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At least 109 records · Page 6

Bulk Production of Any Ratio 12 C: 13 C Turbostratic Flash Graphene and Its Unusual Spectroscopic Characteristics

As graphene enjoys worldwide research and deployment, the biological impact, geologic degradation, environmental retention, and even some physical phenomena remain less well studied. Bulk production of 13 C-graphene yields a powerful route to study all of these questions. Gram scale synthesis of high quality and high purity turbostratic flash graphene with varying amounts of 13 C-enrichment, from 5% to 99% is reported here. Here, the material is characterized by solid state nuclear magnetic resonance spectroscopy, Raman spectroscopy, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy and inductively coupled plasma mass spectrometry. Notably, an unusual enhancement in the Raman spectroscopic D’ peak is observed, resulting from the modification in vibrational frequency through isotopic enrichment favoring intravalley phonon scattering modes. While the IR absorbance spectrum of graphene is for the most part silent, we prepare here 13 C-enhanced graphene samples that show a large aromatic 12 C= 13 C stretch that reveals this IR-active mode.

01 COAL, LIGNITE, AND PEAT↗

Exascale models of stellar explosions: Quintessential multi-physics simulation

The ExaStar project aims to deliver an efficient, versatile, and portable software ecosystem for multi-physics astrophysics simulations run on exascale machines. The code suite is a component-based multi-physics toolkit, built on the capabilities of current simulation codes (in particular Flash-X and Castro), and based on the massively parallel adaptive mesh refinement framework AMReX. It includes modules for hydrodynamics, advanced radiation transport, thermonuclear kinetics, and nuclear microphysics. The code will reach exascale efficiency by building upon current multi- and many-core packages integrated into an orchestration system that uses a combination of configuration tools, code translators, and a domain-specific asynchronous runtime to manage performance across a range of platform architectures. The target science includes multi-physics simulations of astrophysical explosions (such as supernovae and neutron star mergers) to understand the cosmic origin of the elements and the fundamental physics of matter and neutrinos under extreme conditions.

79 ASTRONOMY AND ASTROPHYSICS↗

Molecular weight growth by the phenyl + cyclopentadienyl reaction: Well-skipping, ring-opening, and dissociation

Radical-radical reactions contribute to molecular weight growth of polycyclic aromatic hydrocarbons (PAHs), but their role is not well understood. The phenyl (Ph, C 6 H 5 ) + cyclopentadienyl (C 5 H 5 ) reaction has not been studied but can serve as a surrogate reaction for many reactions of larger aryl-σ radicals with resonance-stabilized π-radicals. The adducts of these reactions easily lose an H atom to produce a new π-radical. Here, through a combination of dilute flash pyrolysis experiments, theory, and simulation, we find that for the title reaction, substantial Ph—C 5 H 4 + H is formed, dominantly by a well-skipping pathway, at conditions around 30 Torr and 1400 K. This radical is thermally stable at moderate temperatures but decomposes at higher temperatures following ring opening of the 5-member ring. Products corresponding to the loss of H, C 2 H 2 , and C 3 H 3 are observed experimentally. Calculation of the C 11 H 9 potential energy surface affirms that these are expected decomposition products and reveals multiple possible pathways.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Exploring the Use of Radar for Physically-Based Nowcasting of Lightning Cessation

NASA's Marshall Space Flight Center and the University of Alabama in Huntsville (UAHuntsville) are collaborating with the 45th Weather Squadron (45WS) at Cape Canaveral Air Force Station (CCAFS) to enable improved nowcasting of lightning cessation. This project centers on use of dual-polarimetric radar capabilities, and in particular, the new C-band dual polarimetric weather radar acquired by the 45WS. Special emphasis is placed on the development of a physically-based operational algorithm to predict lightning cessation. While previous studies have developed statistically based lightning cessation algorithms driven primarily by trending in the actual total lightning flash rate, we believe that dual polarimetric radar variables offer the possibility to improve existing algorithms through the inclusion of physically meaningful trends reflecting interactions between in-cloud electric fields and ice-microphysics. Specifically, decades of polarimetric radar research using propagation differential phase has demonstrated the presence of distinct phase and ice crystal alignment signatures in the presence of strong electric fields associated with lightning. One question yet to be addressed is: To what extent can propagation phase-based ice-crystal alignment signatures be used to nowcast the cessation of lightning activity in a given storm? Accordingly, data from the UAHuntsville Advanced Radar for Meteorological and Operational Research (ARMOR) along with the NASA-MSFC North Alabama Lightning Mapping Array are used in this study to investigate the radar signatures present before and after lightning cessation. Thus far our case study results suggest that the negative differential phase shift signature weakens and disappears after the analyzed storms ceased lightning production (i.e., after the last lightning flash occurred). This is a key observation because it suggests that while strong electric fields may still have been present, the lightning cessation signature was encompassed in the period of the polarimetric negative phase shift signature. To the extent this behavior is repeatable in other cases, even if only in a substantial fraction of those cases, the analysis suggests that differential propagation phase may prove to be a useful parameter for future lightning cessation algorithms. Indeed, a preliminary analysis of 15+ cases has shown additional indications of the weakening and disappearance of this ice alignment signature with lightning cessation. A summary of these case-study results is presented.

