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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Developing Non-Food Grade Brassica Biofuel Feedstock Cultivars with High Yield, Oil Content, and Oil Quality that are Suitable for Low Input Production Dryland Systems (Final Report)

The U.S. uses a substantial amount of fossil fuel as an energy source for a wide range for functions including home heating, agriculture and transportation. In the transportation sector, diesel and jet fuel are consumed at a rapid rate, and alternative liquid energy is being investigated globally and nationally to reduce our dependence on fossil fuel and reduce the impact of our carbon footprint on global climate change. Non-food Brassica crops have the potential of producing high oil yield (over 250 gal acre-1) and have oil quality highly desirable for use as biodiesel or bio jet fuel. Developing oilseed feedstock Brassica cultivars with higher seed and oil yield, with high oil quality and with resistance to pathogens, that can be grown with few chemical inputs will helping break our dependence on fossil fuels and reduce importation of fossil fuels. While some oilseed Brassicas have been grown on a small scale for many years in the Pacific Northwest (PNW), adoption has been limited, and the potential of the crops have not been realized or even fully investigated. This report summarizes the results of a study to develop superior non-food grade winter (B. napus) and spring (B. napus and B. juncea) oilseed cultivars suitable for a range of PNW, and other US environments with high resistance to the biotic and abiotic stresses suitable for high-quality biofuel feedstocks. In conducting this work, genome-wide association selection was used to dissect the genetic architecture of industrial Brassica oilseed germplasm for yield, quality, and resistance to biotic and abiotic stresses. A genome-wide bioinformatics approach was used to identify putative PRR (pattern recognition receptor) - type resistance genes that confer durable resistance to blackleg. A novel transgenic approach was developed to generate resistant non-food oilseed lines using PPR genes Br1033 and Br8486. These genes were inserted into regionally adapted oilseed cultivars.

09 BIOMASS FUELS↗
NASA NTRS1969

Discrimination of fish oil and mineral oil slicks on sea water

Fish oil and mineral oil slicks on sea water can be discriminated by their different spreading characteristics and by their reflectivities and color variations over a range of wavelengths. Reflectivities of oil and oil films are determined using a duel beam reflectance apparatus.

Mac Dowall, J.↗
NASA NTRS1982

Analysis of remote sensing data collected for detection and mapping of oil spills: Reduction and analysis of multi-sensor airborne data of the NASA Wallops oil spill exercise of November 1978

Airborne, remotely sensed data of the NASA Wallops controlled oil spill were corrected, reduced and analysed. Sensor performance comparisons were made by registering data sets from different sensors, which were near-coincident in time and location. Multispectral scanner images were, in turn, overlayed with profiles of correlation between airborne and laboratory-acquired fluorosensor spectra of oil; oil-thickness contours derived (by NASA) from a scanning fluorosensor and also from a two-channel scanning microwave radiometer; and synthetic aperture radar X-HH images. Microwave scatterometer data were correlated with dual-channel (UV and TIR) line scanner images of the oil slick.

Source record↗
NASA NTRS2012

Comparison of an Inductance In-Line Oil Debris Sensor and Magnetic Plug Oil Debris Sensor

The objective of this research was to compare the performance of an inductance in-line oil debris sensor and magnetic plug oil debris sensor when detecting transmission component health in the same system under the same operating conditions. Both sensors were installed in series in the NASA Glenn Spiral Bevel Gear Fatigue Rig during tests performed on 5 gear sets (pinion/gear) when different levels of damage occurred on the gear teeth. Results of this analysis found both the inductance in-line oil debris sensor and magnetic plug oil debris sensor have benefits and limitations when detecting gearbox component damage.

Dempsey, Paula J.↗
DOE OSTI2023

Recent Progress in Electrochemical Upgrading of Bio-Oil Model Compounds and Bio-Oils to Renewable Fuels and Platform Chemicals

