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At least 109 records · Page 6

Fuel Cycle Performance of Fast Spectrum Molten Salt Reactor Designs

In the search for new ways to generate low-carbon, reliable base-load power, a resurgence of interest in advanced nuclear energy technologies, including Molten Salt Reactors (MSRs), has produced multiple new conceptual MSRs including fast neutron spectrum designs. The fuel cycle performance of four historical fast MSR designs is analyzed using a recently developed SCALE/TRITON 6.2.4 Alpha with a continuous online reprocessing functionality. The fast spectrum and continuous feed and removal of material enable these concepts to have remarkable fuel cycle metrics: (1) resource utilization is approximately 18 times better than for a typical low-enriched thermal spectrum once-through fuel cycle (i.e., from approximately 180 t/GWe-year to 1 t/GWe-year); (2) fast MSRs generate approximately 25 times less nuclear waste than the current once-through fuel cycle. These metrics are consistent with the Evaluation and Screening Study, which produced a technology-agnostic quantification of the characteristic performance of alternate fuel cycles. Additionally, full-core and unit cell transport models were created and compared to verify the viability of using simplified unit cell geometries for long-term depletion simulation. The unit cell approximation provided a speedup of 20 times relative to the full-core simulation, with depleted mass relative error for major isotopes of less than 2%. Additional fast MSRs design and analysis challenges associated with different fuel cycles and the use of MSR technology are addressed and discussed.

Rykhlevskii, Andrei↗

SAM Co-Development to Support Fluoride-salt-cooled High-temperature Reactor Design and Licensing (CRADA 2018-18177 Final Report)

This project aims to raise the SAM code's technical and commercial maturity level to enable the Kairos Power ("Kairos") to use SAM to support its KP-FHR design analysis and licensing application. Argonne National Laboratory ("Argonne") has actively developed and maintained SAM, a modern system-level analysis tool for advanced nonlight water reactors safety analysis. Kairos is currently actively pursuing development of an FHR design and associated technology, and consequently requires a pedigreed safety analysis tool. The purpose of this project is to increase the maturity of the SAM code for the modeling and simulation of the KP-FHR design, thus enabling its use in safety analyses that support licensing application. Argonne will primarily be responsible for software design, development, and testing; while Kairos will be responsible for software requirements, assessment of software capabilities, needs, gaps, and priorities, and development of proprietary models. The research and development activities for the joint SAM development project include: a series of identification and prioritization studies on design characteristics, event sequences, relevant phenomena, and software capabilities; SAM capability enhancements for specific KP-FHR systems and components; performing code verification and validations; integrating uncertainty quantification (UQ), model calibration, and sensitivity analysis (SA) techniques in safety analyses; and raising the software quality rigor level for commercial-grade applications.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Assessment of the Neutronic and Fuel Cycle Performance of the Transatomic Power Molten Salt Reactor Design

This report presents results from a collaboration between Transatomic Power Corporation (TAP) and Oak Ridge National Laboratory (ORNL) to provide neutronic and fuel cycle analysis of the TAP core design through the Department of Energy Gateway for Accelerated Innovation in Nuclear (GAIN) Nuclear Energy Voucher program. The TAP concept is a molten salt reactor using configurable zirconium hydride moderator rod assemblies to shift the neutron spectrum in the core from mostly epithermal at beginning of life to thermal at end of life. Additional developments in the ChemTriton modeling and simulation tool provide the critical moderator-to-fuel ratio searches and time-dependent parameters necessary to simulate the continuously changing physics in this complex system. The implementation of continuous-energy Monte Carlo transport and depletion tools in ChemTriton provide for full-core three-dimensional modeling and simulation. Results from simulations with these tools show agreement with TAP-calculated performance metrics for core lifetime, discharge burnup, and salt volume fraction, verifying the viability of reducing actinide waste production with this concept. Additional analyses of mass feed rates and enrichments, isotopic removals, tritium generation, core power distribution, core vessel helium generation, moderator rod heat deposition, and reactivity coeffcients provide additional information to make informed design decisions. This work demonstrates capabilities of ORNL modeling and simulation tools for neutronic and fuel cycle analysis of molten salt reactor concepts.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Application of Analytical Hierarchy Process for Narrowing Down Nep Candidate Reactor Designs

