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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

U.S. Spacesuit Knowledge Capture Accomplishments in Fiscal Years 2012 and 2013

The NASA U.S. spacesuit knowledge capture (KC) program has been in operations since the beginning 2008. The program was designed to augment engineers and others with information about spacesuits in a historical way. A multitude of seminars have captured spacesuit history and knowledge over the last six years of the programs existence. Subject matter experts have provided lectures and were interviewed to help bring the spacesuit to life so that lessons learned will never be lost. As well, the program concentrated in reaching out to the public and industry by making the recorded events part of the public domain through the NASA technical library via You Tube media. The U.S. spacesuit KC topics have included lessons learned from some of the most prominent spacesuit experts and spacesuit users including current and former astronauts. The events have enriched the spacesuit legacy knowledge from Gemini, Apollo, Skylab, Space Shuttle and International Space Station Programs. As well, expert engineers and scientists have shared their challenges and successes to be remembered. The last few years have been some of the most successful years of the KC program program's life with numerous recordings and releases to the public. It is evidenced by the thousands that have view the recordings online. This paper reviews the events accomplished and archived over Fiscal Years 2012 and 2013 and highlights a few of the most memorable ones. This paper also communicates ways to access the events that are available internally to NASA as well as in the public domain.

Chullen, Cinda↗
NASA NTRS2014

U.S. Spacesuit Knowledge Capture Accomplishments in Fiscal Years 2012 and 2013

The NASA U.S. Spacesuit Knowledge Capture (KC) program has existed since the beginning of 2008. The program was designed to augment engineers and other technical team members with historical spacesuit information to add to their understanding of the spacesuit, its evolution, its limitations, and its capabilities. Over 40 seminars have captured spacesuit history and knowledge over the last six years of the program's existence. Subject matter experts have provided lectures and some were interviewed to help bring the spacesuit to life so that lessons learned will never be lost. As well, the program concentrated in reaching out to the public and industry by making the recorded events part of the public domain through the NASA technical library through YouTube media. The U.S. Spacesuit KC topics have included lessons learned from some of the most prominent spacesuit experts and spacesuit users including current and former astronauts. The events have enriched the spacesuit legacy knowledge from Gemini, Apollo, Skylab, Space Shuttle and International Space Station Programs. As well, expert engineers and scientists have shared their challenges and successes to be remembered. Based on evidence by the thousands of people who have viewed the recordings online, the last few years have been some of the most successful years of the KC program's life with numerous digital recordings and public releases. This paper reviews the events accomplished and archived over Fiscal Years 2012 and 2013 and highlights a few of the most memorable ones. This paper also communicates ways to access the events that are available internally on the NASA domain as well as those released on the public domain.

Chullen, Cinda↗
NASA NTRSDate not supplied

Maipo River Valley Agriculture: Determining Crop Coefficients Using Remote Sensing for the Maipo River Valley Basin in Chile

Agriculture is the primary use of water in the Maipo River basin of Central Chile, accounting for ~ 75% of the total demand. Assessment of irrigation needs for agricultural production has commonly relied on reference crop coefficients (Kc) derived from geographic and climatic conditions that differ from those of Chile. In partnership with the Centro de Información de Recursos Naturales (CIREN), this work focused on calculating site-specific crop coefficients tailored to crop production in the water-stressed Maipo River Valley. Two distinct approaches were implemented, each relying on remotely-sensed Earth observation datasets from NASA over consecutive growing seasons from 2019 to 2022. The first method estimated Kc values based on their linear relationship with the Normalized Difference Vegetation Index (NDVI) obtained from either Terra Moderate Resolution Imaging Spectroradiometer (MODIS) or Landsat 8 Operational Land Imager (OLI) surface reflectance. The second technique leveraged information from the ISS Ecosystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) by computing the ratio between actual crop evapotranspiration (ET) and potential evapotranspiration (PET). Both procedures showed promising results that can build on one another. The former approach best captured vegetation signals of annual crops while the latter appeared suited for perennials. Overall, this study provides a strong basis and novel way to accurately estimate Kc using remote sensing, with the potential for improved irrigation management and reduction in water consumption.

