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At least 109 records · Page 6

A cloudiness transition in a marine boundary layer

Boundary layer cloudiness plays several important roles in the energy budget of the earth. Low level stratocumulus are highly reflective clouds which reduce the net incoming shortwave radiation at the earth's surface. Climatically, the transition to a small area fraction of scattered cumulus clouds occurs as the air flows over warmer water. Although these clouds reflect less sunlight, they still play an important role in the boundary layer equilibrium by transporting water vapor upwards, and enhancing the surface evaporation. The First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) included a marine stratocumulus experiment off the southern California coast from June 29 to July 19, 1987. The objectives of this experiment were to study the controls on fractional cloudiness, and to assess the role of cloud-top entrainment instability (CTEI) and mesoscale structure in determining cloud type. The focus is one research day, July 7, 1987, when coordinated aircraft missions were flown by four research aircraft, centered on a LANDSAT scene at 1830 UTC. The remarkable feature of this LANDSAT scene is the transition from a clear sky in the west through broken cumulus to solid stratocumulus in the east. The dynamic and thermodynamic structure of this transition in cloudiness is analyzed using data from the NCAR Electra. By averaging the aircraft data, the internal structure of the different cloud regimes is documented, and it is shown that the transition between broken cumulus and stratocumulus is associated with a change in structure with respect to the CTEI condition. However, this results not from sea surface temperature changes, but mostly from a transition in the air above the inversion, and the breakup appears to be at a structure on the unstable side of the wet virtual adiabat.

Betts, Alan K.↗

HIS analyses of mesoscale phenomena

Results are presented from two sets of measurements made by the High-resolution Interferometer Sounder (HIS) during two aircraft flights over the Cooperative-Huntsville-Meteorological-Experiment region on June 15 and 19, 1986. It is shown that the temperature and the dew-point field retrieved from HIS spectra contain distinct mesoscale structures. The features in the HIS dew-point fields agreed well with the cloud and moisture structures observed in visible and 6.7 micron GOES imagery.

Bradshaw, John T.↗

Doppler lidar sampling strategies and accuracies: Regional scale

It has been proposed that a Doppler lidar be placed in a polar orbit and scanned to provide estimates of lower tropospheric winds twice per day and with a spatial resolution of 300 km. Initial feasibility studies conducted primarily by NOAA and NASA presented an optimistic outlook for a space based lidar. The technology appeared within reach and initial computer simulations suggested that acceptable accuracies could be obtained. Those early studies exposed, however, several potential problem areas which included: (1) the algorithms for computing the wind vectors did not perform well when there were coherent gradients in the wind fields; and (2) the lifetime and power requirements of the lidar put severe restrictions on the pulse repetition frequency (PRF). These two basic problems are currently being addressed by a Doppler lidar simulation study focussed upon three primary objectives: (1) to develop optimum scan parameters and shot patterns for a satellite-based Doppler lidar; (2) to develop robust algorithms for computing wind vectors from lidar returns; and (3) to evaluate the impact of coherent mesoscale structures (wind gradients, clouds, aerosols) on up-scale wind estimates. An overview is provided of the simulation efforts with particular emphasis upon rationale and methodology. Since this research is currently underway, any results shown are meant only as evidence of progress.

Emmitt, G. D.↗

On The Genesis of Tropical Cyclones: Role of Mesoscale Interactions

Before the last decades of the 20th century, observations were rarely adequate to assess the role of mesoscale circulations in the formation of tropical cyclones. Recent developments in remote-sensing technology have allowed routine collection of measurements that reveal the small- and mesoscale structure of forming tropical cyclones. Additional information is contained in the original extended abstract.

Ritchie, Elizabeth↗

TRMM: Status of Precipitation Estimates and Science Highlights

As a part of NASA's Earth System Enterprise, the Tropical Rainfall Measuring Mission (TRMM) seeks to understand the mechanisms through which changes in tropical rainfall influence global circulation. Over the past 3 years, TRMM has contributed significantly towards reducing uncertainty in satellite estimates of rainfall in the Tropics, where almost 67% of the Earth's rain falls. TRMM has provided knowledge related to the climatology, seasonality, and variation of tropical rainfall; the mesoscale structure of rain-producing systems; and the physics of precipitation. An overview of these results will be presented. Additionally, a summary of research highlights will be presented focusing on application of TRMM data to topics such as hurricane monitoring, climate analysis, forecasting, microphysics, environmental impacts, and El Nino/La Nina. Examples and plans for operational use of TRMM data in tropical cyclone monitoring and other applications will also be given.