Schultz, Elise V.↗

The Kinematic and Microphysical Control of Lightning Rate, Extent and NOX Production

The Deep Convective Clouds and Chemistry (DC3) experiment seeks to quantify the relationship between storm physics, lightning characteristics and the production of nitrogen oxides via lightning (LNOx). The focus of this study is to investigate the kinematic and microphysical control of lightning properties, particularly those that may govern LNOx production, such as flash rate, type and extent across Alabama during DC3. Prior studies have demonstrated that lightning flash rate and type is correlated to kinematic and microphysical properties in the mixed-phase region of thunderstorms such as updraft volume and graupel mass. More study is required to generalize these relationships in a wide variety of storm modes and meteorological conditions. Less is known about the co-evolving relationship between storm physics, morphology and three-dimensional flash extent, despite its importance for LNOx production. To address this conceptual gap, the NASA Lightning Nitrogen Oxides Model (LNOM) is applied to North Alabama Lightning Mapping Array (NALMA) and Vaisala National Lightning Detection Network(TM) (NLDN) observations following ordinary convective cells through their lifecycle. LNOM provides estimates of flash rate, flash type, channel length distributions, lightning segment altitude distributions (SADs) and lightning NOx production profiles. For this study, LNOM is applied in a Lagrangian sense to multicell thunderstorms over Northern Alabama on two days during DC3 (21 May and 11 June 2012) in which aircraft observations of NOx are available for comparison. The LNOM lightning characteristics and LNOX production estimates are compared to the evolution of updraft and precipitation properties inferred from dual-Doppler and polarimetric radar analyses applied to observations from a nearby radar network, including the UAH Advanced Radar for Meteorological and Operational Research (ARMOR). Given complex multicell evolution, particular attention is paid to storm morphology, cell mergers and possible dynamical, microphysical and electrical interaction of individual cells when testing various hypotheses.

Carey, Lawrence↗

Code-to-code comparison and validation of the radiation-hydrodynamics capabilities of the FLASH code using a laboratory astrophysical jet

The potential for laser-produced plasmas to yield fundamental insights into high energy density physics (HEDP) and deliver other useful applications can sometimes be frustrated by uncertainties in modeling the properties and behavior of these plasmas using radiation-hydrodynamics codes. In an effort to overcome this and to corroborate the accuracy of the HEDP capabilities in the publicly available FLASH radiation-hydrodynamics code, we present detailed code-to-code comparisons between FLASH and the HYDRA code developed at Lawrence Livermore National Laboratory using previously published HYDRA simulations from Grava et al. [Phys. Rev. E 78, 016403 (2008)]. That study describes a laser experiment that produced a jet-like feature that the authors compare to astrophysical jets. Importantly, the Grava et al. [Phys. Rev. E 78, 016403 (2008)] experiment included detailed x-ray interferometric measurements of electron number densities and a time-integrated measurement of the soft x-ray spectrum. Despite markedly different methods for treating the computational mesh, and different equations of state and opacity models, the FLASH results resemble the results from HYDRA and, most importantly, the experimental measurements of electron density. Having validated the FLASH code in this way, we use the code to further investigate and understand the formation of the jet seen in the Grava et al. [Phys. Rev. E 78, 016403 (2008)] experiment and discuss its relation to the Wan et al. [Phys. Rev. E 55, 6293 (1997)] experiment at the NOVA laser.

