Equilibrium radiation from isothermal hydrogen- helium plasmas.
Isothermal hydrogen helium plasmas equilibrium radiation, discussing composition and radiation measurement, layers, line and continuum processes
Goulard, R.↗
SEARCH · Engineering Papers
Results for “ISOTHERMAL LAYER”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Unraveling the core of fuel cell performance: engineering the ionomer/catalyst interface
The biggest obstacle to the widespread implementation of polymer electrolyte membrane fuel cells (PEMFCs) is their cost, primarily due to the use of platinum catalysts. The high intrinsic catalyst activity exhibited on a rotating disk electrode (RDE) is rarely realized in a membrane electrode assembly (MEA), which is a long-standing challenge for PEMFCs and a cause of low catalyst utilization. To translate the high RDE performance of a catalyst into a MEA, the design of an ideal ionomer/catalyst interface is proposed: a thin, conformal ionomer film covers the maximum surface of a Pt nanoparticle and thus simultaneously maximizes catalyst utilization, (i.e., high mass activity and electrochemically active surface area) and O 2 diffusion rate (i.e., high current density performance) without compromising proton conduction. Building such an interface is a long-standing challenge due to the lack of interaction between the ionomer and catalyst particles, resulting in large ionomer agglomerates and inhomogeneous ionomer coverage over the catalyst nanoparticle, with consequent poor fuel cell performance. In this work, this ionomer/catalyst interface has been engineered, utilizing the electrostatic attraction between positively charged catalyst and negatively charged ionomer particles in a catalyst ink and preserved in a solid catalyst layer. As a result, this interface leads to previously unachieved proton exchange membrane fuel cell performance in terms of both catalyst utilization (75% vs. 45%) and peak/rated power density (i.e., 1.430/0.930 W cm -2 , H 2 /air, cathode Pt loading: 0.1 mgPt cm -2 ) for pure Pt catalysts, even better than those of Pt alloy catalysts. This work demonstrates the formation of an interface in the liquid phase (using ultra-small-angle X-ray scattering in combination with cryo-TEM, isothermal–titration–calorimetry) and the preservation of the interface in the solid catalyst layer (using TEM) and estimates the effective coverage and thickness of the ionomer film (using limiting current density, RDE and fuel cell performance).
25 ENERGY STORAGE↗
Single-Atom Doping at the Molecule–Metal Interface: How Rh Affects Surface Explosion Kinetics
Controlling chemical reactions at interfaces is central to many fields, including atmospheric, environmental, and biological chemistry as well as catalysis and corrosion. We performed a fundamental study of how catalytically active Rh atoms placed at and above a molecule-metal interface influence the surface reaction kinetics of tartaric acid (TA) decomposition. Specifically, TA decomposition on Cu(100) exhibits autocatalytic decomposition kinetics involving a slow initiation step followed by fast decomposition of the molecular layer. These so-called “surface explosions” are extremely sensitive to initial conditions, making it fundamentally interesting to study how the placement of reactive atoms affects the reaction rate. Temperature-programmed reaction (TPR) experiments reveal that Rh atoms embedded in the Cu(100) surface beneath TA (TA/Rh/Cu) or atop the TA layer (Rh/TA/Cu) reduce the decomposition temperature and modify the reaction rate constants. Isothermal TPR analysis reveals that Rh enhances both the initiation rate constant, k i , and the explosion rate constant, k e , facilitating explosive decomposition at lower temperatures. This result provides evidence that both the initiation and explosion steps occur at the metal-molecule interface and are accelerated by the presence of Rh at this interface. This study illustrates how small amounts of reactive elements may be used to control nonlinear kinetic processes at interfaces.
desorption↗
Pulsation and mass loss in Mira variables
The behavior of pulsation in the outer layers of a typical Mira variable was studied in the adiabatic and isothermal limits. A shock wave propagates outward once per period and the radial velocity obtained from observations of hydrogen emission lines is identified with the velocity of gas in the post shock region. In the adiabatic case, mass loss in the form of a steady stellar wind was produced. In the isothermal case, no continuous mass loss was produced but occasional ejection of shells occur. Pulsation introduced into a star undergoing steady mass loss as a result of radiation pressure acting on grains caused the mass loss rate to increase by a factor of approximately 40, while the terminal velocity of the flow was almost unaltered.
