Observations of "Hystereris" in Backscattered Ultraviolet Ozone Data
The backscattered ultraviolet (BUV) technique has been used for almost 3 decades to monitor global total ozone and the distribution of ozone in the stratosphere. Satellite BUV measurements in the 250-340 mn wavelength region are technically challenging because the Earth's radiance varies by approximately 4 orders of magnitude during a single scan. Further, the observed signal increases by over three orders of magnitude in about 2 minutes as the satellite emerges into daylight. The gain of the instrument's photomultiplier tube (PMT) detector is low when the spacecraft first emerges into the sunlit portion of the orbit relative to the gain observed after the PMT has experienced moderately high current levels. This "hysteresis" effect was first observed on the Nimbus-7 SBUV and TOMS instruments. The effect is difficult to characterize prelaunch because of the high signal levels and rapid variations required. We have recently observed and quantified the hysteresis effect for the NOAA-9 SBUV/2 instrument, which collected ozone data from February 1985 to February 1998. The instrument gain is observed to be up to 3% low at high solar zenith angles [Chi = 85-90 degrees] in the emergent hemisphere (i.e. Southern Hemisphere at launch). The gain error decreases as the SZA decreases and average PMT current increases, and is generally negligible for Chi < 65 degrees. The magnitude of the hysteresis effect varies with season, and exhibits long-term changes as the NOAA-9 sun-synchronous orbit drifts. In the latter portion of the record, when the spacecraft emerged from the dark in the Northern Hemisphere, hysteresis effects were then observed in the North. NOAA-9 total ozone errors due to the hysteresis effect are typically on the order of 2%, but can reach 5% in extreme cases. We have developed a quantitative correction for the hysteresis effect that incorporates both seasonal and long-term variations in magnitude. Results of similar analyses for the NOAA-11 and NOAA-14 SBUV/2 instruments will also be discussed. The characterization of the hysteresis effect in high solar zenith angle SBUV/2 ozone data represents a significant step towards reconciling polar ozone measurements from different satellite instruments.