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DOE OSTI2024

An Impedance Humidity Sensor Based on CVD Grown WSe 2 2D Films

2D materials-based planar devices have been sought after for gas and humidity sensor applications owing to their high sensitivity due to their ultrathin nature and increased surface area. Herein, 2D WSe 2 films-based planner devices were fabricated to evaluate their performance for potential application in humidity sensors. The structure and morphology of the WSe 2 sensing films were studied by Raman spectroscopy, photoluminescence, optical microscopy, and scanning electron microscopy (SEM) techniques. The relative humidity-dependent sensing performances of the 2D WSe 2 films were evaluated using current–voltage (I–V), relative impedance, and complex total impedance (electrochemical impedance spectroscopy, EIS) techniques. This sensor showed a very stable and repeatable performance investigated over the period of 18 months. The response and recovery times of the WSe 2 -based impedance sensors were found to be 40 and 30 s, respectively. The WSe 2 sensor exhibits a 2 ± 1% minimum hysteresis at a lower humidity level (50% RH) and around 8 ± 2% maximum hysteresis at relative humidity level (70% RH). This value of hysteresis is in the acceptable range during the initial investigation of any material to explore its potential for application in humidity sensors. The density functional theory (DFT) analysis was performed with the interaction from water molecules of the WSe 2 sample for a better understanding of the sensing mechanism of devices.

2D- WSe2↗

DOE OSTI2026

Measurement of Local Impedance Characteristics of In-Plane PEM Electrolyzer Component Features via Segmented Cell

Segmented cells are a class of advanced diagnostic devices that enable the measurement of current distribution within the active area of an electrochemical cell, allowing for the evaluation of localized impacts from operating conditions, flow fields and component inhomogeneities. Segmented cell devices have been applied to support R&D efforts for the advancement of polymer electrolyte membrane fuel cell technologies and more recently proton exchange membrane water electrolysis (PEMWE). Beyond current density distributions, segmented cells have been successfully deployed to collect the distribution of other relevant parameters such as high frequency resistance and electrode potentials. Very recently, a promising impedance method has been reported for water electrolysis where a one-dimensional segmented cell is coupled to a multichannel potentiostat, to enable the measurement of local cell impedances, further expanding the diagnostic capabilities of the segmented cell. In this study, we will present recent efforts to accurately measure local impedance characteristics for a PEMWE cell using a two-dimensional segmented cell device coupled with a multichannel potentiostat. The distribution of local resistances, i.e. high frequency, charge transfer, mass transport and catalyst layer, and iR-free overpotentials were successfully measured after eliminating sources of random and systematic error. We will discuss the application of this diagnostic on a cell containing a 1 cm feature simulating an ionomer skin. The results from these tests give insights if such an irregularity needs to be classified as a defect, and highlight the usefulness of coupling impedance spectroscopy with segmented cells for holistic spatial diagnostics of electrochemical devices.

08 HYDROGEN↗

NASA NTRSDate not supplied

An Improved Impedance Eduction Process for the NASA Langley GFIT

The Grazing Flow Impedance Tube (GFIT) is regularly employed to characterize the frequency response of acoustic liners through the eduction of their specific acoustic impedance. Acoustic pressures acquired in the facility are processed with various eduction methods to arrive at these impedance values. Recent implementation of the Swept-Sine Method provides much greater frequency resolution when characterizing the acoustic properties of a liner. The attendant increase in data that must be processed from this method has highlighted a need for greater efficiency in educing acoustic impedance. The current work details efforts to improve the eduction process through use of a hybrid approach that combines a Prony-based method with the Convected Helmholtz-based calculation generally used for this type of data. Comparisons of efficiency and accuracy are shown for this new hybrid approach versus earlier methods for three acoustic liners tested under various conditions in the GFIT with stepped-sine and recently implemented swept-sine sources.

