Separator development for a heat sterilizable battery Quarterly summary progress report no. 2, 1 Sep. - 30 Nov. 1966
Polymer separator materials for heat sterilizable battery
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Polymer separator materials for heat sterilizable battery
Under a Phase II SBIR project funded by NASA Johnson Space Center (Contract No. 80NSSC25C0088), Analytical Scientific Products LLC (ASP) has been developing an actively controlled louver to protect spacecraft radiators from degradation due to exposure to various types of environmental conditions. Of particular interest are ionizing radiation during spacecraft transit through the Van Allen belts, dust during spacecraft landing and surface operations on the moon, and excessive heat loss during the long lunar night especially near the poles where the local ambient temperatures can drop below -200°C. Exposure to ionizing radiation and dust can degrade the optical properties of the radiator coating that in turn reduces its ability to reject excess heat from the spacecraft into the environment. Exposure to the extremely low temperature conditions during the lunar night near the poles can freeze the radiator fluids that can compromise the integrity of the radiator. Passive louvers constructed using thick aluminum vanes are used currently to protect spacecraft radiators from some of the above effects, but they have several drawbacks: (i) their high aerial density makes it impractical to scale them to protect the much larger spacecraft radiators needed for future manned missions to the moon and beyond, (ii) the bimetallic actuators used to open and close the vanes in passive louvers rely on external temperature alone and so the louver cannot offer protection from dust and ionizing radiation when the ambient temperatures are high, and (iii) the bimetallic actuators need time scales of the order of hours to open and close. We have addressed the above limitations of passive louvers through the development of a low aerial density and rapidly actuating actively controlled louver. It is constructed from a custom alloy that offers much higher levels of protection against the ionizing radiation, dust and excessive heat loss at a fraction of weight compared to passive louvers while providing opening and closing time scales of the order of a second. Our modular design makes it easy to scale the system up or down depending on the application. We have recently constructed a 31 inch × 31 inch module of this louver and tested its functionality and effectiveness. These tests have shown that the louver can be opened and closed in less than 2 s. It reduces the transmission of ionizing radiation by 78% to 100% (depending on the radiation source), dust transmission by more than 93%, and heat loss by more than 97%. We are currently preparing to evaluate this device at the Johnson Space Center’s cryogenic vacuum chamber where it can be subjected to simulated lunar surface conditions. This paper provides a detailed discussion of the test designs as well as the data from tests that demonstrate the effectiveness in reducing the transmission of ionizing radiation, dust, and heat under laboratory conditions.
Under a Phase II SBIR project funded by NASA Johnson Space Center (Contract No. 80NSSC25C0088), Analytical Scientific Products LLC (ASP) has been developing an actively controlled louver to protect spacecraft radiators from degradation due to exposure to various types of environmental conditions. Of particular interest are ionizing radiation during spacecraft transit through the Van Allen belts, dust during spacecraft landing and surface operations on the moon, and excessive heat loss during the long lunar night especially near the poles where the local ambient temperatures can drop below -200°C. Exposure to ionizing radiation and dust can degrade the optical properties of the radiator coating that in turn reduces its ability to reject excess heat from the spacecraft into the environment. Exposure to the extremely low temperature conditions during the lunar night near the poles can freeze the radiator fluids that can compromise the integrity of the radiator. Passive louvers constructed using thick aluminum vanes are used currently to protect spacecraft radiators from some of the above effects, but they have several drawbacks: (i) their high aerial density makes it impractical to scale them to protect the much larger spacecraft radiators needed for future manned missions to the moon and beyond, (ii) the bimetallic actuators used to open and close the vanes in passive louvers rely on external temperature alone and so the louver cannot offer protection from dust and ionizing radiation when the ambient temperatures are high, and (iii) the bimetallic actuators need time scales of the order of hours to open and close. We have addressed the above limitations of passive louvers through the development of a low aerial density and rapidly actuating actively controlled louver. It is constructed from a custom alloy that offers much higher levels of protection against the ionizing radiation, dust and excessive heat loss at a fraction of weight compared to passive louvers while providing opening and closing time scales of the order of a second. Our modular design makes it easy to scale the system up or down depending on the application. We have recently constructed a 31 inch × 31 inch module of this louver and tested its functionality and effectiveness. These tests have shown that the louver can be opened and closed in less than 2 s. It reduces the transmission of ionizing radiation by 78% to 100% (depending on the radiation source), dust transmission by more than 93%, and heat loss by more than 97%. We are currently preparing to evaluate this device at the Johnson Space Center’s cryogenic vacuum chamber where it can be subjected to simulated lunar surface conditions. This paper provides a detailed discussion of the test designs as well as the data from tests that demonstrate the effectiveness in reducing the transmission of ionizing radiation, dust, and heat under laboratory conditions.