Shepherd, J. Marshall↗

Land Surface Data Assimilation and the Northern Gulf Coast Land/Sea Breeze

A technique has been developed for assimilating GOES-derived skin temperature tendencies and insolation into the surface energy budget equation of a mesoscale model so that the simulated rate of temperature change closely agrees with the satellite observations. A critical assumption of the technique is that the availability of moisture (either from the soil or vegetation) is the least known term in the model's surface energy budget. Therefore, the simulated latent heat flux, which is a function of surface moisture availability, is adjusted based upon differences between the modeled and satellite observed skin temperature tendencies. An advantage of this technique is that satellite temperature tendencies are assimilated in an energetically consistent manner that avoids energy imbalances and surface stability problems that arise from direct assimilation of surface shelter temperatures. The fact that the rate of change of the satellite skin temperature is used rather than the absolute temperature means that sensor calibration is not as critical. The sea/land breeze is a well-documented mesoscale circulation that affects many coastal areas of the world including the northern Gulf Coast of the United States. The focus of this paper is to examine how the satellite assimilation technique impacts the simulation of a sea breeze circulation observed along the Mississippi/Alabama coast in the spring of 2001. The technique is implemented within the PSU/NCAR MM5 V3-4 and applied on a 4-km domain for this particular application. It is recognized that a 4-km grid spacing is too coarse to explicitly resolve the detailed, mesoscale structure of sea breezes. Nevertheless, the model can forecast certain characteristics of the observed sea breeze including a thermally direct circulation that results from differential low-level heating across the land-sea interface. Our intent is to determine the sensitivity of the circulation to the differential land surface forcing produced via the assimilation of GOES skin temperature tendencies. Results will be quantified through statistical verification techniques.

Lapenta, William M.↗

Large Forecast Centers Using TRMM Real-Time Data

As a part of NASA's Earth System Enterprise, The Tropical Rainfall Measuring Mission (TRMM) seeks to understand the mechanisms through which changes in tropical rainfall influence global circulation. Over the past 3 years, TRMM has contributed significantly towards reducing uncertainty in satellite estimates of rainfall in the Tropics, where almost 67% of the Earth's rain falls. TRMM has provided knowledge related to the climatology, seasonality, and variation of tropical rainfall; the mesoscale structure of rain-producing systems, and the physics of precipitation. As with many NASA missions, however, TRMM has provided surprising new knowledge and insight in scientific areas ranging from hurricane diagnosis/prediction to weather forecasting. Examples of current and future plans for use of TRMM data by operational weather centers will be discussed.

Shepherd, James Marshall↗

Application of Land Surface Data Assimilation to Simulations of Sea Breeze Circulations

A technique has been developed for assimilating GOES-derived skin temperature tendencies and insolation into the surface energy budget equation of a mesoscale model so that the simulated rate of temperature change closely agrees with the satellite observations. A critical assumption of the technique is that the availability of moisture (either from the soil or vegetation) is the least known term in the model's surface energy budget. Therefore, the simulated latent heat flux, which is a function of surface moisture availability, is adjusted based upon differences between the modeled and satellite- observed skin temperature tendencies. An advantage of this technique is that satellite temperature tendencies are assimilated in an energetically consistent manner that avoids energy imbalances and surface stability problems that arise from direct assimilation of surface shelter temperatures. The fact that the rate of change of the satellite skin temperature is used rather than the absolute temperature means that sensor calibration is not as critical. The sea/land breeze is a well-documented mesoscale circulation that affects many coastal areas of the world including the northern Gulf Coast of the United States. The focus of this paper is to examine how the satellite assimilation technique impacts the simulation of a sea breeze circulation observed along the Mississippi/Alabama coast in the spring of 2001. The technique is implemented within the PSUNCAR MM5 V3-5 and applied at spatial resolutions of 12- and 4-km. It is recognized that even 4-km grid spacing is too coarse to explicitly resolve the detailed, mesoscale structure of sea breezes. Nevertheless, the model can forecast certain characteristics of the observed sea breeze including a thermally direct circulation that results from differential low-level heating across the land-sea interface. Our intent is to determine the sensitivity of the circulation to the differential land surface forcing produced via the assimilation of GOES skin temperature tendencies. Results will be quantified through statistical verification techniques.

