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At least 109 records · Page 6

Knowledge Management: FY22 Los Alamos National Laboratory Hydrothermal Lab for Spent Fuel Campaign R&D

The use of Engineered Barrier Systems (EBS) for spent nuclear fuel disposal is being investigated by the U.S. Department of Energy as a part of the Spent Fuel and Waste Disposition (SFWD) Campaign. Such dry spent fuel canisters would be loaded with fuel bundles, and then transported and stored at a nuclear waste repository. Once the canisters are in place underground, the space between the canister and the wall rock will be filled with bentonite clay. Recent research has prioritized high temperature interactions of EBS materials, including phase transitions in bentonite clay, in order to reduce worker dose and repository cost. Higher temperature (i.e., 200ºC) thermal limits are a new area of investigation by the U.S. and international repository science programs. The hydrothermal experimental laboratory at Los Alamos, consisting of rocking autoclaves and cold seal assemblies, is critical to the campaign and presents a significant temperature / pressure safety hazard. Therefore, working competently and safely with these systems is very important to the knowledge management procedures developed at this laboratory. Therefore, the operation of these two systems (rocking autoclaves and cold seal assemblies) will be discussed first.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Report on the Analysis of Plutonium-238 Oxide, Campaign #P5PO

Oak Ridge National Laboratory (ORNL) is currently producing Plutonium-238 oxide for NASA space programs. Through the irradiation of NpO 2 pellets in the High Flux Isotope Reactor (HFIR), the production of Pu-238 oxide will be used for electrical power and heat on NASA spacecraft such as the Curiosity Mars Rover and the Voyager 1 and 2. The Transuranium Analytical Laboratory (TAL) leads the analytical effort for this project, which includes the dissolution of plutonium product oxide (PUP) and the analysis of the dissolved product solution using both radiological and inductively coupled plasma mass spectrometry (ICP-MS) techniques that are required to meet product specifications. The Transuranic Analytical Laboratory received three samples of Pu-238 oxide for analysis in January of 2022. This report documents the analytical protocols performed by the TAL along with the results produced from said analytical protocols. This report also includes a comparison with the general-purpose heat source (GPHS) specifications.

07 ISOTOPE AND RADIATION SOURCES↗

Commission < 5 µm spatial resolution x-ray imager for High Resolution Turbulence experiments

This report presents the successful development, commissioning, and deployment of the Scintillation-Based X-ray Imager (SBXI) for the High-Resolution Turbulence (HRT) campaign at the National Ignition Facility (NIF). The SBXI system was designed to overcome the spatial resolution and efficiency limitations of conventional x-ray imaging detectors. Through careful system engineering, rigorous laboratory characterization, and experimental validation at NIF, the SBXI has demonstrated spatial resolution at the object plane of 5 μm (±0.5 μm) and a detective quantum efficiency (DQE) of 34% at 7.2 keV, both of which surpass the requirements set by the campaign, and meeting the L2 milestone. The system’s deployment enables high-fidelity imaging of fine-scale hydrodynamic instabilities, directly supporting advanced turbulence model validation and future high energy density physics research.

42 ENGINEERING↗

Assessment of EOS Aqua AMSR-E Arctic Sea Ice Concentrations using Landsat-7 and Airborne Microwave Imagery

An assessment of Advanced Microwave Scanning Radiometer Earth Observing System (AMSR-E) sea ice concentrations under winter conditions using ice concentrations derived from Landsat-7 Enhanced Thematic Mapper Plus (ETM+) imagery obtained during the March 2003 Arctic sea ice validation field campaign is presented. The National Oceanic and Atmospheric Administration Environmental Technology Laboratory's Airborne Polarimetric Scanning Radiometer Measurements, which were made from the National Aeronautics and Space Administration P 3B aircraft during the campaign, were used primarily as a diagnostic tool to understand the comparative results and to suggest improvements to the AMSR-E ice concentration algorithm. Based on the AMSR-E/ETM+ comparisons, a good overall agreement with little bias (approx. 1%) for areas of first year and young sea ice was found. Areas of new ice production result in a negative bias of about 5% in the AMSR-E ice concentration retrievals, with a root mean square error of 8%. Some areas of deep snow also resulted in an underestimate of the ice concentration (approx. 10%). For all ice types combined and for the full range of ice concentrations, the bias ranged from 0% to 3%, and the rms errors ranged from 1% to 7%, depending on the region. The new-ice and deep-snow biases are expected to be reduced through an adjustment of the new-ice and ice-type C algorithm tie points.