Benjamin Goffin↗
DOE OSTI2023

Lewis Acid Supported Nickel Nitrenoids

Abstract Metalation of the polynucleating ligand F,tbs LH 6 (1,3,5‐C 6 H 9 (NC 6 H 3 −4‐F−2‐NSiMe 2 t Bu) 3 ) with two equivalents of Zn(N(SiMe 3 ) 2 ) 2 affords the dinuclear product ( F,tbs LH 2 )Zn 2 ( 1 ), which can be further deprotonated to yield ( F,tbs L)Zn 2 Li 2 (OEt 2 ) 4 ( 2 ). Transmetalation of 2 with NiCl 2 (py) 2 yields the heterometallic, trinuclear cluster ( F,tbs L)Zn 2 Ni(py) ( 3 ). Reduction of 3 with KC 8 affords [KC 222 ][( F,tbs L)Zn 2 Ni] ( 4 ) which features a monovalent Ni centre. Addition of 1‐adamantyl azide to 4 generates the bridging μ 3 ‐nitrenoid adduct [K(THF) 3 ][( F,tbs L)Zn 2 Ni(μ 3 ‐NAd)] ( 5 ). EPR spectroscopy reveals that the anionic cluster possesses a doublet ground state ( S = ). Cyclic voltammetry of 5 reveals two fully reversible redox events. The dianionic nitrenoid [K 2 (THF) 9 ][( F,tbs L)Zn 2 Ni(μ 3 ‐NAd)] ( 6 ) was isolated and characterized while the neutral redox isomer was observed to undergo both intra‐ and intermolecular H‐atom abstraction processes. Ni K‐edge XAS studies suggest a divalent oxidation state for the Ni centres in both the monoanionic and dianionic [Zn 2 Ni] nitrenoid complexes. However, DFT analysis suggests Ni‐borne oxidation for 5 .

Juda, Cristin E.↗
DOE OSTI2023

Lewis Acid Supported Nickel Nitrenoids

Metalation of the polynucleating ligand F,tbs LH 6 (1,3,5-C 6 H 9 (NC 6 H 3 −4-F−2-NSiMe 2 t Bu) 3 ) with two equivalents of Zn(N(SiMe 3 ) 2 ) 2 affords the dinuclear product ( F,tbs LH 2 )Zn 2 (1), which can be further deprotonated to yield ( F,tbs L)Zn 2 Li 2 (OEt 2 ) 4 (2). Transmetalation of 2 with NiCl 2 (py) 2 yields the heterometallic, trinuclear cluster ( F,tbs L)Zn 2 Ni(py) (3). Reduction of 3 with KC 8 affords [KC 222 ][( F,tbs L)Zn 2 Ni] (4) which features a monovalent Ni centre. Addition of 1-adamantyl azide to 4 generates the bridging μ 3 -nitrenoid adduct [K(THF) 3 ][( F,tbs L)Zn 2 Ni(μ 3 -NAd)] (5). EPR spectroscopy reveals that the anionic cluster possesses a doublet ground state (S = 1/2). Cyclic voltammetry of 5 reveals two fully reversible redox events. The dianionic nitrenoid [K 2 (THF) 9 ][( F,tbs L)Zn 2 Ni(μ 3 -NAd)] (6) was isolated and characterized while the neutral redox isomer was observed to undergo both intra- and intermolecular H-atom abstraction processes. Here, Ni K-edge XAS studies suggest a divalent oxidation state for the Ni centres in both the monoanionic and dianionic [Zn 2 Ni] nitrenoid complexes. However, DFT analysis suggests Ni-borne oxidation for 5.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

A Uranium(II) Arene Complex That Acts as a Uranium(I) Synthon

We report two-electron reduction of the amidate-supported U(III) mono(arene) complex U(TDA) 3 (2) with KC 8 yields the anionic bis(arene) complex [K[2.2.2]cryptand][U(TDA) 2 ] (3) (TDA = N-(2,6-di-isopropylphenyl)pivalamido). EPR spectroscopy, magnetic susceptibility measurements, and calculations using DFT as well as multireference CASSCF methods all provide strong evidence that the electronic structure of 3 is best represented as a 5f 4 U(II) metal center bound to a monoreduced arene ligand. Reactivity studies show 3 reacts as a U(I) synthon by behaving as a two-electron reductant toward I 2 to form the dinuclear U(III)–U(III) triiodide species [K[2.2.2]cryptand][(UI(TDA) 2 ) 2 (μ-I)] (6) and as a three-electron reductant toward cycloheptatriene (CHT) to form the U(IV) complex [K[2.2.2]cryptand][U(η 7 -C 7 H 7 )(TDA) 2 (THF)] (7). The reaction of 3 with cyclooctatetraene (COT) generates a mixture of the U(III) anion [K[2.2.2]cryptand][U(TDA) 4 ] (1-crypt) and U(COT) 2 , while the addition of COT to complex 2 instead yields the dinuclear U(IV)–U(IV) inverse sandwich complex [U(TDA) 3 ] 2 (μ-η 8 :η 3 -C 8 H 8 ) (8). Two-electron reduction of the homoleptic Th(IV) amidate complex Th(TDA) 4 (4) with KC 8 gives the mono(arene) complex [K[2.2.2]cryptand][Th(TDA) 3 (THF)] (5). The C–C bond lengths and torsion angles in the bound arene of 5 suggest a direduced arene bound to a Th(IV) metal center; this conclusion is supported by DFT calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Tale of Three Molecular Nitrides: Mononuclear Vanadium (V) and (IV) Nitrides As Well As a Mixed-Valence Trivanadium Nitride Having a V 3 N 4 Double-Diamond Core

