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Results for “INFRARED SPECTRA”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

The microwave and far-infrared spectra of the O-(18)H radical

Far-infrared laser magnetic resonance (LMR) spectroscopy was used to calculate the frequencies, wavelengths, and line strengths for transitions of O-(18)H molecules at microwave and far-infrared frequencies. In this experiment, a molecular transition frequency is tuned into coincidence with that of a fixed frequency laser by the application of a variable magnetic field. The O-(18)H radicals, detected in natural abundance (0.20 percent), were produced by the reaction of hydrogen atoms with nitrogen dioxide. These data together with microwave frequencies ascertained by Gottlieb, Redford, and Smith (1974) were used to determine the parameters of an effective Hamiltonian. Rotational levels up to J = 5.5 were involved. Results are indicated schematically and the low-lying energy levels of O-(18)H are shown. It is concluded that the frequencies of transitions between levels studied directly in the LMR experiment are reliable.

Comben, E. R.↗
NASA NTRS2014

Infrared Spectra and Optical Constants of Astronomical Ices: II. Ethane and Ethylene

Infrared spectroscopic observations have established the presence of hydrocarbon ices on Pluto and other TNOs, but the abundances of such molecules cannot be deduced without accurate optical constants (n, k) and reference spectra. In this paper we present our recent measurements of near- and mid-infrared optical constants for ethane (C2H6) and ethylene (C2H4) in multiple ice phases and at multiple temperatures. As in our recent work on acetylene (C2H2), we also report new measurements of the index of refraction of each ice at 670 nm. Comparisons are made to earlier work where possible, and electronic versions of our new results are made available.

Ices↗
NASA NTRS1967

Study made of far infrared spectra of silicate minerals

Study of mineral in the far infrared region of the spectrum examines the problems and feasibility of remote sensing of the composition of the moon or tenuous atmosphere planets. Most of the work described utilized reflection techniques.

Source record↗
NASA NTRS1972

Infrared spectra of group III A metal oxides

The measurement of infrared frequencies of metal-oxygen species which could be formed in the matrix and to investigate with an oxygen-18 enrichment study the controversy on the vibrational assignments for the suboxide. Several new molecules, Al3O2, Ga3O, In3O, In4O2, IntaO, IntaO2, and In2WO4, were found by mass spectrometric sampling to exist in extremely minor concentrations in the vapor phase. The latter three species were formed by reaction with the crucible materials and were unimportant for an infrared analysis. The infrared spectroscopic measurements were obtained by the matrix isolation technique of molecular beam sampling. The MO2 species were formed by direct reaction between metal and O2 in the matrix. A C2v structure and an O-M-O bond angle near 40 deg was favored for these molecules by analogy with a similar investigation of the alkali metals. The vibrational frequencies which were determined are given.

Lynch, D. A., Jr.↗
NASA NTRS1985

Infrared spectra and interstellar reddening of anonymous type II OH/IR stars

Infrared positions and multicolor infrared photometry for a sample of type II OH/IR stars are reported. The infrared colors and 11.4-micron silicate optical depths of the confirmed sources in this group increase as a function of distance, suggesting that interstellar reddening must be taken into account in assessing their infrared energy distributions and physical characteristics.

Gehrz, R. D.↗
NASA NTRS1989

Hydrogen sulfide on Io - Evidence from telescopic and laboratory infrared spectra

Evidence is reported for hydrogen sulfide on Io's surface. An infrared band at 3.915 (+ or - 0.015) micrometers in several ground-based spectra of Io can be accounted for by reflectance from H2S frost deposited on or cocondensed with sulfur dioxide frost. Temporal variation in the occurrence and intensity of the band suggests that condensed H2S on Io's surface is transient, implying a similar variation of H2S abundance in Io's atmosphere.

Nash, Douglas B.↗
NASA NTRS1981

Accurate frequency and intensity measurements of the infrared spectra of atmospheric molecules

Various problems encountered and solutions found in infrared laboratory measurements on atmospheric molecules are discussed. The advantages and limitations of various measurement techniques and equipment are discussed, with emphasis placed on calibration techniques and measurement accuracy and precision. Frequency calibration aids are presented, including the current and planned tables of absorption frequency standards being developed by the Bureau of Standards for the calibration of high-resolution devices with an accuracy of + or - 3 MHz. It is noted that intensity measurements are highly susceptible to systematic errors and that great care must be taken to obtain accuracies better than + or - 10%. What is even more difficult is knowing the accuracy of a particular measurement. Recent work done on providing accurate intensity data are described.

