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Boron and carbon hydrides and carbon deuteride molecular ions radiative lifetime measurements, computing absolute oscillator strengths
The hook method is used in conjunction with absorption equivalent width measurements to determine the oscillator strengths and line widths of the Al I multiplet 3s2 3p2 P0 - 3s 3p2 2P at 176 nm. Autoionization is found to be the dominant decay channel for the two levels of the 3p2 2P term, with autoionizing widths of 4.0 and 0.87 x 10 to the 10th/sec for J of 3/2 and 1/2, respectively. The van der Waals scattering cross section for the Al I transition at 176.91 nm by He is determined to be (1.3 + or - 0.3) x 10 to the -14th sq cm at 2400 K, and a solar spectrum calculation centered at 176 nm shows that the Al I features are possible diagnostic probes of (1) solar non-LTE processes, and (2) the temperature minimum and structure of the lower chromosphere.
The electron-impact excitations of 12 states of O I are analyzed using a close-coupling approximation. The absorption oscillator strengths for dipole-allowed transitions among the states are calculated. Cross sections for excitation of the states by electron impact in the energy region 13.87 to 100 eV are compared with the data of Smith (1976) and Doering and Gulcicek. It is observed that there is a correlation between the data at energies 13.87, 20, and 30 eV for the (3)P-3p(5)P transition and at energies 13.87 and 16.5 eV for the (3)P-3s(5)S(0) transitions; however, for the dipole-allowed (3)P-3d(3)D(0) and (3)P-3s(prime)(3)D(0) transitions there are discrepancies in magnitude.
For more than 40 years, most astrophysical observations and laboratory studies of two key soft x-ray diagnostic 2p - 3d transitions, 3C and 3D, in Fe XVII ions found oscillator strength rations f(3C)/f(3D) disagreeing with theory, but uncertainties had precluded definitive statements on this much studied conundrum. Here, we resonantly excite these lines using synchrotron radiation at PETRA III, and reach, at a millionfold lower photon intensities, a 10 times higher spectral resolution, and 3 times smaller uncertainty than earlier work. Our final result of f(3C)/f(3D) = 3.09(8)(6) supports many of the earlier clean astrophysical and laboratory observations, while departing by five sigmas from our own newest large-scale ab initio calculations, and excluding all proposed explanations, including those invoking nonlinear effects and population transfers.
Measurement of a radiative lifetime of 9.6 (plus or minus 1.0) nsec for the SiO A(super 1)Pi state is reported. RKR Franck-Condon factors have been computed and, with these, absolute oscillator strengths are calculated. A band system at 3022 A has been found that may be due to SiO+, but the band is not resolved at our experimental resolution, and identification remains uncertain. The upper state of the carrier of this spectrum has a radiative lifetime of 8.3 (plus or minus 0.8) nsec.
IUE absorption-line data obtained at 110-320 nm with resolution 10-30 pm toward the B-star component of the multiple system of Alpha Sco are presented in graphs and tables and used to characterize the circumstellar shell around the M1.5 Iab component. Resonant lines of Ni II are identified at strengths in excess of 4 pm and fit to a growth curve constructed using the Fe II, Si II, and Mn II lines, and the results are found to confirm the oscillator strengths determined by Kurucz and Peytremann (1975) to within 50 percent. Shell depletions 2-20 times smaller than those for dense clouds such as the surrounding Oph complex are calculated and attributed to the formation of circumstellar dust. The implications of the results for the condensation of various elements in dense and diffuse clouds are explored.
Molecular nitrogen plays a central role in the energetics of the earth's upper atmosphere and is the major constituent of the atmospheres of the planetary satellites Titan and Triton. This paper reports a new set of absorption oscillator strengths measured at higher resolution for seven bands in the 95.8-99.4 nm region. The results are compared with earlier, lower resolution absorption measurements, electron scattering measurements, and calculations based on a deperturbation analysis of the excited states.
The beam-foil technique has been used to study the 2S(2)S-2p(2)P(0) doublet in S XIV. The results confirm the doublet splitting measured aboard Skylab during solar flare events. In addition, the oscillator strengths for the resonance transitions comprising this doublet have been measured and found to agree well with recent relativistic f-value calculations.
Shock-tube data are used to examine systematic f-value behavior in prominent visible transition arrays for the homologous emitter sequence Si-II, Ge-II, Sn-II, and Pb-II. Regularities found in these data are compared with trends in lighter elements. Agreements and disparities with theoretical and experimental oscillator strengths from existing literature are noted.
