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At least 109 records · Page 6

Optical properties of cometary dust

The application of measured optical constants to the interaction of electromagnetic radiation with small cometary dust particles is discussed, with emphasis on the interpretation of cometary observations. It is found that in some spectral regions optical constants vary greatly with wavelength. The optical constants may be incorrect. Because of errors in measurement, or the application of the Kramers-Kronig relationship over too small a spectral region, or an improperly prepared sample, the derived optical constants may be in error. It is suggested that a full Kramers-Kronig analysis and application of the more important sum rules should be performed on any set of optical constants whose accuracy is important. Optical constants derived from the measurement of inhomogeneous materials, where the inhomogeneities are of comparable size to that of the beam of radiation used in the experiment, should not be used to predict the optical properties of small particles.

Lien, David J.↗

Optical properties of the Moon's surface.

Optical photometric properties of lunar surface, discussing brightness effects, solar wind, albedo, reflectivity, backscatter, chemical composition, ion bombardment effects, etc

OPTICAL PROPERTY↗

Measured physical and optical properties of the passive geodetic satellite /Pageos/ and Echo 1.

Two satellites used for geodesy, Pageos and Echo 1, have been observed in a continuing program since 1966 to determine the stability of their physical and optical properties. Measurements are made in the UBVRI spectral system. The amount of solar radiation reflected from a satellite's surface is measured photoelectrically and is calibrated against known stellar magnitudes by standard astronomical techniques. The calibrated satellite magnitudes are analyzed with respect to the sun-satellite-observer phase angle to infer the shape and size of the satellite and the reflective properties of the satellite's surface material. The physical and optical properties are used to determine proper position of the solar image on the satellite's surface, resulting in more precise geometric geodesy. Quantitative results from five observing periods indicate that, although local structural anomalies appear to exist, both satellites essentially maintained their nominal average 30.48-meter (50-ft) radius of curvature and specular reflecting characteristics.

Mcdougal, D. S.↗

Optical Properties of Boreal Region Biomass Burning Aerosols in Central Alaska and Seasonal Variation of Aerosol Optical Depth at an Arctic Coastal Site

Long-term monitoring of aerosol optical properties at a boreal forest AERONET site in interior Alaska was performed from 1994 through 2008 (excluding winter). Large interannual variability was observed, with some years showing near background aerosol optical depth (AOD) levels (<0.1 at 500 nm) while 2004 and 2005 had August monthly means similar in magnitude to peak months at major tropical biomass burning regions. Single scattering albedo (omega (sub 0); 440 nm) at the boreal forest site ranged from approximately 0.91 to 0.99 with an average of approximately 0.96 for observations in 2004 and 2005. This suggests a significant amount of smoldering combustion of woody fuels and peat/soil layers that would result in relatively low black carbon mass fractions for smoke particles. The fine mode particle volume median radius during the heavy burning years was quite large, averaging approximately 0.17 micron at AOD(440 nm) = 0.1 and increasing to approximately 0.25 micron at AOD(440 nm) = 3.0. This large particle size for biomass burning aerosols results in a greater relative scattering component of extinction and, therefore, also contributes to higher omega (sub 0). Additionally, monitoring at an Arctic Ocean coastal site (Barrow, Alaska) suggested transport of smoke to the Arctic in summer resulting in individual events with much higher AOD than that occurring during typical spring Arctic haze. However, the springtime mean AOD(500 nm) is higher during late March through late May (approximately 0.150) than during summer months (approximately 0.085) at Barrow partly due to very few days with low background AOD levels in spring compared with many days with clean background conditions in summer.

Eck, T. F.↗

Contrasting Inherent Optical Properties and Carbon Metabolism Between Five Northeastern (USA) Estuary-plume Systems