Mackaro, Scott↗

An LES Survey of Cold-Air Outbreaks Spanning ACTIVATE and COMBLE

Two recent field campaigns offer unique new opportunities to survey coupled aerosol and cloud processes operating within cold-air outbreaks (CAOs). NASA's 2019-2023 Aerosol Cloud meTeorology Interactions oVer the western Atlantic Experiment (ACTIVATE) project provided airborne in situ and remote sensing observations in multiple CAOs off the central US Eastern Seaboard. Contemporaneously, DOE's 2019-2020 Cold-air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) provided continuous ground-based in situ and remote sensing measurements during hundreds of hours of CAO conditions at two sites flanking the Norwegian Sea. Here we highlight lessons learned from contrasting sets of aerosol-aware Lagrangian large-eddy simulation case studies derived from each campaign, as well as outstanding uncertainties. Cases simulated include all of the most extensively sampled CAO flights during ACTIVATE, and a wide range of CAO strengths and mesoscale structures during COMBLE. Each case study is also suitable for simulation with large-scale models in single-column model mode or with a limited-domain approach using periodic boundary conditions. We seek to address the central question: what microphysical process pathways control the Lagrangian evolution of surface and top-of-atmosphere radiative fluxes under ACTIVATE and COMBLE conditions? Many science team members, co-investigators, and collaborators will be gratefully acknowledged in association with their contributions to making this work possible.

cold-air outbreaks↗

Research aircraft observations of the mesoscale and microscale structure of a cold front over the eastern Pacific Ocean

The structure of an oceanic cold front is described on the basis of research aircraft observations taken during the Ocean Storms field experiment. Synoptic and mesoscale analyses compare the structure of an upper-level jet-front system observed slightly downstream from the wind speed maximum to its structure in the upstream entrance region. Stratospheric potential vorticity and ozone were found within the frontal zone down to about 800 mb. Microscale analyses of the front near the sea surface were carried out for a portion of the front having the signature of a 'rope' cloud in satellite imagery. A narrow (less than 1 km) zone of upward motion (about 4 m/s) and of horizontal shear (about 0.01/s) characterized the front near the surface. Significant alongfront variability was found, including lateral displacements in the frontal zone where there were weaker updrafts.

Bond, Nicholas A.↗

Revealing Mesoscale Ionomer Membrane Structure by Tender Resonant X-ray Scattering

Nafion, a perfluorosulfonic acid ionomer, has been well-studied for decades due to its key role as an ion-conductive membrane in electrochemical energy conversion and storage applications. When hydrated, this membrane phase separates into a complex hierarchical nanostructure with hydrophilic domains that facilitate ion transport. Hard X-ray scattering has been a powerful technique in understanding Nafion due to its capabilities in capturing the ionomer’s nanophase separated structure, which gives rise to contrast between polymer and water domains. More recently, resonant X-ray scattering, which tunes to elemental absorption edges to provide specificity on constituent elements, has been explored to highlight key interactions related to the sulfonic acid groups within its structure. Here, in this work, we study the Nafion nanostructure by combining hard X-ray scattering and tender resonant X-ray scattering (TReXS) at the sulfur K-edge to reveal a mesoscopic feature corresponding to a correlation length of approximately 40 nm that has been challenging to resolve with hard X-ray studies. Additionally, we study the effect of the dispersion solvent composition that plays a key role in the formation of this mesoscale feature. Notably, TReXS can attain high contrast to decipher this mesoscale morphology even for dry polymer membranes under a vacuum, which typically have reduced contrast for hard X-rays. We find that the correlation length of this mesoscale feature decreases with increasing water fraction in the dispersion, which is the opposite trend exhibited by the smaller intercrystalline feature in the same membranes. This study showcases the utility of TReXS to uncover multiscale morphological details in functional polymers that are not always revealed by other methods like hard X-ray scattering. We illustrate this with Nafion, which is a relevant ion-conducting polymer for electrochemical technologies.

