Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Mixture design”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

An experimental investigation of agglutinate melting mechanisms - Shocked mixtures of sodium and potassium feldspars

The results of an experiment designed to test the validity of the model for agglutinate formation involving fusion of the finest fraction or F3 are reported. Impact glasses were formed from various mixes of orthoclase and albite powders, which were used as analogs for soils with chemically constrasting coarse and fine fractions. The results showed that the single most important factor displacing the composition of a small-scale impact melt from the bulk composition of the source regolith is the fractionated composition of the finest soil fraction. Volatile loss and the amount of melting, which in turn are determined by the degree of shock, are also important. As predicted by the model, the lower pressure melts are the most fractionated, and higher pressure is accompanied by increased melting causing glass compositions to approach the bulk. In general, the systematics predicted by the model are observed; the model appears to be valid.

Simon, S. B.↗

Propulsion requirements for the supply of lunar-derived oxygen for a manned Mars mission

The use of lunar-derived liquid oxygen with hydrogen for robust manned explorations beyond earth is discussed. The propellant mixture ratio for optimal performance is near the current design point of r = 6. The results of NASA-sponsored studies of missions using cryogenic bipropellant H2-O2 for most functions reveal the potential benefits from a propellant terminal in cis-lunar space. The main propulsion technologies associated with Mars mission case studies include: in-space fluid transfer, zero-g ignition, oxygen-enriched propellant mixtures, throttling of main engines, and H2-O2 based auxiliary propulsion.

Wrobel, J. Richard↗

Development of a condenser for the dual catalyst water recovery system

Conceptual evaporation/condensation systems suitable for integration with the catalytic water recovery method were evaluated. The primary requirements for each concept were its capability to operate under zero-gravity conditions, condense recovered water from a vapor-noncondensable gas mixture, and integrate with the catalytic system. Specific energy requirements were estimated for concepts meeting the primary requirements, and the concept most suitable for integration with the catalytic system was proposed. A three-man rate condenser capable of integration with the proposed system, condensing water vapor in presence of noncondensables and transferring the heat of condensation to feed urine was designed, fabricated, and tested. It was treated with steam/air mixtures at atmospheric and elevated pressures and integrated with an actual catalytic water recovery system. The condenser has a condensation efficiency exceeding 90% and heat transfer rate of approximately 85% of theoretical value at coolant temperature ranging from 7 to 80 deg C.

Budinikas, P.↗

Thermal design of a Mars oxygen production plant

The optimal design of the thermal components of a system that uses carbon dioxide from the Martian atmosphere to produce oxygen for spacecraft propulsion and/or life support is discussed. The gases are pressurized, heated and passed through an electrochemical cell. Carbon dioxide is reduced to carbon monoxide and oxygen due to thermal dissociation and electrocatalysis. The oxygen thus formed is separated from the gas mixture by the electrochemical cell. The objective of the design is to optimize both the overall mass and the power consumption of the system. The analysis shows that at electrochemical cell efficiencies of about 50 percent and lower, the optimal system would require unspent carbon dioxide in the exhaust gases to be separated and recycled. Various methods of efficiently compressing the intake gases to system pressures of 0.1 MPa are investigated. The total power requirement for oxygen production rates of 1, 5, and 10 kg/day at various cell efficiencies are presented.

Sridhar, K. R.↗

Designing Molten Salt Eutectics: A Combined Thermodynamic Modeling and Machine Learning Approach

Designing stable electrolytes with target properties is an important challenge in realizing next generation energy storage devices. Molten salt eutectics-based electrolytes are known for their stability with minimal parasitic reactions when compared to traditional organic electrolytes and are an attractive option for different battery chemistries. The operating temperature of the molten salt batteries depends on the melting temperature of the eutectic and hence there is a necessity to discover novel low melting temperature molten salt eutectic mixtures for energy storage applications. In this work we develop a high throughput computational screening approach for molten salt mixtures using thermodynamic modeling and machine learning (ML). COSMO-SAC model and ML approaches were independently developed based on the existing experimental data and these models were further used to predict the eutectic melting temperature and composition of several new binary, ternary, and quaternary mixtures. We show that combining ML and thermodynamic modeling strategies is effective in exploring the vast design space of molten salt mixtures.

