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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS2019

Outstanding Natural Occurrence of TiO2-II at the Chicxulub Crater - Anatomy of A Shock-Produced High-Pressure Polymorph

Scientific drilling of the end-Cretaceous, approximately 180 kilometers-diameter Chicxulub crater (Yucatan Peninsula, Mexico) during IODP–ICDP (Integrated Ocean Drilling Program - International Continental Scientific Drilling Program) Expedition 364 has provided new insights into the formation, shock metamorphism, structural evolution, and thermal history of peak rings in large complex impact craters. An outstanding feature in uplifted granitoid rocks of the Chicxulub peak ring is the preservation of TiO2-II, an orthorhombic high-pressure polymorph of TiO2 with an alpha-PbO2 structure, produced during the impact from rutile and/or anatase at shock pressures of approximately 12.5-17.5 gigapascals. Unlike other mostly micro- and cryptocrystalline occurrences of TiO2-II at terrestrial impact sites, ejecta deposits, and in rare ultra-high pressure metamorphic rocks, TiO2-II at Chicxulub occurs as abundant euhedral crystals greater than or equal to 70 microns in size within aggregates of altered magmatic titanite. This mode of occurrence provides an excellent opportunity to investigate the crystallography and transformation kinetics of the shock-produced high-pressure polymorph using scanning electron microscopic, micro-Raman, electron backscatter diffraction (EBSD), focused ion beam (FIB), as well as transmission-EBSD and transmission electron microscopic (TEM) techniques. Here we present refined microstructural and new crystallographic results for TiO2-II at the Chicxulub crater.

Schmieder, Martin↗
NASA NTRS1977

A chemical model for lunar non-mare rocks

Nearly all rocks returned from the moon are readily divided into three broad categories on the basis of their chemical compositions: (1) mare basalts, (2) non-mare rocks of basaltic composition (KREEP, VHA), and (3) anorthositic rocks. Only mare basalts may unambiguously be considered to have original igneous textures and are widely understood to have an igneous origin. Nearly all other lunar rocks have lost their original textures during metamorphic and impact processes. For these rocks one must work primarily with chemical data in order to recognize and define rock groups and their possible modes of origin. Non-mare rocks of basaltic composition have chemical compositions consistent with an origin by partial melting of the lunar interior. The simplest origin for rocks of anorthositic chemical composition is the crystallization and removal of ferromagnesian minerals. It is proposed that the rock groups of anorthositic and non-mare basaltic chemical composition could have been generated from a single series of original, but not necessarily primitive, lunar materials.

Hubbard, N. J.↗
NASA NTRS1997

Geochemistry of approximately 1.9 Ga sedimentary rocks from northeastern Labrador, Canada