Wood, P. R.↗
Simultaneous concentration and purification through gradient deformation chromatography
Mobile-phase additives, commonly used to modulate absorbate retention in gradient elution chromatography, are usually assumed to be either linearly retained or unretained. Previous theoretical work from our laboratory has shown that these modulators, such as salts in ion-exchange and hydrophobic interaction chromatography and organic modifiers in reversed-phase chromatography, can absorb nonlinearly, giving rise to gradient deformation. Consequently, adsorbate peaks that elute in the vicinity of the head of the deformed gradient may exhibit unusual shapes, form shoulders, and/or be concentrated. These effects for a reversed-phase sorbent with aqueous acetonitrile (ACN) as the modulator are verified experimentally. Gradient deformation is demonstrated experimentally and agrees with simulations based on ACN isotherm parameters that are independently determined from batch equilibrium studies using the layer model. Unusual absorbate peak shapes were found experimentally for single-component injections of phenylalanine, similar to those calculated by the simulations. A binary mixture of tryptophan and phenylalanine is used to demonstrate simultaneous concentration and separation, again in agreement with simulations. The possibility of gradient deformation in ion-exchange and hydrophobic interaction chromatography is discussed.
NASA Discipline Number 93-10↗
Insights into Controls of Mineralogy and Pore Structure on the Density of Methane Adsorption Phase in Shales under Supercritical Conditions
With gradually increasing enhancing population and industrialization, exploitation of shale gas is enhancing in the world to satisfy the growing demand for energy worldwide. To exploit shale gas efficiently, accurate assessment of shale gas in place (GIP) is necessary for determining production strategies. Unlike free and dissolved gas, adsorbed gas contributes to the shale GIP up to 85% due to the well-developed surface area and micropores. Measured excess adsorption of methane (up to over 95% of subsurface shale gas) is often corrected to absolute adsorption to obtain the actual amount of adsorption under supercritical (or geological) conditions. During the correction, adsorption phase density (APD) is critical. However, the APD of subsurface shale gas and the effects of shale properties (e.g., mineralogy and pore structure) on APD remain poorly understood. A series of high-pressure methane adsorption isotherms (HPMAI) on Caney Shales were collected and analyzed in conjunction with other United States and Chinese shales from the literature at 35–125 °C and up to 15 MPa. Here, a three-layer Ono–Kondo (OK3) model is utilized to derive the temperature- and pressure-dependent APD coupling low-pressure nitrogen adsorption isotherms (LPNAI) and HPMAI. X-ray diffraction and organic geochemistry are combined to reveal the mineralogy. Brunauer–Emmett–Teller, Barrett–Joyner–Halenda, and Horvath–Kawazoe analyses via LPNAI are used to investigate the pore structures. Results show that APD increases with organic matter (OM) proxied by total organic carbon and decreases with clay minerals and the sum of quartz and feldspar. OM dramatically contributes to the APD as multiple-layer adsorption exists, and the APD for OM could be 1.4–8.5 times that for clay minerals. Other inorganic minerals contribute less to APD. The properties and constitution of the surface area instead of the volume fraction contribute to the APD in shales. APD does not show an obvious correlation with micropore volume, likely related to the ratio of micropore volume to the total pore volume. Here, we provide a significant and comprehensive study of petrological factors that impact the APD of subsurface shale gas, which will improve the estimation of supercritical adsorption and shale GIP under reservoir conditions. Also, the findings in this work can provide applications for subsurface carbon dioxide adsorption and storage.
58 GEOSCIENCES↗
Thermal evolution of neutron stars with internal frictional heating
It has been suggested that the frictional interaction of neutron superfluids with normal matter in the inner crust of neutron stars dissipates rotational energy of superfluids and generates heat. Incorporating a general formula of internal heating into the detailed numerical codes of thermal evolution, we examine the effects of the internal heating on thermal evolution of neutron stars. We find that when a very stiff equation of state is used, it takes as long as about 2 x 10 exp 4 yr for the interior of a neutron star to reach the isothermal state, even if a strong heat source is placed in a thin layer of the inner crust. This time scale reduces to a few hundred years or less when medium to soft equations of state are used. A neutron star cools by neutrino emissions during the earlier stages referred to as the neutrino cooling era, while during the later photon cooling era it cools primarily by emission of photons from its surface. We show that heating rates expected in the current superfluid-crust interaction model can greatly increase the surface temperature in the photon cooling era, significantly changing the thermal evolution of relatively old neutron stars if a stiff equation of state is adopted.