Orban, Chris (ORCID:0000000312004538)↗

Global Patterns of Lightning Properties Derived by LIS

The Lightning Imaging Sensor LIS aboard the TRMM satellite provides unmatched empirical data of the global lightning distribution (up to approx.35deg S/N) since end of 1997. Climatological flash rate densities derived from LIS are standard references, e.g. for flash rate parameterizations used in GCMs. It is known that flash characteristics are quite variable, and that various quantities (like the flash energy or the NOx production per flash) vary considerably, statistically as well as systematically on regional and seasonal scales. LIS provides information beyond flash counts, in particular radiance and flash footprint. Here we present an analysis of global patterns of various lightning properties derived from LIS, in relation to the number of flashes. These normalized flash characteristics show consistent spatial patterns of regions with "strong" versus regions with "weak" lightning. Most striking is a clear land-ocean contrast, with oceanic flashes being "stronger" than continental flashes. But also over continents, flash strength shows systematic variations. Highest continental values are found over the US, while values over South America and India are quite low. These regional variations cannot be simply parameterized as function of latitude. Information on spatial patterns of mean flash "strength", though rather qualitative up to now, is potentially a valuable input for improving empirical parameterizations based on flash counts (like precipitation or lightning NOx). Further investigation is in progress to come to a more physical and quantitative understanding of the spatial patterns of the different LIS properties. In particular, it has to be checked how far they could be related to established lightning properties (like energy or the fraction of intra-cloud to cloud-to-ground flashes) or to meteorological quantities (like CAPE).

Beirle, S.↗

The influence of intake flow and coolant temperature on gasoline spray morphology during early-injection DISI engine operation

Multi-hole gasoline injectors operating at conditions spanning throttled early-intake stroke operation produce spray plumes that either remained separated or merge and collapse due to flash boiling. Flash boiling occurs due to the sudden expansion of gas bubbles in the liquid fuel at high fuel temperature and low ambient pressure. This study records high-speed images of spray-morphology changes due to in-cylinder flow, thereby revealing operating conditions that do and do not affect the self-induced morphology observed in quiescent vessels. Specifically, in a central-injection, four-valve, high-tumble engine, where the thermodynamic state and in-cylinder cross flow are dynamic. Motivated by cold start and hot restart operation, the fuel pressure, coolant temperature, in-cylinder air pressure, and engine rpm were systematically varied over relevant operating conditions, which bracketed the range from non- to flash-boiling sprays. The results reveal the operating conditions at which the in-cylinder cross flow disrupts the spray morphology as well as the extent of the disruption. At 650 rpm, the spray morphology was similar to that observed in quiescent vessels at nominally equivalent fuel temperature and in-cylinder pressure, indicating that the spray’s self-induced entrainment flow dominated the in-cylinder flow. However, for fuel temperature and ambient pressure near the transition between non- and flash-boiling, the intake cross flow at higher engine speed (1950 rpm) significantly disrupted the spray morphology. The high cross-flow velocity appears to induce plume merging and collapse, whereas none was evident at low rpm (650 rpm). This study led to the postulate that the spray merging and collapse are governed by the rate of atomization near the nozzle exit, presumed to be controlled by either or both aerodynamic atomization and flash-boiling intensity. It would then follow that spray modeling in CFD requires atomization models that blend the effects of both physical processes.

42 ENGINEERING↗

Advances in Land Surface Models and Indicators for Drought Monitoring and Prediction

Millions of people across the globe are affected by droughts every year, and recent droughts have highlighted the considerable agricultural impacts and economic costs of these events. Monitoring the state of droughts depends on integrating multiple indicators that each capture particular aspects of hydrologic impact and various types and phases of drought. As the capabilities of land surface models and remote sensing have improved, important physical processes such as dynamic, interactive vegetation phenology, groundwater, and snowpack evolution now support a range of drought indicators that better reflect coupled water, energy, and carbon cycle processes. In this work, we discuss these advances, including newer classes of indicators that can be applied to improve the characterization of drought onset, severity, and duration. We utilize a new model-based drought reconstruction to illustrate the role of dynamic phenology and groundwater in drought assessment. Further, through case studies on flash droughts, snow droughts, and drought recovery, we illustrate the potential advantages of advanced model physics and observational capabilities, especially from remote sensing, in characterizing droughts.

Christa D Peters-lidard↗

Advances in Land Surface Models and Indicators for Drought Monitoring and Prediction

Millions of people across the globe are affected by droughts every year, and recent droughts have highlighted the considerable agricultural impacts and economic costs of these events. Monitoring the state of droughts depends on integrating multiple indicators that each capture particular aspects of hydrologic impact and various types and phases of drought. As the capabilities of land surface models and remote sensing have improved, important physical processes such as dynamic, interactive vegetation phenology, groundwater, and snowpack evolution now support a range of drought indicators that better reflect coupled water, energy, and carbon cycle processes. In this work, we discuss these advances, including newer classes of indicators that can be applied to improve the characterization of drought onset, severity, and duration. We utilize a new model-based drought reconstruction to illustrate the role of dynamic phenology and groundwater in drought assessment. Further, through case studies on flash droughts, snow droughts, and drought recovery, we illustrate the potential advantages of advanced model physics and observational capabilities, especially from remote sensing, in characterizing droughts.

