durfee, R. L.↗

Polyimide foam for the thermal insulation and fire protection

The preparation of chemically resistant and flame retardant foams from polyfunctional aromatic carboxylic acid derivatives and organic polyisocyanates is outlined. It was found that polyimide foams of reproducible density above 1 lb./ft. and below 6 lbs./cu ft. can be obtained by employing in the reaction of least 2% by weight of siloxane-glycol copolymer as a surfactant which acts as a specific density control agent. Polyimide foams into which reinforcing fibers such as silicon dioxide and carbon fibers may be incorporated were also produced.

Rosser, R. W.↗

Low density polybenzimidazole foams

A description is presented of the relationship between prepolymer purity, processing parameters, and additives. The studies included the investigation of the effects of an addition of surfactants and fibers. Changes in foam characteristics due to variations in the cure and postcure schedules were also explored. A direct relationship was established between the amount of fiber additive and the resulting foam density.

Kourtides, D. A.↗

Effect of processing variables on the thermophysical properties of polybenzimidazole foams

The relationships are described among prepolymer purity, processing parameters, and additives to the thermophysical and chemical properties of polybenzimidazole foams in the density range from 24 to 80 kg/cu m. Foam properties are shown to be affected by differences in prepolymer purity, curing schedule, and the presence of additives in the foam. High-temperature compressive properties were improved by postcuring at 527 C. Surfactant additives were found to improve uniformity of cell size. Foams were characterized according to high-temperature mechanical properties, density, porosity, thermal diffusivity, thermal conductivity, and specific heat.

Kourtides, D. A.↗

Wash water waste pretreatment system study

The use of real wash water had no adverse effect on soap removal when an Olive Leaf soap based system was used; 96 percent of the soap was removed using ferric chloride. Numerous chemical agents were evaluated as antifoams for synthetic wash water. Wash water surfactants used included Olive Leaf Soap, Ivory Soap, Neutrogena and Neutrogena Rain Bath Gel, Alipal CO-436, Aerosol 18, Miranol JEM, Palmeto, and Aerosol MA-80. For each type of soapy wash water evaluated, at least one antifoam capable of causing nonpersistent foam was identified. In general, the silicones and the heavy metal ions (i.e., ferric, aluminum, etc.) were the most effective antifoams. Required dosage was in the range of 50 to 200 ppm.

Source record↗

Thermocapillary flows and their stability

Steady convective flows for geometries of varying complexity are described. This in general involves the solution of nonlinear free boundary problems. The stability of these flows were determined to more complicated (perhaps time dependent) modes of fluid motion. These include shear flow and free surface instability modes, with possible coupling between them. The effect of surface chemical species is described, including impurities which act as surfactants and insoluble oxide films, on the convective patterns and their stability.

Davis, S.↗

The Marangoni effect and translation of free non-deformable drops

A model is presented for flow caused by interface tension gradients, the so called Marangoni effect, on a free, nondeformable drop. A free drop, initially at rest, undergoes a translation motion upon the action of surface flow. The experiments carried out by injecting a drop with surfactants, which induce an interface tension gradient, are in good agreement with the theoretical model proposed.

Chifu, E.↗

Partial Analysis of Insta-Foam

Insta-Foam, used as a thermal insulator for the non-critical area of the external tank during the prelaunch phase to minimize icing, is a two-component system. Component A has polyisocyanates, blowing agents, and stabilizers; Component B has the polyols, catalysts, blowing agents, stabilizers and fire retardant. The blowing agents are Freon 11 and Freon 12, the stabilizers are silicone surfactants, the catalysts are tertiary amines, and the fire retardant is tri-(beta-chloro-isopropyl) phosphate (PCF). High performance liquid chromatography (HPLC) was quantitatively identified polyols and PFC.

Chou, L. W.↗

The ball bearing as a rheological test device

An angular-contact ball bearing provides an easily obtainable, precise mechanical system for rheological tests on thin films under high pressure. The test conditions are by definition similar to those found in practice. Accessible independent variables include size, pressure, bulk temperature, roughness, adsorbed surfactant, fluid type, fluid quantity, fluid supply rate, film thickness, entrainment velocity, transit time, and combined strain. Easily measured or inferred variables include slip, changes in film thickness with time (transients), strain rate, lubricant elastic modulus (thin film, high pressure), tractive force, lubricant chemical degradation rate, and lubricant degradation product. Methods for setting and obtaining these quantities in a bearing are discussed, together with experimental limitations on them.