Steam generation in the food sector requires substantial energy and cost expenditures, requiring nearly half of its energy intake. Here, we used life cycle assessment and life cycle cost assessment to investigate the cost and energy impacts of steam generating alternatives: NG, biomass and hydrogen boilers and grid-supplied and self-generated electric steam generation systems (electric boilers, renewable thermal energy storage and industrial heat pumps). The analysis starts with a set of average U.S. conditions, where biomass boilers are the most cost-competitive alternative to NG. In a series of scenarios beyond average conditions, the analysis shows energy procurement costs dominate the total life cycle cost for all technologies and, unfortunately, are highly variable geographically and temporally, significantly affecting the viability of the alternatives. Results show that site-energy consumption ranges from 0.3 MMBtu/klb for industrial heat pumps to 1.6 MMBtu/klb for biomass boilers, with heat pumps achieving up to 78% lower energy use compared to natural gas systems. For the steam costs, the results show a range between $\$$8 and $\$$50/klb for NG, with biomass following closely ($\$$11 – $\$$44/klb) and grey hydrogen and IHP next ($\$$13 – $\$$33/klb and $\$$6 - $\$$78/klb), with cost reductions if IHP's cooling is utilized. Factors like operating hours, the need for cooling, and the ability to negotiate utility rates complicate the decision, making site-specific analyses critical. Therefore, we present a decision-making matrix to help manufacturers identify which steam generating technology is the best business decision for their situation. Overall, these results highlight the importance of steam generation for the facility's organizational goals, as well as the criticality of conducting individual site analyses.
Inorganic fillers and pressure effects on films for separators for heat sterilizable silver zinc battery
In order to provide in-situ heat rejection to the thin Martian atmosphere, approaches relying on forced convection and buoyancy flow are conceptualized. A convective radiator concept utilizing a fan to draw local atmosphere through an expanded metal foam heat exchanger panel is developed. To provide a pumped fluid loop interface, flow tubes are embedded in the heat exchanger panel and heat is transferred from the tubes to the foam via conduction and subsequently convectively to the environment. To forgo the use of a specialized high throughput fan, a concept utilizing a buoyant chimney tower to draw atmospheric flow through a low pressure drop heat exchanger is also considered. Both concepts may best align with moderate- to high-temperature heat loads that provide a significant delta temperature relative to the ambient atmosphere temperature. While eliminating dust accumulation on radiator surfaces, some type of serviceable filtration or screening may be required to prevent accumulation of dust inside the expanded metal foam heat exchanger for both concepts.
Exposure to heat is a growing concern nationwide. Temperatures can be elevated in cities compared to surrounding rural areas, referred to as an “urban heat island” (UHI) effect, which is intensified during heat waves. The lack of dense networks of air temperature measurements results in few studies on urban heat. Now, a vast amount of high spatial and temporal satellite data on land surface temperature is available. We identified satellite datasets with the longest surface temperature records but different spatial and temporal resolutions: Landsat (1985-current, biweekly at 60 m and 100 m spatial resolution) and the Moderate Resolution Imaging Spectroradiometer (MODIS) data from the Terra and Aqua satellites (2000-current, daily at 1 km spatial resolution). We investigated how satellites with different spatial and temporal resolutions detect UHI effects differently. We hypothesized that 1) a dataset’s spatial resolution impacts the precision of detected UHIs spatially, since high spatial resolution Landsat data better captures spatial variability in temperature, and 2) daily surface temperature data can detect temporal patterns of UHIs and heatwave frequencies. We analyzed Landsat and MODIS satellite data in the Washington, D.C. and Baltimore region. We found that Landsat describes higher spatial variability of the UHI effect than MODIS data. However, MODIS data shows more consistent seasonal surface temperature patterns than Landsat when compared to in situ air temperature measurements. MODIS data was also able to consistently measure the frequency of heat waves. This study demonstrates the value of NASA satellite data for urban heat and climate change studies.