Fifty-eight rock chips from fifteen samples of sedimentary rocks from the Ramah Group (approximately 1.9 Ga) in northeastern Labrador, Canada, were analyzed for major and minor elements, including C and S, to elucidate weathering processes on the Earth's surface about 1.9 Ga ago. The samples come from the Rowsell Harbour, Reddick Bight, and Nullataktok Formations. Two rock series, graywackes-gray shales of the Rowsell Harbour, Reddick Bight and Nullataktok Formations, and black shales of the Nullataktok Formation, are distinguishable on the basis of lithology, mineralogy, and major and trace element chemistry. The black shales show lower concentrations than the graywackes-gray shales in TiO2 (0.3-0.7 wt% vs. 0.7-1.8 wt%), Al2O3 (9.5-20.1 wt% vs. 13.0-25.0 wt%), and sigma Fe (<1 wt% vs. 3.8-13.9 wt% as FeO). Contents of Zr, Th, U, Nb, Ce, Y, Rb, Y, Co, and Ni are also lower in the black shales. The source rocks for the Ramah Group sediments were probably Archean gneisses with compositions similar to those in Labrador and western Greenland. The major element chemistry of source rocks for the Ramah Group sedimentary rocks was estimated from the Al2O3/TiO2 ratios of the sedimentary rocks and the relationship between the major element contents (e.g., SiO2 wt%) and Al2O3/TiO2 ratios of the Archean gneisses. This approach is justified, because the Al/Ti ratios of shales generally retain their source rock values; however, the Zr/Al, Zr/Ti, and Cr/Ni ratios fractionate during the transport of sediments. The measured SiO2 contents of shales in the Ramah Group are generally higher than the estimated SiO2 contents of source rocks by approximately 5 wt%. This correction may also have to be applied when estimating average crustal compositions from shales. Two provenances were recognized for the Ramah Group sediments. Provenance I was comprised mostly of rocks of bimodal compositions, one with SiO2 contents approximately 45 wt% and the other approximately 65 wt%, and was the source for most sedimentary rocks of the Ramah Group, except for black shales of the Nullataktok Formation. The black shales were apparently derived from Provenance II that was comprised mostly of felsic rocks with SiO2 contents approximately 65 wt%. Comparing the compositions of the Ramah Group sedimentary rocks and their source rocks, we have recognized that several major elements, especially Ca and Mg, were lost almost entirely from the source rocks during weathering and sedimentation. Sodium and potassium were also leached almost entirely during the weathering of the source rocks. However, significant amounts of Na were added to the black shales and K to all the rock types during diagenesis and/or regional metamorphism. The intensity of weathering of source rocks for the Ramah Group sediments was much higher than that of typical Phanerozoic sediments, possibly because of a higher PCO2 in the Proterozoic atmosphere. Compared to the source rock values, the Fe3+/Ti ratios of many of the graywackes and gray shales of the Ramah Group are higher, the Fe2+/Ti ratios are lower, and the sigma Fe/Ti ratios are the same. Such characteristics of the Fe geochemistry indicate that these sedimentary rocks are comprised of soils formed by weathering of source rocks under an oxygen-rich atmosphere. The atmosphere about 1.9 Ga was, therefore, oxygen rich. Typical black shales of Phanerozoic age exhibit positive correlations between the organic C contents and the concentrations of S, U, and Mo, because these elements are enriched in oxygenated seawater and are removed from seawater by organic matter in sediments. However, such correlations are not found in the Ramah Group sediments. Black shales of the Ramah Group contain 1.7-2.8 wt% organic C, but are extremely depleted in sigma Fe (<1 wt% as FeO), S (<0.3 wt%), U (approximately l ppm), Mo (<5 ppm), Ni (<2 ppm), and Co (approximately 0 ppm). This lack of correlation, however, does not imply that the approximately 1.9 Ga atmosphere-ocean system was anoxic. Depletion of these elements from the Ramah Group sediments may have occurred during diagenesis.

Non-NASA Center↗
NASA NTRS1992

Bohemian circular structure, Czechoslovakia: Search for the impact evidence

Test of the impact hypothesis for the origin of the circular, 260-km-diameter structure of the Bohemian Massif led to the discovery of glasses and breccias in the Upper Proterozoic sequence that can be compared to autogeneous breccias of larger craters. The black recrystallized glass contains small exsolution crystals of albite-oligoclase and biotite, regularly dispersed in the matrix recrystallized to quartz. The occurrence of these rocks is limited to a 1-sq-km area. It is directly underlain by the breccia of the pelitic and silty rocks cemented by the melted matrix, found on several tens of square kilometers. The melt has the same chemistry as rock fragments in major and in trace elements. It is slightly impoverished in water. The proportion of melted rocks to fragments varies from 1:5 to 10:1. The mineralogy of melt viens is the function of later, mostly contact metamorphism. On the contact of granitic plutons it abounds on sillimanite, cordierite, and small bullets of ilmenite. Immediately on the contact with syenodiorites it contains garnets. The metamorphism of the impact rock melt seems the most probable explanation of the mineralogy and the dry total fusion of rocks accompanied by the strong fragmentation. Other aspects of this investigation are discussed.

Rajlich, Petr↗
NASA NTRS1992

Heat sources for tertiary metamorphism and anatexis in the Annapurna-Manaslu region, central Nepal

The metamorphic evolution of the rocks near the Main Central Thrust in the Annapurna-Manaslu region of central Nepal is examined. In this region, all three types of metamorphic features can be observed: regional metamorphism, anatectic granitoids, and inverted metamorphic isograds. In this work, each phase of metamorphism is treated separately to estimate the heat sources required for each process. This approach makes it possible to identify the important parameters for each process, to draw preliminary conclusions about the heat sources required for each of these phases, and to determine which parameters need to be measured more precisely in order to constrain these heat sources.