We have recently developed the ability to rapidly assess Surface inherent optical properties (IOP), oxygen concentration and pCO2 in estuarine-plume systems using flow-through instrumentation. During the summer of 2004, several estuarine-plume systems were surveyed which include the Pleasant (ME), Penobscot (ME), Kennebec-Androscoggin (ME), Merrimack (NH-MA) and Hudson (NY). Continuous measurements of surface chlorophyll and colored dissolved organic carbon (CDOM) fluorescence, beam attenuation, temperature, salinity, oxygen and pC02 were taken at each system along a salinity gradient from fresh water to near oceanic endmembers. CTD and IOP profiles were also taken at predetermined surface salinity intervals. These were accompanied by discrete determinations of chlorophyll (HPLC and fluorometric), total suspended solids (TSS), dissolved organic carbon (DOC) and alkalinity. IOP data were calibrated using chlorophyll, DOC and TSS data to enable the retrieval of these constituents from IOP data. Considerable differences in the data sets were observed between systems. These ranged from the DOC-enriched, strongly heterotrophic Pleasant River System to the high-chlorophyll autotrophic Merrimack River System. Using pCO2 and oxygen saturation measurements as proxies for water column metabolism, distinct relationships were found between trophic status and inherent optical properties. The nature of these relationships varies between systems and is likely a function of watershed and estuarine attributes including carbon and nutrient loading, in-situ production and related autochthonous inputs of DOC and alkalinity. Our results suggest that IOP data may contain significant information about the trophic status of estuarine and plume systems.

Vandemark, Doug↗

Correlation of optical properties with particle size, morphology, and polymorph of fine- and nano-particle formulations of titanium dioxide powders

Titanium dioxide (TiO 2 ) particulates are known to exhibit different visible and infrared optical properties compared to the bulk material, showing strong dependence on particle size, crystal structure, and morphology. In this study, the optical properties, sizes, and morphologies of TiO 2 particles from two different sources (nano and fine powders) having a) nominally different particle sizes and b) various crystal polymorph mixture fractions are compared using a combination of single particle mass spectrometry, optical spectroscopies, and aerosol characterization methods. The nano sample was found to be largely particles of the anatase polymorph (88% by mass), while the fine sample was found to consist largely of rutile particles (95% by mass). Two distinct particle morphologies (fractal and compact) were found in each powder sample and could be identified and separated in-situ based on particle aerodynamic properties. The attenuation of near-infrared, visible and ultraviolet light by TiO 2 particles shows strong dependence on particle morphology. Furthermore, while the fine particles were found to have larger near-infrared (675–800 nm) extinction coefficients by mass than the nanoparticles, the reverse was true in the ultraviolet and visible regions (370–675 nm). However, for polydisperse particles with different sizes and shapes, the optical behaviors are not straightforward to directly correlate to a combination of physical parameters.

Lockwood, Schuyler P. [Pacific Northwest National ↗

Measurements of the optical properties of thin films of silver and silver oxide

The optical properties of silver films and their oxides are measured to better characterize such films for use as sensors for atomic oxygen. Good agreement between properties of measured pure silver films and reported optical constants is observed. Similar comparisons for silver oxide have not been possible because of a lack of reported constants, but self-consistencies and discrepancies in our measured results are described.

Peters, Palmer N.↗

Exciton-Defect Interaction and Optical Properties from a First-Principles T-Matrix Approach

Understanding exciton-defect interactions is critical for optimizing optoelectronic and quantum information applications in many materials. However, ab initio simulations of material properties with defects are often limited to high defect density. Here, we study effects of exciton-defect interactions on optical absorption and photoluminescence spectra in monolayer MoS 2 using a first-principles T-matrix approach. We demonstrate that exciton-defect bound states can be captured by the disorderaveraged Green’s function with the T-matrix approximation and further analyze their optical properties. Our approach yields photoluminescence spectra in good agreement with experiments and provides a new, computationally efficient framework for simulating optical properties of disordered 2D materials from firstprinciples.

T-matrix↗

Estimation of the end-of-life optical properties of Z-93 thermal control coating for the Space Station Freedom

This paper describes an approach to estimating the 30-year end-of-life optical properties of Z-93 white, thermal control coating on the Space Station Freedom. Estimations of the 30-year end-of-life properties of thermal control coatings are necessary for sizing the thermal radiators. The available flight and ground data and computer generated contamination models are used to predict the effects of ground handling, exposure to UV radiation, and on-orbit contamination on the optical properties of Z-93. The solar absorptance for portions of the thermal control system radiator surfaces is predicted to change from 0.15 to 0.36 after 30 years of low earth orbit environmental exposure. The infrared emittance is predicted to change from 0.92 to 0.90.