Christa D Peters-lidard↗

Advances in Land Surface Models and Indicators for Drought Monitoring and Prediction

Millions of people across the globe are affected by droughts every year, and recent droughts have highlighted the considerable agricultural impacts and economic costs of these events. Monitoring the state of droughts depends on integrating multiple indicators that each capture particular aspects of hydrologic impact and various types and phases of drought. As the capabilities of land-surface models and remote sensing have improved, important physical processes such as dynamic, interactive vegetation phenology, groundwater, and snow pack evolution now support a range of drought indicators that better reflect coupled water, energy and carbon cycle processes. In this work, we discuss these advances, including newer classes of indicators that can be applied to improve the characterization of drought onset, severity and duration. We utilize a new model-based drought reconstruction to illustrate the role of dynamic phenology and groundwater in drought assessment. Further, through case studies on flash droughts, snow droughts, and drought recovery, we illustrate the potential advantages of advanced model physics and observational capabilities, especially from remote sensing, in characterizing droughts.

Drought↗

The Flash ADC system and PMT waveform reconstruction for the Daya Bay experiment

To better understand the energy response of the Antineutrino Detector (AD), the Daya Bay Reactor Neutrino Experiment installed a full Flash ADC readout system on one AD that allowed for simultaneous data taking with the current readout system. This paper presents the design, data acquisition, and simulation of the Flash ADC system, and focuses on the PMT waveform reconstruction algorithms. For liquid scintillator calorimetry, the most critical requirement to waveform reconstruction is linearity. Several common reconstruction methods were tested but the linearity performance was not satisfactory. A new method based on the deconvolution technique was developed with 1% residual non-linearity, which fulfills the requirement. Here, the performance was validated with both data and Monte Carlo (MC) simulations, and 1% consistency between them has been achieved.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

TIA: A forward model and analyzer for Talbot interferometry experiments of dense plasmas

Interferometry is one of the most sensitive and successful diagnostic methods for plasmas. However, owing to the design of most common interferometric systems, the wavelengths of operation and, therefore, the range of densities and temperatures that can be probed are severely limited. Talbot–Lau interferometry offers the possibility of extending interferometry measurements to x-ray wavelengths by means of the Talbot effect. While there have been several proof-of-concept experiments showing the efficacy of this method, it is only recently that experiments to probe High Energy Density (HED) plasmas using Talbot–Lau interferometry are starting to take place. To improve these experimental designs, we present here the Talbot-Interferometry Analyzer (TIA) tool, a forward model for generating and postprocessing synthetic x-ray interferometry images from a Talbot–Lau interferometer. Although TIA can work with any two-dimensional hydrodynamic code to study plasma conditions as close to reality as possible, this software has been designed to work by default with output files from the hydrodynamic code FLASH, making the tool user-friendly and accessible to the general plasma physics community. Here, the model has been built into a standalone app, which can be installed by anyone with access to the MATLAB runtime installer and is available upon request to the authors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

New insights from a global view of X-ray bursts

It is shown here that the behavior of nuclear burning on accreting neutron stars depends on the mass accretion rate per unit area sigma-dot, the temperature T, and the column density of accreted matter sigma, and is thus intrinsically a three-dimensional problem. The concepts of a nuclear fuel surface and an ignition surface in (sigma-dot, T, sigma) space is introduced. It is shown that certain cuts taken through the ignition surface correspond to particular physical situations. It is found that at high temperatures a succession of hydrogen flashes leads eventually to a pure helium flash. At low temperatures, compressional heating completely determines the burst behavior. Burst sources are expected to show highly erratic behavior if they lie near the boundaries of the H and He ignition surfaces, resolving a major discrepancy between the thermonuclear flash model and observations.

Fushiki, Ikko↗

The Influence of Environmental State on Lightning and Convective Parameter Distributions

A merged and highly reduced database of TRMM level 1 (precipitation radar, microwave imager, lightning) and NCEP reanalysis (basic state, radiative and surface flux) data has been assembled for three years of the TRMM mission. This allows direct examination of the dependence of convective spectra (as observed through radar reflectivity, microwave brightness temperature and lightning flash rate) on environmental basic states and anomalies. Such analysis may be more physically justified and instructive than traditional geographic and/or seasonal binning. The dependence of convective spectra on several environmental forcing parameters is presented, including surface Bowen ratio (sensible heat to total turbulent flux), net atmospheric radiative flux convergence and net atmospheric enthalpy flux convergence. The latter are basic drivers of net moisture convergence in simple quasi-equilibrium models of tropical atmospheric convection.