England, Philip↗
NASA NTRS1986

Fluid-absent metamorphism in the Adirondacks

Results on late Proterozoic metamorphism of granulite in the Adirondacks are presented. There more than 20,000 sq km of rock are at granulite facies. Low water fugacites are implied by orthopyroxene bearing assemblages and by stability of k'spar-plag-quartz assemblages. After mentioning the popular concept of infiltration of carbon dioxide into Precambrian rocks and attendent generation of granulite facies assemblages, several features of Adirondack rocks pertinent to carbon dioxide and water during their metamorphism are summarized: wollastonite occurs in the western lowlands; contact metamorphism by anorthosite preceeding granulite metamorphism is indicated by oxygen isotopes. Oxygen fugacity lies below that of the QFM buffer; total P sub water + P sub carbon dioxide determined from monticellite bearing assemblages are much less than P sub total (7 to 7.6 kb). These and other features indicate close spatial association of high- and low-P sub carbon dioxide assemblages and that a vapor phase was not present during metamorphism. Thus Adirondack rocks were not infiltrated by carbon dioxide vapor. Their metamorphism, at 625 to 775 C, occurred either when the protoliths were relatively dry or after dessication occurred by removal of a partial melt phase.

Valley, J. W.↗
NASA NTRS1992

Hong Kong is an impact crater: Proof from the geomorphological and geological evidence

Hong Kong is a city in southern China. The urban districts of Hong Kong, Kowloon, and Victoria Harbour are situated within Hong Kong. Hong Kong is surrounded by mountains with a diameter of 11 km. Three million people live inside the basin. The round structure of the mountains in Hong Kong has been describd as a granite dome that is deeply eroded (batholith). The circularity of the mountains, the existence of a central hill, the inner slope of the mountains being greater than the outer slope, the presence of deep layer rock inside the basin, and the depth-to-diameter ratio were studied. All this evidence shows that the Hong Kong structure satisfies the geomorphological requirement of an impact crater. Some shock metamorphic phenomena of the rocks in Hong Kong such as planar features, microspherilitic silica glass (lechaterlierite), fused margins of rock fragments, concussion fractures, impact glass in which some schlierens are consistent with pyroxene spiculites, etc., were first discovered in Oct. 1990. In Hong Kong Island, an impact melt sheet was observed from the Victoria Peak to the southern shore. Quenching fractures of quartz in Kowloon fine-grained granite was also discovered. In our work, the K-Ar age (83.34 + 1.26 m.y.) of the impact melt rock, which is younger in comparison to the K-Ar age (117 m.y.) in Hong Kong and Kowloon granite, was measured, and the phenomena indicate that after the granite body formed, there was another geologic event. Maybe it is the Hong Kong cratering event.

Chan, Chu-Lok↗
NASA NTRS1992

Diaplectic transformation of minerals: Vorotilov drill core, Puchezh-Katunki impact crater, Russia

The Vorotilov core was drilled in the central uplift of the Puchezh-Katunki astrobleme to a depth of 5.1 km. Impactites are revealed in the rocks of the core beginning from a depth of 366 m: suevites (66 m), allogenic breccias (112 m), and autogenic breccias (deeper than 544 m). These rocks are represented by shocked-metamorphic gneisses, schists, amphibolites of Archean age, and magmatic rocks (dolerites, olivines, and peridotites) that lie between them.

Feldman, V. I.↗
NASA NTRS1975

Rb-Sr study of a lunar dunite and evidence for early lunar differentiates

An Rb-Sr study of Boulder 3 from Station 2 sampled during the Apollo 17 mission is reported. The investigated boulder is a metaclastic rock, inferred to have come from the South Massif, and contains a variety of lithic clasts. Since the rock type may be critical in understanding lunar differentiation processes, an extensive investigation was carried out of the dunite clast and other clasts as well as of the fine-grained matrix. The investigation had the purpose to define the age of crystallization of the dunite and to determine the extent to which later metamorphism of the host rock may have effected the isotopic systematics of this clast. The isochron determined yielded an age of 4.55 plus or minus 0.10 AE for the dunite. This result demonstrates that differentiation began close to the time of formation of the moon and that relics of this process are preserved.