NASA is currently studying the possibility of human exploration of Mars in the late 2030s timeframe using a hybrid nuclear electric propulsion (NEP)/chemical propulsion system. Present analyses indicate such a mission could require a reactor power system in the range of 2 to 6 MWe operating for approximately 3 years. At present, the Technology Readiness Levels (TRL) of key NEP technologies are still low, implying that significant technology development activities must be undertaken prior to making informed design selections for an integrated propulsion system. NASA’s Space Nuclear Propulsion (SNP) project has recently undertaken an in-depth effort to identify NEP candidate technologies and determine the required developmental work to mature these technologies to the point where they could realistically support the design and assembly of a full NEP system. A version of the Analytical Hierarchy Process is being employed to narrow the technology candidates for SNP investment planning. This multi-attribute decision-making process relies on quantified technical inputs and the judgement of Subject Matter Experts (SMEs) to evaluate technology options against key technical and programmatic Figures-of-Merit (FOM) at the subsystem and optimized system level. The process and an example evaluation of nuclear fuel/moderator combinations in a sodium heat pipe honeycomb-geometry reactor concept are described. The evaluation and analysis methodology described in this paper can be employed for pairwise comparisons between reactor concepts and technology choices as new data become available.

Dasari V Rao↗

Reactor design and integration with product detection to accelerate screening of electrocatalysts for carbon dioxide reduction

Identifying new catalyst materials for complex reactions such as the electrochemical reduction of CO 2 poses substantial instrumentation challenges due to the need to integrate reactor control with electrochemical and analytical instrumentation. Performing accelerated screening to enable exploration of a broad span of catalyst materials poses additional challenges due to the long time scales associated with accumulation of reaction products and the detection of the reaction products with traditional separation-based analytical methods. The catalyst screening techniques that have been reported for combinatorial studies of (photo)electrocatalysts do not meet the needs of CO 2 reduction catalyst research, prompting our development of a new electrochemical cell design and its integration to gas and liquid chromatography instruments. To enable rapid chromatography measurements while maintaining sensitivity to minor products, the electrochemical cell features low electrolyte and head space volumes compared to the catalyst surface area. Additionally, the cell is operated as a batch reactor with electrolyte recirculation to rapidly concentrate reaction products, which serves the present needs for rapidly detecting minor products and has additional implications for enabling product separations in industrial CO 2 electrolysis systems. To maintain near-saturation of CO 2 in aqueous electrolytes, we employ electrolyte nebulization through a CO 2 -rich headspace, achieving similar gas-liquid equilibration as vigorous CO 2 bubbling but without gas flow. The instrument is demonstrated with a series of electrochemical experiments on an Au-Pd combinatorial library, revealing non-monotonic variations in product distribution with respect to catalyst composition. The highly integrated analytical electrochemistry system is engineered to enable automation for rapid catalyst screening as well as deployment for a broad range of electrochemical reactions where product distribution is critical to the assessment of catalyst performance.

47 OTHER INSTRUMENTATION↗

ECAR-5021 Source Term Estimates for SCO Micro-Reactor Designs

The purpose of this document is to provide source term estimates and the associated technical basis for Strategic Capabilities Office (SCO) microreactor designs that use TRISO fuel. This estimate can be used for relevant environmental and safety analyses that will be done as part of the project for all of the selected suppliers for a safety design strategy. This is a combined quantitative and qualitative analysis.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Edible foodstuffs and bio reactor design

Methods of production of edible filamentous fungal biomat formulations are provided as standalone protein sources and/or protein ingredients in foodstuffs as well as a one-time use or repeated use self-contained biofilm-biomat reactor comprising a container with at least one compartment and placed within the compartment(s), a feedstock, a fungal inoculum, a gas-permeable membrane, and optionally a liquid nutrient medium.

Kozubal, Mark A.↗

Edible foodstuffs and bio reactor design

Methods of production of edible filamentous fungal biomat formulations are provided as standalone protein sources and/or protein ingredients in foodstuffs as well as a one-time use or repeated use self-contained biofilm-biomat reactor comprising a container with at least one compartment and placed within the compartment(s), a feedstock, a fungal inoculum, a gas-permeable membrane, and optionally a liquid nutrient medium.