Sustainable production of renewable carbon-based fuels and chemicals remains a necessary but immense challenge in the fight against climate change. Bio-oil derived from lignocellulosic biomass requires energy-intense upgrading to produce usable fuels or chemicals. Traditional upgrading methods such as hydrodeoxygenation (HDO) require high temperatures (200–400 °C) and 200 bar of external hydrogen. Electrochemical hydrogenation (ECH), on the other hand, operates at low temperatures (<80 °C), ambient pressure, and does not require an external hydrogen source. These environmental and economically favorable conditions make ECH a promising alternative to conventional thermochemical upgrading processes. ECH combines renewable electricity with biomass conversion and harnesses intermediately generated electricity to produce drop-in biofuels. This review aims to summarize recent studies on bio-oil upgrading using ECH focusing on the development of novel catalytic materials and factors impacting ECH efficiency and products. Here, electrode design, reaction temperature, applied overpotential, and electrolytes are analyzed for their impacts on overall ECH performance. We find that through careful reaction optimization and electrode design, ECH reactions can be tailored to be efficient and selective for the production of renewable fuels and chemicals. Preliminary economic and environmental assessments have shown that ECH can be viable alternative to convention upgrading technologies with the potential to reduce CO2 emissions by 3 times compared to thermochemical upgrading. While the field of electrochemical upgrading of bio-oil has additional challenges before commercialization, this review finds ECH a promising avenue to produce renewable carbon-based drop-in biofuels. Finally, based on the analyses presented in this review, directions for future research areas and optimization are suggested.

09 BIOMASS FUELS↗
DOE OSTI2020

3D Structure of Oil Droplets in Hardened Geopolymer Emulsions: Impact of Various Commercial Liquid Oils - 20184

Cement-based solidification/stabilization (S/S) is a widely applied technique for the immobilization of inorganic hazardous constituents. However, S/S is considered less compatible for organic liquid waste (OLW) because organic compounds may inhibit binder hydration. Geopolymers (i.e. alumino-silicate materials) are an alternative for applications in which Portland cements are inappropriate. In a previous work, we proposed a direct immobilization of organic liquid waste in a geopolymer binder (GEOIL composite). We demonstrated the feasibility for producing various composites on model system (hexadecane) and on a hydraulic oil, which are dispersed in the geopolymer binder as droplets (10-50 μm typical size). In nuclear facilities, legacy waste based on organic liquids are currently stored. Many of them have been used for various applications in the nuclear industry (lubrication, cutting, analysis, liquid/liquid extraction..) with very wide chemical compositions. In this study, we study the influence of various commercial organic oils immobilized in hardened geopolymer emulsions by X-ray micro-tomography. Image analysis make it possible to determine the 3D spatial and size distributions of oil droplets in geopolymer emulsions. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Improved Lubricating Performance by Combining Oil-Soluble Hairy Silica Nanoparticles and an Ionic Liquid as an Additive for a Synthetic Base Oil

This article reports on improved lubricating performance by combining oil-soluble poly(lauryl methacrylate) brush-grafted silica nanoparticles (hairy NPs or HNP) and an oil-miscible phosphonium-phosphate ionic liquid (IL) as a friction-reducing additive for a polyalphaolefin (PAO) oil. The HNP was synthesized by surface-initiated reversible addition–fragmentation chain transfer polymerization. At a total concentration of 2% and sufficiently high individual concentrations for HNP and IL in PAO, high-contact stress, ball-on-flat reciprocating tribological tests showed that the friction decreased by up to 23% compared with 2% HNP alone in PAO and by up to 35% compared to the PAO mixed with 2% IL. Scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy (XPS) analysis revealed that the tribofilm formed from the PAO containing 1% HNP + 1% IL was enriched with both Si and P, indicating that both hairy NPs and IL were involved in the tribochemical reactions. In addition, the O 1s and Si 2p peaks in the core-level XPS spectra exhibited significant shifts for the mixture of 1% HNP + 1% IL compared to those for 2% HNP, suggesting the possible formation of new covalent bonds. These results indicated that HNP and IL reacted with each other and also with the metal substrate during the rubbing process, which likely strengthened the tribofilm and its bonding with the substrate and thus further improved the lubrication.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Structural transitions of 4:1 methanol–ethanol mixture and silicone oil under high pressure

A 4:1 (volume ratio) methanol–ethanol (ME) mixture and silicone oil are two of the most widely used liquid pressure-transmitting media (PTM) in high-pressure studies. Their hydrostatic limits have been extensively studied using various methods; however, the evolution of the atomic structures associated with their emerging nonhydrostaticity remains unclear. Here, we monitor their structures as functions of pressure up to ∼30 GPa at room temperature using in situ high-pressure synchrotron x-ray diffraction (XRD), optical micro-Raman spectroscopy, and ruby fluorescence spectroscopy in a diamond anvil cell. No crystallization is observed for either PTM. The pressure dependence of the principal diffraction peak position and width indicates the existence of a glass transition in the 4:1 ME mixture at ∼12 GPa and in the silicone oil at ∼3 GPa, beyond which a pressure gradient emerges and grows quickly with pressure. There may be another liquid-to-liquid transition in the 4:1 ME mixture at ∼5 GPa and two more glass-to-glass transitions in the silicone oil at ∼10 GPa and ∼16 GPa. By contrast, Raman signals only show peak weakening and broadening for typical structural disordering, and Raman spectroscopy seems to be less sensitive than XRD in catching these structural transitions related to hydrostaticity variations in both PTM. These results uncover rich pressure-induced transitions in the two PTM and clarify their effects on hydrostaticity with direct structural evidence. The high-pressure XRD and Raman data on the two PTM obtained in this work could also be helpful in distinguishing between signals from samples and those from PTM in future high-pressure experiments.