36 MATERIALS SCIENCE↗

Mesoscale and microscale structure of cirrus clouds - Three case studies

The structure and composition of various types of cirrus clouds were examined using coordinated aircraft and on-ground polarization lidar and Doppler radar measurements carried out during three case studies conducted during autumn or spring in Colorado, Wisconsin, and Utah states. A variety of cirrus cloud types observed included a multilayered orographic cirrus, a 6-km-deep cirrostratus overcast, and a group of fibrous cirrus cloud bands associated with tropopause generating cells, representing three basic cirrus-cloud types. The results on the structure and composition of these clouds provide insights into the microphysical processes and characteristic physical scales involved in the generation of cirrus clouds.

Sassen, Kenneth↗

Global Variability of Mesoscale Convective System Anvil Structure from A-Train Satellite Data

Mesoscale convective systems (MCSs) in the tropics produce extensive anvil clouds, which significantly affect the transfer of radiation. This study develops an objective method to identify MCSs and their anvils by combining data from three A-train satellite instruments: Moderate Resolution Imaging Spectroradiometer (MODIS) for cloud-top size and coldness, Advanced Microwave Scanning Radiometer for Earth Observing System (AMSR-E) for rain area size and intensity, and CloudSat for horizontal and vertical dimensions of anvils. The authors distinguish three types of MCSs: small and large separated MCSs and connected MCSs. The latter are MCSs sharing a contiguous rain area. Mapping of the objectively identified MCSs shows patterns of MCSs that are consistent with previous studies of tropical convection, with separated MCSs dominant over Africa and the Amazon regions and connected MCSs favored over the warm pool of the Indian and west Pacific Oceans. By separating the anvil from the raining regions of MCSs, this study leads to quantitative global maps of anvil coverage. These maps are consistent with the MCS analysis, and they lay the foundation for estimating the global radiative effects of anvil clouds. CloudSat radar data show that the modal thickness of MCS anvils is about 4-5 km. Anvils are mostly confined to within 1.5-2 times the equivalent radii of the primary rain areas of the MCSs. Over the warm pool, they may extend out to about 5 times the rain area radii. The warm ocean MCSs tend to have thicker non-raining and lightly raining anvils near the edges

Yuan, Jian↗

Mesoscale Frank–Kasper Crystal Structures from Dendron Assembly by Controlling Core Apex Interactions

Single-component polymeric materials open up a great potential for self-assembly into mesoscale complex crystal structures that are known as Frank-Kasper (FK) phases. Predicting the packing structures of the soft-matter spheres, however, remains a challenge even when the molecular design is precisely known. Here, we investigate the role of the molecules' enthalpic interaction in determining the low-symmetry crystal structures. To this end, we synthesize architecturally asymmetric dendrons by varying their apex functionalities and examine the packing structures of the second-generation (G2) dendritic wedges. Our work shows that weakening the hydrogen bonding of the dendron apex makes the particles softer and smaller, and leads to the formation of various FK structures at lower temperatures, including the new observation of a FK C14 phase in the cone-shaped dendron systems. As a consequence of the free energy balance between the particle's interfacial tension and the chain's stretching, various packing structures are mainly tuned by designing the hydrogen bonding interaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Periodic Solar Wind Structures Observed in Measurements of Elemental and Ionic Composition in situ at L1

Mesoscale periodic structures observed in solar wind plasma serve as an important diagnostic tool for constraining the processes that govern the formation of the solar wind. These structures have been observed in situ and in remote data as fluctuations in proton and electron density. However, only two events of this type have been reported regarding the elemental and ionic composition. Composition measurements are especially important in gaining an understanding of the origin of the solar wind as the composition is frozen into the plasma at the Sun and does not evolve as it advects through the heliosphere. Here, we present the analysis of four events containing mesoscale periodic solar wind structure during which the Iron and Magnesium number density data, measured by the Solar Wind Ion Composition Spectrometer (SWICS)on board the Advanced Composition Explorer spacecraft, are validated at statistically significant count levels. We use a spectral analysis method specifically designed to extract periodic signals from astrophysical time series and apply it to the SWICS 12-minute native resolution dataset. We find variations in the relative abundance of elements with low first ionization potential, mass dependencies, and charge state during time intervals in which mesoscale periodic structures are observed. These variations are linked to temporal or spatial variations in solar source regions and put constraints on the solar wind formation mechanisms that produce them. Techniques presented here are relevant for future, higher-resolution studies of data from new instruments such as Solar Orbiter’s Heavy Ion Sensor.