Cavalieri, Donald J.↗

Update on NREL Outdoor Exposure Campaign of Solar Mirrors

Beginning in 2018, the National Renewable Energy Laboratory restarted exposure campaigns on new and archived samples as part of a multiyear project, some with outdoor exposure for more than a decade. By resuming exposure and collecting and analyzing data on thousands of samples going back decades, several goals can be advanced that can be difficult to determine within the timeline of most projects: 1) correlating an accelerated exposure campaign to outdoor aging, specifically with xenon arc lamp exposure chambers; 2) drawing conclusions between specific corrosion mechanisms and weather patterns; and 3) finding novel relationships between mirror composition and performance. In addition to building and mining a database, we will experiment with new characterization techniques, primarily focused on macroscopic and microscopic imaging. In introducing these techniques more broadly, it may be possible to reveal a more direct line between optical performance and exposure campaigns by better understanding the degradation mechanisms occurring.

characterization techniques↗

Sequential Design of Experiments for Pilot Testing of Novel Solvent System

The CCSI2 program is supporting a six-month test campaign at the National Carbon Capture Center (NCCC) for evaluation of a novel water-lean solvent. This presentation describes CCSI2’s efforts in process modeling of the solvent system for both coal and natural gas-based flue gas sources and initial uncertainty quantification (UQ) work to estimate parametric uncertainty in key sub-models of interest (e.g., thermodynamics, mass transfer, reaction kinetics). Moreover, perspective is provided on how UQ and sequential design of experiments (SDoE) tools are used to assess the impact of model uncertainty on projected process performance, use this information to optimize data collection during the campaign, and refine process models through data collection. This framework is expected to reduce the overall model uncertainty, and thus risk associated with scale-up as the process moves towards commercialization.

Morgan, Joshua↗

Methane Emissions from Gathering Compressor Stations in the U.S.

Using results from a nationally representative measurement campaign at 180 gathering compressor stations conducted with nine industry partners, this study estimated emissions for the U.S. gathering sector, where sector-specific emission factors have not been previously available. The study drew from a partner station population of 1705 stations—a significantly larger pool than was available for prior studies. Data indicated that whole gas emission rates from components on gathering stations were comparable to or higher than emission factors utilized by the EPA’s greenhouse gas reporting program (GHGRP) but less than emission factors used for similar components on transmission compressor stations. Field data also indicated that the national population of stations likely has a higher fraction of smaller stations, operating at lower throughput per station, than the data used to develop the per-station emission factor used in EPA’s greenhouse gas inventory (GHGI). This was the first national study to incorporate extensive activity data reported to the GHGRP, including 319 basin-level reports, covering 15,895 reported compressors. Further, combining study emission data with 2017 GHGRP activity data, the study indicated statistically lower national emissions of 1290 [1246–1342] Gg methane per year or 66% [64–69%] of current GHGI estimates, despite estimating 17% [12–22%] more stations than the 2017 GHGI (95% confidence interval). Finally, we propose a replicable method that uses GHGRP activity data to annually update GHGI gathering and boost sector emissions.

03 NATURAL GAS↗

Hotspot conditions achieved in inertial confinement fusion experiments on the National Ignition Facility

We describe the overall performance of the major indirect-drive inertial confinement fusion campaigns executed at the National Ignition Facility. With respect to the proximity to ignition, we can describe the performance of current experiments both in terms of no-burn ignition metrics (metrics based on the hydrodynamic performance of targets in the absence of alpha-particle heating) and in terms of the thermodynamic properties of the hotspot and dense fuel at stagnation—in particular, the hotspot pressure, temperature, and areal density. We describe a simple 1D isobaric model to derive these quantities from experimental observables and examine where current experiments lie with respect to the conditions required for ignition.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Carbon ablator areal density at fusion burn: Observations and trends at the National Ignition Facility