A turbine engine assembly includes a heat exchanger that is in thermal communication with an exhaust gas flow. A bypass passage is provided that is configured to selectively route at least a portion of the exhaust gas flow around the heat exchanger in response to a predefined engine operating condition.
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Filler and matrix composite materials for use in silver-zinc battery separators
The Department of Defense (DoD) faces the substantial challenge of cost-effectively retrofitting one to two installations per month, each comprising approximately 1,000 buildings, to improve resilience, reduce energy consumption, and enhance energy supply security. Achieving these objectives requires optimal system selection and effective risk mitigation during system integration. To address this need, we introduce Platform-Based Design (PBD), a structured, hierarchical methodology adapted from other industrial sectors to the domain of energy system retrofits. We demonstrate the effectiveness of PBD through a techno-economic feasibility study comparing geothermal-coupled thermal energy networks (TENs) with conventional energy systems for heating, cooling, and powering 17 buildings at Joint Base Andrews (JBA) in Maryland. Our analysis illustrates that the PBD approach enables rigorous, data-driven, sequential decision making, resulting in a family of Pareto-optimal systems, among which the TEN emerged as the most promising solution. The selected TEN design integrates geothermal borefields, heat recovery heat pumps, photovoltaic (PV) arrays, and battery storage. Compared to the baseline system – gas heating combined with air-source chillers – the proposed TEN reduces annual imported energy by 74% and peak electricity demand by 45%, achieves a levelized cost of energy of $\$0.210$/kWh, and substantially enhances resilience. Life-cycle costs increase by approximately 6%, and initial investment costs are about 2.5 times higher than the baseline. However, if central plant infrastructure, district loops, and utility-scale PV and battery systems are privately funded and operated, the initial investment would fall below the baseline system cost. Critical to achieving these significant performance improvements were detailed nonlinear dynamic simulations coupling geothermal heat transfer, energy system operation, and realistic feedback control logic. These simulations identified essential design modifications and control strategy refinements that substantially reduced energy use, peak demand, and compressor shortcycling, thereby improving durability and reliability—issues that would have been significantly more expensive to resolve during operation. Additionally, the verification step highlighted sensitivities to key design parameters that could reduce initial investment by approximately $\$2$ million and reduce annual life-cycle costs more than $\$300,000$. We recommend adopting the PBD methodology for future feasibility studies and TEN pilot projects to gain valuable operational experience. Furthermore, we recommend that DoD invest in transferring and scaling the PBD methodology to other installations. This entails developing standardized computational frameworks and component libraries as well as training industry in conducting PBD. Such investments would enable rapid, robust, reliable, and cost-effective retrofits, supporting DoD’s ambitious energy system modernization goals.
The StarBurst Multimessenger Pioneer is a small satellite mission serving as a wide-field gamma-ray observatory designed to capture the initial emissions of short gamma-ray bursts, electromagnetic signatures of neutron star mergers. This paper presents the final thermal design and analysis of the StarBurst Instrument, comprising the bus-to-instrument interface plate, control electronics, and twelve crystal detector units, which form the core of the mission’s science capability. The passive thermal control system design requires consideration of restrictive keep-out zones, unknown orbital parameters, and narrow temperature limits of the detectors. Also summarized is the instrument level thermal vacuum cycle test, correlated model refinements, and updated model results. Following successful completion of the instrument test campaign, the hardware was integrated with the spacecraft bus for spacecraft level testing, including additional thermal vacuum testing. The results from the spacecraft level thermal vacuum test will further inform the instrument thermal model, ensuring accurate flight temperature predictions. StarBurst launches as a secondary payload in 2027 and has a mission duration of at least one year.