Irena Gershkovich↗

The Impact of Microphysics on Intensity and Structure of Hurricanes and Mesoscale Convective Systems

During the past decade, both research and operational numerical weather prediction models, e.g. Weather Research and Forecast (WRF) model, have started using more complex microphysical schemes originally developed for high-resolution cloud resolving models (CRMs) with a 1-2 km or less horizontal resolutions. WRF is a next-generation mesoscale forecast model and assimilation system that has incorporated modern software framework, advanced dynamics, numeric and data assimilation techniques, a multiple moveable nesting capability, and improved physical packages. WRF model can be used for a wide range of applications, from idealized research to operational forecasting, with an emphasis on horizontal grid sizes in the range of 1-10 km. The current WRF includes several different microphysics options such as Purdue Lin et al. (1983), WSM 6-class and Thompson microphysics schemes. We have recently implemented three sophisticated cloud microphysics schemes into WRF. The cloud microphysics schemes have been extensively tested and applied for different mesoscale systems in different geographical locations. The performances of these schemes have been compared to those from other WRF microphysics options. We are performing sensitivity tests in using WRF to examine the impact of six different cloud microphysical schemes on precipitation processes associated hurricanes and mesoscale convective systems developed at different geographic locations [Oklahoma (IHOP), Louisiana (Hurricane Katrina), Canada (C3VP - snow events), Washington (fire storm), India (Monsoon), Taiwan (TiMREX - terrain)]. We will determine the microphysical schemes for good simulated convective systems in these geographic locations. We are also performing the inline tracer calculation to comprehend the physical processes (i.e., boundary layer and each quadrant in the boundary layer) related to the development and structure of hurricanes and mesoscale convective systems.

Tao, Wei-Kuo↗

The structure and dynamics of mesoscale systems influencing severe thunderstorm development during AVE/SESAME 1

Relationships between meso-beta scale systems and thunderstorm formation were examined as part of the NASA atmospheric variability experiment/severe environmental storms and mesoscale experiment 1979. The McIdas program was employed for meso-beta scale analyses of atmospheric structure and dynamics in kinematic computations of the Abilene Triangle on a grid mesh of 100 km for station spacing of 275 km. Mesoscale short wave systems were detected imbedded and propagating cyclonically around upper-level vortex circulation and creating environmental conditions conducive to thunderstorm development. TIROS-N and GOES satellite data served to connect the systems with two convective storms which developed. The necessity to use spaceborne instrumentation carried on the Shuttle or on free-flying satellites for enhancing the data-base on storm development is noted.

Wilson, G. S.↗

Carbonation of Alkaline Earth Metal Hydroxides: Structure across Nano- to Mesoscales

The conversion of gaseous CO 2 into a solid constitution through mineralization is an active area of carbon capture, and alkaline earth metal hydroxides (M(OH) 2 , M = Ca 2+ , Mg 2+ ) are frontrunners in this area. As model systems, nanolime samples are excellent templates for the study of this reaction. Here, we have examined these under ambient pressure conditions with controlled humidity and CO 2 . Utilizing a broad range of analytical methods, we first established the purity and structures of the selected materials. We then examined the structural changes due to carbonation, using infrared spectroscopy, X-ray scattering, and neutron scattering. The resulting structural changes are resolved from nanoscale to mesoscale and from early-stage to late-stage carbonation. Ca(OH) 2 and Mg(OH) 2 are found to behave quite differently. As expected from prior work, the carbonation of Ca(OH) 2 is kinetically favored. Further, our structure studies suggest this is due to a facile reaction at the fractal interface of the particles. From early- to late-stage carbonation, there is a consistent increase in the fractal roughness. This is in contrast to Mg(OH) 2 where the same surface evolves into a smooth conformal coating. For this material the major reacting component is at the mesoscale, suggesting globular particle growth or evolving macro-porosity. Because neutron scattering is sensitive to hydrogen content, we expected a significant change as M(OH) 2 evolves to MCO 3 . Such a change is found for Ca(OH) 2 but not for Mg(OH) 2 , providing evidence for the formation of hydrated carbonates for the later material. The formation of a conformal layer along with water-rich carbonate formation is an impediment to the use of Mg(OH) 2 for carbon capture. For energy-efficient carbon capture, it would be desirable to enhance carbonation rates for Mg(OH) 2 , and one possible route would be the use of anhydrous fluids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