For inertial confinement fusion experiments, the pusher is composed of a high-density deuterium tritium cyrogenic fuel layer and an ablator, often made of carbon. In an ideal, no-mix implosion, increasing the areal density of the pusher transfers more pressure to the hot spot and increases the hot spot confinement time. There has been a lack of knowledge about the final compressed state of the ablator for implosions at the National Ignition Facility. 14 MeV fusion neutrons inelastically scattering on the remaining carbon ablator excites a nuclear metastable state that emits a prompt 4.4 MeV gamma ray. The gamma reaction history diagnostic data, when reduced by a new data analysis technique, can isolate and measure the carbon gamma rays, which are proportional to the areal density of the ablator during fusion burn. The trends over many National Ignition Facility campaigns show that the ablator areal density is weakly sensitive to the maximum shell velocity, the cold fuel radius, the ablator mass remaining, or the laser picket intensity. Controlled parameter scans reveal that, for specific campaigns, ablator compression has a strong dependence on laser coast time, high Z dopants, and the laser drive foot duration. Using a model of the compressed ablator density profile reveals that the greatest variation of the ablator areal density comes from its thickness, with highly compressed, thin layers having high areal density values. The compression and thickness of the ablator are other metrics that designers should understand to differentiate the types of capsule degradation and maximize the inertial confinement fusion performance.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

High-volume and -adiabat capsule (“HVAC”) ignition: Lowered fuel compression requirements using advanced Hohlraums

Lower-than-expected deuterium–tritium fuel areal densities have been experimentally inferred across a variety of high-convergence, nominally low-adiabat implosion campaigns at the National Ignition Facility (NIF) using cylinder-shaped Hohlraums [Hurricane et al., Phys. Plasmas 26, 052704 (2019)]. A leading candidate explanation is the presence of atomic mix between the fuel and ablator from hydrodynamic instability growth [Clark et al., Phys. Plasmas 26, 050601 (2019)], leading to reduced fuel compressibility and an effectively higher (in-flight) fuel adiabat α. Tolerating a high-α implosion can be obtained with significantly higher capsule absorbed energy Ecap according to the one-dimensional (1-D) ignition-threshold-factor analytic scaling [S. Atzeni and J. Meyer-ter-Vehn, Nucl. Fusion 41, 465 (2001)], ITF∼Ecap·α−1.8. Recent experiments with large Al shells in rugby-shaped Hohlraums have established high laser-capsule coupling efficiencies of ≽ 30% [Ping et al., Nat. Phys. 15, 138 (2019)], enabling a path to Ecap≽ 0.5 MJ at the NIF and increased performance margin M ≡ ITF − 1. The ability to operate at high adiabat with large capsules using nonstandard Hohlraums leads to the predicted onset of a volume-ignition mode, defined as when both the entire fuel is the “hot spot” and inertial confinement is principally provided by the ablator compared with the compressed fuel. Such an ignition mode, normally reserved for high-Z targets, e.g., double shells [Amendt et al., Phys. Plasmas 14, 056312 (2007)], is predicted to lead to lower fuel convergence and less exposure to mix due to the intended high adiabat—but at the expense of ∼3–4 × reduced (1-D) yield compared with conventional central hot-spot ignition designs.

Amendt, Peter (ORCID:0000000174021777)↗

Coupling multi-fidelity xRAGE with machine learning for graded inner shell design optimization in double shell capsules

