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At least 109 records · Page 6

Ceres Obliquity History and Its Implications for the Permanently Shadowed Regions

Due to the small current obliquity of Ceres ( epsilon approximately equal to 4), permanently shadowed regions (PSRs) exist on the dwarf planets surface. Since the existence and persistence of the PSRs depend on the obliquity, we compute the obliquity history over the last 3 My and find that it undergoes large oscillations with a period of 24.5 ky and a maximum of max 19:5. During periods of large obliquity, most of the present-day PSRs receive direct sunlight. Some craters in Ceres polar regions possess bright crater floor deposits (BCFDs).We find an apparent correlation between BCFDs and the most persistent PSRs. In the north, only two PSRs remain at max and they both contain BCFDs. In the south, one of the two only craters that remain in shadow at max contains a BCFD. The location of BCFDs within persistent PSRs strongly suggests BCFDs consist of volatiles accumulated in PSR cold traps: either water molecules trapped from the exosphere or exposed ground ice.

Ermakov, A. I.↗

Strangeness Physics at CLAS in the 6 GeV Era

A very brief overview is presented of varied strangeness-physics studies that have been conducted with the CLAS system in the era of 6 GeV beam at Jefferson Lab. A full bibliography of articles related to open strangeness production is given, together with some physics context for each work. One natural place where these studies could be continued, using a K L beam and the GlueX detector, is in the further investigation of the Λ(1405) baryon. The line shapes and cross sections of this state were found, using photoproduction at CLAS, to differ markedly in the three possible Σπ final states. The analogous strong-interaction reactions using a K L beam could further bring this phenomenon into focus. 1. The CLAS program ran from 1998 to 2012, during the time when the maximum Jefferson Lab beam energy was 6 GeV. An important thrust of this program was to investigate the spectrum of N * and Δ * (non-strange) baryon resonances using photo-and electro-production reactions. To this end, final states containing strange particles (K mesons and low-mass hyperons) played a significant role. The reason for this is partly due to favorable kinemat-ics. When the total invariant energy W (= √ s) of a baryonic system exceeds 1.6 GeV it becomes possible to create the lightest strangeness-containing final state, K + Λ. This is a two-body final state that is straightforward to reconstruct in the CLAS detector system [1], and theoretically it is easier to deal with two-body reaction amplitudes than with three-and higher-body reaction amplitudes. In the mass range W > 1.6 GeV the decay modes of excited nucleons tend to not to favor two-body π-nucleon final states but rather multi-pion states. As input to partial-wave decompositions and resonance-extraction models, therefore, the strangeness-containing final states of high-mass nucleon excitations have had importance. Excited baryons decay through all possible channels simultaneously, constrained by unitarity of course, and channel-coupling is crucial to determining the spectrum of excita-tions. Within this mix of amplitudes, however, the KY decay modes have proven useful. The end result has been, as summarized in the recent edition of the Review of Particle Properties [2], clearer definition of the spectrum of baryonic excitations, with definite contributions from the strangeness sector channels. To this end, strangeness photoproduction cross sections measurements at CLAS for the K + Λ, K + Σ 0 and K 0 Σ + channels on a proton target were published [3–6]. Cross sections are not enough, in general, to define the reaction mechanism, including the underlying N * excitation spectrum. Photoproduction of pseudo-scalar mesons is described by four complex amplitudes, leading to fifteen spin observables in addition to the cross section. Full knowledge of these spin observables would exhaust the information that can be gleaned experimentally about any given reaction channel. Here the hyperonic channels offer another advantage when compared with the non-strange reaction channels: the polarization of most hyperons can be measured directly through their parity-violating weak decay asymmetries. Unlike 163

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Excited Baryon Structure Using Exclusive Reactions with CLAS12