Kozubal, Mark A.↗

Edible foodstuffs and bio reactor design

Methods of production of edible filamentous fungal biomat formulations are provided as standalone protein sources and/or protein ingredients in foodstuffs as well as a one-time use or repeated use self-contained biofilm-biomat reactor comprising a container with at least one compartment and placed within the compartment(s), a feedstock, a fungal inoculum, a gas-permeable membrane, and optionally a liquid nutrient medium.

Kozubal, Mark A.↗

Edible foodstuffs and bio reactor design

Methods of production of edible filamentous fungal biomat formulations are provided as standalone protein sources and/or protein ingredients in foodstuffs as well as a one-time use or repeated use self-contained biofilm-biomat reactor comprising a container with at least one compartment and placed within the compartment(s), a feedstock, a fungal inoculum, a gas-permeable membrane, and optionally a liquid nutrient medium.

Kozubal, Mark A.↗

SFCOMPO-2.0: An OECD NEA database of spent nuclear fuel isotopic assays, reactor design specifications, and operating data

SFCOMPO-2.0 is the new release of the Organisation for Economic Co-operation and Development (OECD) Nuclear Energy Agency (NEA) database of experimental assay measurements. These measurements are isotopic concentrations from destructive radiochemical analyses of spent nuclear fuel (SNF) samples. We supplement the measurements with design information for the fuel assembly and fuel rod from which each sample was taken, as well as with relevant information on operating conditions and characteristics of the host reactors. These data are necessary for modeling and simulation of the isotopic evolution of the fuel during irradiation. SFCOMPO-2.0 has been developed and is maintained by the OECD NEA under the guidance of the Expert Group on Assay Data of Spent Nuclear Fuel (EGADSNF), which is part of the NEA Working Party on Nuclear Criticality Safety (WPNCS). Significant efforts aimed at establishing a thorough, reliable, publicly available resource for code validation and safety applications have led to the capture and standardization of experimental data from 750 SNF samples from more than 40 reactors. These efforts have resulted in the creation of the SFCOMPO-2.0 database, which is publicly available from the NEA Data Bank. Our paper describes the new database, and applications of SFCOMPO-2.0 for computer code validation, integral nuclear data benchmarking, and uncertainty analysis in nuclear waste package analysis are briefly illustrated.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Understanding flow dynamics in membrane distillation: Effects of reactor design on polarization

Optimization and design of full-scale membrane distillation (MD) systems usually require Sherwood and Nusselt correlations that are developed from lab-scale systems. However, entrance effects in lab-scale systems can significantly impact heat, mass and momentum transfer in the reactor, therefore affect the accuracy of the developed experimental Sherwood and Nusselt correlations. Here, Computational Fluid Dynamics (CFD) simulations using OpenFOAM are performed to understand the effects of right-angled bends and inlet design on flow dynamics, temperature and concentration polarization in MD systems. Simulation results show that the presence of right-angled bends and inlets with sudden expansions lead to the formation of Dean vortices. Dean vortices enhance perpendicular mixing in MD systems and reduce both temperature and concentration polarization. Temperature and concentration polarization coefficients in MD systems with right-angled bends and inlets with sudden expansions vary significantly for the same volumetric flow rate. Our studies show that lab-scale systems with the same volumetric flow rate but different designs lead to significantly different Nusselt and Sherwood correlations. Here, this study demonstrates the importance of CFD-informed design of lab-scale systems to minimize entrance effects and suppress Dean vortices for consistent model development and calibration across multiple scales.