Thermodynamics↗

Designing Molten Salt Eutectics

Designing stable electrolytes with target properties is an important challenge in realizing next generation energy storage devices. Molten salt eutectics-based electrolytes are known for their stability with minimal parasitic reactions when compared to traditional organic electrolytes and are an attractive option for different battery chemistries. The operating temperature of the molten salt batteries depends on the melting temperature of the eutectic and hence there is a necessity to discover novel low melting temperature molten salt eutectic mixtures for energy storage applications. In this work we develop a high throughput computational screening approach for molten salt mixtures using thermodynamic modeling and machine learning (ML). COSMO-SAC model and ML approaches were independently developed based on the existing experimental data and these models were further used to predict the eutectic melting temperature and composition of several new binary, ternary, and quaternary mixtures. We show that combining ML and thermodynamic modeling strategies is effective in exploring the vast design space of molten salt mixtures.

Ashwin Ravichandran↗

Life problems of dc and RF-excited low-power CW CO2 waveguide lasers

A number of different, RF-excited 3-W CW CO2 waveguide lasers have been built. Four of these lasers, after continuously working for 15,000-30,000 h, still yield about 70 percent of their original power output. The design variations cover N2and CO-bearing gas mixtures, as well as internal- and external-capacitively coupled excitation electrodes. A similar laser survived 50,000 5-min-ON/5-min-OFF cycles without significant mirror damage. It was not possible to find suitable cold cathodes that allow the building of longitudinally dc-excited CW CO2 waveguide lasers that work for such extended periods of time.

Hochuli, U. E.↗

Jet Mixing in a Reacting Cylindrical Crossflow

This paper addresses the mixing of air jets into the hot, fuel-rich products of a gas turbine primary zone. The mixing, as a result, occurs in a reacting environment with chemical conversion and substantial heat release. The geometry is a crossflow confined in a cylindrical duct with side-wall injection of jets issuing from round orifices. A specially designed reactor, operating on propane, presents a uniform mixture without swirl to mixing modules consisting of 8, 9, 10, and 12 holes at a momentum-flux ratio of 57 and a jet-to-mainstream mass-flow ratio of 2.5. Concentrations of O2, CO2, CO, and HC are obtained upstream, downstream, and within the orifice plane. O2 profiles indicate jet penetration while CO2, CO, and HC profiles depict the extent of reaction. Jet penetration is observed to be a function of the number of orifices and is found to affect the mixing in the reacting system. The results demonstrate that one module (the 12-hole) produces near-optimal penetration defined here as a jet penetration closest to the module half-radius, and hence the best uniform mixture at a plane one duct radius from the orifice leading edge.

Leong, M. Y.↗

Establishing Hazardous Gas Launch Commit Criteria for the Space Shuttle External Tank Intertank Compartment

Until recently, the simultaneous detection and evaluation of multiple Space Transportation System (STS) element compartments for propellant leakage was not possible during the External Tank (ET) pre-pressurization (pre-press) phase of propellant loading; late in the loading sequence (T-3 min to T-0). There exist launch commit criteria (LCCS) designed to protect against leaks resulting in flammable mixtures in the intertank during the functional life of the ET; start of propellant loading through ET-Orbiter separation. However thus far, leak protection had relied on the premise that if a propellant supply system leak were to exist, it would be a leak of fixed area present at the start of propellant loading (dumb leak mode) and such a leak could be detected earlier in the loading sequence than the pre-press phase. No measures had ever been implemented which would protect against leaks potentially developing late in the loading sequence (smart leak mode), The STS community had baselined this situation as an accepted risk their decision supported by exhaustive hardware acceptance criteria and a history of many successful launches. With the recent development of improvements to the hazardous gas detection system (HGDS), an opportunity arose to monitor the intertank compartment for hazardous gas concentrations beyond the T-3 minute mark. In this timeframe the propellant supply system is pressurized for flight and protection was sought against potential leaks generated by this pressurization process. The challenge at hand was to develop LCCs in this timeframe that were not too conservative to unnecessarily prohibit a launch, yet not too liberal to endanger crew safety and mission success. Since essentially no measurement history existed in this timeframe, the LCCs would have to rely on analysis alone. At NASA's direction, Lockheed Martin Michoud Space Systems (LMMSS) developed requirements that would protect against a smart leak during pre-press. A smart leak protection strategy is noteworthy from an STS main propulsion system (NWS) community perspective. This paper presents the resultant requirements as well as the technical and program issues involved with establishing hazardous gas LCCs for the ET intertank compartment.