Studying excited nucleon structure through exclusive electroproduction reactions is an important avenue for exploring the nature of the non-perturbative strong interaction. Electrocouplings for $N^*$ states in the mass range below 1.8~GeV have been determined from analyses of CLAS $\pi N$, $\eta N$, and $\pi \pi N$ data. This work made it clear that consistency of independent analyses of exclusive channels with different couplings and non-resonant backgrounds but the same $N^*$ electro-excitation amplitudes, is essential to have confidence in the extracted results. In terms of hadronic coupling, many high-lying $N^*$ states preferentially decay through the $\pi \pi N$ channel instead of $\pi N$. Data from the $KY$ channels will therefore be critical to provide an independent analysis to compare the extracted electrocouplings for the high-lying $N^*$ states against those determined from the $\pi N$ and $\pi \pi N$ channels. A program to study excited $N^*$ decays to non-strange and strange exclusive final states using CLAS12 will measure differential cross sections to be used as input to extract the $\gamma_vNN^*$ transition form factors for the most prominent $N^*$ states in the range of invariant energy $W$ up 3~GeV in the virtually unexplored domain of momentum transfers $Q^2$ up to 12~GeV$^2$.

Carman, Daniel↗

Advances in the studies of the nucleon resonance spectrum in experiments with electromagnetic probes

The studies of the nucleon resonance spectrum with the focus on the search for new baryon states for a long time remain the challenging topic in hadron physics. Full resonance spectrum plays a critical role in the evolution of ~ millisecond age Universe in the transition from the quark-gluon to the hadron gas phases. Recent LQCD evaluations of the N*-spectrum from the first QCD principles suggest existence as much new nucleon resonances as expected in the quark models employed SU(6)*O(3) symmetry. Discovery of several new nucleon resonances in the global analyses of exclusive meson photoproduction off protons data with decisive impact from the CLAS measurements of exclusive KY photoproduction will be presented. Combined studies of charged double pion photo- and electroproduction data from CLAS revealed strong evidence for another N'(1720)3/2+ new baryon state. The information on electroexcitation amplitudes of this state has become available for the first time offering the insight to the new baryon state structure. The prospects for the search of the new states of baryon matter with glue as the structural component in the experiments with the CLAS12 detector will be outlined.

Mokeev, Viktor↗

Panel Session 120B: DOE Portsmouth Paducah Project Office (PPPO) Update

This panel focused on the Portsmouth/Paducah Project Office (PPPO) of the US DOE Office of Environmental Management, Lexington, Kentucky, the US DOE Featured Site for Thursday. It showcased recent progress, challenges and planned efforts in radioactive waste management, waste disposition, environmental remediation and D and D at the Portsmouth (Ohio) and Paducah (KY) Gaseous Diffusion Plant Sites, as well as the Depleted Uranium Hexafluoride (DUF6) Conversion Project with facilities at both sites Presentations proposed include: 1 - Portsmouth/Paducah Project Office (PPPO) (Joel Bradburne, US DOE Portsmouth/Paducah Project Office (USA)); 2 - Portsmouth (Jeff Bettinger, US DOE Portsmouth/Paducah Project Office (USA)); 3 - Paducah (Jennifer Woodard, US DOE Portsmouth/Paducah Project Office (USA)); 4 - Depleted Uranium Hexafluoride Conversion Project (Reinhard Knerr, US DOE Portsmouth/Paducah Project Office (USA)); 5 - Portsmouth Deactivation and Demolition Project (Bob Smith, Fluor-BWXT Portsmouth (USA)); 6 - Paducah Deactivation and Remediation Project (Jeff Bradford, Four Rivers Nuclear Partnership - FRNP (USA)); 7 - Seven Lines-One Project (Zack Smith, SNC Lavalin (USA))

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Crystallization of nanopore-confined imidazolium ionic liquids probed by temperature-resolved in situ grazing-incidence wide angle X-ray scattering (GIWAXS)

The crystallization behavior of ionic liquids (ILs) 1-butyl-3-methylimidazolium [BMIM] hexafluorophosphate [PF 6 ] and chloride [Cl] is investigated upon confinement in 2.3 or 8.2 nm diameter silica nanopore arrays, along with the effects of covalently modifying the pore walls with 1-(3-trimethoxysilylpropyl)3-methylimidazolium [TMS-MIM] + groups. In situ grazing-incidence wide angle x-ray scattering (GIWAXS) is performed during heating from as low as -110 °C to room temperature. Partially ordered “nanodomains” are observed in both ILs in the bulk molten state, but they are disrupted by nanoconfinement. Melting point depression consistent with capillary effects is observed for [BMIM][PF 6 ] in 2.3 nm pores. However, the melting point is elevated for [BMIM][PF 6 ] in 8.2 nm pores, which provide sufficient space to stabilize the crystalline phase. For [BMIM][Cl], crystallization is observed only in 8.2 nm bare silica pores, but the melting point is severely depressed. Tethering with IL-like [TMS-MIM + ] also promotes the crystallization of [BMIM][PF 6 ], resulting in elevated melting points. The combined effects of a larger pore size and pore surface tethering on [BMIM][PF 6 ] result in a single stable crystal phase that persists from -140 °C to 25 °C (vs. the bulk melting point of -11 °C). These results show that when ILs are used in confined systems, complex crystallization behavior can emerge depending on the counterion, pore size, and surface modification that require consideration of ion layering in the confined space in addition to surface free energy effects.