42 ENGINEERING↗

Economics of Hybrid-Energy Systems and the Impact on Advanced Reactor Design and Operation

The economics of electricity production in the U.S. is changing with the introduction of recent federal regulations limiting carbon dioxide emissions in the electric power industry. This has already resulted in the closing of coal plants, plants which in the past to a degree served to balance production with daily variation in load. The resulting loss of electricity production is being made up with wind and solar renewables and gas-fired units, and with an increasing need for energy storage. It would appear that with the loss of the baseload component of the coal plants, the duty-cycle of the gas-fired units may necessarily increase, encroaching on the traditional nuclear plant domain with its inexpensive fuel. Gas plants are costly to operate on a continuous basis with relatively volatile fuel prices. It appears then that nuclear plants that are capable of flexible operation have the potential on an economic basis to displace gas-fired power units. For flexible operation with renewables advanced reactors have advantages over the current generation of pressurized water reactors (PWR) and the new small modular reactors (SMR). For PWRs and SMRs, pellet-cladding mechanical interaction, xenon poisoning, and thermal stress concentrations in structures place limits on the all-important response time for operation with renewables. These phenomena are, however, not as limiting for the liquid-metal fast reactor (LMR). This may permit greater power ramp rates than in a light water reactor which bestows an economic advantage in energy systems with renewables. An economic model is developed for studying electric grid options including plant mix and market rules for the case of a high renewable fraction. It returns the minimum cost solution from among a mix of plant types including nuclear, gas, and storage (i.e. hybrid energy systems) for a given fraction of electricity production by renewables. This model can be used to assess the economic advantage of nuclear plants over gas plants and advanced reactors over light water reactors in an electric grid with a high fraction of renewables. The model has an explicit treatment of plant dynamic effects, an important feature for analysis of hybrid energy systems with a renewables production component that is unpredictable and uncontrollable.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Thermal-striping analysis methodology for sodium-cooled reactor design

Computational fluid dynamics simulations have been performed to study the applicability of engineering CFD methods for thermals striping analysis. Thermal striping is the fluctuating temperature profile in a solid caused by fluctuating fluid temperature, and the resulting fluctuating thermal stresses cause high cycle fatigue and eventual material failure. Here this study presents the methodology for thermal striping analysis that including a transient conjugate heat transfer RANS model and benchmark the results against a sodium triple jet experiment. The multiphysics calculations are implemented to analyze the thermal stresses in the solid domain caused by the coupled heat transfer between the fluid and solid domains. Validation data from a liquid sodium triple jet experiment include time-averaged temperature measurements and power spectra of the temperature signal. The numerical results agree well with these experimental measures, demonstrating key features such as the dominant frequency of temperature fluctuations. The applicability of a low-cost wall treatment method is demonstrated, enabling key computational savings. Finally, the performance of two finite element stress analysis software packages is compared, and the validity of the lower-cost method is confirmed. These results demonstrate the applicability of engineering methods for computational thermal striping calculations, enabling thermal striping estimations in large fluid systems such as the core of a Sodium-cooled nuclear reactor.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Fast Neutron Spectrum Potassium Worth for Space Power Reactor Design Validation

A variety of critical experiments were constructed of enriched uranium metal (oralloy ) during the 1960s and 1970s at the Oak Ridge Critical Experiments Facility (ORCEF) in support of criticality safety operations at the Y-12 Plant. The purposes of these experiments included the evaluation of storage, casting, and handling limits for the Y-12 Plant and providing data for verification of calculation methods and cross-sections for nuclear criticality safety applications. These included solid cylinders of various diameters, annuli of various inner and outer diameters, two and three interacting cylinders of various diameters, and graphite and polyethylene reflected cylinders and annuli. Of the hundreds of delayed critical experiments, one was performed that consisted of uranium metal annuli surrounding a potassium-filled, stainless steel can. The outer diameter of the annuli was approximately 13 inches (33.02 cm) with an inner diameter of 7 inches (17.78 cm). The diameter of the stainless steel can was 7 inches (17.78 cm). The critical height of the configurations was approximately 5.6 inches (14.224 cm). The uranium annulus consisted of multiple stacked rings, each with radial thicknesses of 1 inch (2.54 cm) and varying heights. A companion measurement was performed using empty stainless steel cans; the primary purpose of these experiments was to test the fast neutron cross sections of potassium as it was a candidate for coolant in some early space power reactor designs.The experimental measurements were performed on July 11, 1963, by J. T. Mihalczo and M. S. Wyatt with additional information in its corresponding logbook. Unreflected and unmoderated experiments with the same set of highly enriched uranium metal parts were performed at the Oak Ridge Critical Experiments Facility in the 1960s and are evaluated in the International Handbook for Evaluated Criticality Safety Benchmark Experiments (ICSBEP Handbook) with the identifier HEU MET FAST 051. Thin graphite reflected (2 inches or less) experiments also using the same set of highly enriched uranium metal parts are evaluated in HEU MET FAST 071. Polyethylene-reflected configurations are evaluated in HEU-MET-FAST-076. A stack of highly enriched metal discs with a thick beryllium top reflector is evaluated in HEU-MET-FAST-069, and two additional highly enriched uranium annuli with beryllium cores are evaluated in HEU-MET-FAST-059. Both detailed and simplified model specifications are provided in this evaluation. Both of these fast neutron spectra assemblies were determined to be acceptable benchmark experiments. The calculated eigenvalues for both the detailed and the simple benchmark models are within ~0.26 % of the benchmark values for Configuration 1 (calculations performed using MCNP6 with ENDF/B-VII.1 neutron cross section data), but under-calculate the benchmark values by ~7s because the uncertainty in the benchmark is very small: ~0.0004 (1s); for Configuration 2, the under-calculation is ~0.31 % and ~8s. Comparison of detailed and simple model calculations for the potassium worth measurement and potassium mass coefficient yield results approximately 70 – 80 % lower (~6s to 10s) than the benchmark values for the various nuclear data libraries utilized. Both the potassium worth and mass coefficient are also deemed to be acceptable benchmark experiment measurements.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Thermochemical Heat Storage for Concentrated Solar Power: Thermochemical System Reactor Design for Thermal Energy Storage