Maki, A. G.↗
NASA NTRS1978

Preliminary results of study of infrared spectra of Venus from the orbital spacecraft Venera-9 and Venera-10

The infrared spectrum of Venus in the spectral range 1.6 to 2.8 was measured by means of the spectrometers aboard 'Venera-9' and 'Venera-10' orbital spacecrafts. Approximately 20 series of measurements were made near the pericenter of the orbit, each of which contains 150 spectra for each path intersecting the planet from the terminator to the limb. Phase angles lie within the limits from 60 to 120 deg.

Gnedykh, V.↗
NASA NTRS1993

High-resolution mid-infrared spectra of Co II, Ni I, and Fe II in SN 1987A

Ground-based infrared observations of SN 1987A on day 612 after the explosion have yielded resolved line profiles of Co II, Ni I, Fe II at 10.52, 11.31, and 17.94 micron, respectively. The spectra were taken at a resolving power of about 1000 with an array grating spectrometer on the 4 m telescope of Cerro Tololo Inter-American Observatory. Based on the observed line intensities we have estimated the minimum mass of each ion: M(Co II) = (6.0 +/- 1.8) x 10 exp -5 solar mass; M(Ni I) = (1.1 +/- 0.1) x 10 exp -3 solar mass; and M(Fe II) = (8.0 +/- 1.5) x 10 exp -3 solar mass. From these we infer total masses for cobalt, nickel, and iron in the ejecta. The nickel and iron line profiles are markedly asymmetric. We interpret these as arising from two components, one centered on the stellar rest velocity with an approximately 3250 km/s full width, and the second at about +1200 km/s with an approximately 1100 km/s full width. The asymmetry may represent a large-scale fracturing of the ejecta by Rayleigh-Taylor instabilities.

Jennings, D. E.↗
NASA NTRS1975

Infrared spectra of planetary atmospheres

The development of high spectral resolution and highly sensitive long infrared wavelength instruments is reported. This instrumentation is used to examine molecular lines in planetary atmospheres in enough detail to obtain new information about these atmospheres. Such information includes (1) pressure and temperature relations in planetary atmospheres, and (2) molecular and isotopic composition.

Townes, C. H.↗
NASA NTRS1982

Far infrared spectra of H2 mixtures of H2-CH4 and H2-He

Laboratory measurements of the far infrared absorption of H2 and of mixtures of H2 with CH4 and He are presented, and fits to the pure H2 spectra with a semiempirical line shape are described. Such results are needed in analyzing the thermal emission from the atmospheres of the outer planets.

Birnbaum, G.↗
NASA NTRS1978

Estimation of Venus wind velocities from high-resolution infrared spectra

Zonal velocity profiles in the Venus atmosphere above the clouds were estimated from measured asymmetries of HCl and HF infrared absorption lines in high-resolution Fourier interferometer spectra of the planet. These asymmetries are caused by both pressure-induced shifts in the positions of the hydrogen-halide lines perturbed by CO2 and Doppler shifts due to atmospheric motions. Particularly in the case of the HCl 2-0 band, the effects of the two types of line shifts can be easily isolated, making it possible to estimate a profile of average Venus equatorial zonal velocity as a function of pressure in the region roughly 60 to 70 km above the surface of the planet. The mean profiles obtained show strong vertical shear in the Venus zonal winds near the cloud-top level, and both the magnitude and direction of winds at all levels in this region appear to vary greatly with longitude relative to the sub-solar point.