The dipole radial integral for an initial discrete 1s state and a final continuum state has been calculated under the screened hydrogenic model. In this model, single-electron hydrogenic wave functions are employed, and the initial and the final states are treated by two different effective-charge parameters. Numerical values of differential oscillator strengths for transitions from 1s2 1S to the continuum for the helium sequence ions are obtained. Also calculated are the dipole polarizabilities, which are found to be in excellent agreement with the results of other authors.
Shock tube data are used to examine the systematic f value behavior in prominent visible transition arrays (ns-np, np-(n+l)s, np-nd) for the homologous emitter sequence Si 11, Ge 11, Sn 11, and Pb 11. Regularities found for these data are compared with trends in lighter elements. Agreements and s disparities with theoretical and experimental oscillator strengths from the literature are noted.
This was the fourth in a series of colloquia begun at the University of Lund, Sweden in 1983 and subsequently held in Toledo, Ohio and Amsterdam, The Netherlands. The purpose of these meetings is to provide an international forum for communication between major users of atomic spectroscopic data and the providers of these data. These data include atomic wavelengths, line shapes, energy levels, lifetimes, and oscillator strengths. Speakers were selected from a wide variety of disciplines including astrophysics, laboratory plasma research, spectrochemistry, and theoretical and experimental atomic physics.
Use of the high-frequency deflection technique to measure radiative lifetimes for the 4p and 5p upper states in Na I, along with relative populations of a number of ns and nd states. These data have been used to obtain f-values for the corresponding resonance transitions in Na I, which proved to be in reasonable agreement with previous oscillator strengths. From the theoretical curve of growth for pure Doppler broadening, revised line ratios for D1/3303 are given and are compared with observations of Na I in zeta Oph.
We report Si II experimental log (gf)-values of -2.38(4) for the 180.801 nm line, of -2.18(4) for the 181.693 nm line, and of -3.29(5) for the 181.745 nm line, where the number in parentheses is the uncertainty in the last digit. The overall uncertainties (about 10 percent) include the 1 sigma random uncertainty (about 6 percent) and an estimate of the systematic uncertainty. The oscillator strengths are determined by combining branching fractions and radiative lifetimes. The branching fractions are measured using standard spectroradiometry on an optically thin source; the radiative lifetimes are measured using time-resolved laser-induced fluorescence.
Energy levels and electric dipole radiative transitions were determined for O III. The wavefunctions for the bound and continuum states were derived by solving coupled integrodifferential equations in the close-coupling approximation with the aid of two methods, the R-matrix and linear algebraic methods. Configuration interaction wavefunctions are presented for eight states of the O IV target with configurations of 2s(x)sp(y) (x + y = 3). Oscillator strengths are calculated for the transitions between, and photoionization cross sections from, bound states of O III with configurations of 2s(x)2p(y)nl (for n of not greater than 10 and l of not greater than 3).
The moments S(mu) for mu at least -6 but no more than 2 and L(mu) for mu = 0, 1, and 2 are calculated for the helium sequence for atomic numbers (Z) up to 30 under a screened hydrogenic model. The model describes the atom by single-particle hydrogenic wave functions and treats the initial and the final state as characterized by two different effective charge parameters Zi and Zf, respectively. The differential oscillator strength of the screened hydrogenic model is asymptotically expanded. Assuming the value of 287.6 for the coefficient of the term epsilon to the -7/2 for helium atoms, the parameter Zf is determined for the helium sequence.
Equivalent width data from Copernicus and IUE appear to have an exponential, rather than a Gaussian distribution of errors. This is probably because there is one dominant source of error: the assignment of the background continuum shape. The maximum likelihood method of parameter estimation is presented for the case of exponential statistics, in enough generality for application to many problems. The method is applied to global fitting of Si II, Fe II, and Mn II oscillator strengths and interstellar gas parameters along many lines of sight. The new values agree in general with previous determinations but are usually much more tightly constrained. Finally, it is shown that care must be taken in deriving acceptable regions of parameter space because the probability contours are not generally ellipses whose axes are parallel to the coordinate axes.
Cross sections of O2 at 79 K have been obtained from photoabsorption measurements at various pressures throughout the wavelength region 179.3-198.0 nm with a 6.65-m photoelectric scanning spectrometer equipped with a 2400-lines/mm grating and having an instrumental width (FWHM) of 0.0013 nm. The measured absorption cross sections of the Schumann-Runge bands (12,0) through (2,0) are independent of the instrumental width. The measured cross-sections are presented graphically here and are available at wavenumber intervals of about 0.1/cm as numerical compilations stored on magnetic tape from the National Space Science Data Center, NASA/Goddard. Band oscillator strengths of these bands have been determined by direct numerical integration of the measured cross sections.