Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Material Attributes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

Laser Materials Processing for NASA's Aerospace Structural Materials

Lasers are useful for performing operations such as joining, machining, built-up freeform fabrication, and surface treatment. Due to the multifunctional nature of a single tool and the variety of materials that can be processed, these attributes are attractive in order to support long-term missions in space. However, current laser technology also has drawbacks for space-based applications. Specifically, size, power efficiency, lack of robustness, and problems processing highly reflective materials are all concerns. With the advent of recent breakthroughs in solidstate laser (e.g., diode-pumped lasers) and fiber optic technologies, the potential to perform multiple processing techniques in space has increased significantly. A review of the historical development of lasers from their infancy to the present will be used to show how these issues may be addressed. The review will also indicate where further development is necessary to realize a laser-based materials processing capability in space. The broad utility of laser beams in synthesizing various classes of engineering materials will be illustrated using state-of-the art processing maps for select lightweight alloys typically found on spacecraft. Both short- and long-term space missions will benefit from the development of a universal laser-based tool with low power consumption, improved process flexibility, compactness (e.g., miniaturization), robustness, and automation for maximum utility with a minimum of human interaction. The potential advantages of using lasers with suitable wavelength and beam properties for future space missions to the moon, Mars and beyond will be discussed. The laser processing experiments in the present report were performed using a diode pumped, pulsed/continuous wave Nd:YAG laser (50 W max average laser power), with a 1064 nm wavelength. The processed materials included Ti-6AI-4V, Al-2219 and Al-2090. For Phase I of this project, the laser process conditions were varied and optimized to see the effects on melt-quenching, cladding/alloying (using the pre-placed powder technique), and cutting. Key parameters such laser power, pulse repetition frequency, process speed, and shield gas flow and the observed process characteristics such as plasma formation during laser/material interaction, have been reported for all experimental runs. Preliminary materials characterization of select samples was carried out using various microscopy, diffraction, spectroscopy and microhardness test methods, and reported. Select nitridation results of Ti-6AI-4V using nitrogen assist gas indicated the successful formation of hard titanium nitrides with much higher hardness (2180 kg/sq mm). A cost-effective and simple powder delivery system has been successfully fabricated for the further experimentation in Phase H.

Nagarathnam, Karthik↗

Electrochemical, Polarization, and Crevice Corrosion Testing of Inconel X750: A Supplement to the Environmental Control and Life Support System Sustaining Metal Materials Compatibility Study

In previous studies, electrochemical test results were experimentally acquired and then presented for several noble alloys in two specific solutions representative of waste liquids generated or present within the Environmental Control and Life Support System (ECLSS) aboard the International Space Station (ISS). Subsequently, another metal candidate, Inconel X750, has been submitted and was subjected to the same test routines in the same solutions and evaluated with the same statistical/analytical methodologies as those utilized in the earlier studies. Previous studies included three titanium grades, (Commercially Pure, 6Al-4V alloy, and 6Al-4V Low Interstitial alloy), two nickel-chromium alloys (Inconel® 625 and Hastelloy® C276), one high tier stainless steel (Cronidur® 30), and a nickel-titanium alloy (Nitinol 60). Thus far, all candidate alloys have exhibited excellent corrosion protection and galvanic compatibility attributes and have been deemed qualified materials for application within the ECLSS facility. Inconel X750 now joins that group. The titanium alloys gave the best results of all the metal candidates by demonstrating superior nobility and galvanic protection properties. It is worth noting that the corrosion performance properties for the three titanium alloys were essentially indistinguishable. As such and for expediency, this study and all future evaluations will refer only to the comparative properties already documented for Titanium 6Al-4V as this alloy is representative of all three alloys and considered to be more mainstream. Now the measured corrosion properties for Inconel X750 were very similar to those determined previously for Inconel 625 and Hastelloy C276 which were also determined to be very high performers. For the current effort, the results have clearly shown that Inconel X750 possesses exceptional anti-corrosion attributes comparable to metals in the highest tier of the galvanic series. Overall, one can conclude that Inconel X750 is quite noble, highly corrosion resistant and galvanically compatible with the other metal groups from both an electrochemical perspective and a long-term exposure scenario. This was clearly demonstrated after utilizing the same techniques as those applied in previous studies which included linear, Tafel and cyclic polarization, galvanic coupling with each of the other metal candidates, and pitting/crevicing assessments after one full year of immersion in the subject test solutions. Attributes defining the nobility and anti-corrosion capabilities for X750 appear to be on par with all the other candidates thus far and this alloy can now be classified as ‘excellent’ exhibiting very high resistance toward general, localized, and galvanic corrosion in the subject test media.