Bayesian optimization has shown promise for the design optimization of inertial confinement fusion targets. Specifically, in Vazirani et al. [Phys. Plasmas 28 , 122709 (2021)], optimal designs for double shell capsules with graded inner shells were identified using one-dimensional xRAGE simulation yield calculations. While the machine learning models were able to accurately learn and predict one-dimensional simulation target performance, using simulations with higher fidelity would improve design optimization and better match with the expected experimental performance. However, higher fidelity physics modeling, i.e., two-dimensional xRAGE simulations, requires significantly larger computational time/cost, usually at least an order of magnitude, in comparison with one-dimensional simulations. This study presents a multi-fidelity Bayesian optimization, in which the machine learning model leverages low-fidelity (one-dimensional xRAGE) and high-fidelity (two-dimensional xRAGE) simulations to more accurately predict “pre-shot” target performance with respect to the expected experimental performance. By building a multi-fidelity Bayesian optimization framework coupled with xRAGE, the low-fidelity and high-fidelity simulations are able to inform one another, such that we have: (1) improved physics modeling in comparison with using low-fidelity simulations alone, (2) reduced computational time/cost in comparison with using high-fidelity simulations alone, and (3) more confidence in the expected performance of optimized targets during real-world experiments. In the future, we plan to use this robust multi-fidelity Bayesian optimization methodology to expedite the design of graded inner shells further and eventually full capsules as a part of the current double shell campaign at the National Ignition Facility.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

The dynamics, mixing, and thermonuclear burn of compressed foams with varied gas fills

Inertial confinement fusion (ICF) implosions involve highly coupled physics and complex hydrodynamics that are challenging to model computationally. Due to the sensitivity of such implosions to small features, detailed simulations require accurate accounting of the geometry and dimensionality of the initial conditions, including capsule defects and engineering features such as fill tubes used to insert gas into the capsule, yet this is computationally prohibitive. It is therefore difficult to evaluate whether discrepancies between the simulation and experiment arise from inadequate fidelity to the capsule geometry and drive conditions, uncertainties in physical data used by simulations, or inadequate physics. We present results from detailed high-resolution three-dimensional simulations of ICF implosions performed as part of the MARBLE campaign on the National Ignition Facility [Albright et al., Phys. Plasmas 29, 022702 (2022)]. These experiments are foam-filled separated-reactant experiments, where deuterons reside in the foam and tritons reside in the capsule gas fill and deuterium–tritium (DT) fusion reactions only occur in the presence of mixing between these materials. Material mixing in these experiments is primarily seeded by shock interaction with the complex geometry of the foam and gas fill, which induces the Richtmyer–Meshkov instability. We compare results for experiments with two different gas fills (ArT and HT), which lead to significant differences in the hydrodynamic and thermodynamic developments of the materials in the implosion. Our simulation results show generally good agreement with experiments and demonstrate a substantial impact of hydrodynamic flows on measured ion temperatures. The results suggest that viscosity, which was not included in our simulations, is the most important unmodeled physics and qualitatively explains the few discrepancies between the simulation and experiment. The results also suggest that the hydrodynamic treatment of shocks is inadequate to predict the heating and yield produced during shock flash, when the shock converges at the center of the implosion. Alternatively, underestimation of the level of radiative preheat from the shock front could explain many of the differences between the experiment and simulation. Nevertheless, simulations are able to reproduce many experimental observables within the level of experimental reproducibility, including most yields, time-resolved X-ray self-emission images, and an increase in burn-weighted ion temperature and neutron down-scattered ratio in the line of sight that includes a jet seeded by the glue spot that joins capsule hemispheres.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Deeply Rooted: Evaluating Plant Rooting Depth as a Means for Enhanced Soil Carbon Sequestration (Full Technical Report)

