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All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Chemical and petrographic constraints on the origin of chondrules and inclusions in carbonaceous chondrites

Bulk chemical compositions of the various petrographic types of chondrules and inclusions in Type 3 carbonaceous chondrites (excluding those affected by metamorphism) have been determined by microprobe defocused-beam analysis. Inclusion compositions follow approximately the theoretical compositional trajectory for equlibrium condensation. Chondrules occurring in the same meteorites have higher silica contents and show only slight overlap with inclusion compositions. Dust fusion is apparently an inadequate mechanism for producing the wide chemical variations observed among chondrules. Impact-melting models require sampling of complex target rocks which are unknown as components of meteorites; this mechanism also demands efficient mechanical processing of chondrules before accretion. A genetic relationship between chondrules and inclusions in carbonaceous chondrites is suggested by the compositional continuum between these objects. A condensation sequence which dips into the liquid stability field at lower temperatures is advocated for the production of both inclusions and chondrules. Textural relationships between intergrown chondrules and inclusions support such a sequence. This model suggests that the assembled components (inclusions and chondrules) of carbonaceous chondrites are related by a common process.

Mcsween, H. Y., Jr.↗
NASA NTRS1978

Pyroxene stability and the composition of the lunar magma ocean

Data on the liquidus stability fields of pyroxene phases in lunar-like systems are used to predict the crystallization sequence and residual liquid composition of lunar magma oceans. Fractional and equilibrium crystallization of major and trace elements are modeled quantitatively through use of analytical expressions for liquidus phase boundaries. According to the model, a magma ocean that differentiated chiefly at low pressure and contained 6-8 wt% A1203 and a subchondritic Ca/Al ratio probably formed the lunar crust. The chondrite-normalized pattern of heavy REE depletion in the magma ocean could have developed by self-contamination of extensively fractionated liquids, or could have been imparted during accretion.

Longhi, J.↗
NASA NTRS1979

The upper mantle transition region - Eclogite

The upper mantle transition region is usually considered to be peridotite which undergoes a series of phase changes involving spinel and post-spinel assemblages. There are difficulties associated with attempts to explain the 220, 400 and 670 km discontinuities in terms of phase changes in a peridotitic mantle. Moreover, in a differentiated earth there should be large quantities of eclogite in the upper mantle. Eclogite is denser than Al2O3-poor mantle to depths of 670 km, but it stays in the garnet stability field to pressures in excess of those required to transform depleted mantle to denser phases such as ilmenite and perovskite. Eclogite, therefore, remains above 670 km. The seismic properties of the transition region are more consistent with eclogite than peridotite. Most of the mantle's inventory of incompatible trace elements may be in this layer, which is a potential source region for some basalt magmas. The radioactivity in this layer is the main source of mantle heat flow, 0.7 microcalorie/sq cm-sec, and drives upper mantle convection.

Anderson, D. L.↗
NASA NTRS1980

Tectonics and composition of Venus

The uncompressed density of Venus is a few percent less than the Earth. The high upper mantle temperature of Venus deepens the eclogite stability field and inserts a partial melt field. A thick basaltic crust is therefore likely. The anomalous density of Venus relative to the progression from Mercury to Mars may therefore have a tectonic rather than a cosmo-chemical explanation. There may be no need to invoke differences in composition or oxidization state.

Anderson, D. L.↗
NASA NTRS1983

Experimental deformation of polycrystalline H2O ice at high pressure and low temperature - Preliminary results

A preliminary study is carried out of involving 70 constant strain deformation tests on pure polycrystalline H2O ice under conditions covering most of the stability field of ice I sub h. Brittle failure of I sub h is found to be promoted by lower P, lower T, and higher strain rates. Ductile flow is found to be promoted by higher P, higher T, and lower strain rates. The brittle failure of ice I sub h is found to be most unusual. The fracture strength is a positive function of P only below 50 MPa. At pressures greater than this, the fracture strength is independent of P, and the fracture plane lies approximately 45 deg from the load axis. It is believed that existing extrapolation based on existing experimental data to Ganymede and Callisto may be badly in error.