Eduction↗

NASA NTRS2022

Implementation of the NASA High Intensity Modal Impedance Tube

This paper provides a description of the High Intensity Modal Impedance Tube (HIMIT) and its use for the evaluation of acoustic liners. Tests conducted with two liners, one linear and one nonlinear, are used to evaluate the suitability of the HIMIT for evaluation at frequencies up to 6 kHz and sound pressure levels up to 155 dB. Two impedance eduction methods are used, one suitable for plane wave frequencies and the other applicable over the full frequency range. These educed impedances are compared against those computed with an impedance prediction method and against those educed with another zero-flow test rig. These results confirm that the HIMIT can be used with confidence for the evaluation of acoustic liners over these frequency and sound pressure level ranges.

impedance↗

NASA NTRSDate not supplied

Impedance Measurements of Motor Drives and Supplies in NASA NEAT Facility

Many electrified aircraft configurations consist of a number of power components operating on the same shared electrical bus. Understanding the impedance performance of electrical loads and sources is key to understanding, and designing for, acceptable overall vehicle power quality and power system stability. This paper discusses impedance measurements made on the NASA Electric Aircraft Testbed (NEAT) Electrical Power System (EPS) at NASA Glenn Research Center. First, an overall discussion of the NEAT facility configuration during testing is presented. Then, details of the impedance measurement approach and the various testing configurations are discussed. Next, input impedance measurements at NEAT, including sources (DC supplies) and loads (multiple motor drives, electric machines, and resistive load banks, with long interconnecting cable leads), are performed under a number of conditions, and results, including load model comparisons and stability analysis, are presented and discussed.

electrified aircraft propulsion↗

NASA NTRSDate not supplied

Impedance Measurements of Motor Drives and Supplies in NASA NEAT Facility

Many electrified aircraft configurations consist of a number of power components operating on the same shared electrical bus. Understanding the impedance performance of electrical loads and sources is key to understanding, and designing for, acceptable overall vehicle power quality and power system stability. This paper discusses impedance measurements made on the NASA Electric Aircraft Testbed (NEAT) Electrical Power System (EPS) at NASA Glenn Research Center. First, an overall discussion of the NEAT facility configuration during testing is presented; then details of the impedance measurement approach and the various testing configurations are discussed. Next, input impedance measurements at NEAT, including sources (DC supplies) and loads (multiple motor drives, electric machines, and resistive load banks, with long interconnecting cable leads), are performed under a number of conditions, and results, including load model comparisons and stability analysis, are presented and discussed.

electrified aircraft propulsion↗

NASA NTRSDate not supplied

Impedance Measurements of Motor Drive and Supply in SPEED Testbed

Many electrified aircraft configurations consist of a number of power components operating on the same shared electrical bus. Understanding the impedance performance of electrical loads and sources is key to understanding, and designing for, acceptable overall vehicle power quality and power system stability. To enable these measurements, personnel at NASA’s Glenn Research Center have designed and built the Scaled Power ElEctrified Drivetrain (SPEED) Testbed. This paper will present data taken in the SPEED lab, including impedance measurements of a DC supply (source) and a motor drive and electric machine (load) under a number of conditions. Impacts of load power, drive controller tuning, and field-weakening on load impedance are measured, presented, and discussed; as are source impedance data, stability, and DC bus current spectra at different loading levels.

electrified aircraft propulsion↗

NASA NTRSDate not supplied

Impedance Measurements of Motor Drives and Supply in SPEED Testbed

Many electrified aircraft configurations consist of a number of power components operating on the same shared electrical bus. Understanding the impedance performance of electrical loads and sources is key to understanding, and designing for, acceptable overall vehicle power quality and power system stability. To enable these measurements, personnel at NASA’s Glenn research Center have designed and built the Scaled Power ElEctrified Drivetrain (SPEED) Testbed. This paper will present data taken in the SPEED lab, including impedance measurements of a DC supply (source) and a motor drive and electric machine (load) under a number of conditions. Impacts of load power, drive controller tuning, and field weakening on load impedance are measured, presented, and discussed; as are source impedance data, and DC bus current spectra at different loading levels.

electrified aircraft propulsion↗

DOE OSTI2026

Experimental considerations and applications for time-resolved impedance on silicon-anode battery systems

Dynamic electrochemical impedance spectroscopy (dEIS) utilizes a superimposed multi-sinusoidal waveform and enables temporally resolved investigations on various electrochemical processes; however, the signal-to-noise ratio must be maximized while retaining linearity and stationarity within the system. In the present work, we probe the impact of the waveform’s total amplitude as well as the waveform and phase profiles. The equal amplitude multi-sinusoidal waveform with 35 mV total amplitude (<1 mV per frequency) and random phase profile exhibits the lowest impedance noise. This input signal is sufficient in avoiding the high frequency signal attenuation from the potentiostat’s low-pass filter. Additionally, we demonstrate the optimized dEIS waveform’s utility in investigating surface passivation within thin-film and composite silicon (Si) anodes. Within a two-electrode Si-lithium metal coin cell, the charge transfer resistance (RCT) associated with alloying kinetics dominates the overall impedance. RCT increases with state of charge indicating a kinetic bottleneck at higher lithiation states. To explore this further, we utilize a three-electrode Si-LiNi0.8Mn0.1Co0.1O2 pouch cell to deconvolute the Si impedance contributions. The evolution of the solid electrolyte interphase (SEI) and charge transfer resistances correlate to specific Li–Si alloy phases. We attribute this to the influence of Si particle volume expansion on SEI instabilities and a kinetic bottleneck at higher lithiation states.

