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At least 109 records · Page 6

Cross-linking connectivity in bone collagen fibrils: the COOH-terminal locus of free aldehyde

Quantitative analyses of the chemical state of the 16c residue of the alpha 1 chain of bone collagen were performed on samples from fetal (4-6-month embryo) and mature (2-3 year old) bovine animals. All of this residue could be accounted for in terms of three chemical states, in relative amounts which depended upon the age of the animal. Most of the residue was incorporated into either bifunctional or trifunctional cross-links. Some of it, however, was present as free aldehyde, and the content increased with maturation. This was established by isolating and characterizing the aldehyde-containing peptides generated by tryptic digestion of NaB3H4-reduced mature bone collagen. We have concluded that the connectivity of COOH-terminal cross-linking in bone collagen fibrils changes with maturation in the following way: at first, each 16c residue in each of the two alpha 1 chains of the collagen molecule is incorporated into a sheet-like pattern of intermolecular iminium cross-links, which stabilizes the young, nonmineralized fibril as a whole. In time, some of these labile cross-links maturate into pyridinoline while others dissociate back to their precursor form. The latter is likely due to changes in the molecular packing brought about by the mineralization of the collagen fibrils. The resultant reduction in cross-linking connectivity may provide a mechanism for enhancing certain mechanical characteristics of the skeleton of a mature animal.

NASA Discipline Musculoskeletal

Considerations for Isochronous Data Services over the Proximity-1 Space Link

Future mission concepts for robotic and human explorations will involve a high level of real time control/monitoring operations such as tele-operation for spacecraft rendezvous and surface mobile platforms carrying life-support equipments. The timely dissemination of voice, command, and real-time telemetry for monitoring and coordination purposes is critical for mission success. It is envisioned that future missions will require a network infrastructure capable of supporting isochronous data services. The CCSDS Proximity-1 Space Link Protocol1 could be used to carry isochronous traffic. This paper we will focus on the data link layer portion of the Proximity-1 protocol specification and analyze its jitter and performance for supporting isochronous applications. In particular we will focus on constrained scenarios where the protocol operates in full-duplex mode, carrying isochronous traffic in one direction and error-controlled traffic in the other direction. We analyze the impact of the strict priority scheme in Proximity-1 used to arbitrate channel access on the latency jitter of the isochronous traffic and the efficiency of the reliable data transfer. In general, jitter performance is driven by the loading of the acknowledgement traffic on the forward link. Under light loading condition, the upper-bound of the delay jitter is the transmission duration of an acknowledgement frame on the forward link; for higher loading scenarios, the maximum jitter is scaled up by the inverse of the residual bandwidth, i.e., the spare capacity available in the forward link after accounting for the acknowledgement traffic. We derive analytical expression on the maximum jitter and discuss its performance.

space link

Distinguishing Single and Linked Ruptures in the Laboratory and Nature

Earthquakes can grow either monotonically from a single, stressed patch or through linking multiple stressed regions. The distinction has implications for magnitude predictability with single ruptures requiring knowledge of the local stress state, while linked ruptures require knowing the global stress and energy distribution. Here, we use a laboratory fault that allows direct observation of slip to determine which fault conditions promote linked ruptures, and how to observationally evaluate their likelihood. Higher concentrations of normal stress due to increased normal force, applied stress asperities, or larger heterogeneity between the samples, all lead to significant increases in linked rupture likelihood. The mean radiated energy enhancement factor (REEF) of large events is an excellent proxy for linked event likelihood, and a combination of REEF and duration can identify the rupture style of some but not all events. The results imply that globally observed variations of REEF can be interpreted as variations in stress concentration.

earthquakes

Reversible two-way tuning of thermal conductivity in an end-linked star-shaped thermoset