Durham, W. B.↗
NASA NTRS1985

Models for the Archean thermal regime

Different regonalized thermal evolution models are presented. The models are used to determine the concentration of heat-producing elements such as U, Th, and K, which are required to have a present-day mantle potential temperature of 1350 C starting from a high temperature of 2000 C, 4.5 billion years ago and to calculate the thermal structure of the continental lithosphere through time. The parameterized equations for the various convective regimes considered, are discussed. It is shown that only the models with layered mantle convection and a continental lithosphere of fixed thickness (greater than or equal to 175 km) are able to satisfy the constraints of some part of the lithosphere being in the diamond stability field during the Archean and an interior temperature greater than 1600 C during the Archean to account for the high-magnesian komatiites of that period.

Richter, F. M.↗
NASA NTRS1986

Chondrules in the Murray CM2 meteorite and compositional differences between CM-CO and ordinary chondrite chondrules

Thirteen of the least aqueously altered chondrules in Murray (CM2) were analyzed for bulk compositions, by means of a broad beam electron microprobe, to explore the compositional differences between the CM-CO, and the ordinary chondrite OC chondrules. The CO chondrules are richer in refractory lithophiles and poorer in Cr, Mn, and volatile lithophiles than the OC chondrules; much lower refractory lithophile abundances in CM chondrules resulted from aqueous alteration. Evidence is found for two important lithophile precursor components of CM-CO chondrite chondrules: (1) pyroxene- and refractory-rich, FeO-poor, and (2) olivine-rich, refractoryand FeO-poor. It is suggested that the pyroxene- and refractory-rich, FeO-poor lithophile precursor component has formed by an incomplete evaporation of presolar silicates that brought these materials into the enstatite stability field.

Rubin, A. E.↗
NASA NTRS1987

Thermally induced phase changes, lateral heterogeneity of the mantle, continental roots, and deep slab anomalies

Factors which influence the lateral heterogeneity in density and seismic velocity with depth in the upper earth mantle are discussed. It is emphasized that most of the increases in density and seismic velocity with depth are caused by pressure-induced solid-solid phase changes in the high-density high-velocity phases of mineral assemblage, due to variations in temperature. In particular, the ilmenite form of MgSiO3 and the gamma-spinel form of Mg2SiO4 have broad stability fields in cold mantle and are not stable in hotter mantle. It is emphasized that the density and velocity anomalies associated with temperature-induced phase changes in mineral assemblage must be taken into account in the thermal models of the slabs; when these effects are accounted for, the geoid and seismic anomalies associated with subducted slabs are consistent with slab confinement to the upper mantle and with layered models of mantle convection.

Anderson, Don L.↗
NASA NTRS1988

An assessment of ground effects determined by static and dynamic testing techniques

A new testing technique was developed wherein the rate of descent can be included as a parameter in ground effects investigations. This technique simulates the rate of descent by horizontal motion of a model over an inclined ground board in the Langley Vortex Research Facility (VRF) During initial evaluations of the technique, dynamic ground effects data were obtained over the inclined ground board, steady state ground effects data were obtained over a flat portion of the ground board, and the results were compared to conventional static wind tunnel ground effect data both with and without a moving belt ground plane simulation. Initial testing and analysis led to the following conclusions: the moving belt ground plane had little effect on static ground effects for the configurations tested unless thrust reversers were employed; in general, rate-of-descent reduced ground effects to the point that for reversed thrust cases an expected loss of lift due to ground effects was eliminated at approach conditions; and, in general, the steady state results from the VRF matched static results obtained from the wind tunnel once the flow field stabilized over the flat portion of the ground board.