Lam, Steven [ORNL]↗

DOE OSTI2025

Rotated-Droop Control for Enhanced Stability and Power Decoupling in Microgrids With Complex Line Impedances

Classical droop control in microgrids predominantly assumes inductive line impedance, which simplifies implementation but causes power coupling and steady-state errors in systems with resistive and inductive lines. This paper proposes a rotated-droop control strategy for grid-forming inverters that reformulates the power equations by incorporating the magnitude and angle of the line impedance within a rotated reference frame. This method enhances the decoupling of active and reactive power dynamics without increasing complexity or requiring communication links. A small-signal state-space model was created to capture the dynamic behavior of the system under varying impedance parameters, preserving the original droop gains by rotating the power control structure. This allows eigenvalue-based stability analysis and enhances damping and transient performance. Simulation and experimental results validated the improved power-sharing performance, faster response, and robustness of the proposed method under different impedance conditions. This approach maintains the decentralized structure of the conventional droop control while enabling greater adaptability and scalability, making it suitable for modern inverter-based microgrids with dynamic topologies.

Campo-Ossa, Daniel Dario [Univ. of Puerto Rico, Ag↗

NASA NTRS1972

AC impedance of silicon solar cells.

The equivalent source impedance of a solar array is an important parameter in the design and analysis of solar array power conditioning equipment. Laboratory impedance tests have been performed on individual silicon solar cells and the test results have been correlated with P-N junction theory as developed by Shockley. The impedance has been broken into resistive and reactive components. The impedance has been expressed as a function of DC operating point and frequency. A practical application of the individual cell characteristics is presented in a solar array simulator design.

Zerbel, D. W.↗

NASA NTRS1975

Generalized wave envelope analysis of sound propagation in ducts with stepped noise source profiles and variable axial impedance

A finite difference formulation is presented for sound propagation in a rectangular two-dimensional duct without steady flow. Before the difference equations are formulated, the governing Helmholtz equation is first transformed to a form whose solution tends not to oscillate along the length of the duct. This transformation reduces the required number of grid points by an order of magnitude. Example solutions indicate that stepped noise source profiles have much higher attenuation than plane waves in a uniform impedance liner. Also, multiple stepped impedance liners are shown to have higher attenuation than uniform ducts if the impedances are chosen properly. For optimum noise reduction with axial variations in impedance, the numerical analysis indicates that for a plane wave input the resistance should be near zero at the entrance of a suppressor duct, while the reactance should be near the optimum value associated with the least-attenuated mode in a uniform duct.

Baumeister, K. J.↗

NASA NTRS1978

Duct wall impedance control as an advanced concept for acoustic suppression enhancement

A systems concept procedure is described for the optimization of acoustic duct liner design for both uniform and multisegment types. The concept was implemented by the use of a double reverberant chamber flow duct facility coupled with sophisticated computer control and acoustic analysis systems. The optimization procedure for liner insertion loss was based on the concept of variable liner impedance produced by bias air flow through a multilayer, resonant cavity liner. A multiple microphone technique for in situ wall impedance measurements was used and successfully adapted to produce automated measurements for all liner configurations tested. The complete validation of the systems concept was prevented by the inability to optimize the insertion loss using bias flow induced wall impedance changes. This inability appeared to be a direct function of the presence of a higher order energy carrying modes which were not influenced significantly by the wall impedance changes.

Dean, P. D.↗

NASA NTRS1978

The role of rotor impedance in the vibration analysis of rotorcraft

In an improved method which retains the advantage of separate treatment of rotor and airframe, the rotor impedance is used to correct the input to the airframe. This improved method is illustrated for a strongly idealized case of vertical excitation and then for rolling and pitching moment excitation of a four bladed hingeless rotor on an up-focussing flexible mount. Contrary to the usual approach that represents aeroelastic blade motions by a series of normal blade modes in vacuum, the aeroelastic rotor impedances are computed directly with a finite blade element method that includes aerodynamics. The rotor impedance matrix for three or more blades is determined from the root moment impedance for a single blade by a simple multiblade transformation rule. Force and moment amplitudes transferred from the rotor to the support are found to be critically dependent on the support dynamics.