Chen, Xiehang (ORCID:0000000168541506)↗
DOE OSTI2017

Impact of Expanded North Slope of Alaska Crude Oil Production on Crude Oil Flows in the Contiguous United States

The National Transportation Fuels Model was used to simulate a hypothetical increase in North Slope of Alaska crude oil production. The results show that the magnitude of production utilized depends in part on the ability of crude oil and refined products infrastructure in the contiguous United States to absorb and adjust to the additional supply. Decisions about expanding North Slope production can use the National Transportation Fuels Model take into account the effects on crude oil flows in the contiguous United States.

02 PETROLEUM↗
NASA NTRS1983

Oil film thickness using airborne laser-induced oil fluorescence backscatter

Remote airborne measurement of oil film thickness on ocean surface using laser-induced water Raman backscatter is discussed. It is pointed out that the theoretical model of oil fluorescence by Horvath et al. (1971) contains the necessary constituents to provide for the natural background fluorescence that is also induced by the laser during the course of an oil thickness experiment. How the various parameters of the model are obtained from typical airborne profile data is discussed, and it is shown that the water Raman backscatter may be used to assist further in the application of the data. The regions or water types over which the technique might be most useful or applicable are discussed.

Hoge, F. E.↗
DOE OSTI2018

Synthesis and Properties Modified Feather Keratin-Based Motor Oil Sorbing Cryogels with High Oil Holding Capacity

Oleic acid was used to modify keratin extracted from chicken feathers by free radical initiated graft copolymerization. Thereafter, the modified keratin was used for the synthesis of cryogels. The influence of oleic acid modification, the crosslinker content, and the protein concentration on the properties of the cryogels were investigated by Fourier transform infrared spectroscopy, scanning electron microscopy, SDS-PAGE, and through oil holding capacity tests. To enhance the sorption properties, the cryogels were crosslinked with glutaraldehyde. Varying protein concentration from 1.27 to 5.09 wt% and glutaraldehyde concentration from 0 to 5 wt% produced cryogels with oil holding capacity ranging from 4.56 to 10.76 g/g. The highest results exceeded the sorption capacity of previously published oleic acid modified woodchips (6.3 g/g) as well as polypropylene (6 g/g), which is the standard material used in industry.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Impact of Expanded North Slope of Alaska Crude Oil Production on Oil Flows in the Contiguous United States (Summary)

Crude oil produced on the North Slope of Alaska (NSA) is primarily transported on the Trans-Alaska Pipeline System (TAPS) to in-state refineries and the Valdez Marine Terminal in southern Alaska. From the Terminal, crude oil is loaded onto tankers and is transported to export markets or to three major locations along the U.S. West Coast: Anacortes-Ferndale area (Washington), San Francisco Bay area, and Los Angeles area. North Slope of Alaska production has decreased about 75% since the 1980s, which has reduced utilization of TAPS.

02 PETROLEUM↗
DOE OSTI2017

DOE/DOT Crude Oil Characterization Research Study, Task 2 Test Report on Evaluating Crude Oil Sampling and Analysis Methods

The Crude Oil Characterization Research Study is designed to evaluate whether crude oils currently transported in North America, including those produced from "tight" formations, exhibit physical or chemical properties that are distinct from conventional crudes, and how these properties associate with combustion hazards with may be realized during transportation and handling.

02 PETROLEUM↗
DOE OSTI2020

Potential Oil Supply and CO2 Demand for CO2 Enhanced Oil Recovery in the United States

This presentation was given at the 2020 Pittsburgh Coal Conference on Sept 10, 2020. It describes an analysis using the FE/NETL CO<sub>2</sub> EOR Evaluation System in order to develop price curves for both oil supply as well as CO<sub>2</sub> demand resulting from potential application of CO<sub>2</sub> EOR. The analysis was conducted on a dataset of conventional oil reservoirs in the lower-48 states.

Morgan, David↗