He, Yuxin [University of Kentucky, Lexington, KY (↗

Angle-resolved polarized Raman spectroscopy study of phosphorene nanoribbons

We present a systematic angle-resolved polarized Raman spectroscopy (ARPRS) study of black phosphorus (BP) nanostructures formed via electrochemical sodium- and lithium-ion intercalation. Sodium intercalation leads to bundles of densely packed, highly uniform phosphorene nanoribbons (PNRs) separated by parallel amorphous channels, whereas lithium intercalation results in shorter, irregular nanoribbon-like segments with lower aspect ratios. In both cases, six additional Raman peaks (P1–P6) appear alongside the three primary Raman-active modes of BP (A$^{1}_{g}$, B 2g , and A$^{2}_{g}$). These peaks are attributed to the amorphous regions, as confirmed by their isotropic angular dependence in ARPRS measurements. The three BP modes show pronounced angular variations that differ significantly between the two intercalated samples. In sodium-intercalated BP, A$^{1}_{g}$ and A$^{2}_{g}$ modes retain a dumbbell-like angular dependence under parallel polarization with enhanced anisotropy and reduced symmetry under crossed polarization. At the same time, the B 2g mode transitions from four-lobed (cloverleaf) polar plot to a butterfly-like one. In contrast, lithium-intercalated BP exhibits weaker anisotropy and less distinct angular polar plots for all three modes. These differences reflect the sensitivity of phonon behavior to underlying nanostructure morphology. The vibrational frequencies density of states (FDOS) calculations attribute the B 2g mode transformation to phonon band folding and mode mixing in PNRs. This study demonstrates the power of ARPRS in probing phonon-structure relationships and highlights the influence of edge geometry and quantum confinement on phonon dispersion in PNRs.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

A haplotype‐resolved reference genome of Quercus alba sheds light on the evolutionary history of oaks

Summary White oak ( Quercus alba ) is an abundant forest tree species across eastern North America that is ecologically, culturally, and economically important. We report the first haplotype‐resolved chromosome‐scale genome assembly of Q. alba and conduct comparative analyses of genome structure and gene content against other published Fagaceae genomes. We investigate the genetic diversity of this widespread species and the phylogenetic relationships among oaks using whole genome data. Despite strongly conserved chromosome synteny and genome size across Quercus , certain gene families have undergone rapid changes in size, including defense genes. Unbiased annotation of resistance (R) genes across oaks revealed that the overall number of R genes is similar across species – as are the chromosomal locations of R gene clusters – but, gene number within clusters is more labile. We found that Q. alba has high genetic diversity, much of which predates its divergence from other oaks and likely impacts divergence time estimations. Our phylogenetic results highlight widespread phylogenetic discordance across the genus. The white oak genome represents a major new resource for studying genome diversity and evolution in Quercus . Additionally, we show that unbiased gene annotation is key to accurately assessing R gene evolution in Quercus .

Larson, Drew A. [Department of Biology Indiana Uni↗

Carbon source-induced changes in the transcriptional landscape of Novacetimonas hansenii

Novacetimonas hansenii is a model organism for bacterial cellulose (BC) production, a biopolymer with broad industrial applications. To better understand its carbon source-dependent metabolism, we conducted the first time-resolved transcriptomic analysis of N. hansenii ATCC 23769 grown on five carbon sources (glucose, fructose, mannitol, galactose, and sucrose) across five time points (24–120h). Glucose, fructose, and mannitol supported growth and efficient BC production, whereas galactose and sucrose resulted in poor yields, likely due to limited transport and enzymatic capacity. Solid-state NMR revealed that cellulose crystallinity and polymorphism were carbon source-dependent, with reduced bcsD expression correlating with lower crystallinity. Transcriptomic profiling showed distinct metabolic responses. Cultures containing glucose and mannitol activated core metabolic pathways, fructose induced a delayed adaptive shift, and galactose and sucrose triggered stress-related gene expression. These results highlight the metabolic plasticity of N. hansenii and offer insights for enhancing BC production through carbon source optomization.