Kingsbury, E.↗

Processing of sintered alpha SiC

Processing methods of sintered alpha SiC for engine applications are developed in a cost effective manner, using a submicron sized powder blended with sintering aids (boron and carbon). The processes for forming a green powder compact, such as dry pressing, cold isostatic pressing and green machining, slip casting, aqueous extrusion, plastic extrusion, and injection molding, are described. Dry pressing is the simplest route to component fabrication, and is carried out at approximately 10,000 psi pressure, while in the cold isostatic method the pressure could go as high as 20,000 psi. Surfactants are added to control settling rates and casting characteristics in the slip casting. The aqueous extrusion process is accomplished by a hydraulic ram forcing the aqueous mixture through a die. The plastic forming processes of extrusion and injection molding offer the potential of greater diversity in shape capacity. The physical properties of sintered alpha SiC (hardness, Young's modulus, shear modulus, and thermal diffusivity) are extensively tested. Corrosion resistance test results of silicon carbide are included.

Storm, R. S.↗

Coculture Production of Butanol by Clostridium Bacteria

Production of butanol by anaerobic fermentation of sugars enhanced by use of two Clostridium species, one of which feeds on metabolic product of other. Renewed interest in fermentation process for making butanol stimulated by potential use of butanol as surfactant in enhanced oil recovery. Butanol also used as fuel or as chemical feedstock and currently produced synthetically from petroleum.

Bergstrom, S. L.↗

Development of a Persistent Chemical Agent Simulator System (PCASS)

The development of a persistent chemical agent simulation system (PCASS) is described. This PCASS is to be used for the military training of troops to simulate actual chemical warfare. The purpose of this system is to facilitate in the determination of chemical contamination and effectiveness of decontamination for training purposes. The fluorescent tracer employed has no daylight activation, but yet is easily removed with a decontaminate solution or water and surfactants. Also employed is a time delayed color developing system. When an individual is subjected to the PCASS and does not decontaminate adequately, red blotches or red coloration will develop as a function of time and temperature. The intent of this is to simulate the delayed chemical reaction of mustard contaminates.

Mcginness, W. G.↗

Production of large-particle-size monodisperse latexes

The research program achieved two objectives: (1) it has refined and extended the experimental techniques for preparing monodisperse latexes in quantity on the ground up to a particle diameter of 10 microns; and (2) it has demonstrated that a microgravity environment can be used to grow monodisperse latexes to larger sizes, where the limitations in size have yet to be defined. The experimental development of the monodisperse latex reactor (MLR) and the seeded emulsion polymerizations carried out in the laboratory prototype of the flight hardware, as a function of the operational parameters is discussed. The emphasis is directed towards the measurement, interpretation, and modeling of the kinetics of seeded emulsion polymerization and successive seeded emulsion polymerization. The recipe development of seeded emulsion polymerization as a function of particle size is discussed. The equilibrium swelling of latex particles with monomers was investigated both theoretically and experimentally. Extensive studies are reported on both the type and concentration of initiators, surfactants, and inhibitors, which eventually led to the development of the flight recipes. The experimental results of the flight experiments are discussed, as well as the experimental development of inhibition of seeded emulsion polymerization in terms of time of inhibition and the effect of inhibitors on the kinetics of polymerization.

Vanderhoff, J. W.↗

Physical phenomena in containerless glass processing

Flight experiments are planned on drops containing bubbles. The experiments involve stimulating the drop via non-uniform heating and rotation. The resulting trajectories of the bubbles as well as the shapes of the drops and bubble will be videotaped and analyzed later frame-by-frame on the ground. Supporting ground based experiments are planned in the area of surface tension driven motion of bubbles, the behavior of compound drops settling in an immiscible liquid and the shapes and trajectories of large bubbles and drops in a rotating liquid. Theoretical efforts will be directed at thermocapillary migration of drops and bubbles, surfactant effects on such migration, and the behavior of compound drops.

Subramanian, R. Shankar↗