Polymeric thermal switches that can reversibly tune and significantly enhance their thermal conductivities are desirable for diverse applications in electronics, aerospace, automotives, and medicine; however, they are rarely achieved. Here, we report a polymer-based thermal switch consisting of an end-linked star-shaped thermoset with two independent thermal conductivity tuning mechanisms—strain and temperature modulation—that rapidly, reversibly, and cyclically modulate thermal conductivity. The end-linked star-shaped thermoset exhibits a strain-modulated thermal conductivity enhancement up to 11.5 at a fixed temperature of 60 °C (increasing from 0.15 to 2.1 W m –1 K –1 ). Additionally, it demonstrates a temperature-modulated thermal conductivity tuning ratio up to 2.3 at a fixed stretch of 2.5 (increasing from 0.17 to 0.39 W m –1 K –1 ). When combined, these two effects collectively enable the end-linked star-shaped thermoset to achieve a thermal conductivity tuning ratio up to 14.2. Moreover, the end-linked star-shaped thermoset demonstrates reversible tuning for over 1000 cycles. The reversible two-way tuning of thermal conductivity is attributed to the synergy of aligned amorphous chains, oriented crystalline domains, and increased crystallinity by elastically deforming the end-linked star-shaped thermoset.

42 ENGINEERING

Anticipating Optical Availability in Hybrid RF/FSO Links Using RF Beacons and Deep Learning

Radiofrequency (RF) communications offer reliable but low data rates and energy-inefficient satellite links, while free-space optical (FSO) promises high bandwidth but struggles with disturbances imposed by atmospheric effects. A hybrid RF/FSO architecture aims to achieve optimal reliability along with high data rates for space communications. Accurate prediction of dynamic ground-to-satellite FSO link availability is critical for routing decisions in low-earth orbit constellations. In this paper, we propose a system leveraging ubiquitous RF links to proactively forecast FSO link degradation prior to signal drops below threshold levels. This enables pre-calculation of rerouting to maximally maintain high data rate FSO links throughout the duration of weather effects. We implement a supervised learning model to anticipate FSO attenuation based on the analysis of RF patterns. Through the simulation of a dense lower earth orbit (LEO) satellite constellation, we demonstrate the efficacy of our approach in a simulated satellite network, highlighting the balance between predictive accuracy and prediction duration. An emulated cloud attenuation model is proposed to provide insight into the temporal profiles of RF signals and their correlation to FSO channel dynamics. Our investigation sheds light on the trade-offs between prediction horizon and accuracy arising from RF beacon numbers and proximity.

FSO availability

A multigigabit link layer protocol for single picosecond latency determinism using AMD ultrascale+ GTH and GTY transreceivers

recision timing distribution systems require determin istic and repeatable high speed serial data link latency. The EIC Timing Data Link will employ a specialized link layer protocol for deterministic multigigabit communication us ing AMD Ultrascale+ GTH and GTY transceivers. Link la tency must also be measurable to accurately compensate in real time for latency variations of the physical medium. The point-to-point link is full duplex and fully synchronous with a latency control algorithm to align the internal clocks of each system with picosecond resolution. Deterministic clock domain crossing between systems is ensured using static timing analysis of the elastic buffer control signals.

43 PARTICLE ACCELERATORS

Solar Power Satellite (SPS) fiber optic link assessment

A feasibility demonstration of a 980 MHz fiber optic link for the Solar Power Satellite (SPS) phase reference distribution system was accomplished. A dual fiber-optic link suitable for a phase distribution frequency of 980 MHz was built and tested. The major link components include single mode injection laser diodes, avalanche photodiodes, and multimode high bandwidth fibers. Signal throughput was demonstrated to be stable and of high quality in all cases. For a typical SPS link length of 200 meters, the transmitted phase at 980 MHz varies approximately 2.5 degrees for every deg C of fiber temperature change. This rate is acceptable because of the link length compensation feature of the phase control design.