Lee, R. E.↗

Permittivity Measurement System Using Stripline Method for the Europa Clipper Mission

High radiation Jovian environment can deposit electrons in highly resistive dielectric materials, which could result in internal electrostatic discharge (IESD) causing damage to sensitive electronics such as the radar for Europa Assessment and Sounding: Ocean to Near-Surface (REASON) instrument on NASA’s Europa Clipper mission. Special dielectric materials like static dissipative Polyetheretherketone (PEEK) ESD are under consideration for the Europa Clipper mission. PEEK loaded with carbon nanofibers improves the ESD performance for this material but the RF characteristics are unknown. We have developed a method to characterize the dielectric constant of a material as a function of frequency and temperature down to 30K. We present the measurement results of four samples of ESD. The measured data shows the permittivity of TECAPEEK ESD 11 is in the range of 7 to 10 at HF and in the range of 6.8 to 8.3 for VHF frequencies. The change in permittivity of ESD 11 down to 30 K is less than 7% at HF and less than 3% at VHF frequency. The sample to sample variability can be attributed to the inhomogeneity of the material.

Decrossas, Emmanuel↗

Thermal emission spectra of Mars (5.4-10.5 microns) - Evidence for sulfates, carbonates, and hydrates

Spectra of the Martian thermal emission in the 5.4-10.5 micron region are reported. Emission features at 7.8 and 9.7 microns are attributed to surface silicates, and an emission feature at 6.1 micron is attributed to a molecular water component of the surface material. An absorption band at 8.7 micron and a possible one at 9.8 microns is attributed to sulfate or bisulfate anions probably located at a distorted crystalline site, and an absorption band at 6.7 microns is attributed to carbonate or bicarbonate anions located in a distorted crystalline site. Spectral simulations indicate that the sulfate- and carbonate-bearing minerals are contained in the same particles of airborne dust as the dominant silicate minerals, that the dust optical depth is about 0.6 at a reference wavelength of 0.3 micron over the area of the observed spots, and that sulfates and carbonates constitute 10-15 percent and 1-3 percent by volume of the airborne dust, respectively.

Pollack, James B.↗

Compression Strength of Sulfur Concrete Subjected to Extreme Cold

Sulfur concrete cubes were cycled between liquid nitrogen and room temperature to simulate extreme exposure conditions. Subsequent compression testing showed the strength of cycled samples to be roughly five times less than those non-cycled. Fracture surface examination showed de-bonding of the sulfur from the aggregate material in the cycled samples but not in those non-cycled. The large discrepancy found, between the samples is attributed to the relative thermal properties of the materials constituting the concrete.

Grugel, Richard N.↗

High Tensile Strength Amalgams for In-Space Fabrication and Repair

Amalgams are well known for their use in dental practice as a tooth filling material. They have a number of useful attributes that include room temperature fabrication, corrosion resistance, dimensional stability, and very good compressive strength. These properties well serve dental needs but, unfortunately, amalgams have extremely poor tensile strength, a feature that severely limits other potential applications. Improved material properties (strength and temperature) of amalgams may have application to the freeform fabrication of repairs or parts that might be necessary during an extended space mission. Advantages would include, but are not limited to: the ability to produce complex parts, a minimum number of processing steps, minimum crew interaction, high yield - minimum wasted material, reduced gravity compatibility, minimum final finishing, safety, and minimum power consumption. The work presented here shows how the properties of amalgams can be improved by changing particle geometries in conjunction with novel engineering metals.