Paulson, John W., Jr.↗
NASA NTRS1989

Phase diagram for ammonia-water mixtures at high pressures - Implications for icy satellites

The (NH3)x(H2O)1-x phase diagram for X from 0 to 0.50 has been reexamined at temperatures from 125 K to 400 K and at pressures from 6.0 GPa using diamond anvil cells, and the implications of the findings for icy satellites are addressed. Titan is likely to have a thicker NH3-H2O ocean than previously suspected, because the stability field of NH3-H2O is found to be smaller than previously supposed. The implications for methane and ammonia volcanism on Titan are briefly discussed. The experimentally observed reactivity between the liquid and iron may also have implications for planetary and satellite evolution.

Cynn, H. C.↗
NASA NTRS1993

Thorium-uranium fractionation by garnet - Evidence for a deep source and rapid rise of oceanic basalts

Mid-ocean ridge basalts (MORBs) and ocean island basalts (OIBs) are derived by partial melting of the upper mantle and are marked by systematic excesses of thorium-230 activity relative to the activity of its parent, uranium-238. Experimental measurements of the distribution of thorium and uranium between the melt and solid residue show that, of the major phases in the upper mantle, only garnet will retain uranium over thorium. This sense of fractionation, which is opposite to that caused by clinopyroxene-melt partitioning, is consistent with the thorium-230 excesses observed in young oceanic basalts. Thus, both MORBs and OIBs must begin partial melting in the garnet stability field or below about 70 kilometers. A calculation shows that the thorium-230-uranium-238 disequilibrium in MORBs can be attributed to dynamic partial melting beginning at 80 kilometers with a melt porosity of 0.2 percent or more. This result requires that melting beneath ridges occurs in a wide region and that the magma rises to the surface at a velocity of at least 0.9 meter per year.

Latourrette, T. Z.↗
NASA NTRS1993

Chondrite thermal histories from Low-CA pyroxene microstructures: Autometamorphism versus prograde metamorphism revisited

In order to constrain the thermal histories of chondritic meteorites, a detailed study of the microstructures of low-Ca pyroxenes produced experimentally and in types 4 and 5 ordinary chondrites was carried out. Cooling experiments on synthetic MgSiO3 at cooling rates between 2 and 10000 C/hr from the protopyroxene stability field into that of orthopyroxene (OPX) were performed and the products of these experiments were annealed for a variety of annealing times. There are clear microstructural differences between samples which were cooled and those which were subsequently annealed. A comparison of the microstructures observed in the experimental samples with those in H4-5 ordinary chondrites shows that they cannot have experienced a single stage cooling history, as proposed for the autometamorphism model.

Brearley, Adrian J.↗
NASA NTRS1993

Molecular equilibria and condensation sequences in carbon rich gases

Chemical equilibria in stellar atmospheres have been investigated by many authors. Lattimer, Schramm, and Grossman presented calculations in both O rich and C rich environments and predicted possible presolar condensates. A recent paper by Cherchneff and Barker considered a C rich composition with PAH's included in the calculations. However, the condensation sequences of C bearing species have not been investigated in detail. In a carbon rich gas surrounding an AGB star, it is often assumed that graphite (or diamond) condenses out before TiC and SiC. However, Lattimer et al. found some conditions under which TiC condenses before graphite. We have performed molecular equilibrium calculations to establish the stability fields of C(s), TiC(s), and SiC(s) and other high temperature phases under conditions of different pressures and C/O. The preserved presolar interstellar dust grains so far discovered in meteorites are graphite, diamond, SiC, TiC, and possibly Al2O3.