Hohenemser, K. H.↗

NASA NTRS1987

Experimental validation of a two-dimensional shear-flow model for determining acoustic impedance

Tests were conducted to validate a two-dimensional shear-flow analytical model for determining the acoustic impedance of a liner test specimen in a grazing-incidence, grazing-flow environment. The tests were limited to a test specimen chosen to exhibit minimal effects of grazing flow so that the results obtained by using the shear-flow analytical model would be expected to match those obtained from normal-incidence impedance measurements. Impedances for both downstream and upstream sound propagation were generally consistent with those from normal-incidence measurements. However, sensitivity of the grazing-incidence impedance to small measurement or systematic errors in propagation constant varied dramatically over the range of test frequencies.

Parrott, Tony L.↗

NASA NTRS1987

The radiation impedance of an electrodynamic tether with end connectors

Electrodynamic tethers are wires deployed across the earth's geomagnetic field through which a current is flowing. The radiation impedance of a tether with end connectors carrying an ac current is computed from classical antenna theory. This simulates the use of a tether on a space structure. It is shown that the current flow pattern at the tether connector is critical to determining the overall radiation impedance. If the tether makes direct electrical contact with the ionosphere then radiation impedances of the order of several thousand Ohms can be expected. If the only electrical contact is through the end connectors then the impedance is only a few Ohms for a dc current rising to several tens of Ohms for an ac current with frequencies in the whistler range.

Hastings, Daniel E.↗

NASA NTRS1988

An electrochemical study of corrosion protection by primer-topcoat systems on 4130 steel with ac impedance and dc methods

To investigate metal surface corrosion and the breakdown of metal protective coatings, the ac impedance method is applied to six systems of primer coated and primer topcoated 4130 steel. Two primers were used: a zinc-rich epoxy primer and a red lead oxide epoxy primer. The epoxy-polyamine topcoat was used in four of the systems. The EG and G-PARC Model 368 ac impedance measurement system, along with dc measurements with the same system using the polarization resistance method, were used to monitor changing properties of coated 4230 steel disks immersed in 3.5 percent NaCl solutions buffered at pH 5.4 over periods of 40 to 60 days. The corrosion system can be represented by an electronic analog called an equivalent circuit consisting of resistors and capacitors in specific arrangements. This equivalent circuit parallels the impedance behavior of the corrosion system during a frequency scan. Values for the resistors and capacitors, that can be assigned in the equivalent circuit following a least-squares analysis of the data, describe changes that occur on the corroding metal surface and in the protective coatings. Two equivalent circuits have been determined that predict the correct Bode phase and magnitude of the experimental sample at different immersion times. The dc corrosion current density data are related to equivalent circuit element parameters. Methods for determining corrosion rate with ac impedance parameters are verified by the dc method.

Mendrek, M. J.↗

NASA NTRS1990

Calculation of rotor impedance for use in design analysis of helicopter airframe vibrations

Excessive vibration is one of the most prevalent technical obstacles encountered in the development of new rotorcraft. The inability to predict these vibrations is primarily due to deficiencies in analysis and simulation tools. The Langley Rotorcraft Structural Dynamics Program was instituted in 1984 to meet long term industry needs in the area of rotorcraft vibration prediction. As a part of the Langley program, this research endeavors to develop an efficient means of coupling the rotor to the airframe for preliminary design analysis of helicopter airframe vibrations. The main effort was to modify the existing computer program for modeling the dynamic and aerodynamic behavior of rotorcraft called DYSCO (DYnamic System COupler) to calculate the rotor impedance. DYSCO was recently developed for the U.S. Army and has proven to be adaptable for the inclusion of new solution methods. The solution procedure developed to use DYSCO for the calculation of rotor impedance is presented. Verification of the procedure by comparison with a known solution for a simple wind turbine model is about 75 percent completed, and initial results are encouraging. After the wind turbine impedance is confirmed, the verification effort will continue by comparison to solutions of a more sophisticated rotorcraft model. Future work includes determination of the sensitivity of the rotorcraft airframe vibrations to helicopter flight conditions and rotor modeling assumptions. When completed, this research will ascertain the feasibility and efficiency of the impedance matching method of rotor-airframe coupling for use in the analysis of airframe vibrations during the preliminary rotorcraft design process.

Nygren, Kip P.↗