Here, transmetallation of [VCl 3 (THF) 3 ] and [TlTp tBu,Me ] afforded [(Tp tBu,Me )VCl 2 ] (1, Tp tBu,Me = hydro-tris(3-tert-butyl-5-methylpyrazol-1-yl)borate), which was reduced with KC 8 to form a $C_{3v}$ symmetric V II complex, [(Tp tBu,Me )VCl] (2). Complex 1 has a high-spin ($\textit{S}$ = 1) ground state and displays rhombic high-frequency and -field electron paramagnetic resonance (HFEPR) spectra, while complex 2 has an $\textit{S}$ = 3/2 4 A 2 ground state observable by conventional EPR spectroscopy. Complex 1 reacts with NaN 3 to form the V V nitride-azide complex [(Tp tBu,Me )V≡N(N 3 )] (3). A likely V III azide intermediate en route to 3, [(Tp tBu,Me )VCl(N 3 )] (4), was isolated by reacting 1 with N 3 SiMe 3 . Complex 4 is thermally stable but reacts with NaN3 to form 3, implying a bis-azide intermediate, [(Tp tBu,Me )V(N 3 ) 2 ] (A), leading to 3. Reduction of 3 with KC 8 furnishes a trinuclear and mixed-valent nitride, [{(Tp tBu,Me )V} 2 ($μ_{4-}$VN 4 )] (5), conforming to a Robin–Day class I description. Complex 5 features a central vanadium ion supported only by bridging nitride ligands. Contrary to 1, complex 2 reacts with NaN 3 to produce an azide-bridged dimer, [{(Tp tBu,Me )V} 2 (1,3-$μ_2$-N 3 ) 2 ] (6), with two antiferromagnetically coupled high-spin V II ions. Complex 5 could be independently produced along with [($κ_2$-Tp tBu,Me ) 2 V] upon photolysis of 6 in arene solvents. The putative {V IV ≡N} intermediate, [(Tp tBu,Me )V≡N] (B), was intercepted by photolyzing 6 in a coordinating solvent, such as tetrahydrofuran (THF), yielding [(Tp tBu,Me )V≡N(THF)] (B-THF). In arene solvents, B-THF expels THF to afford 5 and [($κ_2$-Tp tBu,Me ) 2 V]. A more stable adduct (B-OPPh 3 ) was prepared by reacting B-THF with OPPh 3 . These adducts of B are the first neutral and mononuclear V IV nitride complexes to be isolated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

The Volume-complete Sample of M Dwarfs with Masses 0.1 ≤ M/M{sub ⊙} ≤ 0.3 within 15 Parsecs

M dwarfs with masses 0.1 ≤ M/M {sub ⊙} ≤ 0.3 are under increasing scrutiny because these fully convective stars pose interesting astrophysical questions regarding their magnetic activity and angular momentum history. They also afford the most accessible near future opportunity to study the atmospheres of terrestrial planets. Because they are intrinsically low in luminosity, the identification of the nearest examples of these M dwarfs is essential for progress. We present the volume-complete, all-sky list of 512 M dwarfs with masses 0.1 ≤ M/M {sub ⊙} ≤ 0.3 and with trigonometric distances placing them within 15 pc (π {sub trig} ≥ 66.67 mas) from which we have created a sample of 413 M dwarfs for spectroscopic study. We present the mass function for these 512 M dwarfs, which increases with decreasing stellar mass in linear mass space, but is flat in logarithmic mass space. As part of this sample, we present new V {sub J} R {sub KC} I {sub KC} photometry for 17 targets, measured as a result of the RECONS group’s long-term work at the CTIO/SMARTS 0.9 m telescope. We also note the details of targets that are known to be members of multiple systems and find a preliminary multiplicity rate of 21% ± 2% for the primary M dwarfs in our sample when considering known stellar and brown dwarf companions at all separations from their primaries. We further find that 43 ± 2% of all M dwarfs with masses 0.1 ≤ M/M {sub ⊙} ≤ 0.3 are found in multiple systems with primary stars of all masses within 15 pc.