Soils store three times as much carbon (C) as the atmosphere, but are not at capacity, and enhanced soil C storage is considered an essential strategy to mitigate rising atmospheric CO 2 levels. Agricultural soils have experienced substantial C loss in the past century due to poor agricultural practices and erosion. A shift towards deep-rooting crops and low-impact soil management could potentially increase long-term sequestration of C fixed by plants and stored in their root tissues, particularly for crops that have naturally deep root systems (>1 meter). A substantial amount of the CO 2 taken up by plants is allocated to their root systems, and because C deposited in deep soil layers has a longer residence time (up to millennia, in contrast to C deposited in topsoils), C increases at depth may have better long-term C sequestration potential than topsoils. However, the accrual, turnover, and stabilization of C in subsoils is a critical knowledge gap. We investigated a deeply rooted plant, switchgrass (Panicum virgatum), as a means of increasing carbon stocks in marginal and agricultural soils. We hypothesized that deep (>30 cm) SOC stocks would be greater under bioenergy crops relative to stocks under shallow-rooted conventional crop cover. To test this hypothesis, we compared soil depth profiles beneath deeply rooted switchgrass (cultivated for 4-30 years) and paired shallowrooted annual controls. We studied 12 field sites, 3 that were collected in 2018 before the start of the project as part a Department of Energy (DOE) Sustainable Biofuels study, and 9 that we collected in 2019 on a national field sampling campaign across the eastern US. In our publication from the 2018 study, which was written in collaboration with the LLNL Soil Microbiome Scientific Focus Area (SFA), we found that C stocks increased under switchgrass, but that the increases were dependent on soil texture. In the 2019 study, we found that carbon accrual tended to occur most consistently in low C soil in the southern US, which could indicate that perennial grasses may be a viable strategy to increase SOC in marginals soils in this region. We have published two studies from the 2019 sampling campaign thus far, we measured microbial growth parameters that will aid in modeling subsoil carbon cycling, and we found that switchgrass appears to move water upward in the soil profile and could promote drought tolerance, which a phenomenon commonly performed by trees known as ‘hydraulic redistribution;’ our study is the first to show this can occur in deep-rooted grasses. Finally, we published a modeling paper in collaboration with the LLNL Soil Microbiome SFA, where we found that poorly crystalline minerals are abundant and strongly correlated with organic C in geographically limited zones with enhanced weathering rates. Our results will inform technological development in the agricultural carbon sequestration sector as well as future negative emissions policies.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Development of a framework for sequential Bayesian design of experiments: Application to a pilot-scale solvent-based CO 2 capture process

In this paper, a methodology is developed for sequential design of experiments (SDoE) for process systems and applied to a solvent-based CO 2 capture system. In this approach, the prior knowledge of the system is used to prioritize process data collection at specific operating conditions. These data are then incorporated into a Bayesian inference methodology for updating a stochastic model by refining estimations of its underlying parameters, and the updated model is then used to generate the next set of test runs. Thus, the new knowledge obtained from the data is used to guide subsequent iterations of the experimental runs, ensuring that the overall data collection is maximally informative given that most experimental campaigns, especially at pilot or higher-scale plants, are costly, time-consuming, and resource-limited. The test run objective for this work was to minimize the maximum model prediction uncertainty for key output variables, but the methodology is generic and can be readily applied to other test run objectives. This methodology is applied to an aqueous monoethanolamine (MEA) pilot plant campaign at the National Carbon Capture Center (NCCC) in Wilsonville, Alabama, USA. The SDoE framework was utilized for two iterations, while collecting 18 sets of data representing different process conditions, and this resulted in an overall average reduction in uncertainty of approximately 50% in the prediction of CO 2 capture percentage. Moreover, 11 additional data sets were obtained with variation of absorber packing height for further model validation. This work shows the capability of the SDoE framework to maximize learning given limited resources, allowing for the reduction of model uncertainty, which is of great importance for many applications including reduction of technical risk associated with scale-up and economic analysis.

20 FOSSIL-FUELED POWER PLANTS↗

Completion of Transport Property Measurements on Multiple Actinide Fluoride Mixtures

One of the missions of the US Department of Energy’s Office of Nuclear Energy (DOE-NE) Molten Salt Reactor (MSR) Campaign under the Advanced Reactor Technology program has been to experimentally measure thermophysical properties of MSR-relevent salt systems, with the intent of supporting the development of the Molten Salt Thermal Properties Database (MSTDB). This database is jointly funded by the DOE-NE Nuclear Energy Advanced Modeling and Simulation Program and the MSR Campaign. Multiple DOE national laboratories, including Oak Ridge National Laboratory (ORNL), have been conducting measurements of thermophysical properties to support MSTDB development and provide MSR developers with access to new data that has been measured using modern methodologies and more advanced sample characterization techniques. These data may either fill gaps in the database or provide updated higher quality data to replace legacy data. Researchers at ORNL have recognized significant gaps in the transport property data of actinide-bearing fluoride salt systems of MSR industry interest. Moreover, for the data present in MSTDB in this category, the uncertainty margins are generally high, leading to questionability in our current understanding of the thermophysical characterization of actinide fluoride mixtures. As such, the focus of this study has been to generate new transport property data of actinide fluoride mixtures that are of immediate interest to MSR developers. Specifically, the mixtures NaF-UF 4 (78 - 22 mol%) and NaF-KF-UF 4 (57-16.04-26.91 mol%) have been studied—NaF-UF 4 for thermal conductivity and viscosity and NaF-KF-UF 4 for viscosity. Thermal conductivity measurements have been conducted with a variable gap apparatus, whereas viscosity has been measured with a rolling ball viscometer. Methodological and calibration details are provided for both measurement processes, along with measurement system updates that have enabled easier manufacturing of components and fewer challenges associated with conducting the measurements themselves. The resultant data collected for NaF-UF 4 (78–22 mol%) and NaF-KF-UF 4 (57-16.04-26.91 mol%) have been compared with relevant mixture data within the thermophysical arm of the MSTDB (MSTDB-TP).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Global monitoring of atmospheric properties by the EOS MODIS