Baran, Adam J.↗

Effect of Jet Injection Angle and Number of Jets on Mixing and Emissions From a Reacting Crossflow at Atmospheric Pressure

The mixing of air jets into hot, fuel-rich products of a gas turbine primary zone is an important step in staged combustion. Often referred to as "quick quench," the mixing occurs with chemical conversion and substantial heat release. An experiment has been designed to simulate and study this process, and the effect of varying the entry angle (0 deg, 22.5 deg and 45 deg from normal) and number of the air jets (7, 9, and 11) into the main flow, while holding the jet-to-crossflow mass-low ratio, MR, and momentum-flux ratio, J, constant (MR = 2.5;J = 25). The geometry is a crossflow confined in a cylindrical duct with side-wall injection of jets issuing from orifices equally spaced around the perimeter. A specially designed reactor, operating on propane, presents a uniform mixture to a module containing air jet injection tubes that can be changed to vary orifice geometry. Species concentrations of O2, CO, CO2, NO(x) and HC were obtained one duct diameter upstream (in the rich zone), and primarily one duct radius downstream. From this information, penetration of the jet, the spatial extent of chemical reaction, mixing, and the optimum jet injection angle and number of jets can be deduced.

St.John, D.↗

A Resonant Pulse Detonation Actuator for High-Speed Boundary Layer Separation Control

A variety of different types of actuators have been previously investigated as flow control devices. Potential applications include the control of boundary layer separation in external flows, as well as jet engine inlet and diffuser flow control. The operating principles for such devices are typically based on either mechanical deflection of control surfaces (which include MEMS flap devices), mass injection (which includes combustion driven jet actuators), or through the use of synthetic jets (diaphragm devices which produce a pulsating jet with no net mass flow). This paper introduces some of the initial flow visualization work related to the development of a relatively new type of combustion-driven jet actuator that has been proposed based on a pulse detonation principle. The device is designed to utilize localized detonation of a premixed fuel (Hydrogen)-air mixture to periodically inject a jet of gas transversely into the primary flow. Initial testing with airflow successfully demonstrated resonant conditions within the range of acoustic frequencies expected for the design. Schlieren visualization of the pulsating air jet structure revealed axially symmetric vortex flow, along with the formation of shocks. Flow visualization of the first successful sustained oscillation condition is also demonstrated for one configuration of the current test section. Future testing will explore in more detail the onset of resonant combustion and the approach to conditions of sustained resonant detonation.

Beck, B. T.↗

Development of an advanced spacecraft tandem mass spectrometer

The purpose of this research was to apply current advanced technology in electronics and materials to the development of a miniaturized Tandem Mass Spectrometer that would have the potential for future development into a package suitable for spacecraft use. The mass spectrometer to be used as a basis for the tandem instrument would be a magnetic sector instrument, of Nier-Johnson configuration, as used on the Viking Mars Lander mission. This instrument configuration would then be matched with a suitable second stage MS to provide the benefits of tandem MS operation for rapid identification of unknown organic compounds. This tandem instrument is configured with a newly designed GC system to aid in separation of complex mixtures prior to MS analysis. A number of important results were achieved in the course of this project. Among them were the development of a miniaturized GC subsystem, with a unique desorber-injector, fully temperature feedback controlled oven with powered cooling for rapid reset to ambient conditions, a unique combination inlet system to the MS that provides for both membrane sampling and direct capillary column sample transfer, a compact and ruggedized alignment configuration for the MS, an improved ion source design for increased sensitivity, and a simple, rugged tandem MS configuration that is particularly adaptable to spacecraft use because of its low power and low vacuum pumping requirements. The potential applications of this research include use in manned spacecraft like the space station as a real-time detection and warning device for the presence of potentially harmful trace contaminants of the spacecraft atmosphere, use as an analytical device for evaluating samples collected on the Moon or a planetary surface, or even use in connection with monitoring potentially hazardous conditions that may exist in terrestrial locations such as launch pads, environmental test chambers or other sensitive areas. Commercial development of the technology could lead to a new family of environmental test instruments that would be small and portable, yet would give quick analyses of complex samples.