Sharp, C. M.↗
NASA NTRS1994

Characteristics of finite amplitude stationary gravity waves in the atmosphere of Venus

This paper extends the study of stationary gravity waves generated near the surface of Venus reported previously by Young et al. to include finite amplitude effects associated with large amplitude waves. Waves are forced near the surface of Venus by periodic forcing. The height-dependent profiles of static stability and mean wind in the Venus atmosphere play a very important role in the evolution of the nonlinear behavior of the waves, just as they do in the linear wave solutions. Certain wave properties are qualitatively consistent with linear wave theory, such as wave trapping, resonance, and wave evanescence for short horizontal wavelenghts. However, the finite amplitude solutions also exhibit many other interesting features. In particular, for forcing amplitudes representative of those that could be expected in mountainous regions such as Aphrodite Terra, waves generated near the surface can reach large amplitudes at and above cloud levels, with clear signatures in the circulation pattern. At still higher levels, the waves can reach large enough amplitude to break, unless damping rates above the clouds are sufficient to limit wave amplitude growth. Well below cloud levels the waves develop complex flow patterns as the result of finite amplitude wave-wave interactions, and waves are generated having considerably shorter horizontal wavelenghts than that associated with the forcing near the surface. Nonlinear interactions can excite waves that are resonant with the background wind and static stability fields even when the primary surface forcing does not, and these waves can dominate the wave spectrum near cloud levels. A global map of Venus topographic slopes derived from Magellan altimetry data shows that slopes of magnitude comparable to or exceeding that used to force the model are ubiquitous over the surface.

Young, Richard E.↗
NASA NTRS1994

Phase E in a water-saturated peridotite system at 9.3 GPa

The stability of hydrous phases in a natural upper mantle system has been investigated at 9.3 GPa using a gel of KLB-1 peridotite composition with brucite which contains 14 wt. percent (30 atom. percent) water. No hydrous mineral was found at 950 (+150 -50) degree C. At 800 degree C, an assemblage of phase A, phase E, enstatite, clinohumite, and garnet is obtained. Although there is a significant thermal gradient over the sample, phase E is found to be surrounded by phase A in the lower temperature part. Electron probe analyses show that phase E has 35.5 SiO2, 4.4 Al2O3, 41.1 MgO and 8.5 wt. percent FeO* (Mg value is 90) with an oxide sum of 89.7 wt. percent, and possesses a stoichiometry similar to that proposed by Kanzaki. CaO and TiO2 are both less than 0.1 wt. percent. Coexisting phase A has 0.5 wt. percent CaO but only 0.4 wt. percent Al2O3 concentration. Phase A coexists with only enstatite in the water-saturated MgO-FeO-SiO2 system at 800 degree C and 9.3 GPa as well as the results in the water-saturated MgO-SiO2 system. Therefore it is suggested that the addition of Al2O3 expands the stability field of phase E to lower than 13 - 17 GPa in the water-saturated MgO-SiO2 system.

Kawamoto, Tatsuhiko↗
NASA NTRS1994

The oxidation state of the surface of Venus

We present experimental results showing that basalt is oxidized in CO-CO2 gas mixtures having CO number densities close to those (approximately 2 times higher) at the surface of Venus. The results suggest that the red color observed by Pieters et al at the Venera 9 and 10 landing sites is due to subaerial oxidation of Fe(2+)-bearing basalt on the surface of Venus, and that hematite, instead of magnetite, is present on the surface of Venus. Well-characterized basalt powder was iosthermally heated in 1000 ppm CO-CO2 gas mixtures at atmospheric pressure for several days. The starting material and reacted samples were analyzed by Mossbauer spectroscopy to determine the amount of Fe(2+) and Fe(3+) in the samples. X-ray diffraction and optical microscopy were also used to characterize samples. The basalt oxidation occurs because the CO and CO2 do not equilibrate in the gas mixture at the low temperatures used. Thus, the basalt reacts with the more abundant CO2 and is oxidized. We propose that the red color of the surface of Venus is due to failure of CO and CO2 to equilibrate with one another in the near-surface atmosphere of Venus, leading to subaerial oxidation of erupted Fe(2+)-bearing basalts. Our interpretation is supported by our studies of magnetite oxidation, which show that synthetic magnetite powders are oxidized to hematite in CO-CO2 gas mixtures inside the magnetite stability field, by our studies of pyrite decomposition, and by independent work on CO-CO2 equilibration in furnace gases.