Grugel, Richard N.↗

Search for a meteoritic component at the Beaverhead impact structure, Montana

The Beaverhead impact structure, in southwestern Montana, was identified recently by the presence of shatter cones and impactites in outcrops of Proterozoic sandstones of the Belt Supergroup. The cones occur over an area greater than 100 sq km. Because the geologic and tectonic history of this region is long and complex, the outline of the original impact crater is no longer identifiable. The extent of the area over which shatter cones occur suggests, however, that the feature may have been at least 60 km in diameter. The absence of shatter cones in younger sedimentary units suggests that the impact event occurred in late Precambrian or early Paleozoic time. We have collected samples of shocked sandstone from the so-called 'Main Site' of dark-matrix breccias, and of impact breccias and melts from the south end of Island Butte. The melts, occurring often as veins through brecciated sandstone, exhibit a distinctive fluidal texture, a greenish color, and a cryptocrystalline matrix, with small inclusions of deformed sandstone. Samples of the same type, along with country rock, were analyzed previously for major- and trace-element abundances. It was found that, although the major-element composition as relatively uniform, trace-element composition showed variations between the melt material and the adjacent sandstone. These variations were attributed to extensive weathering and hydrothermal alteration. In a more specific search for a possible meteoritic signature in the breccia and the melt material we have conducted a new series of trace-element analyses on powders of our own samples by thermal neutron activation analysis. Our results indicate that Ir abundances in the breccia, the melts, and the adjacent sandstone clasts are no greater than about 0.1 ppb, suggesting no Ir enrichment of the breccia or the melts relative to the country rock. However, both the breccia and the melt material exhibit notable enrichments in Cr (8- and 10-fold), in U (9- and 5-fold), and in the heavy REE's (1.5- and 3-fold), respectively.

Lee, Pascal↗

Experimental Investigation of the Mechanical Behavior of a Filled Elastomer at Pressures Below 10 to the -6th Power Torr

The mechanical behavior of a filled elastomer was studied with emphasis on understanding the vacuum-material interactions occurring, and to develop analytical techniques for predicting the vacuum behavior. The test results indicate that two separate mechanisms are involved in the observed property changes: the first controls the time response to applied stress; the second determines the initial internal state of the materials as the result of stresses. It is concluded that the mechanical property changes are attributable to changes in the relaxation processes occurring in the material. These changes are brought about by outgassing of water. Recommendations for future investigations are included.

Gregory, G. L.↗

Manufacture and static firing of X259-E6 rocket motor serial number XJ04/0001

A single motor was cast and static fired to demonstrate the performance of high energy crosslinked double base (XLDB) propellant in standard X259 rocket motor hardware. Prior to motor fabrication, the motor was analyzed to predict the results of static firing the X259 motor loaded with XLDB propellant. As a result of the analyses, a forward dome shrinkage liner was added to the design. With this design change it was determined that adequate margins of safety existed. The motor, designated the X259-E6 model with serial number XJ04/0001, was fabricated using a slurry-casting technique and was assembled with a standard X259-B4 nozzle which had the nozzle throat machined to a smaller inside diameter than the B4 model and the exit cone cut short for Bacchus Works altitude expansion. The motor was static fired on 20 February 1974 with the nozzle failing during motor operation. Nozzle failure was attributed to spalling of the throat material leading to complete nozzle break-up. However, the propellant functioned as predicted in the motor chamber, ignition was normal, and char and erosion of the internal insulator were as expected.