47 OTHER INSTRUMENTATION↗
NASA NTRS1967

A calibration means for spectrum analyzers

Spectrum analyzer calibration system is rapid and provides an accurate family of adjustable markers at any point in the spectrum. Pulse width controls determine the number of markers. The unit operates with a repetition rate from 300 cps to 40 kc at a center frequency from 10 kc to 2 Mc.

Larson, M. S.↗
NASA NTRS1976

Optimization and design of three-dimensional aerodynamic configurations of arbitrary shape by a vortex lattice method

A new method based on vortex lattice theory has been developed which can be applied to the combined analysis, induced drag optimization, and aerodynamic design of three-dimensional configurations of arbitrary shape. Geometric and aerodynamic constraints can be imposed on both the optimization and the design process. The method is compared with several known analytical solutions and is applied to several different design and optimization problems, including formation flight and wingtip fins for the Boeing KC-135 tanker airplane. Good agreement has been observed between the theoretical predictions and the wind tunnel test results for the KC-135 modification.

Feifel, W. M.↗
NASA NTRS1977

Conceptual design for spacelab two-phase flow experiments

KC-135 aircraft tests confirmed the gravity sensitivity of two phase flow correlations. The prime component of the apparatus is a 1.5 cm dia by 90 cm fused quartz tube test section selected for visual observation. The water-cabin air system with water recycle was a clear choice for a flow regime-pressure drop test since it was used satisfactorily on KC-135 tests. Freon-11 with either overboard dump or with liquid-recycle will be used for the heat transfer test. The two experiments use common hardware. The experimental plan covers 120 data points in six hours with mass velocities from 10 to 640 kg/sec-sq m and qualities 0.01 to 0.64. The apparatus with pump, separator, storage tank and controls is mounted in a double spacelab rack. Supporting hardware, procedures, measured variables and program costs are defined.

Bradshaw, R. D.↗
NASA NTRS1980

Optical measurements of degradation in aircraft boundary layers

Visible wavelength measurements of the degradation of optical beams when transmitted through the thin aerodynamic boundary layers around an aircraft are reviewed. The measured results indicated degradation levels for the KC-135 airplanes between 0.10 to 0.13 lambda increasing to 0.18 lambda (rms wavefront distortion). For the Lear Jet, degradation with a 25 mm diameter optics was roughly 0.07 lambda. The corresponding infinite aperture degradation levels are also calculated. The corresponding measured correlation lengths of roughly 12 mm for the KC-135 aircraft and 6 mm for the Lear Jet scale to roughly 20 and 25 mm, respectively, for infinite apertures. These boundary layer correlation lengths do not appear to reflect the different boundary layer thicknesses on the two different aircraft.

Kelsall, D.↗
NASA NTRS1981

Subsonic tests of an all-flush-pressure-orifice air data system

The use of an all-flush-pressure-orifice array as a subsonic air data system was evaluated in flight and wind tunnel tests. Two orifice configurations were investigated. Both used orifices arranged in a cruciform pattern on the airplane nose. One configuration also used orifices on the sides of the fuselage for a source of static pressure. The all-nose-orifice configuration was similar to the shuttle entry air data system (SEADS). The flight data were obtained with a KC-135A airplane. The wind tunnel data were acquired with a 0.035-scale model of the KC-135A airplane. With proper calibration, several orifices on the vertical centerline of the vehicle's nose were found to be satisfactory for the determination of total pressure and angle of attack. Angle of sideslip could be accurately determined from pressure measurements made on the horizontal centerline of the aircraft. Orifice pairs were also found that provided pressure ratio relationships suitable for the determination of Mach number. The accuracy that can be expected for the air data determined with SEADS during subsonic orbiter flight is indicated.