Papanastassiou, D. A.↗
NASA NTRS1996

Diogenites: Cumulates from Asteroid 4 Vesta: Insights from Orthopyroxene and Spinel Chemistry

Cumulate rocks are important planetary lithologies, but they can be difficult to interpret. Important clues to the nature of their parental melts may still be present in the interiors of cumulus phases. However, in some cases, even the cores of the cumulus grains may have been modified by postcrystallization reactions with trapped melt and other cumulus phases. We have previously studied the major-, minor-, and trace-element chemistry of orthopyroxene from a suite of diogenites and concluded that their chemical attributes can best be explained by crystallization from parental melts that were derived from a depleted mantle source that had already experienced eucrite removal. However, we and others have had difficulty explaining the great range in concentration of minor elements (Al, Ti) and trace elements (REE, Y, Zr) if all diogenites were derived from a single magmatic system. Therefore, we have investigated the chemistry of diogenitic spinels to see if they still held clues to the diogenite parental melt compositions. Although spinel is low in abundance in diogenites (<5 vol%) it still may hold clues to the maomatic and metamorphic history of these rocks.

Papike, James J.↗
NASA NTRS1988

Metasediments of the deep crustal section of Southern Karnataka

A review of the rocks of supracrustal origin in the amphibolite and granulite facies terrane in southern Karnataka was presented. In addition to introducing the metasediments in the field area of the workshop, a review was presented of the common occurrence of metasediments in amphibolite and granulite facies rocks worldwide. Models of granulite metamorphism must include a mechanism for the burial of these sediments to the depths recorded by the geobarometers in granulite metamorphism in addition to their reexposure at the surface. Unfortunately, the common occurrence of supracrustals in granulite facies rocks, sometimes with remarkably little deformation was deemed significant.

Devaraju, T. C.↗
NASA NTRS2018

Enigmatic Nodule-Bearing Rocks in the Mafic to Ultramafic Diana Mills Pluton, Piedmont Province, Virginia

The Silurian Diana Mills pluton is a metamorphosed mafic-ultramafic body in the Piedmont Province of Virginia. Major rock types in the pluton include metadiorite and chlorite‐amphibole rock, with lesser amounts of hornblendite. However, the most visually striking rocks, found at 4 locations, consist of tan‐weathering nodules in a dark green matrix. The purpose of this study was to investigate the origin of these nodular rocks. All rocks show evidence of greenschistfacies metamorphism, but relict igneous textures are preserved locally. Apart from the nodules, Ca‐amphibole is ubiquitous in all rock types. Nodules are dominated by serpentine or talc (+magnetite +/- chromite), and many show a thin (less than or equal to 5 mm) radially oriented shell of serpentine against adjacent matrix. The nodules are ultramafic (Mg# approx. 80-90, up to7,563 ppm Cr, up to 2,038 ppm Ni), and their normative mineralogy is dominated by olivine and orthopyroxene. Thus, they represent metamorphosed harzburgites and pyroxenites. Matrix minerals are dominantly amphibole + chlorite, along with variable amounts of talc + magnetite. Some matrix samples are chlorite‐rich, probably reflecting metasomatic reaction with nodules (i.e., they are small‐scale ''blackwalls''). Matrix samples are also ultramafic (high Mg#, Cr, and Ni). The matrix of the nodule‐bearing outcrops is essentially the same as other chlorite‐amphibole rocks elsewhere in the pluton. We consider these rocks to represent emplacement of an original hornblende peridotite crystal mush (a mixture of crystals and hydrous melt), which locally carried harzburgitic nodules. The nodules most likely represent the earliest‐formed cumulates from the Diana Mills parent magma.