Hasegawa, Mark M.↗

Parameterizations of the Vertical Variability of Tropical Cirrus Cloud Microphysical and Optical Properties

Our multi-investigator effort was targeted at the following areas of interest to CRYSTAL-FACE: (1) the water budgets of anvils, (2) parameterizations of the particle size distributions and related microphysical and optical properties (3) characterizations of the primary ice particle habits, (4) the relationship of the optical properties to the microphysics and particle habits, and (5) investigation of the ice-nuclei types and mechanisms in anvil cirrus. Dr. Twohy's effort focused on (l), (2), and (5), with the measurement and analysis of ice water content and cirrus residual nuclei using the counterflow virtual impactor (CVI).

Twohy, Cynthia↗

Improving Coastal Ocean Color Validation Capabilities through Application of Inherent Optical Properties (IOPs)

Understanding how the different components of seawater alter the path of incident sunlight through scattering and absorption is essential to using remotely sensed ocean color observations effectively. This is particularly apropos in coastal waters where the different optically significant components (phytoplankton, detrital material, inorganic minerals, etc.) vary widely in concentration, often independently from one another. Inherent Optical Properties (IOPs) form the link between these biogeochemical constituents and the Apparent Optical Properties (AOPs). understanding this interrelationship is at the heart of successfully carrying out inversions of satellite-measured radiance to biogeochemical properties. While sufficient covariation of seawater constituents in case I waters typically allows empirical algorithms connecting AOPs and biogeochemical parameters to behave well, these empirical algorithms normally do not hold for case I1 regimes (Carder et al. 2003). Validation in the context of ocean color remote sensing refers to in-situ measurements used to verify or characterize algorithm products or any assumption used as input to an algorithm. In this project, validation capabilities are considered those measurement capabilities, techniques, methods, models, etc. that allow effective validation. Enhancing current validation capabilities by incorporating state-of-the-art IOP measurements and optical models is the purpose of this work. Involved in this pursuit is improving core IOP measurement capabilities (spectral, angular, spatio-temporal resolutions), improving our understanding of the behavior of analytical AOP-IOP approximations in complex coastal waters, and improving the spatial and temporal resolution of biogeochemical data for validation by applying biogeochemical-IOP inversion models so that these parameters can be computed from real-time IOP sensors with high sampling rates. Research cruises supported by this project provides for collection and processing of seawater samples for biogeochemical (pigments, DOC and POC) and optical (CDOM and POM absorption coefficients) analyses to enhance our understanding of the linkages between in-water optical measurements (IOPs and AOPs) and biogeochemical constituents and to provide a more comprehensive suite of validation products.

Mannino, Antonio↗

Temperature dependence of optical properties of GaAs

The effect of temperature on the optical properties of GaAs was investigated using spectroscopic ellipsometry measurements, between room temperature and about 610 C in increments of 50 C, of pseudodielectric functions and related optical constants of GaAs. A quantitative analysis of the pseudodielectric function spectrum was carried out using a harmonic-oscillator approximation (HOA) to fit the measured dielectric functions. Good fits were obtained with this model, which provides a convenient means of reproducing the GaAs dielectric function at any temperature, by using the temperature-dependent oscillator parameters. The HOA analysis also provides information about band-gap variation with temperature. Using the measured optical constants at a number of fixed temperatures, an algorithm was developed for computing the dielectric function spectrum at an arbitrary temperature in the range 22-610 C.

Yao, Huade↗

Containerless laser-induced flourescence study of vaporization and optical properties for sapphire and alumina

Evaporation of aluminum oxide was studied from 1800 to 2327 K by laser-induced flourescence (LIF) detection of Al atom vapor over sapphire and alumina spheres that were levitated in an argon gas jet and heated with a continuous wave CO2 laser. Optical properties were determined from apparent specimen temperatures measured with an optical pyrometer and true temperatures deduced from the LIF intensity versus temperature measurements using the known temperature dependence of the Al atom vapor concentration in equilibrium with Al2O3. The effects of impurities and dissolved oxygen on the high-temperature optical properties of aluminum oxide were discussed.

Nordine, Paul C.↗

Optical properties of KD*P modulators

Longitudinal KD*P modulators are used in ground-based solar magnetographs to eliminate seeing effects. Although the modulators can be used as variable retarders, the optical properties when zero voltage is applied influences the performance on instruments requiring very accurate polarization measurements. Measurements at the Marshall Space Flight Center are discussed in terms of the optical properties of KD*P modulators when zero voltage is applied. The measurements can be used to predict the modulation characteristics of the devices and to determine the polarization accuracy that can be expected from the vector magnetograph.

West, E. A.↗