Boccippio, D.↗

Transformative Technology for FLASH Radiation Therapy

The general concept of radiation therapy used in conventional cancer treatment is to increase the therapeutic index by creating a physical dose differential between tumors and normal tissues through precision dose targeting, image guidance, and radiation beams that deliver a radiation dose with high conformality, e.g., protons and ions. However, the treatment and cure are still limited by normal tissue radiation toxicity, with the corresponding side effects. A fundamentally different paradigm for increasing the therapeutic index of radiation therapy has emerged recently, supported by preclinical research, and based on the FLASH radiation effect. FLASH radiation therapy (FLASH-RT) is an ultra-high-dose-rate delivery of a therapeutic radiation dose within a fraction of a second. Experimental studies have shown that normal tissues seem to be universally spared at these high dose rates, whereas tumors are not. While dose delivery conditions to achieve a FLASH effect are not yet fully characterized, it is currently estimated that doses delivered in less than 200 ms produce normal-tissue-sparing effects, yet effectively kill tumor cells. Despite a great opportunity, there are many technical challenges for the accelerator community to create the required dose rates with novel compact accelerators to ensure the safe delivery of FLASH radiation beams.

43 PARTICLE ACCELERATORS↗

Battery metal recycling by flash Joule heating

The staggering accumulation of end-of-life lithium-ion batteries (LIBs) and the growing scarcity of battery metal sources have triggered an urgent call for an effective recycling strategy. However, it is challenging to reclaim these metals with both high efficiency and low environmental footprint. We use here a pulsed dc flash Joule heating (FJH) strategy that heats the black mass, the combined anode and cathode, to >2100 kelvin within seconds, leading to ~1000-fold increase in subsequent leaching kinetics. There are high recovery yields of all the battery metals, regardless of their chemistries, using even diluted acids like 0.01 M HCl, thereby lessening the secondary waste stream. The ultrafast high temperature achieves thermal decomposition of the passivated solid electrolyte interphase and valence state reduction of the hard-to-dissolve metal compounds while mitigating diffusional loss of volatile metals. Life cycle analysis versus present recycling methods shows that FJH significantly reduces the environmental footprint of spent LIB processing while turning it into an economically attractive process

36 MATERIALS SCIENCE↗

Lightning Strike Distance Distribution Beyond a Preexisting Lightning Area

The 45th Weather Squadron (45 WS) asked the Applied Meteorology Unit (AMU) to review the 30-year-old, lightning stand-off distances of 5 nautical miles (nmi) for applicability to today's operations. This was based on the realization that previous lightning strike distance studies did not match how 45 WS issues lightning warnings (Roeder, 2008). The previous lightning distance studies were from the point of origin of the lightning or the average starting location that would tend to be in the core of the thunderstorm. However, the 45 WS issues lightning warnings based on the edge of a preexisting lightning area. Before beginning the AMU project, it took several years to develop a method to calculate a distance distribution beyond a preexisting area (Roeder, 2015). The AMU pulled Lightning Detection and Ranging (LDAR) sensor data from 1/1/2013 to 12/31/2013. This dataset consisted of 37 million individual source data points from the LDAR sensors. Only sources within 50 km north, south, east or west of the LDAR grid center were included in the dataset. This limited the use of LDAR data to that with the greatest accuracy of source detection and increased data processing. Points were grouped into flashes based on spatial and temporal criteria. Based on the sensitivity analysis the AMU performed on the flash clustering algorithm, a time value of 0.3 seconds was found to model flashes adequately. Distance parameters were tested from 1,500 to 7,500 meters (m) in 500 m increments. Distance parameters of both 3,000 m and 4,000 m produced results in the plotting tool that were most representative of the physical behavior of lightning. Thus statistics were gathered for the most representative of these spatial and temporal criteria on the flash size and the polygon expansion distance in order to find the correct data distributions. The best fit curves for the LDAR polygon expansion frequency vs. distances for both the 3 kilometer (km) and 4 km distance threshold values were exponential decay functions and had R2 values of > 0.998, indicating good model fits. The equations of the best fit curves were then used to calculate a desired safety radius of 4 nmi for either 3 km or 4 km distance threshold criteria. The AMU analysis concludes the safe reduction of the 5 nmi lightning warning circles to 4 nmi should improve the operational impact by 36% if based on distance from the center of the property area being protected. If based on the edge of the property being protected, then the reduction is 4.5 nmi to 4 nmi and the operational impact is decreased by 21%. For the 6 nmi lightning warning circles, the recommended 4 nmi stand-off distance will result in a safe reduction of operational impact of 31% if based on the center of the area being protected, or 16% if based on the edge of the property.

Flash clustering algorithm↗