Owens, Brent E.↗
NASA NTRS1985

Thermal history of a metamorphic core complex

Fission track (FT) thermochronology studies of lower plate rocks of the Ruby Mountains-East Humbolt Range metamorphic core complex provide important constraints on the timing an nature of major middle Tertiary extension of northeast Nevada. Rocks analyzed include several varieties of mylonitic orthogneiss as well as amphibolitic orthognesses from the non-mylonitic infrastructural core. Oligocene-age porphyritic biotite granodiorite of the Harrison Pass pluton was also studied. The minerals dated include apatite, zircon, and sphene and were obtained from the same rocks that have been previously studied. FT ages are concordant and range in age from 26.4 Ma to 23.8 Ma, with all showing overlap at 1 sigma between 25.4 to 23.4 Ma. Concordancy of all FT ages from all structural levels indicates that the lower plate cooled rapidly from temperatures above approx. 285 C (assumed sphene closure temperature (2)) to below approx. 150 C (assumed apatite closure temperature) near the beginning of the Miocene. This suggests that the lower plate cooled at a rate of at least approx. 36 deg C/Ma during this event. Rapid cooling of the region is considered to reflect large-scale tectonic denudation (intracrustal thinning), the vertical complement to intense crustal extension. FT data firmly establish the upper limit on the timing of mylonitization during detachment faulting and also coincide with the age of extensive landscape disruption.

Dokka, R. K.↗
NASA NTRS1986

Isukasia area: Regional geological setting (includes excursion guide)

A brief account of the geology of the Isukasis area is given and is biased toward the main theme of the itinerary for the area: What has been established about the protoliths of the early Archean rocks of the area - the Isua supracrustal belt and the Amitsoq gneisses? The area's long and complex tectonometamorphic history of events can be divided into episodes using a combination of dike chronology, isotopic, and petrological studies. The earliest dikes, the ca 3700 Ma Inaluk dikes, intrude the earliest (tonalitic) components of the Amitsoq gneisses but are themselves cut up by the injection of the younger (granitic and pegmatitic) phases of the Amitsoq gneisses of the area. The areas of low late Archean deformation, strongly deformed early Archean mafic rocks have coarse grained metamorphic segregations and are cut by virtually undeformed mid-Archean Tarssartoq (Ameralik) dikes devoid of metamorphic segregations. The shows that the area was affected by regional amphibolite facies metamorphism in the early Archean. Late Archean and Proterozoic metamorphic imprints are marked to very strong in the area. Much of the early Archean gneiss complex was already highly deformed when the mid-Archean Tarssartoq dikes were intruded.

Nutman, A. P.↗
NASA NTRS1988

Characterization of fluids involved in the Gneiss-Charnockite transformation in Southern Kerala (India)

The characterization of fluids involved in the gneiss-charnockite transformation in southern Kerala are discussed. Using a variety of techniques, including microthermometry, Raman laser probe analysis, and mass spectrometry, it was concluded that the CO2-rich, N2-bearing metamorphic fluids in these rocks were internally-derived rather than having been introduced by CO2-streaming.

Klatt, E.↗
NASA NTRS1993

Rubidium and cesium in the earth and the moon

The purpose of the study is to provide an alternative perspective on both the mass balance issue and on the issue of secular change in the Rb-Cs ratio in the earth mantle. In particular, it is argued that the apparent secular change in the Rb/Cs ratio may be simply an artifact of alteration of older rocks through weathering and/or metamorphism subsequent to formation. It is also shown that there is not necessarily a need for a hidden, undepleted reservoir, and the consistency of this result with other mass calculations is explored. New methods for estimating the Rb/Cs ratio of the bulk silicate earth are suggested.

Jones, John H.↗
NASA NTRS1993

Manson impact structure, Iowa: First geochemical results for drill core M-1

The Manson Impact Structure is a large complex impact crater centered ca. S km north of the town of Manson, Iowa. It is the largest intact impact structure recognized in the United States (35 km in diameter). Its Ar-40/Ar-39 age is indistinguishable from that of the Cretaceous-Tertiary (K-T) boundary. The Manson structure may be one element of the events at the K-T boundary. The crater is completely covered by Quaternary glacial sedimentary deposits that are normally underlain by Cretaceous clastic sediments and flat-lying carbonate sediments of Phanerozoic age, as well as Proterozoic red clastic, metamorphic, volcanic, and plutonic rock sequences. The study of a reflection seismic profile, provided by Amoco, was critical in interpreting the structure. In the 35 km diameter zone that marks the extension of the crater the normal rock sequence is disturbed due to the impact, and at the center of the structure granitic basement rocks are present that have been uplifted from about 4 km depth. Our studies consist of detailed petrological and geochemical characterization of all cores, with emphasis on a detailed description of all rock types found in the core samples and their relationship to target rocks. Geochemical data on samples from the Manson M-1 core are presented.

Koeberl, Christian↗