Drew, Russell C.↗

Plasma torch igniter for scramjets

A small, uncooled plasma torch was developed and used in combination with an injector designed to study ignition and flameholding in hydrogen-fueled supersonic flows. The plasma torch was operated on mixtures of hydrogen and argon with total flows of 10 to 70 scfh. The fuel injector design consisted of five small upstream pilot fuel injectors, a rearward facing step for recirculation, and three main fuel injectors downstream of the step. The plasma torch was located in the recirculation region, and all injection was perpendicular to the Mach 2 stream. Both semi-freejet and ducted tests were conducted. The experimental results indicate that a low power plasma torch operating on a 1:1 volumetric mixture of hygrogen and argon and located in the recirculation zone fueled by the upstream pilot fuel injectors is a good igniter for flow conditions simulating a flight Mach number of 3.7. The total temperature required to autoignite the hydrogen fuel for this injector geometry was 2640 R. The injector configuration was shown to be a good flameholder over a wide range of total temperature. Spectroscopic measurements were used to verify the presence of air total temperatures below 1610 R.

Wagner, Timothy C.↗

Plasma torch igniter for scramjets

A small, uncooled plasma torch was developed and used in combination with an injector designed to study ignition and flameholding in hydrogen-fueled supersonic flows. The plasma torch was operated on mixtures of hydrogen and argon with total flows of 10 to 70 scfh. The fuel injector design consisted of five small upstream pilot fuel injectors, a rearward facing step for recirculation, and three main fuel injectors downstream of the step. The plasma torch was located in the recirculation region, and all injection was perpendicular to the Mach 2 stream. Both semi-freejet and ducted tests were conducted. The experimental results indicate that a low power plasma torch operating on a 1:1 volumetric mixture of hydrogen and argon and located in the recirculation zone fueled by the upstream pilot fuel injectors is a good igniter for flow conditions simulating a flight Mach number of 3.7. The total temperature required to autoignite the hydrogen fuel for this injector geometry was 2640 R. The injector configuration was shown to be a good flameholder over a wide range of total temperature. Spectroscopic measurements were used to verify the presence of air total temperatures below 1610 R.

Wagner, Timothy C.↗

Cryogenic Liquid Sample Acquisition System for Remote Space Applications

There is a need to acquire autonomously cryogenic hydrocarbon liquid sample from remote planetary locations such as the lakes of Titan for instruments such as mass spectrometers. There are several problems that had to be solved relative to collecting the right amount of cryogenic liquid sample into a warmer spacecraft, such as not allowing the sample to boil off or fractionate too early; controlling the intermediate and final pressures within carefully designed volumes; designing for various particulates and viscosities; designing to thermal, mass, and power-limited spacecraft interfaces; and reducing risk. Prior art inlets for similar instruments in spaceflight were designed primarily for atmospheric gas sampling and are not useful for this front-end application. These cryogenic liquid sample acquisition system designs for remote space applications allow for remote, autonomous, controlled sample collections of a range of challenging cryogenic sample types. The design can control the size of the sample, prevent fractionation, control pressures at various stages, and allow for various liquid sample levels. It is capable of collecting repeated samples autonomously in difficult lowtemperature conditions often found in planetary missions. It is capable of collecting samples for use by instruments from difficult sample types such as cryogenic hydrocarbon (methane, ethane, and propane) mixtures with solid particulates such as found on Titan. The design with a warm actuated valve is compatible with various spacecraft thermal and structural interfaces. The design uses controlled volumes, heaters, inlet and vent tubes, a cryogenic valve seat, inlet screens, temperature and cryogenic liquid sensors, seals, and vents to accomplish its task.

Mahaffy, Paul↗