Development and testing of vivyl polymer separator materials for sterilized silver-zinc secondary battery
Observations (from thermistor sensors and a hurricane glider) and model-based temperature were used to answer questions including the following: 1) What physical and environmental conditions explain the rapid intensification of Hurricane Laura? 2) How did the pre-existing warm mixed layer at Stone mooring (StM) influence the degree of cooling in the mixed layer? 3) How did vertical mixing, surface heat fluxes, and advective processes collectively shape the mixed layer heat evolution at StM? Observations measured by thermistor sensors showed that Hurricane Laura induced a cooling of -1.2oC in the mixed layer when Hurricane Laura’s wind speed increased to 47 m/s on 26 August. This contrasts with the -1.04oC mixed layer temperature change estimated from model-based temperature. At StM, the presence of a 31oC warm mixed layer and elevated heat content (60-80kJ/cm2) effectively preconditioned the upper ocean ahead of Hurricane Laura’s passage. After Hurricane Laura passed, turbulent mixing associated with the storm transported the heat anomalies downward into subsurface layers. In addition, this study shows that a surface heat flux of 5.04 kJ/cm2 supported the intensity of Hurricane Laura as it traversed over the StM. Using a mixed layer heat balance model, this study shows that entrainment flux and surface flux mostly contributed to the observed change in the mixed layer temperature.
In an effort to transform future space power system architectures and operations, the Advanced Modular Power Systems (AMPS) project is currently developing an interface standard for power electronic modules to enable modular architectures for space power systems. Each architecture would consist of one or more modular electronic units (MEU) that would comprise of a tailored combination of modules. The standard currently comprises modules enabling switchgear, power conversion, and data interfacing. The objective of the AMPS project is to enable the modularity and interchangeability of different architectures using these standardized modules in hopes of reducing complexity and cost, increasing inherent redundancy and reliability, and minimizing power system redesign for future programs. A key enabler to these future modular architectures will be the thermal management system, which has to contend with acquiring heat from the electronics modules at the card level and then transporting that heat to the radiator of the larger system. The focus of this paper, therefore, will be the thermal design and analysis of multiple AMPS power electronics modules and the development of their thermal-vacuum test.
Shape memory alloys (SMA) have been identified for use in spacecraft components as replacement for conventional deployment mechanisms. They may be used in thermal management components such as radiators to create self-deploying radiators. One SMA, NiTi, has also been developed for additive manufacturing processes. Heat pipes are a common way to create highly effective and lightweight spaceflight radiators, and heat pipes can also be made from NiTi and related alloys. The wick is the critical element of a functioning heat pipe, and recent progress over the past years has led to the development of additively manufactured heat pipe wicks in various materials. The combination of these efforts is the focus of this project: creating an additively manufactured, shape memory alloy self-deploying heat pipe radiator. This paper will focus on the experimental characterization of these additively manufactured NiTi heat pipes. The heat pipe coupons were additively manufactured by direct metal laser sintering (DMLS), with an integral liquid cooled condenser. Heat is input to the heat pipe via a thin film heater. Thermocouples were spot welded to the heat pipes to measure temperature at several axial locations. The heat pipes were tested with two working fluids: water and ethanol. Ethanol is not an ideal working fluid for heat pipes but is useful in characterizing them because it wets well to a wide variety of surfaces. Water is in general a superior working fluid for heat pipes, but its contact angle and therefore wicking performance strongly depends on the surface chemistry of the surface it is in contact with. A particular measurement of interest in this test is the evaporator to condenser thermal conductance, which will be compared in the full paper to recently published correlations for additively manufactured heat pipes. Experimental results for two straight geometry and one bellows geometry heat pipe will be presented. The bellows geometry is of interest for condenser of the self-deploying radiator design.
This work focused on improving the understanding and modeling of conjugate heat transfer in the Stable Salt Reactor (SSR), particularly the transfer of heat from molten fuel salt inside narrow fuel pins, through the metal cladding and into the surrounding coolant salt.