Robertson, D. R.↗

Mars surface properties observed by earth-based radar at 70-, 12.5-, and 3.8-cm wavelengths

In the present paper, the results are summarized of a study aimed at determining the small-scale surface properties of Mars (for the Viking project) from a thorough review of all available Martian radar data for the 1973 opposition. Analysis of the quasi-specular echo component showed changes in apparent reflectivity of at least 5 to 1. If attributed entirely to variations in surface material, these correspond to dielectric constants between 1.6 and 4.0. Values of rms surface slope on 1- to 100-m scales range from as low as 0.5 degrees in tablelands near Valles Marineris to more than 3.0 degrees in certain other areas. There is a weak correlation between the small-scale surface characteristics inferred from radar and those inferred from Mariner 9 images and other remote-sensing data sets.

Simpson, R. A.↗

Thermophysical properties data on graphite/polyimide composite materials

Experimental data for the thermal conductivity, thermal expansion, specific heat, and emittance of laminates of HTS/NR 150B2 and HTS/PMR 15 are presented. Measurements were made over the temperature range 116 K to 588 K. Results for the two materials were similar with some differences attributable to laminate quality. Higher expansion coefficients for the HTS/PMR 15 specimens in the resin-dominated directions indicate a higher coefficient for PMR 15 than NR 150B2.

Campbell, M. D.↗

Thermophysical properties data on graphite/polyimide composite materials

Experimental data for the thermal conductivity, thermal expansion, specific heat, and emittance of laminates of HTS/NR 150B2 and HTS/PMR 15 are presented. Measurements were made over the temperature range 116 K to 588 K. Results for the two materials were similar with some differences attributable to laminate quality. Higher expansion coefficients for the HTS/PMR 15 specimens in the resin-dominated directions indicate a higher coefficient for PMR 15 than NR 150B2. Previously announced in STAR as N80-14197

Campbell, M. D.↗

Microstructure and orientation effects on properties of discontinuous silicon carbide/aluminum composites

Composite panels containing up to 40 vol % discontinuous silicon carbide SiC whisker, nodule, or particulate reinforcement in several aluminum matrices are commercially fabricated and the mechanical properties and microstructual characteristics are evaluated. The yield and tensile strengths and the ductility are controlled primarily by the matrix alloy, the temper condition, and the reinforcement content. Particulate and nodule reinforcements are as effective as whisker reinforcement. Increased ductility is attributed to purer, more uniform starting materials and to more mechanical working during fabrication. Comparing mechanical properties with those of other aluminum alloys shows that these low cost, lightweight composites demonstrate very good potential for application to aerospace structures.

Mcdanels, D. L.↗

The possible presence of interstellar PAHs in meteorites and interplanetary dust particles

The Raman spectra of interplanetary dust particles (IDPs) collected in the stratosphere show two bands at about 1350 and 1600 delta cm(-1) and a broader feature between 2200 and 3300 delta cm(-1) that are characteristic of aromatic molecular units with ordered domains smaller than 25A in diameter. This suggests that the carbonaceous material in IDPs may be similar to the polymeric component seen in meteorites, where this material is thought to consist of aromatic molecular units that are randomly inter-linked by short aliphatic bridges. The features in the Raman spectra of IDPs are similar in position and relative strength to interstellar infrared emission features that have been attributed to vibrational transitions in free molecular polycyclic aromatic hydrocarbons (PAHs). The Raman spectra of some IDPs also showed photoluminescence that is similar to the excess red emission from some astronomical objects and that has also been attributed to PAHs and PAH-related materials. Moreover, a part of the carbonaceous phase in IDPs contains deuterium to hydrogen ratios that are far greater than those found in terrestrial samples. Deuterium enrichment is expected in small free PAHs that are exposed to ultraviolet radiation in the interstellar medium. Taken together, these observations suggest that some fraction of the carbonaceous material in IDPs may have been produced in circumstellar dust shells and only slightly modified in interstellar space. Since many, if not most, IDPs come from comets, this supports the view that cometary material contains primitive components which can provide clues about early solar system (and perhaps even interstellar and circumstellar) processes.