Bacterial cellulose↗

Breakthrough Zn(II) Catalyst for Direct Air Capture Employing CO 2 Hydration

Direct air capture (DAC) represents a vital technology for atmospheric CO₂ remediation, but few studies have tested catalysts at dilute atmospheric CO₂ concentrations. Inspired by the carbonic anhydrase metalloenzyme, we report a catalytic DAC strategy employing robust zinc(II) enzyme mimics that enable efficient CO₂ sequestration pathways. A catalyst-mediated CO₂ hydration cycle in aqueous sorbents facilitates accelerated capture from dilute atmospheric air, thereby addressing the kinetic limitations observed in carbonate-based systems. Our developed complexes [ZnC1] and [ZnC2] enhance capture rates up to two-fold at millimolar concentrations and improve CO₂ mass transfer by 40-60% in 1 M K₂CO₃ sorbent under ambient conditions. These bench-stable, earth-abundant zinc catalysts operate effectively under dilute CO₂ concentrations, overcoming the kinetic limitations of conventional carbonate-based sorbents. As a result, mechanistic studies support a biomimetic catalytic cycle that facilitates rapid CO₂ conversion, demonstrating that catalyst-assisted DAC can enable energy-efficient, scalable carbon capture technologies.

Atmospheric chemistry↗

Structure and mechanism of biosynthesis of Streptococcus mutans cell wall polysaccharide

Streptococcus mutans, the causative agent of human dental caries, expresses a cell wall attached Serotype c-specific Carbohydrate (SCC) that is critical for cell viability. SCC consists of a polyrhamnose backbone of →3)α-Rha(1 → 2)α-Rha(1→ repeats with glucose (Glc) side-chains and glycerol phosphate (GroP) decorations. This study reveals that SCC has one predominant and two more minor Glc modifications. The predominant Glc modification, α-Glc, attached to position 2 of 3-rhamnose, is installed by SccN and SccM glycosyltransferases and is the site of the GroP addition. The minor Glc modifications are β-Glc linked to position 4 of 3-rhamnose installed by SccP and SccQ glycosyltransferases, and α-Glc attached to position 4 of 2-rhamnose installed by SccN working in tandem with an unknown enzyme. Both the major and the minor β-Glc modifications control bacterial morphology, but only the GroP and major Glc modifications are critical for biofilm formation.

59 BASIC BIOLOGICAL SCIENCES↗

Design, characterization and shape recovery behavior of 3D/4D printed shape memory polymers (SMPs)

Shape memory polymers (SMPs) represent a paradigm shift in material science, uniquely capable of undergoing reversible shape transformations triggered by external stimuli, positioning them as pivotal in developing next-generation biomedical devices, aerospace components, and adaptive structures. Extensive research has been done on SMPs with a major focus on high-temperature programming methods, which can limit energy efficiency and applicability with temperature-sensitive materials. Additionally, while various SMP blends have demonstrated great potential, limited work has been done on the suitability for 3D printing these materials, particularly under high-strain and ambient temperature programming conditions. In this study, a three-component optimized SMP composition was evaluated by 3D printing via the Material Extrusion (MEX) technique and investigating its ambient temperature-programming behavior at high strains. The SMP formulation studied was a tailored blend of thermoplastic polyurethane (TPU), polycaprolactone (PCL), and an octadecane diol-based copolymer (OBC) that exhibits robust shape memory behavior, high strain tolerance, and efficient force generation. Rigorous thermal, mechanical, and shape recovery analyses, along with optimized printing parameters and consistent shape recovery rates of up to 90%, were achieved under dynamic mechanical analysis (DMA), even under ambient programming conditions. This work demonstrates the SMP composition’s potential for adaptive, self-deployable systems with 4D printing characteristics ideal for bio-inspired structures and artificial muscle fibers.