Fegley, B., Jr.↗
NASA NTRS1995

Chemical and physical studies of type 3 chondrites 12: The metamorphic history of CV chondrites and their components

The induced thermoluminescence (TL) properties of 16 CV and CV-related chondrites, four CK chondrites and Renazzo (CR2) have been measured in order to investigate their metamorphic history. The petrographic, mineralogical and bulk compositional differences among the CV chondrites indicate that the TL sensitivity of the approximately 130 C TL peak is reflecting the abundance of ordered feldspar, especially in chondrule mesostasis, which in turn reflects parent-body metamorphism. The TL properties of 18 samples of homogenized Allende powder heated at a variety of times and temperatures, and cathodoluminescence mosaics of Axtell and Coolidge, showed results consistent with this conclusion. Five refractory inclusions from Allende, and separates from those inclusions, were also examined and yielded trends reflecting variations in mineralogy indicative of high peak temperatures (either metamorphic or igneous) and fairly rapid cooling. The CK chondrites are unique among metamorphosed chondrites in showing no detectable induced TL, which is consistent with literature data that suggests very unusual feldspar in these meteorites. Using TL sensitivity and several mineral systems and allowing for the differences in the oxidized and reduced subgroups, the CV and CV-related meteorites can be divided into petrologic types analogous to those of the ordinary and CO type 3 chondrites. Axtell, Kaba, Leoville, Bali, Arch and ALHA81003 are type 3.0-3.1, while ALH84018, Efremovka, Grosnaja, Allende and Vigarano are type 3.2-3.3 and Coolidge and Loongana 001 are type 3.8. Mokoia is probably a breccia with regions ranging in petrologic type from 3.0 to 3.2. Renazzo often plots at the end of the reduced and oxidized CV chondrite trends, even when those trends diverge, suggesting that in many respects it resembles the unmetamorphosed precursors of the CV chondrites. The low-petrographic types and low-TL peak temperatures of all samples, including the CV3.8 chondrites, indicates metamorphism in the stability field of low feldspar (i.e., less than 800 C) and a metamorphic history similar to that of the CO chondrites but unlike that of the ordinary chondrites.

Guimon, R. Kyle↗
NASA NTRS1999

Wave Dynamics and Transport in the Stratosphere

The report discusses: (1) Gravity waves generated by tropical convection: A study in which a two-dimensional cloud-resolving model was used to examine the possible role of gravity waves generated by a simulated tropical squall line in forcing the quasi-biennial oscillation was completed. (2) Gravity wave ray tracing studies:It was developed a linear ray tracing model of gravity wave propagation to extend the nonlinear storm model results into the mesosphere and thermosphere. (3) tracer filamentation: Vertical soundings of stratospheric ozone often exhibit laminated tracer structures characterized by strong vertical tracer gradients. (4) Mesospheric gravity wave modeling studies: Although our emphasis in numerical simulation of gravity waves generated by convection has shifted from simulation of idealized two-dimensional squall lines to the most realistic (and complex) study of wave generation by three-dimensional storms. (5) Gravity wave climatology studies: Mr. Alexander applied a linear gravity wave propagation model together with observations of the background wind and stability fields to compute climatologies of gravity wave activity for comparison to observations. (6) Convective forcing of gravity waves: Theoretical study of gravity wave forcing by convective heat sources has completed. (7) Gravity waves observation from UARS: The objective of this work is to apply ray tracing, and other model technique, in order to determine to what extend the horizontal and vertical variation in satellite observed distribution of small-scale temperature variance can be attributed to gravity waves from particular sources. (8) The annual and interannual variations in temperature and mass flux near the tropical tropopause. and (9) Three dimensional cloud model.

Holton, James R.↗