Allamandola, L. J.↗

Material and tribological considerations for turbopump bearings

The frictional heat generation in the rolling/sliding contact areas of high pressure oxygen turbopump (HPOTP) bearings is a key factor in bearing life. Several bulk materials, surface treatments and coatings are examined for their attributes of rolling contact fatigue life, wear and friction. Emphasis is given to the frictional response of these materials under conditions of rolling with incipient sliding as predicted from HPOTP bearing analysis. Rolling contact fatigue life is shown to be significantly improved with silicon nitride. Fatigue life can also be improved by coating the chromium carbide-laden stainless steels (440C, BG42) with TiN and thin dense chrome. The traction (friction under rolling/sliding) of these materials is discussed in terms of microslip and the presence of interfacial films.

Wedeven, L. D.↗

A high-resolution radar and CCD imaging study of crater rays in Mare Serenitatis and Mare Nectaris

Radar and spectral image processing techniques are reviewed and their application to the rays in Mare Serenitatis and Mare Nectaris is discussed. Analysis of data for Mare Serenitatis shows that the ray that passes west of the Bessel Crater is characterized by up to 40 percent highland ejecta. Radar data show that optically bright ray deposits are characterized by enhanced 1-50 cm scale roughness within the upper meter of the regolith, but not by enhanced 1-10 m blockiness. Stokes vector analysis of the 3.0 cm radar echoes shows that the western portion of the Bessel ejecta blanket is characterized by an anomalously high nondiffuse depolarized return. The ray analyzed in Mare Nectaris passes close to Rosse Crater and is characterized by a cluster of bright secondary craters within a radar-rough halo downrange of Tycho. This downrange deposit is attributed to excavation of local fragmental material by a secondary debris surge.

Campbell, Bruce A.↗

Thermogravimetric study of oxidation of a PdCr alloy used for high-temperature sensors

In this study, the oxidation of Pd-13 weight percent Cr, a candidate alloy for high-temperature strain gages, was investigated by thermogravimetry. Although the bulk alloy exhibits linear electrical resistivity versus temperature and stable resistivity at elevated temperatures, problems attributed to oxidation occur when this material is fabricated into strain gages. In this work, isothermal thermogravimetry (TG) was used to study the oxidation kinetics. Results indicate that the oxidation of Pd-13 weight percent Cr was approximately parabolic in time at 600 C but exhibited greater passivation from 700 to 900 C. At 1100 C, the oxidation rate again increased.

Boyd, Darwin L.↗

Space flight printed wiring board measling investigation

A flight printed wiring board (PWB) for a satellite project was observed to have a high incidence of measling. Other PWB's produced for the program by the same manufacturer did not exhibit the degree of measling as did the 'measle-prone' board. Measling susceptibility during hand soldering and measling effects on PWB insulation resistance were investigated for three production PWB's. Measling resistance was significantly different between the three boards: the 'worst' exhibited five times the number of measles as the 'best' board. 'Severe' measling (that which is likely to affect board reliability) did not exist on the 'best' board, even under extreme soldering conditions (399 degrees C for 12-15 sec.), whereas the 'worst' board showed an average of one 'severe' measle for every two pads under more normal soldering conditions (288-343 degrees C for 2-5 sec.). Both soldering time and temperature affected measling, with time having a slightly greater influence (2 percent versus 12 percent). Measling effects on PWB insulation resistance were inconclusive. These were evaluated by in situ resistance measurements on the same three boards at elevated temperature and humidity. The measured resistance for all three boards decreased for exposures greater than 50 degrees C and 50 percent relative humidity. The 'measle-prone' board showed a resistance decrease at only 25 degrees C and 50 percent relative humidity. However, no definitive difference was detected between measled and not-measled (control) samples. The boards evaluated were production boards, so the effect of interlayer traces connecting the plated-through holes was not controlled. It is likely the resistance measurements were over different volumes of PWB laminate, which would account for the widely varying resistances measured. Thermomechanical measurements on board laminate materials did not reveal any differences attributed to measling. Differences in glass transition temperature were significantly different when measured by DTA, but not by SDT. Laminate thermal expansion differences were significant for the 35 degrees C evaluations, but not for any higher temperatures.

Thomas, Walter B., III↗