The Moderate Resolution Imaging Spectroradiometer (MODIS) being developed for the Earth Observing System (EOS) is well suited to the global monitoring of atmospheric properties from space. Among the atmospheric properties to be examined using MODIS observations, clouds are especially important, since they are a strong modulator of the shortwave and longwave components of the earth's radiation budget. A knowledge of cloud properties (such as optical thickness and effective radius) and their variation in space and time, which are our task objectives, is also crucial to studies of global climate change. In addition, with the use of related airborne instrumentation, such as the Cloud Absorption Radiometer (CAR) and MODIS Airborne Simulator (MAS) in intensive field experiments (both national and international campaigns, see below), various types of surface and cloud properties can be derived from the measured bidirectional reflectances. These missions have provided valuable experimental data to determine the capability of narrow bandpass channels in examining the Earth's atmosphere and to aid in defining algorithms and building an understanding of the ability of MODIS to remotely sense atmospheric conditions for assessing global change. Therefore, the primary task objective is to extend and expand our algorithm for retrieving the optical thickness and effective radius of clouds from radiation measurements to be obtained from MODIS. The secondary objective is to obtain an enhanced knowledge of surface angular and spectral properties that can be inferred from airborne directional radiance measurements.

King, Michael D.↗

Implementation of Human System Integration Workshop at NASA for Human Spaceflight

The human is a key element in the complex system of systems underlying space exploration missions. As a critical system, its operating bands and requirements need to be characterized and integrated with other systems. Optimal integration of the human system with hardware and software elements has an impact on multiple aspects of mission execution, including human health and performance, risk mitigation, effective design and functionality, enhanced safety, and reduced lifecycle costs. The field of Human Systems Integration (HSI) represents an interdisciplinary and comprehensive cross-cutting approach encompassing technical and management processes for integrating human as a system consideration and objective within and across all other system components and multiple domains. In addition to human activities, HSI covers training, operations and support dimensions. Moreover, HSI is an essential enabler to systems engineering practice, emphasizing human system aspects toward optimizing fully integrated system of systems performance while systematically infusing the needs of all users during the earliest stages of development. Consistent with the National Space Exploration Campaign, NASA is developing the Gateway, a lunar orbiting platform that will serve as astronaut habitat, support transit to deep space, validate new technologies and systems, and function as a science laboratory and communications hub, among other uses. It is an essential element of a phase that will extend human exploration into deep space through evolvable infrastructure and advanced technology, supporting assembly and logistics of other exploration architecture elements. In an effort to explore the current status and forward plan of HSI implementation in the mission (system of systems) lifecycle, the HSI Employee Resource Group conducted an HSI workshop using the Gateway Program as a case study. It revealed how different organizations at the Johnson Space Center incorporate HSI in their processes in preparation for the development and operation of the Gateway. The workshop focused on HSI methodology for implementation of the six NASA HSI domains: Human Factors Engineering, Operations Resources, Habitability and Environment, Maintainability and Supportability, Safety, and Training. Results from the workshop are reported on this paper, as well as some historical background of HSI at NASA, and the success in using an Employee Resource Group to promote technical knowledge. The authors hope that this information can be used to disseminate best practices for translational applications to other space exploration systems.

Silva-Martinez, Jackelynne↗