Sudan, Kavish [University of Louisville, KY]↗

Decoding the Effect of Anion Identity on the Solubility of N -(2-(2-Methoxyethoxy)ethyl)phenothiazine (MEEPT)

Variations in the solubility of redox-active organic molecules (ROM) of interest for nonaqueous redox flow batteries (RFB), especially as the ROM state-of-charge changes during charge-discharge cycling, present significant molecular design challenges. The situation is further complicated as ROM solubility can be regulated by the choice of electrolyte salt and solvent that together with the ROM comprise the catholyte or anolyte (redox electrolyte) formulation, presenting materials design challenges. The ROM N-(2-(2-methoxyethoxy)ethyl)phenothiazine (MEEPT) is a viscous liquid at room temperature and is miscible in several organic solvents, including acetonitrile and propylene carbonate. The MEEPT radical cation (MEEPT +· ) paired with tetrafluoroborate (BF 4 - ) in acetonitrile presents a 0.5 M solubility, a dramatic decrease when compared to the viscous liquid of neutral MEEPT. Here, in this study, we present a joint experimental, regression modeling, and molecular dynamics (MD) simulations investigation to explore MEEPT-X (where X represents the counteranion) salt solubility variability as a function of concentration and counteranion chemistry in acetonitrile. We find a strong dependence of the salt solubility on the counteranion and relate these findings to explicit intermolecular interactions between MEEPT +· and the counteranion in the electrolyte solution.

Perera, Anton S. [Univ. of Kentucky, Lexington, KY↗

Nitrogenated Graphene Quantum Dot-Derived Copper Single-Atom Catalyst for Oxygen Reduction Reaction

Despite the promise of fuel cells as sustainable energy conversion technologies, their widespread adoption is hindered by the high cost of platinum group metal (PGM) catalysts, particularly for catalyzing the oxygen reduction reaction (ORR) at the cathode. Here, we report copper-based single-atom catalysts (Cu-SACs) as cost-effective non-PGM alternatives for ORR. The catalysts were synthesized via simple pyrolysis of pyrene-derived amine-terminated graphene quantum dots (GQDs) in the presence of nitrogen and metal precursors. The abundant nitrogen functionality in GQDs effectively stabilized isolated Cu atoms during their conversion to porous carbon. A subsequent acid-washing step yielded a high density of atomically dispersed Cu active sites. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and high-resolution scanning transmission electron microscopy (HR-STEM) confirmed the effective incorporation of isolated Cu atoms into the carbon matrix through copper–nitrogen (Cu-N) coordination. Electrochemical measurements revealed excellent ORR activity with a dominant four-electron pathway. This synthetic strategy provides a practical route to developing economically viable, non-precious metal catalysts.

catalysts↗

Integration of CO 2 capture and microalgae cultivation: demonstration assessment of outdoor Scenedesmus acutus cultivation using gaseous ammonia as a nitrogen source

Towards the goal of integrating CO 2 capture using aqueous ammonia with its utilization for algae cultivation, Scenedesmus acutus (UTEX B72) was grown in 1100 L open raceway ponds using CO 2 and NH 3 supplied from gas cylinders. CO 2 /NH 3 mole ratios of 7 and 10 were employed, the gas mixture acting as a surrogate for the output from a CO 2 scrubbing system using aqueous ammonia. Compared to Scenedesmus acutus grown in open ponds using gaseous CO 2 and NaNO 3 as the N-source, the ponds supplied with gaseous CO 2 and NH 3 displayed higher productivity at both CO 2 /NH 3 ratios, with the higher ratio providing the best growth. Depending on the culturing conditions and CO 2 /NH 3 ratio, CO 2 utilization ranged up to 15.8% and NH 3 utilization to 23.0%. These rather low values reflect the fact the high CO 2 /NH 3 feed rate used, resulting in a substantial release of NH 3 from the ORPs (~45%). Finally, these findings demonstrate the suitability of gaseous NH 3 as a N-source for microalgae cultivation, while highlighting the need for a control strategy that closely balances the CO 2 /NH 3 supply with the algae growth rate. The produced algae biomass possessed a high protein and low ash content, rendering it particularly suitable for use as a bioplastic feedstock.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