Larson, T. J.↗
NASA NTRS1985

Graphite Formation in Cast Iron

In the first phase of the project it was proven that by changing the ratio between the thermal gradient and the growth rate for commercial cast iron samples solidifying in a Bridgman type furnace, it is possible to produce all types of graphite structures, from flake to spheroidal, and all types of matrices, from ferritic to white at a certain given level of cerium. KC-135 flight experiments have shown that in a low-gravity environment, no flotation occurs even in spheroidal graphite cast irons with carbon equivalent as high as 5%, while extensive graphite flotation occurred in both flake and spheroidal graphite cast irons, in high carbon samples solidified in a high gravity environment. This opens the way for production of iron-carbon composite materials, with high carbon content (e.g., 10%) in a low gravity environment. By using KC-135 flights, the influence of some basic elements on the solidification of cast iron will be studied. The mechanism of flake to spheroidal graphite transition will be studied, by using quenching experiments at both low and one gravity for different G/R ratios.

Stefanescu, D. M.↗
NASA NTRS1985

Advanced Optical Measurement Techniques

This research analyzes four areas: (1) Improved Techniques for Optical Measurement; (2) KC-135 Low Gravity Simulation Flight Preparation; (3) In-Line Holographic Microscopy; and (4) Holographic Optical Schlieren System (HOSS). The first task provides for laboratory breadboarding of advanced optical measurement techniques which appear promising for use in Material Processing System (MPS) flight experiments. A laboratory schlieren system has been constructed which simulates a similar optical system on the Fluids Experiment System (FES) which is to be flown on Spacelab 3. The second task allows improved optical systems and breadboards to be built for experiments and hardware tests on the KC-135 aircraft. A new, more stable Mach-Zehnder interferometer has been developed and components have been ordered. The third task is concerned with improvements on the optical system being used to study immiscible fluids. Experiments studying the dynamics of nucleation and the separation of immiscible fluids have been conducted. The four task involves building breadboard reconstruction systems for holograms taken in the HOSS. The HOSS is an early prototype of the Fluids Experiments System (FES) which is scheduled to fly on Spacelab 3.

Owen, R. B.↗
NASA NTRS1987

Rapid melt/quench furnace using commercially available hardware

This report describes an off-the-shelf Orbital Tube Welder that can be easily used to melt and resolidify almost any electrically conductive material. This can be done on a KC-135 Aircraft within the microgravity period of one parabola. Melt sizes 3 mm diameter by 10 mm length and larger are feasible with most if not all materials. A highly reproducible, controlled, programmable heat and cool cycle can be provided. Sample measurements would have to be developed and could be as sophisticated or as simple as desired. These could include: optical and thermocouple temperature measurements, Peltier pulser for marking the solidification fronts, dimensional changes and whatever. Sample heat flows could be fixed over a very wide range being limited mostly by the cooling period, the desired sample size, and the 20 sec microgravity period of the KC-135 Aircraft parabola.

Poorman, Richard M.↗
NASA NTRS1987

Low-g propellant gaging

A program to develop and demonstrate technology for low gravity propellant gaging on future geostationary satellites is described. Evaluations were performed to select four gaging concepts for ground tests and low gravity tests in the NASA KC-135 aircraft. The selected concepts were: (1) an ultrasonic point sensor system, (2) a nucleonic gaging system, (3) an ultrasonic torsional wave guide, and (4) an ultrasonic flowmeter. As a result of successful ground and KC-135 tests, two concepts (the ultrasonic point sensor and the nucleonic systems) were selected for orbital test in a shuttle Get-Away-Special experiment.

Orton, George↗
NASA NTRS1987

Electrodeposition and codeposition under low gravity/nonconvecting conditions

An experimental electrodeposition system was developed for modeling the behavior of inert particles codepositing in an electroplating matrix under low-gravity conditions. The device consists of a Co-electrodeposition cell operating in a convectionless mode (cathode over anode) and containing polystyrene particles with density approximating that of the electroplating solution. Data were obtained in shielded cells at 1 g, and the experiment was duplicated at 0.01 g on a KC-135 flight. No difference was found between convection-free bench experiments and the 0.01 g KC-135 experiments with 0.0900 M CuSO4. Codeposition experiments using 11.8-micron matched-density polystyrene spheres in 1 M CoSO4 have revealed that a noticeable particle gradient is created as the solution density mismatches in the vicinity of the cathode; gentle stirring was required to maintain a homogeneous particle suspension. Cr3C2 dust, which readily disperses at 1 g, tended to coagulate into spherical globules at 0.01 g, when stirred.

Riley, Clyde↗