Umeda, Hideyuki↗
Water Uptake by Silica Nanopores: Impacts of Surface Hydrophilicity and Pore Size
Water uptake at 298 K by two mesoporous silicas with different pore sizes was studied using volumetric vapor sorption. Here, through variation of sample pretreatment temperature and time, the number of surface hydroxyl groups was varied, leading to marked changes in the water sorption behavior. With increasing surface hydroxyl density, the adsorption of water to the pore surfaces increases, leading to formation of a thicker and denser water sorption layer. The BET model was used to measure surface hydroxyl density from low pressure parts of water adsorption isotherms. Adsorption of water molecules scales with the number density of surface hydroxyl groups, and monolayer coverage is reached at reduced pressure of ca. 0.3. The onset of adsorption pore condensation of water shifts to lower reduced pressure with increasing surface hydroxyl density, indicating growing thickness of adsorption layers. However, the water pore condensation step of the desorption branch shifts to smaller reduced pressure with increasing surface hydroxylation, reducing the adsorption-desorption hysteresis width. An adsorbed phase model is utilized to calculate the distribution of pore water molecules between adsorbed and pore condensation phases, and characterize the density and thickness of the water sorption phase. In the smaller pores, the adsorbed phase forms a sparse monolayer, while approximately a bilayer is formed in the wider pores. The previously reported silica nanopore underfilling by water is confirmed and rationalized by a significantly reduced water density in the adsorbed phase with respect to bulk, while the pore core is filled with water of approximately bulk density.
36 MATERIALS SCIENCE↗
Sintering Characteristics of Multilayered Thermal Barrier Coatings Under Thermal Gradient and Isothermal High Temperature Annealing Conditions
Pyrochlore oxides have most of the relevant attributes for use as next generation thermal barrier coatings such as phase stability, low sintering kinetics and low thermal conductivity. One of the issues with the pyrochlore oxides is their lower toughness and therefore higher erosion rate compared to the current state-of-the-art TBC material, yttria (6 to 8 wt%) stabilized zirconia (YSZ). In this work, sintering characteristics were investigated for novel multilayered coating consisted of alternating layers of pyrochlore oxide viz Gd2Zr2O7 and t' low k (rare earth oxide doped YSZ). Thermal gradient and isothermal high temperature (1316 C) annealing conditions were used to investigate sintering and cracking in these coatings. The results are then compared with that of relevant monolayered coatings and a baseline YSZ coating.
Thermal Barrier Coatings↗
Influence of Thermally-Grown Oxide (TGO) Layer on the Driving Forces Associated with Failure in Environmental Barrier Coating (EBC) Systems
Environmental barrier coatings (EBC) is an enabling technology for the successful application of ceramic matrix composites (CMCs) in air-breathing gas turbine engines. Spallation of environmental barrier coating (EBC) induced by thermally grown oxide (TGO) layer is a key EBC failure mode. The TGO layer, resulting from steam oxidation, grows either from a silicon bond coat layer (if present) or from the silicon carbide (SiC) based substrate itself. Critical thickness of the TGO layer for failure is in the range of 20-30 microns but it can vary due to exposure temperature, microstructure etc. Current work at NASA Glenn Research Center, under the Revolutionary Tools and Methods (RTM) project is aimed at addressing associated failure modes in EBC systems and developing robust analysis tools to aid in the design/analysis of these systems. The objective of the current work is to conduct a sensitivity study to examine the influence of uniformly and non-uniformly grown oxide layers with or without damage on the associated driving forces leading to spallation of the EBC when subjected to isothermal loading. Initial results indicate that the presence of damage (vertical cracks caused by in-plane stresses) enhances the stresses that are present due to non-uniformity. However, the presence of non-uniformity itself is still the main factor influencing the magnitude of peel and shear stresses in the TGO layer.