Source record

Signal to noise ratio calculation for fiber optics links

The signal to noise ratio (SNR) effect upon the maximum transmission length of a fiberoptic system is discussed. The relationships of different system parameters are discussed. A general formula to obtain the SNR of a single mode fiberoptic system is derived. The SNR attainable with single mode and multimode fiber optics links was calculated from fundamental noise considerations. It was found that for single mode fibers, laser noise dominates the noise contributions for links less than 30 km long, while thermal noise dominates for longer links. Multimode fibers degrade SNR for long links because of intermode dispersion. For frequency standard transmission, as long as the baseband modulation signals are within the bandwidth of the fibers, respectable SNR can be attained with low loss fibers (approximately 1 dB/km) for links as long as 70 km. For wideband transmission SNR is decreased by a factor equal to the ratio of the bandwidth.

Lau, K. Y.

Cross-linked polyvinyl alcohol and method of making same

A film-forming polyvinyl alcohol polymer is mixed with a polyaldehyde-polysaccharide cross-linking agent having at least two monosaccharide units and a plurality of aldehyde groups per molecule, perferably an average of at least one aldehyde group per monosaccharide units. The cross-linking agent, such as a polydialdehyde starch, is used in an amount of about 2.5 to 20% of the theoretical amount required to cross-link all of the available hydroxyl groups of the polyvinyl alcohol polymer. Reaction between the polymer and cross-linking agent is effected in aqueous acidic solution to produce the cross-linked polymer. The polymer product has low electrical resistivity and other properties rendering it suitable for making separators for alkaline batteries.

Hsu, L. C.

Cross-linked polyvinyl alcohol films as alkaline battery separators

Cross-linking methods were investigated to determine their effect on the performance of polyvinyl alcohol (PVA) films as alkaline battery separators. The following types of cross-linked PVA films are discussed: (1) PVA-dialdehyde blends post-treated with an acid or acid periodate solution (two-step method) and (2) PVA-dialdehyde blends cross-linked during film formation (drying) by using a reagent with both aldehyde and acid functionality (one-step method). Laboratory samples of each cross-linked type of film were prepared and evaluated in standard separator screening tests. The pilot-plant batches of films were prepared and compared to measure differences due to the cross-linking method. The pilot-plant materials were then tested in nickel oxide - zinc cells to compare the two methods with respect to performance characteristics and cycle life. Cell test results are compared with those from tests with Celgard.

Sheibley, D. W.

A note on deep space optical communication link parameters

Topical communication in the context of a deep space communication link. Communication link analysis at the optical frequencies differs significantly from that at microwave frequencies such as the traditional S and X-bands used in deep space applications, due to the different technology of transmitter, antenna, modulators, and receivers. In addition, the important role of quantum noise in limiting system performance is quite different than that of thermal noise. The optical link design is put in a design control table format similar to a microwave telecom link design. Key considerations unique to the optical link are discussed.

Dolinar, S. J.

A flight investigation of simulated data-link communications during single-pilot IFR flight. Volume 2: Flight evaluations

Key problems in single pilot instrument flight operations are in the management of flight data and the processing of cockpit information during conditions of heavy workload. A flight data console was developed to allow simulation of a digital data link to replace the current voice communications stem used in air traffic control. This is a human factors evaluation of a data link communications system to determine how such a system might reduce cockpit workload, improve flight proficiency, and be accepted by general aviation pilots. The need for a voice channel as backup to a digital link is examined. The evaluations cover both airport terminal area operations and full mission instrument flight. Results show that general aviation pilots operate well with a digital data link communications system. The findings indicate that a data link system for pilot/ATC communications, with a backup voice channel, is well accepted by general aviation pilots and is considered to be safer, more efficient, and result in less workload than the current voice system.

Parker, J. F., Jr.

Analysis of broadcasting satellite service feeder link power control and polarization

Statistical analyses of carrier to interference power ratios (C/Is) were performed in assessing 17.5 GHz feeder links using (1) fixed power and power control, and (2) orthogonal linear and orthogonal circular polarizations. The analysis methods and attenuation/depolarization data base were based on CCIR findings to the greatest possible extent. Feeder links using adaptive power control were found to neither cause or suffer significant C/I degradation relative to that for fixed power feeder links having similar or less stringent availability objectives. The C/Is for sharing between orthogonal linearly polarized feeder links were found to be significantly higher than those for circular polarization only in links to nominally colocated satellites from nominally colocated Earth stations in high attenuation environments.