Thermal energy storage (TES) is an integral part of a concentrated solar power (CSP) system. It enables plant operator to generate electricity beyond on sun hours and supply power to the grid to meet peak demand. Current CSP sensible heat storage systems employ molten salts as both the heat transfer fluid and the heat storage media. These systems have an upper operating tempera ture limit of around 400°C. Future TES systems are expected to operate at temperatures between 600°C–1000°C for higher thermal efficiencies which should result in lower electricity cost. To meet future operating temperature and electricity cost requirements, a TES concept utilizing thermochemical cycles (TCs) based on multivalent solid oxides was proposed. The system employs a pair of reduction and oxidation (REDOX) reactions to store and release heat. In the storage step, hot air from the solar receiver is used to reduce the oxidation state of an oxide cation, e.g. Fe 3+ to Fe 2+ . Heat energy is thus stored as chemical bonds and the oxide is “charged”. To discharge the stored energy, the reduced oxide is re-oxidized in air and heat is released. Air is used as both the heat transfer fluid and reactant and no storage of fluid is needed. This project investigated the engineering and economic feasibility of this proposed TES concept. The DOE storage cost and LCOE targets are $\$$15/kWh and $\$$0.09/kWh respectively. Sixteen pure oxides cycles were identified through thermodynamics calculations and literature information. Data showed the kinetics of re-oxidation of the various oxides to be a key barrier to implementing the proposed concept. A down selection was carried out based on operating temperature, materials costs and preliminary laboratory measurements. Cobalt oxide, manganese oxide and barium oxide were selected for developmental studies to improve their REDOX reaction kinetics. A novel approach utilizing mixed oxides to improve the REDOX kinetics of the selected oxides was proposed. It partially replaces some of the primary oxide cations with selected secondary cations. This causes a lattice charge imbalance and increases the anion vacancy density. Such vacancies enhance the ionic mass transport and lead to faster re-oxidation. Re oxidation fraction of Mn 3 O 4 → Mn 2 O 3 and CoO → Co 3 O 4 was improved by up to 16 fold through the addition of a secondary oxide. However, no improvement was obtained in barium based mixed oxides. In addition to enhancing the short term re-oxidation kinetics, it was found that the use of mixed oxides also help to stabilize or even improve the TES properties after long term thermal cycling. Part of this improvement could be attributed to a reduced grain size in the mixed oxides. Based on the measurement results, manganese-iron, cobalt-aluminum and cobalt iron mixed oxides have been proposed for future engineering scale demonstration. Using the cobalt and manganese mixed oxides, we were able to demonstrate charge and discharge of the TES media in both a bench top fixed bed and a rotary kiln-moving bed reactor.

14 SOLAR ENERGY↗