Mital, Subodh K.↗
An Engineering Approach to the Variable Fluid Property Problem in Free Convection
An analysis is made for the variable fluid property problem for laminar free convection on an isothermal vertical flat plate. For a number of specific cases, solutions of the boundary layer equations appropriate to the variable property situation were carried out for gases and liquid mercury. Utilizing these findings, a simple and accurate shorthand procedure is presented for calculating free convection heat transfer under variable property conditions. This calculation method is well established in the heat transfer field. It involves the use of results which have been derived for constant property fluids, and of a set of rules (called reference temperatures) for extending these constant property results to variable property situations. For gases, the constant property heat transfer results are generalized to the variable property situation by replacing beta (expansion coefficient) by one over T sub infinity and evaluating the other properties at T sub r equals T sub w minus zero point thirty-eight (T sub w minus T sub infinity). For liquid mercury, the generalization may be accomplished by evaluating all the properties (including beta) at this same T sub r. It is worthwhile noting that for these fluids, the film temperature (with beta equals one over T sub infinity for gases) appears to serve as an adequate reference temperature for most applications. Results are also presented for boundary layer thickness and velocity parameters.
Gregg, J. L.↗
An analysis of the ignition of slot-injected gaseous hydrogen in a supersonic air stream.
Initial air boundary layer effect on ignition of slot-injected gaseous hydrogen in supersonic airstream, discussing isotherm and streamline patterns
Favin, S.↗
Propagation of acoustic waves in a stratified atmosphere, 1
This work is motivated by the chromospheric 3 minute oscillations observed in the K(sub 2v) bright points. We study acoustic gravity waves in a one-dimensional, gravitationally stratified, isothermal atmosphere. The oscillations are excited either by a velocity pulse imparted to a layer in an atmosphere of infinite vertical extent, or by a piston forming the lower boundary of a semi-infinite medium. We consider both linear and non-linear waves.
Kalkofen, W.↗
On Modeling Air/Space-Borne Radar Returns in the Melting Layer
The bright band is the enhanced radar echo associated with the melting of hydrometeors in stratiform rain where the melting process usually occurs below 0 C isotherm over a distance of about 500m. To simulate this radar signature, a scattering model of melting snow is proposed in which the fractional water content is prescribed as a function of the radius of a spherical mixed- phase particle consisting of air, ice and water. The model is based on the observation that melting starts at the surface of the particle and then gradually develops towards the center. To compute the scattering parameters of a non-uniform melting particle, the particle is modeled as a sphere represented by a collection of 64(exp 3) cubic cells of identical size where the probability of water at any cell is prescribed as a function of the radius. The internal field of the particle, used for deriving the effective dielectric constant, is computed by the Conjugate Gradient and Fast Fourier Transform (CGFFT) numerical methods. To make computations of the scattering parameters more efficient, a multi-layer stratified-sphere scattering model is introduced after demonstrating that the scattering parameters of the non-uniformly melting particle can be accurately reproduced by the stratified sphere. In conjunction with a melting layer model that describes the melting fractions and fall velocities of hydrometeors as a function of the distance from the 0 C isotherm, the stratified-sphere model is used to simulate the radar bright band profiles. These simulated profiles are shown to compare well with measurements from the Precipitation Radar (PR) aboard the Tropical Rainfall Measuring Mission (TRMM) satellite and a dual-wavelength airborne radar. The results suggest that the proposed model of a melting snow particle may be useful in studying the characteristics of the bright-band in particular and mixed- phase hydrometeors in general.
Liao, Liang↗
Effect of resistivity on poloidal asymmetries in electron density in the edge and scrape off layer in 3D full-F gyro-fluid simulations with FELTOR
In this contribution, we analyze the poloidal asymmetries in electron density in the edge and scrape-off layer (SOL) in a COMPASS-sized, diverted tokamak with the 3D full-F, isothermal, electromagnetic, and gyro-fluid model FELTOR. The study is performed for different simulations that span over 2 orders of magnitude in resistivity. The poloidal asymmetries of density are evaluated in the edge and the SOL relative to the outer midplane (OMP), where the highest densities are usually found. In the closed magnetic surfaces, the relative poloidal asymmetry with respect to the OMP is not larger than 20% independently of the plasma resistivity. For the open field lines in the SOL, the relative density asymmetry can range from 55% for the highest resistivity to around 40% for the lowest. The lowest densities inside the separatrix are found between the inner midplane and the top of the magnetic configuration, away from the X-point. In the SOL it is usually close to the X-point in the high field side. The observations in the closed field lines are consistent with ballooning transport but in the SOL oppose experimental evidence for high-density plasmas. In conclusion, this indicates the necessity for more complex physics to reproduce the experimental observations in the SOL for higher density plasmas, such as neutral-plasma dynamics and realistic divertor conditions.
