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Photoionization source with a vacuum UV monochromator is used in ion reaction kinetics. Monochromator passes only the photon energies near the threshold of the selected ionization process. Absence of electron impact alleviates creation of different type ions that result in ion fragmentation.
Trace gas analysis using photoionization mass spectrometer
Radial wave functions and photoionization cross sections for neutral atoms from central potential model based on Slater and Klein-Brueckner approximations
Analytical photoionization mass spectrometer with argon gas filter between light source and monochrometer
Shock tube data on far ultraviolet photoionizing radiation flux in precursor plasma of blunt reentry vehicles
Photoionization coefficients and photoelectron impact excitation efficiencies in daytime ionosphere, noting role in dayglow
Cross sections for fluorescence production in carbon dioxide photoionization by 58.4 nm radiation, deriving emission spectra
Atomic N and C photoionization cross sections by shock tube vacuum UV spectrometry
Photoionization mass spectrometry, considering application to appearance potentials determination, ion-neutral reactions and gas analysis
An analysis was conducted of a gas window photoionization device for studying cosmic X-rays in the region 20 eV to 1 keV. The detecting element is an argon proportional counter whose window is a two-dimensional supersonic gas jet. Spectroscopic features of the incoming radiation can be determined by the choice of gas forming the jet (as well by the fluid dynamic parameters of the flow). The choice of gas can be made from pure substances and/or compounds with Z between 1 and 10. The counter walls can be prepared for selective analysis of the extreme ultraviolet radiation.
The measurements have been conducted in the spectral range from 600 to 2000 A. Integrated oscillator strengths were determined for a number of strong Rydberg transitions above 1200 A. From the photoionization curve the first adiabatic ionization potential was found to be 10.87 plus or minus 0.01 eV. As an aid in interpreting the absorption spectrum, theoretical calculations were made using a single-configuration self-consistent field procedure for the Rydberg states and a model which included mixing between the Rydberg and valence states.
Detailed photoionization calculations are used to examine the information conveyed by relative emission-line intensities in QSO spectra. It is found that the elemental abundances cannot be estimated with any assurance; but if ?conventional' values are assumed, then certain restrictions may be placed on the ionizing spectra and gas densities. In particular, the ratio between radiation density and gas density is determined. Narrow filaments or sheets of ionized gas seem to be indicated; these may be compressed regions behind shock fronts.
Demonstration of the importance of core polarizability in a case where cancellation is only moderate, with suggestion of an improvement to the scaled Thomas-Fermi (STF) wave functions of Stewart and Rotenberg (1965). The inclusion of dipole polarizability of the core for argon is shown to substantially improve the agreement between the theoretical and experimental photoionization cross sections for the ground-state configuration.
Photoions produced in methanol and formaldehyde by radiation in the spectral region 450-1150 A were analyzed mass spectrometrically, and their relative yields were determined as a function of wavelength. First ionization potentials were determined, and the ion yield curves were interpreted in terms of ionization processes in conjunction with other data. Fragment ions were detected on mass numbers of 31, 30, 29, 15, and 14 for methanol, and 29, 2, and 1 for formaldehyde. The associated appearance potentials were determined and were used to calculate heats of formation of the ions CH2OH(+) and HCO(+), and the radicals CH3, CH2, and HCO.
Photoionization cross sections for all levels belonging to the configurations of atoms and ions of aluminum, silicon, and argon have been calculated using Hartree-Fock bound-electron wave functions and close-coupling approximation free-electron wave functions. The results are presented in the form of a computationally convenient interpolation formula and should find wide astrophysical application.
The absorption coefficients of 1.15- and 3.39-micrometer radiation for a homogeneous H-He plasma have been measured in a temperature and electron density range where the major absorption mechanisms are electron-ion inverse bremsstrahlung and neutral-atom photoionization. Measurements were made behind both the incident and reflected shock waves in a driven tube by recording the laser intensity transmitted along the tube diameter as a function of time. The measured values compare well with those obtained from theoretical calculations for a gas in thermodynamic equilibrium.
Approximate values for the threshold energies, threshold cross sections, and energy dependence of the cross sections for K-shell photoionization are tabulated for H, He, C, N, O, Ne, Mg, Si, and S in all stages of ionization. The approximation of these data is based on the assumptions that the threshold energy is a simple function of the nuclear charge and the number of electrons present in the atom, and that the threshold values and energy dependence of the cross sections are determined only by the threshold energy.
Simplified photoionization calculations, considering quasar emission lines with ultraviolet rest-wavelengths, can be made including only hydrogen, helium, and carbon ions. With plausible assumptions about the helium abundance and ionizing spectral slope, estimates of the (radiation/gas) pressure ratio and carbon abundance are possible. Proportionality relations, showing the dependences of line ratios upon assumed parameters, may be useful in considering differences between individual spectra.