Smith, M. A. H.↗
NASA NTRS2015

Infrared Spectra and Optical Constants of Elusive Amorphous Methane

New and accurate laboratory results are reported for amorphous methane (CH4) ice near 10 K for the study of the interstellar medium (ISM) and the outer Solar System. Near- and mid-infrared (IR) data, including spectra, band strengths, absorption coefficients, and optical constants, are presented for the first time for this seldom-studied amorphous solid. The apparent IR band strength near 1300 cm(exp −1) (7.69 micrometer) for amorphous CH4 is found to be about 33% higher than the value long used by IR astronomers to convert spectral observations of interstellar CH4 into CH4 abundances. Although CH4 is most likely to be found in an amorphous phase in the ISM, a comparison of results from various laboratory groups shows that the earlier CH4 band strength at 1300 cm(exp −1) (7.69 micrometer) was derived from IR spectra of ices that were either partially or entirely crystalline CH4 Applications of the new amorphous-CH4 results are discussed, and all optical constants are made available in electronic form.

ISM: abundances↗
NASA NTRS2012

Water Vapor in Titan's Stratosphere from Cassini CIRS Far-Infrared Spectra

Here we report the measurement of water vapor in Titan's stratosphere using the Cassini Composite Infrared Spectrometer (CIRS). CIRS senses water emissions in the far infrared spectral region near 50 micron, which we have modeled using two independent radiative transfer codes. From the analysis of nadir spectra we have derived a mixing ratio of 0.14 +/- 0.05 ppb at an altitude of 97 km, which corresponds to an integrated (from 0 to 600 km) surface normalized column abundance of 3.7 +/- 1.3 1014 molecules/cm2. In the latitude range 80S to 30N we see no evidence for latitudinal variations in these abundances within the error bars. Using limb observations, we obtained mixing ratios of 0.13 +/- 0.04 ppb at an altitude of 115 km and 0.45 +/- 0.15 ppb at an altitude of 230 km, confirming that the water abundance has a positive vertical gradient as predicted by photochemical models. We have also fitted our data using scaling factors of 0.1-0.6 to these photochemical model profiles, indicating that the models over-predict the water abundance in Titan's lower stratosphere.

composition↗
NASA NTRS1984

The significance of far-infrared spectra of the interstellar medium

This paper deals with the analysis of interstellar clouds through infrared and submillimeter observations. The determination of temperature, density, state of ionization and abundance of different chemical constituents is discussed for clouds exhibiting a range of optical depths. There is a preferred choice of spectral features useful for examining different types of gaseous complexes. The prospects for improving the understanding of chemical reaction schemes in interstellar clouds are outlined. Prime advances may be expected in improved data on the abundance of atoms; diatomic hydrides; other small, hydrogen-containing molecules; and their ions.

Harwit, M.↗
NASA NTRS1986

Infrared spectra of WC10 planetary nebulae nuclei

The 5.2 to 8.0 micron spectra are presented for two planetary nebulae nuclei Hen1044 (He2-113) and CPD-56 8032. The unidentified infrared (UIR) emission bands at 6.2 microns, 6.9 microns, 7.7 microns are present in the spectra of Hen1044 and in CPD-56 8032, and the 8.6 micron band is present in the long wavelength shoulder of the 7.7 micron band in the spectrum of CPD-56 8032. The 8 to 13 micron spectra of these two stars by Aitken et. al. clearly show the presence of the 8.6 micron band in He2-113 while weakly resolving this feature in the spectra of CPD-56 8032. In their spectra the 11.3 micron band is also clearly detected in both objects. The 6.2 micron and 7.7 micron bands are characteristic of the infrared active C-C stretching modes in polycyclic aromatic hydrocarbons (PAHs); the 3.3 micron, 8.6 micron, and 11.3 micron bands are respectively assigned to the in-plane stretching mode, the in-plane bending mode, and the out-of-plane bending mode of the aromatic CH bond. The weak 6.9 micron emission feature is attributed to the UIR spectrum by Bregman et. al. The IRAS LRS spectra of He2-113 (IRAS 14562-5406) and CPD-56 8032 (IRAS 17047-5650) are presented. Cohen et. al. identify the broad plateau from 11.3 to 13.0 microns in the spectrum of He2-113 with increased hydrogenation of PAHs. This broad plateau is not seen in the LRS spectrum of CPD-56 8032. Also, He2-113 has greater infrared excess emission in the 17-22 micron region than does CPD-56 8032.

Wooden, D. H.↗