3D full-f gyrofluid↗
Molecular Structure of Adsorbed Water Phases in Silica Nanopores
The adsorption of water vapor in silica nanopores with different pore morphologies and surface hydrophilicities was studied to quantify the densities and thicknesses of the water sorption layers and deduce their molecular structures. Water adsorption to surface hydroxyls is described by a multilayer sorption model. At low pressure, the water adsorption isotherms are largely independent of pore size and the adsorbed amounts scale with the surface hydroxyl density. Adsorbed-phase densities corresponding to the adsorption of two water molecules per surface hydroxyl group are found in the first adsorbed water layer for a wide range of surface hydroxyl densities. The densities and layer thickness values found in narrow pores indicate that patchy adsorbed layers form if not enough water molecules exist for a full layer, which coexist with dry pore surface regions. This behavior indicates cooperative adsorption effects, i.e., a preference for the formation of hydrogen bonds between water molecules bound to surface hydroxyls. In narrow pores, pore condensation limits further growth of the sorption layer, and in larger pores and at the planar quartz surface, a second adsorbed water layer is formed, which can hold up to approximately 4 additional water molecules per surface hydroxyl group. The water molecules in these thicker adsorption layers arrange such that the sorption layer density is similar to the bulk water density. Pore confinement limitations on the sorption layers are observed in pores with radii of as large as 8 nm. Molecular dynamics modeling reveals two preferential orientations for water molecules adsorbing to surface hydroxyl groups and suggests an intralayer structuring in the adsorbed monolayer. Furthermore, adsorbed water molecules in the sorption layer are bonded to the surface hydroxyl group via the donation and acceptance of hydrogen bonds.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Reaction of Ta thin film with single crystalline (001) beta-SiC
The reaction between a sputtered-deposited Ta film (320 nm thick) and a single crystalline (001) beta-SiC substrate induced by vacuum annealing at temperatures of 600-1200 C for 1 h (30 min at 1100 C) is investigated by 3 MeV He(+2) backscattering spectrometry, x-ray diffraction, secondary ion mass spectrometry, and transmission and scanning electron microscopies. No significant reaction is observed at 800 C or at lower tempertures. At 900 C, the main product phases are Ta2C and carbon-stabilized Ta5Si3. A minor amount of unreacted Ta is also present. After annealing at 1000 C, all the tantalum has reacted; the reaction zone possesses a multilayered structure of beta-SiC/TaC/carbon-stabilized Ta5Si3/alpha-Ta5Si3/Ta2C. The diffusion path at 1000 C is plotted on the isothermal section of the Ta-Si-C phase diagram. At 1100 C, the reacted layer has an interface with the SiC substrate that is still quite flat but has a rough surface due to the formation of macroscopic voids within the reacted layer. The equilibrium products predicted by the phase diagram are TaC and TaSi2. This final state is reached by annealing at 1200 C for 1 h. At that point, the reacted layer has a latterally very uneven structure and morphology.
Chen, J. S.↗
Heat transfer by condensation of low pressure metal vapors.
The film condensation of low pressure metal vapors on isothermal vertical flat plates or tubes is considered. The liquid film is treated as a thin layer in which the acceleration and pressure forces are negligible and across which the temperature distribution is linear. The average behavior of the vapor is found from the linearized one-dimensional vapor flow equations. In order to calculate the rate of condensation, a consistent distribution function for the vapor particles at the liquid-vapor interface is necessary and is determined. The result of the analysis is a set of algebraic equations from which one can predict the condensation rate of low pressure metal vapors. A large but continuous temperature decrease in the vapor is predicted and calculated.
Huang, Y. S.↗