Sullivan, T. M.

Cross-linked polyvinyl alcohol films as alkaline battery separators

Cross-linking methods have been investigated to determine their effect on the performance of polyvinyl alcohol (PVA) films as alkaline battery separators. The following types of cross-linked PVA films are discussed: (1) PVA-dialdehyde blends post-treated with an acid or acid periodate solution (two-step method) and (2) PVA-dialdehyde blends cross-linked during film formation (drying) by using a reagent with both aldehyde and acid functionality (one-step method). Laboratory samples of each cross-linked type of film were prepared and evaluated in standard separator screening tests. Then pilot-plant batches of films were prepared and compared to measure differences due to the cross-linking method. The pilot-plant materials were then tested in nickel oxide-zinc cells to compare the two methods with respect to performance characteristics and cycle life. Cell test results are compared with those from tests with Celgard.

Sheibley, D. W.

System performance of dual polarization satellite communication links affected by attenuation and depolarization

New models have been developed to analyze the performance of dual polarization frequency re-use links when affected simultaneously by attenuation and depolarization. The models have been used to determine the baseband signal to noise ratio for analog modulation links using FM and bit error rate for links using digital modulation (PSK). The methods are applicable to links using slant paths to satellites and also to terrestrial links.

Pratt, T.

Application of intersatellite links to domestic satellite systems

The results of a study on intersatellite link (ISL) applications for domestic satellite communications are presented. It was determined if any technical, economic, or performance benefits could be gained by introducing intersatellite links into a domestic satellite communication network. Several key systems issues of domestic ISL's are addressed. These include the effect of a skewed traffic distribution on the selection of ISL satellite orbit locations, tolerable satellite spacing, and crosslink traffic-handling requirements. An ISL technology assessment is made by performing a parametric link analysis for several microwave and optical implementations. The impact of the crosslink on the end-to-end link performance is investigated for both regenerative and nonregenerative ISL architectures. A comparison is made between single satellite systems operating at C-, and Ku-bands and the corresponding ISL systems in terms of ground segment cost, space segment cost, and net link performance. Results indicate that ISL's can effectively expand the CONUS orbital arc, with a 60 GHz ISL implementation being the most attractive.

Ponchak, D. S.

Application of intersatellite links to domestic satellite systems

The results of a study on intersatellite link (ISL) applications for domestic satellite communications are presented. It was determined if any technical, economic, or performance benefits could be gained by introducing intersatellite links into a domestic satellite communication network. Several key systems issues of domestic ISL's are addressed. These include the effect of a skewed traffic distribution on the selection of ISL satellite orbit locations, tolerable satellite spacing, and crosslink traffic-handling requirements. An ISL technology assessment is made by performing a parametric link analysis for several microwave and optical implementations. The impact of the crosslink on the end-to-end link performance is investigated for both regenerative and nonregenerative ISL architectures. A comparison is made between single satellite systems operating at C-, and Ku-bands and the corresponding ISL systems in terms of ground segment cost, space segment cost, and net link performance. Results indicate that ISL's can effectively expand the CONUS orbital arc, with a 60 GHz ISL implementation being the most attractive.

Ponchak, D. S.

Minimum-time pointing control of a two-link manipulator

Minimum-time pointing control for the end-effector of a planar, two-link manipulator is developed. Minimum-time pointing control is a new area of research for multilink manipulators, which can be applied to rapid retargeting control of a multibody spacecraft. The minimum-time control problem of aligning the second link of the two-link manipulator with a given target point is considered. A numerical method called the minimizing-boundary-condition method is used to determine optimal solutions for the two-point boundary-value problem associated with first-order necessary conditions. Minimum-time solutions for different models of pointing systems are compared. The results of the comparison show that a two-link manipulator with two degree-of-freedom performs better than a conventional one-link system for minimum-time pointing.

Wie, Bong